GB1152530A

GB1152530A – Improvements in or relating to Electric Cells
– Google Patents

GB1152530A – Improvements in or relating to Electric Cells
– Google Patents
Improvements in or relating to Electric Cells

Info

Publication number
GB1152530A

GB1152530A
GB14207/67A
GB1420767A
GB1152530A
GB 1152530 A
GB1152530 A
GB 1152530A
GB 14207/67 A
GB14207/67 A
GB 14207/67A
GB 1420767 A
GB1420767 A
GB 1420767A
GB 1152530 A
GB1152530 A
GB 1152530A
Authority
GB
United Kingdom
Prior art keywords
electrolyte
cathode
compounds
specified
halogen
Prior art date
1966-03-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB14207/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Honeywell Inc

Original Assignee
Honeywell Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1966-03-29
Filing date
1967-03-29
Publication date
1969-05-21

1967-03-29
Application filed by Honeywell Inc
filed
Critical
Honeywell Inc

1969-05-21
Publication of GB1152530A
publication
Critical
patent/GB1152530A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

H—ELECTRICITY

H01—ELECTRIC ELEMENTS

H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M10/00—Secondary cells; Manufacture thereof

H01M10/05—Accumulators with non-aqueous electrolyte

H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes

H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only

H01M10/0566—Liquid materials

H—ELECTRICITY

H01—ELECTRIC ELEMENTS

H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M6/00—Primary cells; Manufacture thereof

H01M6/14—Cells with non-aqueous electrolyte

H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE

Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation

Y02E60/10—Energy storage using batteries

Abstract

1,152,530. Cells with non-aqueous. HONEYWELL Inc. 29 March, 1967 [29 March, 1966], No. 14207/67. Heading H1B. The invention comprises a cell having a Li anode, a depolarizing cathode and as electrolyte methyl acetate containing MX 4 -, MX 6 3- or M1F 6 anions, where M is B, Al or In, M1 is p6, Sb or As and X is halogen, a total of less than 0À5 mol. per cent of MeOH, CH 3 COOH and H 2 O and less than 500 p.p.m. of H 2 O. The anode may comprise Li or a Li alloy supported on a Ni or Ag screen. The cathode may comprise a depolarizer and a conductor, e.g. a mixture of a depolarizer and a finely divided conductor held together by a binder. Depolarizers specified include heavy metal compounds, transition metal compounds, organic oxidizing agents, cyclic active halogen compounds, positive halogen compounds, halogen addition compounds, inorganic peroxides and free halogens such as AgCl, AgF, AgO, CuCl, CuCl 2 , CuF 2 , MnO 2 , Bi 2 O 3 , potassium dichloroisocyanurate, C 2 O 3 (NH 4 ) 2 S 2 O 8 , HgCl 2 , Ni 2 O 3 , MnF 3 , NiF 2 , CoF 3 , CuS, PbO 2 , HgO, anthraquinone, I 2 , trichloromelamine, o-dinitrobenzene, phenyl mercuric nitrate, I 2 O 5 , KIO 4 , KMnO 4 , and K 2 Cr 2 O 7 ,. Conductors specified are graphite, Ag, Cu and Ni. Binders specified are paper fibres, asbestos and cellulose acetate. The cathode material should have a potential at least 2 volts less than that of Li. The electrolyte anions may originate from a salt which will not oxidize lithium, e.g. a potassium, sodium or lithium salt or a salt of an organic base. Salts specified include: LiBF 4 , LiAlCl 4 , LiAlBr 4 , LiInCl 4 , LiPF 6 , LiSbF 6 , morpholinium hexafluorophosphate, NaBF 4 , KAlBr 4 , NaPF 6 , Li 3 InCl 6 and Na 3 AlF 6 . The electrolyte should be of at least 0À1 M concentration and have a conductivity of 10-3 ohms-1 cm-1 or more. The electrodes may be separated by porous polyethylene, non-woven nylon fibres bonded with a butadiene-acrylonitrile copolymer or porous polypropylene. The cell may be ready for use or » deferred action» type and primary or secondary. In typical Example 1, a lithium on nickel anode and a cathode comprising Bi 2 O 3 , graphite and methyl acetate supported on a silver screen are placed either side of a separator and sealed hermetically into a polyethylene bag. Electrolyte is introduced with a hypodermic syringe. In Examples 50 and 51, multiplate cells are housed in a sealed steel base with a detachable polypropylene lining.

