GB1113722A – Aerobically polymerisable compositions
– Google Patents
GB1113722A – Aerobically polymerisable compositions
– Google Patents
Aerobically polymerisable compositions
Info
Publication number
GB1113722A
GB1113722A
GB20054/65A
GB2005465A
GB1113722A
GB 1113722 A
GB1113722 A
GB 1113722A
GB 20054/65 A
GB20054/65 A
GB 20054/65A
GB 2005465 A
GB2005465 A
GB 2005465A
GB 1113722 A
GB1113722 A
GB 1113722A
Authority
GB
United Kingdom
Prior art keywords
compositions
meth
acrylate
monomer
composition
Prior art date
1964-05-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20054/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-05-21
Filing date
1965-05-12
Publication date
1968-05-15
1965-05-12
Application filed by Minnesota Mining and Manufacturing Co
filed
Critical
Minnesota Mining and Manufacturing Co
1968-05-15
Publication of GB1113722A
publication
Critical
patent/GB1113722A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 – C09J183/16
A—HUMAN NECESSITIES
A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
A61K6/00—Preparations for dentistry
A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Abstract
Compositions which are aerobically polymerizable in the presence of a free radical catalyst comprise one or more mono- and/or bisacrylate or methacrylate monomers and 0.05-6% by weight of the monomer(s) of a triarylborane complex of the formula R3B-Am in which R represents an aryl radical of 6-12 carbon atoms and Am represents sodium hydroxide, ammonia, benzene or an amine. The radical R is preferably free from hydroxyl, carboxyl and amino groups but may contain substituents such as halo, alkyl and alkoxy groups. The (meth)acrylate monomer is one which normally polymerizes only with difficulty with a free radical catalyst unless oxygen is almost completely absent; suitable esters are alkyl, allyl and fusel oil (meth)acrylates, the bisesters of glycols and bisphenols, and the bisester condensation products of phenols and glycidyl(meth)acrylate (which may contain additional ethylenic unsaturation). The composition may also include an oxirane-type monomer, e.g. glycidyl acrylate or methacrylate or a diluent monomer such as phenyl acrylate, hydroxyethyl methacrylate or acrylonitrile. A free base may also be included as a co-catalyst component, e.g. dimethyl-p-toluidine, tri-nbutylamine, diethylenetriamine, N-methylpiperidine, N-methylmorpholine, 2,5-dimethylpiperazine or 1,2,4-trimethylpiperazine. Other optional components include solvents, fillers (e.g. silica, alumina or synthetic fluorapatite), pigments, dyes and plasticizers. To effect polymerization a free radical catalyst is added, e.g. benzoyl peroxide, methyl ethyl ketone peroxide, t-butyl hydroperoxide or azobisisobutyronitrile, and the composition is then activated by heating or acidifying, e.g. with an inorganic or organic acid; the latter is preferably a compound which will copolymerize with the (meth)acrylate monomer, e.g. acrylic, methacrylic, maleic or citraconic acid. The compositions may be stored as multi-component kit, each component containing some of the ingredients of the composition in stable form. The compositions are suitable for coating, moulding, potting, embedding or sealing and, particularly, for use as a vehicle in dental filling compositions, as described in Specification 1,113,723.
