GB1117643A

GB1117643A – Imides and related compounds
– Google Patents

GB1117643A – Imides and related compounds
– Google Patents
Imides and related compounds

Info

Publication number
GB1117643A

GB1117643A
GB42438/65A
GB4243865A
GB1117643A
GB 1117643 A
GB1117643 A
GB 1117643A
GB 42438/65 A
GB42438/65 A
GB 42438/65A
GB 4243865 A
GB4243865 A
GB 4243865A
GB 1117643 A
GB1117643 A
GB 1117643A
Authority
GB
United Kingdom
Prior art keywords
oils
carbon atoms
aminocyclic
group
urea
Prior art date
1964-11-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB42438/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rohm and Haas Co

Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-11-18
Filing date
1965-10-06
Publication date
1968-06-19

1965-10-06
Application filed by Rohm and Haas Co
filed
Critical
Rohm and Haas Co

1968-06-19
Publication of GB1117643A
publication
Critical
patent/GB1117643A/en

Status
Expired
legal-status
Critical
Current

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Classifications

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION

C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium

C10M135/12—Thio-acids; Thiocyanates; Derivatives thereof

C10M135/14—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond

C10M135/16—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiourea type, i.e. containing the group

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07D—HETEROCYCLIC COMPOUNDS

C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings

C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member

C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms

C07D233/30—Oxygen or sulfur atoms

C07D233/32—One oxygen atom

C07D233/36—One oxygen atom with hydrocarbon radicals, substituted by nitrogen atoms, attached to ring nitrogen atoms

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07D—HETEROCYCLIC COMPOUNDS

C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings

C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member

C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms

C07D233/30—Oxygen or sulfur atoms

C07D233/42—Sulfur atoms

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F8/00—Chemical modification by after-treatment

C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups

C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines

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C10L1/00—Liquid carbonaceous fuels

C10L1/10—Liquid carbonaceous fuels containing additives

C10L1/14—Organic compounds

C10L1/22—Organic compounds containing nitrogen

C10L1/234—Macromolecular compounds

C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof

C10L1/2368—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing heterocyclic compounds containing nitrogen in the ring

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C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS

C10L1/00—Liquid carbonaceous fuels

C10L1/10—Liquid carbonaceous fuels containing additives

C10L1/14—Organic compounds

C10L1/22—Organic compounds containing nitrogen

C10L1/234—Macromolecular compounds

C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds

C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)

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C10L1/00—Liquid carbonaceous fuels

C10L1/10—Liquid carbonaceous fuels containing additives

C10L1/14—Organic compounds

C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium

C10L1/2462—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds

C10L1/2475—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon to carbon bonds

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C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen

C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms

C10M133/56—Amides; Imides

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C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions

C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers

C10M2205/026—Butene

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C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings

C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring

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C10M2207/02—Hydroxy compounds

C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings

C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups

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C10M2207/02—Hydroxy compounds

C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings

C10M2207/027—Neutral salts thereof

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C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates

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C10M2207/10—Carboxylix acids; Neutral salts thereof

C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms

C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms

C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic

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C10M2207/10—Carboxylix acids; Neutral salts thereof

C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms

C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids

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C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions

C10M2207/10—Carboxylix acids; Neutral salts thereof

C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms

C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms

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C10M2207/10—Carboxylix acids; Neutral salts thereof

C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings

C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups

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C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings

C10M2207/146—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings having carboxyl groups bound to carbon atoms of six-membeered aromatic rings having a hydrocarbon substituent of thirty or more carbon atoms

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C10M2207/22—Acids obtained from polymerised unsaturated acids

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C10M2207/28—Esters

C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids

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C10M2207/28—Esters

C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids

C10M2207/302—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids derived from the combination of monocarboxylic acids, dicarboxylic acids and dihydroxy compounds only and having no free hydroxy or carboxyl groups

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C10M2207/28—Esters

C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids

C10M2207/304—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids derived from the combination of monohydroxy compounds, dihydroxy compounds and dicarboxylic acids only and having no free hydroxy or carboxyl groups

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C10M2207/28—Esters

C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives

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C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical

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C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type

C10M2209/084—Acrylate; Methacrylate

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C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2040/00—Specified use or application for which the lubricating composition is intended

C10N2040/12—Gas-turbines

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2040/00—Specified use or application for which the lubricating composition is intended

