GB1114187A

GB1114187A – Production of acrylonitrile polymers
– Google Patents

GB1114187A – Production of acrylonitrile polymers
– Google Patents
Production of acrylonitrile polymers

Info

Publication number
GB1114187A

GB1114187A
GB27645/66A
GB2764566A
GB1114187A
GB 1114187 A
GB1114187 A
GB 1114187A
GB 27645/66 A
GB27645/66 A
GB 27645/66A
GB 2764566 A
GB2764566 A
GB 2764566A
GB 1114187 A
GB1114187 A
GB 1114187A
Authority
GB
United Kingdom
Prior art keywords
comonomer
alkyl
acrylonitrile
weight
solutions
Prior art date
1965-06-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB27645/66A
Inventor
Jenoe Szita
Herbert Marzolph
Otto Unger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer AG

Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1965-06-23
Filing date
1966-06-21
Publication date
1968-05-15

1965-06-23
Priority claimed from DE1965F0046409
external-priority
patent/DE1301077B/en

1966-06-21
Application filed by Bayer AG
filed
Critical
Bayer AG

1968-05-15
Publication of GB1114187A
publication
Critical
patent/GB1114187A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof

C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof

C08F20/42—Nitriles

C08F20/44—Acrylonitrile

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F2/00—Processes of polymerisation

C08F2/36—Polymerisation in solid state

Abstract

Spinnable solutions of acrylonitrile polymers are prepared by polymerizing at 30-60 DEG C. a monomeric material containing 80-100% by weight of acrylonitrile and up to 20% by weight of a comonomer in an organic solvent for the polymer in the presence of a Redox catalyst system consisting of an organic peroxide and a sulphone of the formula wherein R represents a monovalent aliphatic or aromatic hydrocarbon radical which may be substituted; R1 and R11 which may be the same or different represent hydrogen or alkyl; and either n is 1 and X is -OH, or n is 2 and X is =NR111, R111 being alkyl, hydroxyalkyl or aryl. The comonomer may be an acrylic ester, e.g. methyl acrylate, vinyl ester, or styrene derivative, or a dyeable component such as sulphostyrene, N-(p-methacryloylamino-phenyl sulphonyl)-benzenesulphonamide or vinyl pyridine. The monomers may contain stabilizers such as thiosemicarbazide, ammonia, hydroquinone and derivatives. Suitable peroxides include cumene and t-butyl hydroperoxides, methyl ethyl ketone, cyclohexanone and lauroyl peroxides and mono-t-butyl peroxymaleate. Organic solvents specified are dimethylformamide, dimethylacetamide, dimethyl sulphoxide, g -butyrolactone and ethylene glycol carbonate. A mineral acid, e.g. hydrochloric, phosphoric or sulphuric acid, may be present to inhibit discoloration or stabilize the solution; and oxalic acid may be present if the solution contains iron impurities. At the end of polymerization, an inhibitor may be added to prevent undesired polymerization of any unreacted monomer or to stop the reaction at incomplete conversion. The solutions can be spun to form filaments having good whiteness and thermostability properties.

GB27645/66A
1965-06-23
1966-06-21
Production of acrylonitrile polymers

Expired

GB1114187A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

DE1965F0046409

DE1301077B
(en)

1965-06-23
1965-06-23

Process for the production of spinnable solutions of polyacrylonitrile

Publications (1)

Publication Number
Publication Date

GB1114187A
true

GB1114187A
(en)

1968-05-15

Family
ID=7101016
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB27645/66A
Expired

GB1114187A
(en)

1965-06-23
1966-06-21
Production of acrylonitrile polymers

Country Status (6)

Country
Link

US
(1)

US3453249A
(en)

AT
(1)

AT271008B
(en)

BE
(1)

BE682925A
(en)

CH
(1)

CH470426A
(en)

GB
(1)

GB1114187A
(en)

NL
(1)

NL151389B
(en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE2602350A1
(en)

*

1976-01-22
1977-07-28
Bayer Ag

SOLUTION POLYMERIZATION OF CROSS-LINKABLE ACRYLNITRILE POLYMERIZES

US4621116A
(en)

*

1984-12-07
1986-11-04
E. I. Du Pont De Nemours And Company
Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt

US4910274A
(en)

*

1987-11-27
1990-03-20
The Dow Chemical Company
Preparation of monohydroxy-containing polymers

Family Cites Families (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

CH311220A
(en)

*

1950-07-17
1955-11-30
Gmbh W C Heraeus

Process for the production of plastics from polymerizable organic compounds with a double-bonded terminal methylene group.

US2768156A
(en)

*

1951-03-08
1956-10-23
Heraeus Gmbh W C
Process for the production of polymerisation products using sulphinc acid salts

BE538514A
(en)

*

1954-05-28

DE1050063B
(en)

*

1954-09-22
1959-02-05
Wacker-Chemie G.m.b.H., München

Process for the production of water-insoluble nitrogen-containing polymers

DE1250127C2
(en)

*

1957-11-04
1973-10-18

PROCESS FOR THE MANUFACTURING OF ACRYLIC NITRILE MIXED POLYMERISATES

1966

1966-06-02
CH
CH804266A
patent/CH470426A/en
not_active
IP Right Cessation

1966-06-09
US
US556286A
patent/US3453249A/en
not_active
Expired – Lifetime

1966-06-13
AT
AT559566A
patent/AT271008B/en
active

1966-06-21
NL
NL666608595A
patent/NL151389B/en
unknown

1966-06-21
GB
GB27645/66A
patent/GB1114187A/en
not_active
Expired

1966-06-22
BE
BE682925D
patent/BE682925A/xx
unknown

Also Published As

Publication number
Publication date

NL151389B
(en)

1976-11-15

BE682925A
(en)

1966-12-01

US3453249A
(en)

1969-07-01

NL6608595A
(en)

1966-12-27

AT271008B
(en)

1969-05-27

CH470426A
(en)

1969-03-31

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