GB14207/67A
1966-03-29
1967-03-29
Improvements in or relating to Electric Cells

Expired

GB1152530A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US538209A

US3415687A
(en)

1966-03-29
1966-03-29
Electric current producing cell

Publications (1)

Publication Number
Publication Date

GB1152530A
true

GB1152530A
(en)

1969-05-21

Family
ID=24145954
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB14207/67A
Expired

GB1152530A
(en)

1966-03-29
1967-03-29
Improvements in or relating to Electric Cells

Country Status (8)

Country
Link

US
(1)

US3415687A
(en)

JP
(1)

JPS4634818B1
(en)

BE
(1)

BE696177A
(en)

DE
(1)

DE1671804B1
(en)

FR
(1)

FR1515724A
(en)

GB
(1)

GB1152530A
(en)

NL
(1)

NL138798B
(en)

SE
(1)

SE314723B
(en)

Cited By (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

FR2461366A1
(en)

*

1979-07-03
1981-01-30
Duracell Int

IMPROVED SALT ELECTROLYTES FOR NON-AQUEOUS ELECTROCHEMICAL CELLS, AND BATTERIES USING SAID ELECTROLYTES

EP0209376A2
(en)

*

1985-07-17
1987-01-21
Nippon Chemi-Con Corporation
An electrolyte for electrolytic capacitor

EP0228790A2
(en)

*

1985-12-28
1987-07-15
Nippon Chemi-Con Corporation
An electrolyte for electrolytic capacitor

EP0231114A2
(en)

*

1986-01-24
1987-08-05
Nippon Chemi-Con Corporation
An electrolyte for electrolytic capacitor

Families Citing this family (46)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

FR1490726A
(en)

*

1966-06-23
1967-08-04
Accumulateurs Fixes

non-aqueous electrolyte with high solvating power

FR1527783A
(en)

*

1966-12-30
1968-06-07
Accumulateurs Fixes

Process for preparing an ionized nonaqueous electrolyte, in particular for primary electrochemical generators and electrolytes and generators thus obtained

FR1516899A
(en)

*

1966-12-30
1968-02-05
Accumulateurs Fixes

Advanced secondary electrochemical generators

IT500094A
(en)

*

1968-04-12

US3531328A
(en)

*

1968-11-13
1970-09-29
Mallory & Co Inc P R
Light metal-copper chloride organic electrolyte cell

US3918988A
(en)

*

1969-03-19
1975-11-11
Honeywell Inc
Electric current-producing cells

FR2052243A5
(en)

*

1969-07-31
1971-04-09
Accumulateurs Fixes

US3639174A
(en)

*

1970-04-22
1972-02-01
Du Pont
Voltaic cells with lithium-aluminum alloy anode and nonaqueous solvent electrolyte system

US3658592A
(en)

*

1970-07-15
1972-04-25
Mallory & Co Inc P R
Lithium-metal chromate organic electrolyte cell

US3945848A
(en)

*

1970-07-15
1976-03-23
P. R. Mallory & Co. Inc.
Lithium-metal oxide organic electrolyte systems

US3751298A
(en)

*

1971-05-21
1973-08-07
Union Carbide Corp
Thermal, rechargeable electrochemical cell having lithium monoaluminide electrode and lithium tetrachloroaluminate electrolyte

US3852113A
(en)

*

1971-12-30
1974-12-03
Osaka Soda Co Ltd
Positive electrode for high energy primary cells and cells using same

US3761578A
(en)

*

1972-03-09
1973-09-25
S Anderson
Method of preparing purified lithium aluminum chloride

US3985577A
(en)

*

1972-08-31
1976-10-12
Eagle-Picher Industries, Inc.
Lithium/fluorographite primary cell with improved electrolyte

US3847667A
(en)