GB20054/65A
1964-05-21
1965-05-12
Aerobically polymerisable compositions
Expired
GB1113722A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US36927764A
1964-05-21
1964-05-21
Publications (1)
Publication Number
Publication Date
GB1113722A
true
GB1113722A
(en)
1968-05-15
Family
ID=23454812
Family Applications (2)
Application Number
Title
Priority Date
Filing Date
GB20054/65A
Expired
GB1113722A
(en)
1964-05-21
1965-05-12
Aerobically polymerisable compositions
GB58597/67A
Expired
GB1113723A
(en)
1964-05-21
1965-05-12
Dental filling material
Family Applications After (1)
Application Number
Title
Priority Date
Filing Date
GB58597/67A
Expired
GB1113723A
(en)
1964-05-21
1965-05-12
Dental filling material
Country Status (6)
Country
Link
JP
(1)
JPS4827735B1
(en)
CH
(2)
CH471165A
(en)
DE
(1)
DE1570971A1
(en)
FR
(1)
FR1458180A
(en)
GB
(2)
GB1113722A
(en)
SE
(1)
SE349236B
(en)
Cited By (22)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4515724A
(en)
*
1982-03-01
1985-05-07
Henkel Kommanditgesellschaft Auf Aktien
Boron alkyl compounds and processes for their manufacture and use
US4638092A
(en)
*
1982-01-21
1987-01-20
Henkel Kommanditgesellschaft Auf Aktien
New organic boron polymers and their use
US4676858A
(en)
*
1982-03-01
1987-06-30
Henkel Kommanditgesellschaft Auf Aktien
Organoboron containing mixtures and their manufacture and use
US5539070A
(en)
*
1994-02-22
1996-07-23
Minnesota Mining And Manufacturing Company
Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5616796A
(en)
*
1995-04-14
1997-04-01
Minnesota Mining And Manufacturing Company
Organoborane polyamine complexes and adhesive composition made therewith
US5621143A
(en)
*
1995-04-14
1997-04-15
Minnesota Mining And Manufacturing Company
Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5686544A
(en)
*
1995-08-11
1997-11-11
Minnesota Mining And Manufacturing Company
Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US5691065A
(en)
*
1995-02-22
1997-11-25
Minnesota Mining And Manufacturing Company
Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5872197A
(en)
*
1995-08-11
1999-02-16
Minnesota Mining & Manufacturing Company
Initiator system and adhesive composition made therewith
US5883208A
(en)
*
1995-11-07
1999-03-16
Minnesota Mining And Manufacutring Company
Initiator system and adhesive composition made therewith
US5935711A
(en)
*
1996-10-23
1999-08-10
3M Innovative Properties Company
Organoborane amine complex initiator systems and polymerizable compositions made therewith
US5952409A
(en)
1996-01-31
1999-09-14
3M Innovative Properties Company
Compositions and methods for imparting stain resistance and stain resistant articles
EP0985684A2
(en)
*
1998-09-10
2000-03-15
MERCK PATENT GmbH
New reactive systems of polymerisable monomers containing peroxyds and stabilised alkyl boron compounds
WO2000066069A1
(en)
*
1999-04-29
2000-11-09
3M Espe Ag
Dental materials
US6252023B1
(en)
1999-03-19
2001-06-26
3M Innovative Properties Company
Organoborane amine complex inatator systems and polymerizable compositions made therewith
DE19959514C1
(en)
*
1999-12-09
2001-08-30
Heraeus Kulzer Gmbh & Co Kg
Dental investment material
US6383655B1
(en)
1998-06-12
2002-05-07
3M Innovative Properties Company
Low odor polymerizable compositions useful for bonding low surface energy substrates
US6479602B1
(en)
2000-03-15
2002-11-12
3M Innovative Properties
Polymerization initiator systems and bonding compositions comprising vinyl aromatic compounds
US6630555B2
(en)
2001-11-06
2003-10-07
Lord Corporation
Internally blocked organoborate initiators and adhesives therefrom
US6799966B1
(en)
1999-03-04
2004-10-05
3M Innovative Properties Company
Fluoropolymeric orthodontic article
US6812308B2
(en)
2000-11-21
2004-11-02
3M Innovative Properties Company
Initiator systems and adhesive compositions made therewith
WO2006026065A2
(en)
*
2004-08-30
2006-03-09
Ultradent Products, Inc.
