GB1040962A – Catalytic halogenation of hydrocarbons
– Google Patents
GB1040962A – Catalytic halogenation of hydrocarbons
– Google Patents
Catalytic halogenation of hydrocarbons
Info
Publication number
GB1040962A
GB1040962A
GB21868/63A
GB2186863A
GB1040962A
GB 1040962 A
GB1040962 A
GB 1040962A
GB 21868/63 A
GB21868/63 A
GB 21868/63A
GB 2186863 A
GB2186863 A
GB 2186863A
GB 1040962 A
GB1040962 A
GB 1040962A
Authority
GB
United Kingdom
Prior art keywords
halide
per cent
dissimilar
mol per
aqueous
Prior art date
1962-06-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21868/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pullman Inc
Original Assignee
Pullman Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1962-06-01
Filing date
1963-05-31
Publication date
1966-09-01
1963-05-31
Application filed by Pullman Inc
filed
Critical
Pullman Inc
1966-09-01
Publication of GB1040962A
publication
Critical
patent/GB1040962A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
B01J27/06—Halogens; Compounds thereof
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C17/00—Preparation of halogenated hydrocarbons
C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C17/00—Preparation of halogenated hydrocarbons
C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
C07C17/12—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the ring of aromatic compounds
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C17/00—Preparation of halogenated hydrocarbons
C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C17/00—Preparation of halogenated hydrocarbons
C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C17/00—Preparation of halogenated hydrocarbons
C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
C07C17/158—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of halogenated hydrocarbons
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C21/00—Acyclic unsaturated compounds containing halogen atoms
C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
C07C21/04—Chloro-alkenes
C07C21/073—Dichloro-alkenes
C07C21/08—Vinylidene chloride
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
B01J2219/00002—Chemical plants
B01J2219/00004—Scale aspects
B01J2219/00006—Large-scale industrial plants
Abstract
In a process for polyhalogenating an unsubstituted or halogen-substituted hydrocarbon containing at least one hydrogen atom of the olefinic or aromatically unsaturated type, the hydrocarbon is reacted with an aqueous composition comprising an aqueous Cu++ or Fe++ halide and as a promoter at least one halide of a dissimilar element, or a dissimilar valence state of the same metal, the metal being selected from Cn, Ag, An, Zn, Cd, Hg, B, Al, Ga, In, Tl, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Sn, Bi, Co or Ni, the concentration of the total metal halides being between 0.001 mol per cent and 50 mol per cent. Halogenation is stated to include chlorination, bromination and iodination. The preferred hydrocarbon or derivative thereof used as starting materials are those olefins containing 2-5 C and benzene. Specified are ethylene, propylene, butene, butadiene, isoprene, toluene, xylene, styrene, vinyl chloride and monochlorobutadiene and mono- and di-chloroethylenes. Reaction temperature is usually 125-165 DEG C. and pressure 60-300 p.s.i.g.ALSO:A catalyst composition comprises an aqueous solution of cupric or ferric halide and as a promoter at least one halide of a dissimilar element or a dissimilar valence of the same element, the element being Cu, Ag, Au, Zn, Cd, Hg, B, Al, Ga, In, Tl, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, Mn, W, Sn, Bi, and Ni, the concentration of the total metal halides in aqueous solution being between 0.001 mol per cent and 50 mol per cent. Specified promoters are FeCl3, CrCl3, HgCl, AlCl3, TiCl3, VCl3 and MnCl2. The catalyst may contain some halide in suspension as well as solution, and sulphates e.g. CuSO4 or Fe2(SO4)3 may be added to control the vapour pressure.
GB21868/63A
1962-06-01
1963-05-31
Catalytic halogenation of hydrocarbons
Expired
GB1040962A
(en)
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
US199329A
US3214481A
(en)
1962-06-01
1962-06-01
Process for the halogenation of hydrocarbons
US199331A
US3214482A
(en)
1962-06-01
1962-06-01
Process for the halogenation of hydrocarbons
Publications (1)
Publication Number
Publication Date
GB1040962A
true
GB1040962A
(en)
1966-09-01
Family
ID=26894654
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB21868/63A
Expired
GB1040962A
(en)
1962-06-01
1963-05-31
Catalytic halogenation of hydrocarbons
Country Status (5)
Country
Link
US
(2)
US3214482A
(en)
BR
(1)
BR6349416D0
(en)
DE
(1)
DE1468141B1
(en)
GB
(1)
GB1040962A
(en)
NL
(2)
NL293443A
(en)
Cited By (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
FR2409793A1
(en)
*
1977-11-25
1979-06-22
Ppg Industries Inc
METAL HALOGENIDE CATALYST AND ITS APPLICATION TO THE PRODUCTION OF ETHYLENE DICHLORIDE
US6680415B1
(en)
1999-11-22
2004-01-20
Dow Global Technologies Inc.