C10N2040/12—Gas-turbines

C10N2040/13—Aircraft turbines

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2050/00—Form in which the lubricant is applied to the material being lubricated

C10N2050/10—Semi-solids; greasy

F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING

F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS

F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL

F02B3/00—Engines characterised by air compression and subsequent fuel addition

F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition

Abstract

Lubricating oil additives are formed by reacting an olefinic succinic anhydride of formula with an aminocyclic urea of formula where R is an alkenyl radical containing 30 to 200 carbon atoms, X is oxygen or sulphur and A and A1 are alkylene radicals containing 2 or 3 carbon atoms in a chain extending between the nitrogen atoms to which they are attached. Preferably the olefinic succinic anhydride is obtained by polymerizing an olefine containing four carbon atoms and then reacting the polymer produced with maleic anhydride. Aminocyclic ureas mentioned are aminoethylethyleneurea, aminopropylethyleneurea, aminoethylethylenethiourea, aminopropylethylenethiourea, aminoethylhexahydropyrimidinone, aminopropylhexahydropyrimidinone, aminopropylhexahydropyrimidithione, 1-(1-methyl-2-aminoethyl) – 5 – methylethyleneurea and 1-(1 – methyl – 2 – aminoethyl) – 5 – methylhexahydropyrimidinone. Either a 1:1 or 1:2 ratio of olefinic succinic anhydride to aminocyclic urea may be employed. Cyclic imides and amide acids may be produced using a 1 : 1 ratio, in the former case the water formed is removed. The amide acids may be reacted with a compound Z-Y-H, followed by reaction with the aminocyclic urea, where Y is oxygen or sulphur and Z is a hydrogen, a C1 to C24 alkyl group, a cycloalkyl group, a phenyl group, a naphthyl group or an alkylphenyl or phenylalkyl group where the alkyl group has 1 to 8 carbon atoms. The alkyl radicals may contain thio, hydroxy or tertiary amino substituents.ALSO:Lubricating oil and fuel additives of formulae are obtained by reacting an olefinic succinic anhydride with an aminocyclic urea of formula In the above formulae one R is a hydrogen atom and the other is an alkenyl radical containing 30 to 200 carbon atoms, R1 is an alkenyl radical containing 30 to 200 carbon atoms, A and A1 are alkylene radicals containing 2 or 3 carbon atoms in a chain extending between the nitrogen atoms to which it is attached, X and Y are oxygen or sulphur atoms and Z is a hydrogen atom, a C1-C24 alkyl group, a phenyl group, a cycloalkyl group, a naphthyl group or an alkylphenyl or phenylalkyl group in which the alkyl radical contains 1 to 8 carbon atoms. The alkyl radicals may be substituted by thio, hydroxy or tertiary amino radicals. The olefinic succinic anhydride is preferably obtained by reacting a polyolefine with maleic anhydride. Additives of formula II can be further reacted with a compound 2-y-H, and then with the aminocyclic urea. The lubricating oils may be mineral oils or synthetic lubricants and they may be of naphthenic or paraffinic nature or mixtures thereof, or they may be distillates or mixtures of neutral oils and bright stocks. The lubricants may be bodied or gelled and used as greases. The oils may vary from spindle oils or hydraulic oils to oils for reciprocating aircraft engines and include oils for sparking combustion and compression ignition engines. Also hydraulic and automatic transmission fluids. Synthetic lubricants include esters, polyethers and silicones. When used as hydraulic fluids phosphate esters are added. Antioxidants, anti-foam agents, anti-rust agents, anti-wear agents, heavy-duty detergents, pour-point depressants, viscosity index improvers, anti-knock agents and ignition control agents may also be present. The fuel include distillate fuels boiling between 75 DEG and 750 DEG F., including gasolines, jet and Diesel fuels and furnace oils.

GB42438/65A
1964-11-18
1965-10-06
Imides and related compounds

Expired

GB1117643A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US41223764A

1964-11-18
1964-11-18

Publications (1)

Publication Number
Publication Date

GB1117643A
true

GB1117643A
(en)

1968-06-19

Family
ID=23632183
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB42438/65A
Expired

GB1117643A
(en)

1964-11-18
1965-10-06
Imides and related compounds

Country Status (5)

Country
Link

BE
(1)

BE672244A
(en)

ES
(1)

ES319508A1
(en)

FR
(1)

FR1460163A
(en)

GB
(1)

GB1117643A
(en)

NL
(1)

NL6514772A
(en)

Cited By (8)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

WO2000053703A1
(en)