Gas releasing sealing and filling compositions
Families Citing this family (4)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
JPS5137092B2
(en)
*
1972-04-28
1976-10-13
IE37703B1
(en)
*
1972-11-16
1977-09-28
Loctite Ltd
Protective adhesive-carrying tape
CA1117685A
(en)
*
1976-11-15
1982-02-02
Narayanan Madhavan
One paste polymeric dental restorative composition
JP6883300B1
(en)
*
2020-03-04
2021-06-09
株式会社球体研究所
Negative thermal expansion fine particles and their manufacturing method
1965
1965-05-12
GB
GB20054/65A
patent/GB1113722A/en
not_active
Expired
1965-05-12
GB
GB58597/67A
patent/GB1113723A/en
not_active
Expired
1965-05-17
DE
DE19651570971
patent/DE1570971A1/en
active
Pending
1965-05-20
FR
FR17704A
patent/FR1458180A/en
not_active
Expired
1965-05-20
CH
CH14668A
patent/CH471165A/en
not_active
IP Right Cessation
1965-05-20
CH
CH707665A
patent/CH475762A/en
not_active
IP Right Cessation
1965-05-21
JP
JP40029655A
patent/JPS4827735B1/ja
active
Pending
1965-05-21
SE
SE06654/65A
patent/SE349236B/xx
unknown
Cited By (42)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4638092A
(en)
*
1982-01-21
1987-01-20
Henkel Kommanditgesellschaft Auf Aktien
New organic boron polymers and their use
US4515724A
(en)
*
1982-03-01
1985-05-07
Henkel Kommanditgesellschaft Auf Aktien
Boron alkyl compounds and processes for their manufacture and use
US4676858A
(en)
*
1982-03-01
1987-06-30
Henkel Kommanditgesellschaft Auf Aktien
Organoboron containing mixtures and their manufacture and use
US5539070A
(en)
*
1994-02-22
1996-07-23
Minnesota Mining And Manufacturing Company
Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US6248846B1
(en)
1994-02-22
2001-06-19
3M Innovative Properties Company
Polymerizable compositions comprising organoborane amine complexes
US6284381B1
(en)
*
1994-02-22
2001-09-04
3M Innovative Properties Company
Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5690780A
(en)
*
1995-02-22
1997-11-25
Minnesota Mining And Manufacturing Company
Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5691065A
(en)
*
1995-02-22
1997-11-25
Minnesota Mining And Manufacturing Company
Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5621143A
(en)
*
1995-04-14
1997-04-15
Minnesota Mining And Manufacturing Company
Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5616796A
(en)
*
1995-04-14
1997-04-01
Minnesota Mining And Manufacturing Company
Organoborane polyamine complexes and adhesive composition made therewith
US5681910A
(en)
*
1995-04-14
1997-10-28
Minnesota Mining And Manufacturing Company
Organoborane polyoxyalkylenepolyamine complexes and adhsesive compositions made therewith
US5718977A
(en)
*
1995-04-14
1998-02-17
Minnesota Mining And Manufacturing Company
Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5795657A
(en)
*
1995-04-14
1998-08-18
Minnesota Mining And Manufaturing Company
Organoborane polyamine complexes and adhesive compositions made therewith
US5684102A
(en)
*
1995-04-14
1997-11-04
Minnesota Mining And Manufacturing Company
Organoborane polyamine complexes and adhesive compositions made therewith
US5872197A
(en)
*
1995-08-11
1999-02-16
Minnesota Mining & Manufacturing Company
Initiator system and adhesive composition made therewith
US5686544A
(en)
*
1995-08-11
1997-11-11
Minnesota Mining And Manufacturing Company
Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US6093778A
(en)
*
1995-08-11
2000-07-25
3M Innovative Properties Company
Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US5990036A
(en)
*
1995-08-11
1999-11-23
3M Innovative Properties Company
Initiator system and adhesive composition made therewith
US5994484A
(en)
*
1995-08-11
1999-11-30
3M Innovative Properties Company
Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US6008308A
(en)
*
1995-08-11
1999-12-28
3M Innovative Properties Company
Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
US6027813A
(en)
*
1995-11-07
2000-02-22
3M Innovative Properties Company
Initiator system and adhesive composition made therewith
US5883208A
(en)
*
1995-11-07
1999-03-16
Minnesota Mining And Manufacutring Company
Initiator system and adhesive composition made therewith
US5952409A
(en)
1996-01-31
1999-09-14
3M Innovative Properties Company
Compositions and methods for imparting stain resistance and stain resistant articles
US5935711A
(en)
*
1996-10-23
1999-08-10
3M Innovative Properties Company
Organoborane amine complex initiator systems and polymerizable compositions made therewith
US7189303B2
(en)
1998-06-12
2007-03-13
3M Innovative Properties Company
Initiator systems and adhesive compositions made therewith
US6383655B1
(en)
1998-06-12
2002-05-07
3M Innovative Properties Company
Low odor polymerizable compositions useful for bonding low surface energy substrates
EP0985684A2
(en)
*
1998-09-10
2000-03-15
MERCK PATENT GmbH
New reactive systems of polymerisable monomers containing peroxyds and stabilised alkyl boron compounds
EP0985684A3
(en)
*
1998-09-10
2000-04-26
MERCK PATENT GmbH
New reactive systems of polymerisable monomers containing peroxyds and stabilised alkyl boron compounds
US6799966B1
(en)
1999-03-04
2004-10-05
3M Innovative Properties Company
Fluoropolymeric orthodontic article
US6252023B1
(en)
1999-03-19
2001-06-26
3M Innovative Properties Company
Organoborane amine complex inatator systems and polymerizable compositions made therewith
US6384165B1
(en)
1999-03-19
2002-05-07
3M Innovative Properties Co.