Oxyhalogenation process using catalyst having porous rare earth halide support
US6797845B1
(en)
1999-11-22
2004-09-28
Dow Global Technologies Inc.
Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent
Families Citing this family (36)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3461180A
(en)
*
1964-01-09
1969-08-12
Pullman Inc
Halogenation of ethylene by contact with aqueous cupric-cuprous chloride solution
US3379780A
(en)
*
1964-04-02
1968-04-23
Nat Distillers Chem Corp
Fluorination process
US3341612A
(en)
*
1964-05-20
1967-09-12
Atlantic Richfield Co
Method for synthesizing vicinal dichlorides
US3366698A
(en)
*
1965-08-19
1968-01-30
Tenneco Chem
Process for the production of 2, 4-dichlorotoluene
DE1254143B
(en)
*
1966-03-08
1967-11-16
Knapsack Ag
Process for the processing of crude vinyl chloride
US3510532A
(en)
*
1966-07-15
1970-05-05
Pullman Inc
Halogenation of an acyclic olefin
US3639270A
(en)
*
1967-05-23
1972-02-01
Shinetsu Chemical Co
Catalyst composition for oxychlorinating hydrocarbons and process for preparing the catalyst composition
GB1179373A
(en)
*
1968-05-31
1970-01-28
Nat Distillers Chem Corp
Process for Aromatic Substitution
US3920764A
(en)
*
1968-10-23
1975-11-18
Lummus Co
Dehydrogenation process
US3670037A
(en)
*
1969-02-19
1972-06-13
Exxon Research Engineering Co
Catalyst system
US3879482A
(en)
*
1969-06-09
1975-04-22
Lummus Co
Vinyl chloride process
US3864410A
(en)
*
1970-03-25
1975-02-04
Gulf Research Development Co
Process for halogenating paraffins
US3725487A
(en)
*
1970-04-13
1973-04-03
Celanese Corp
Preparation of dihaloalkanes and related products
US3717685A
(en)
*
1970-09-28
1973-02-20
Gulf Research Development Co
Process for preparing chlorinated aromatics
US3714277A
(en)
*
1970-09-28
1973-01-30
Gulf Research Development Co
Process for preparing chlorinated aromatics
US4017551A
(en)
*
1975-01-27
1977-04-12
Ppg Industries, Inc.
Liquid phase chlorination of aromatic hydrocarbons using manganese chloride catalyst
US4051168A
(en)
*
1976-05-12
1977-09-27
E. I. Du Pont De Nemours And Company
Fluorination process
US4064115A
(en)
*
1976-08-02
1977-12-20
Phillips Petroleum Company
Bromination of poly(arylene sulfides)
US4039598A
(en)
*
1976-08-23
1977-08-02
Monsanto Company
Production of tetrabromobutadiene by catalytic oxybromination of butane
US4157380A
(en)
*
1976-11-26
1979-06-05
Prahl Walter H
Recovery of hydrogen chloride and chlorine from chlorine-containing organic wastes
US4766103A
(en)
*
1986-07-07
1988-08-23
Phillips Petroleum Company
Preparation of 1,4-dichlorobenzene
US4727201A
(en)
*
1986-07-07
1988-02-23
Phillips Petroleum Company
Preparation of 1,4-dichlorobenzene
US4792642A
(en)
*
1987-03-25
1988-12-20
Eastman Kodak Company
Process for preparing iodinated aromatic compounds
US4806698A
(en)
*
1987-03-25
1989-02-21
Eastman Kodak Company
Liquid phase isomerization of iodoaromatic compounds
US4778939A
(en)
*
1987-03-25
1988-10-18
Eastman Kodak Company
Low temperature oxyiodination of aromatic compounds
DE4318609A1
(en)
1993-01-27
1994-07-28
Hoechst Ag
Process and device for producing 1,2-dichloroethane by direct chlorination
HU219208B
(en)
*
1993-01-27
2001-03-28
Hoechst Ag
Process and device for preparing 1,2-dichlorethane by direct chlorination
SA112330516B1
(en)
2011-05-19
2016-02-22
كاليرا كوربوريشن
Electrochemical hydroxide systems and methods using metal oxidation
US9200375B2
(en)
2011-05-19
2015-12-01
Calera Corporation
Systems and methods for preparation and separation of products
TWI633206B
(en)
2013-07-31
2018-08-21
卡利拉股份有限公司
Electrochemical hydroxide systems and methods using metal oxidation
AU2015317970B2
(en)
2014-09-15
2020-01-30
Calera Corporation
Electrochemical systems and methods using metal halide to form products
CN104437552B
(en)
*
2014-11-21
2017-07-21
江苏长三角精细化工有限公司