*

1998-10-16
2000-09-14
Uniroyal Chemical Company, Inc.
Cyclic thiourea additives for lubricants

WO2001036572A1
(en)

*

1999-11-12
2001-05-25
Crompton Corporation
Substituted linear thiourea compounds as additives for lubricants

EP1359209A2
(en)

*

2002-04-23
2003-11-05
Rohm And Haas Company
Compounds containing amide and carboxyl groups as asphaltene dispersants in crude oil

JP3523235B2
(en)

1999-07-22
2004-04-26
ユニロイヤル ケミカル カンパニー インコーポレイテッド

Imidazolethione additives for lubricants

US7122112B2
(en)

2003-05-29
2006-10-17
Rohm And Haas Company
Compounds containing amide and carboxyl groups as asphaltene dispersants in crude oil

US20110190182A1
(en)

*

2008-07-31
2011-08-04
The Lubrizol Corporation
Novel Copolymers and Lubricating Compositions Thereof

EP2462212A1
(en)

*

2009-08-06
2012-06-13
The Lubrizol Corporation
Asphaltene dispersant containing lubricating compositions

CN115746698A
(en)

*

2022-11-18
2023-03-07
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Families Citing this family (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

FR2414542A1
(en)

*

1978-01-11
1979-08-10
Orogil

NEW COMPOSITIONS BASED ON ALCENYLSUCCINIMIDES, DERIVED FROM TRIS (5-AMINO-THIA-3 PENTYL) AMINE, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS ADDITIVES FOR LUBRICANTS

US5188745A
(en)

*

1991-12-23
1993-02-23
Texaco Inc.
Viton seal compatible dispersant and lubricating oil composition containing same

US5516343A
(en)

*

1995-03-14
1996-05-14
Huntsman Corporation
Hydrocarbon compositions containing a polyetheramide additive

EP1394242A3
(en)

*

2002-08-07
2004-04-21
Rohm And Haas Company
Cyclic thioureas and their use as additives for lubricating oils

1965

1965-10-06
GB
GB42438/65A
patent/GB1117643A/en
not_active
Expired

1965-11-12
ES
ES0319508A
patent/ES319508A1/en
not_active
Expired

1965-11-12
NL
NL6514772A
patent/NL6514772A/xx
unknown

1965-11-12
FR
FR38172A
patent/FR1460163A/en
not_active
Expired

1965-11-12
BE
BE672244D
patent/BE672244A/xx
unknown

Cited By (11)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

WO2000053703A1
(en)

*

1998-10-16
2000-09-14
Uniroyal Chemical Company, Inc.
Cyclic thiourea additives for lubricants

AU760946B2
(en)

*

1998-10-16
2003-05-22
Uniroyal Chemical Company, Inc.
Cyclic thiourea additives for lubricants

JP3523235B2
(en)

1999-07-22
2004-04-26
ユニロイヤル ケミカル カンパニー インコーポレイテッド

Imidazolethione additives for lubricants

WO2001036572A1
(en)

*

1999-11-12
2001-05-25
Crompton Corporation
Substituted linear thiourea compounds as additives for lubricants

EP1359209A2
(en)

*

2002-04-23
2003-11-05
Rohm And Haas Company
Compounds containing amide and carboxyl groups as asphaltene dispersants in crude oil

EP1359209A3
(en)

*

2002-04-23
2004-11-03
Rohm And Haas Company
Compounds containing amide and carboxyl groups as asphaltene dispersants in crude oil

US7122112B2
(en)

2003-05-29
2006-10-17
Rohm And Haas Company
Compounds containing amide and carboxyl groups as asphaltene dispersants in crude oil

US20110190182A1
(en)

*

2008-07-31
2011-08-04
The Lubrizol Corporation
Novel Copolymers and Lubricating Compositions Thereof

EP2462212A1
(en)

*

2009-08-06
2012-06-13
The Lubrizol Corporation
Asphaltene dispersant containing lubricating compositions

CN115746698A
(en)

*

2022-11-18
2023-03-07
江阴市诚信合金材料有限公司
High-wear-resistance chromium-zirconium-copper alloy wire and preparation method thereof

CN115746698B
(en)

*

2022-11-18
2023-09-26
江阴市诚信合金材料有限公司
High-wear-resistance chromium-zirconium-copper alloy wire and preparation method thereof

Also Published As

Publication number
Publication date

ES319508A1
(en)

1966-07-01

BE672244A
(en)

1966-05-12

FR1460163A
(en)

1966-11-25

NL6514772A
(en)

1966-05-20

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