Organoborane amine complex initiator systems and polymerizable compositions made therewith
WO2000066069A1
(en)
*
1999-04-29
2000-11-09
3M Espe Ag
Dental materials
US6652281B1
(en)
1999-04-29
2003-11-25
3M Espe Ag
Dental materials
US6575750B2
(en)
1999-12-09
2003-06-10
Heraeus Kulzer Gmbh & Co. Kg
Dental embedding material, dental kit and method for making a prosthesis
DE19959514C1
(en)
*
1999-12-09
2001-08-30
Heraeus Kulzer Gmbh & Co Kg
Dental investment material
US6479602B1
(en)
2000-03-15
2002-11-12
3M Innovative Properties
Polymerization initiator systems and bonding compositions comprising vinyl aromatic compounds
US6812308B2
(en)
2000-11-21
2004-11-02
3M Innovative Properties Company
Initiator systems and adhesive compositions made therewith
US6841635B2
(en)
2001-11-06
2005-01-11
Lord Corporation
Internally blocked organoborate initiators and adhesives therefrom
US6630555B2
(en)
2001-11-06
2003-10-07
Lord Corporation
Internally blocked organoborate initiators and adhesives therefrom
WO2006026065A2
(en)
*
2004-08-30
2006-03-09
Ultradent Products, Inc.
Gas releasing sealing and filling compositions
WO2006026065A3
(en)
*
2004-08-30
2006-10-05
Ultradent Products Inc
Gas releasing sealing and filling compositions
US7173075B2
(en)
2004-08-30
2007-02-06
Ultradent Products, Inc.
Gas releasing sealing and filling compositions
Also Published As
Publication number
Publication date
GB1113723A
(en)
1968-05-15
FR1458180A
(en)
1966-11-10
JPS4827735B1
(en)
1973-08-25
DE1570971A1
(en)
1970-09-24
SE349236B
(en)
1972-09-25
CH475762A
(en)
1969-07-31
CH471165A
(en)
1969-04-15
Similar Documents
Publication
Publication Date
Title
GB1113722A
(en)
1968-05-15
Aerobically polymerisable compositions
US4097994A
(en)
1978-07-04
Dental restorative composition containing oligomeric BIS-GMA resin and Michler's ketone
US4002669A
(en)
1977-01-11
Hydroxy group containing diesters of acrylic acid
US6552140B1
(en)
2003-04-22
Auto-oxidation systems for air-activatable polymerisable compositions
US4116788A
(en)
1978-09-26
Process for the photopolymerization of acrylic acid ester-containing compositions
ES368340A1
(en)
1971-12-01
Dental filling material
IE43811B1
(en)
1981-06-03
Curable acrylate ester compositions containing hydrazine acelerators and acid co-accelerators
ATE406864T1
(en)
2008-09-15
IMPROVED DENTAL MATERIALS
GB1110673A
(en)
1968-04-24
A process for the production of polymers and copolymers
CA1216994A
(en)
1987-01-20
Curing compositions
US3931678A
(en)
1976-01-13
Dental filling method and composition formed thereby
JPH0345602A
(en)
1991-02-27
Polymerizable composition
GB857032A
(en)
1960-12-29
Improvements in or relating to dough compositions
GB1144755A
(en)
1969-03-12
Self adhesive tapes
GB1521901A
(en)
1978-08-16
Anaerobic polymerisable composition
GB1145564A
(en)
1969-03-19
A process for the production of thermoplastic copolymers
GB1130653A
(en)
1968-10-16
Dental repair material and production thereof
GB1103674A
(en)
1968-02-21
Improved denture compositions and their use
JPS6322809A
(en)
1988-01-30
Storage stable and latent curable acrylic product using polymerized hydroperoxide
US4894356A
(en)
1990-01-16
Catalysts for air-drying compositions
JPH03177471A
(en)
1991-08-01
Adhesive composition
KR900701855A
(en)
1990-12-04
Novel radically polymerizable multicomponent mixtures and uses thereof (ii)
GB1110266A
(en)
1968-04-18
Substituted acrylates and polymers thereof
JPS58185666A
(en)
1983-10-29
Novel cyanoacrylate adhesive
GB1337876A
(en)
1973-11-21
Poly-hydroxy-bis-oxazoline derivatives and their use for manufacturing coating compositions hardenable by irradiation
None