A kind of chlorination toluene catalyst using activated carbon as carrier
CN108290807B
(en)
2015-10-28
2021-07-16
卡勒拉公司
Electrochemical, halogenation and oxyhalogenation system and method
US10619254B2
(en)
2016-10-28
2020-04-14
Calera Corporation
Electrochemical, chlorination, and oxychlorination systems and methods to form propylene oxide or ethylene oxide
US10556848B2
(en)
2017-09-19
2020-02-11
Calera Corporation
Systems and methods using lanthanide halide
US10590054B2
(en)
2018-05-30
2020-03-17
Calera Corporation
Methods and systems to form propylene chlorohydrin from dichloropropane using Lewis acid
Family Cites Families (19)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
CA517009A
(en)
*
1955-09-27
W. Hearne George
Manufacture of olefin dichlorides
CA451379A
(en)
*
1948-09-21
De Simo Martin
Process for halogenation of unsaturated organic compounds
US1963761A
(en)
*
1930-04-12
1934-06-19
Raschig G M B H F
Process of making chlorobenzene
US2310283A
(en)
*
1938-12-22
1943-02-09
Standard Oil Dev Co
Preparation of alkyl esters
US2287244A
(en)
*
1940-12-19
1942-06-23
Firm Danciger Oil & Refineries
Catalytic composition
US2399488A
(en)
*
1941-05-29
1946-04-30
Shell Dev
Halogenation of unsaturated organic compounds
CH254536A
(en)
*
1944-12-19
1948-05-15
Shell Dev
Process for the production of unsaturated halogenated hydrocarbons.
US2644846A
(en)
*
1948-12-11
1953-07-07
Shell Dev
Hydrogen chloride oxidation
NL93818C
(en)
*
1952-06-07
US2822410A
(en)
*
1952-06-11
1958-02-04
Olin Mathieson
Process for utilizing mixtures of ethylene and acetylene without separation thereof
US2809221A
(en)
*
1952-06-11
1957-10-08
Olin Mathieson
Selective chlorination
US2779805A
(en)
*
1952-06-11
1957-01-29
Olin Mathieson
Separation of acetylene from ethylene by hydrochlorination of the ethylene
US2755315A
(en)
*
1952-09-10
1956-07-17
Firestone Tire & Rubber Co
Cracking ethylene dichloride
US2915565A
(en)
*
1953-09-25
1959-12-01
Knapsack Ag
Process of preparing vinylidene halide
US2875255A
(en)
*
1956-11-21
1959-02-24
Firestone Tire & Rubber Co
Catalytic dehydrochlorination of 1, 2-dichloroethane
US3079444A
(en)
*
1957-12-27
1963-02-26
Knapsack Ag
Method of preparing halogen-substituted aliphatic hydrocarbons
NL103439C
(en)
*
1960-05-30
US3055955A
(en)
*
1960-10-12
1962-09-25
Union Carbide Corp
Process for the production of vinyl chloride
FR1309610A
(en)
*
1961-12-29
1962-11-16
Distillers Co Yeast Ltd
Process for the production of halogen-substituted olefins
0
NL
NL132331D
patent/NL132331C/xx
active
NL
NL293443D
patent/NL293443A/xx
unknown
1962
1962-06-01
US
US199331A
patent/US3214482A/en
not_active
Expired – Lifetime
1962-06-01
US
US199329A
patent/US3214481A/en
not_active
Expired – Lifetime
1963
1963-05-28
BR
BR149416/63A
patent/BR6349416D0/en
unknown
1963-05-31
DE
DE19631468141
patent/DE1468141B1/en
active
Pending
1963-05-31
GB
GB21868/63A
patent/GB1040962A/en
not_active
Expired
Cited By (4)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
FR2409793A1
(en)
*
1977-11-25
1979-06-22
Ppg Industries Inc
METAL HALOGENIDE CATALYST AND ITS APPLICATION TO THE PRODUCTION OF ETHYLENE DICHLORIDE
US6680415B1
(en)
1999-11-22
2004-01-20
Dow Global Technologies Inc.
Oxyhalogenation process using catalyst having porous rare earth halide support
US6797845B1
(en)
1999-11-22
2004-09-28
Dow Global Technologies Inc.
Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent
US6821924B2
(en)
1999-11-22
2004-11-23
Dow Global Technologies Inc.
Oxyhalogenation process using catalyst having porous rare earth halide support
Also Published As
Publication number
Publication date
US3214481A
(en)
1965-10-26
NL293443A
(en)
DE1468141B1
(en)
1970-12-03
NL132331C
(en)
1971-04-15
BR6349416D0
(en)
1973-06-12
US3214482A
(en)
1965-10-26
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None