*

1972-09-26
1974-11-12
Esb Inc
Alkali metal-porous conductive carbon battery having a molten alkali metal chloraluminate electrolyte

US4476204A
(en)

*

1972-11-13
1984-10-09
Gte Laboratories Incorporated
Electrochemical cell utilizing a mixture of phosphorus oxychloride and a low freezing solvent as the electrolyte

US3922174A
(en)

*

1973-01-22
1975-11-25
Gte Laboratories Inc
Electrochemical cell

US3898100A
(en)

*

1973-07-31
1975-08-05
Union Carbide Corp
Cathode mix for solid electrolyte devices

US3901730A
(en)

*

1973-07-31
1975-08-26
Union Carbide Corp
Cathode mix for solid electrolyte device

US3891458A
(en)

*

1973-11-15
1975-06-24
Electrochimica Corp
Electric current producing galvanic cell

US3887397A
(en)

*

1974-01-02
1975-06-03
Honeywell Inc
Highly conductive stable electrolyte for lithium batteries

US4444855A
(en)

*

1974-05-29
1984-04-24
Union Carbide Corporation
Non-aqueous electrochemical cell

DE2516704C3
(en)

*

1975-04-16
1981-07-02
Varta Batterie Ag, 3000 Hannover

Galvanic element with a negative electrode made of light metal, a non-aqueous electrolyte and a positive electrode

USRE30661E
(en)

*

1977-03-23
1981-06-30
Electrochimica Corporation
Electric current producing galvanic cell

JPS53120140A
(en)

*

1977-03-29
1978-10-20
Toshiba Ray O Vac
Organic electrolyte battery

US4201839A
(en)

*

1978-11-01
1980-05-06
Exxon Research And Engineering Co.
Cell containing an alkali metal anode, a solid cathode, and a closoborane and/or closocarborane electrolyte

US4177329A
(en)

*

1978-11-02
1979-12-04
P. R. Mallory & Co. Inc.
Electrolyte salts for non aqueous electrochemical cells

US4310609A
(en)

*

1979-12-17
1982-01-12
Wilson Greatbatch Ltd.
Metal oxide composite cathode material for high energy density batteries

US4285122A
(en)

*

1980-03-14
1981-08-25
Union Carbide Corporation
Heat-treated, organic solvent-treated manganese dioxide

US4466470A
(en)

*

1982-01-20
1984-08-21
Polaroid Corporation
Lithium batteries with organic slurry cathodes

US4495266A
(en)

*

1982-05-07
1985-01-22
Gte Laboratories Incorporated
High rate electrochemical cell

US4818647A
(en)

*

1987-03-20
1989-04-04
The United States Of America As Represented By The Secretary Of The Army
Method of making a cathode for use in a rechargeable lithium battery, cathode so made, and rechargeable lithium battery including the cathode

US4960657A
(en)

*

1988-03-01
1990-10-02
Bridgestone Corporation
Lithium cells

US6001325A
(en)

*

1996-11-26
1999-12-14
Fmc Corporation
Process for removing acids from lithium salt solutions

ATE296481T1
(en)

*

1998-08-11
2005-06-15
Fuji Photo Film Co Ltd

PYRIDINIUM COMPOUNDS AND THEIR USE IN A PHOTOELECTROCHEMICAL CELL

CN101261900B
(en)

*

2001-05-11
2011-02-02
三菱化学株式会社
Electrolyte for electrolytic capacitor and electrolytic capacitor using the same

EP2323144A1
(en)

*

2002-10-31
2011-05-18
Mitsubishi Chemical Corporation
Electrolytic capacitor

EP1580774B1
(en)

*

2002-11-08
2014-04-09
Nippon Chemi-Con Corporation
Electrolytic capacitor

EP1580772B1
(en)

*

2002-11-08
2015-03-11
Nippon Chemi-Con Corporation
Electrolytic capacitor

US7407726B2
(en)

*

2003-09-16
2008-08-05
The Gillette Company
Primary alkaline battery containing bismuth metal oxide

US7537863B2
(en)

*

2003-09-16
2009-05-26
The Gillette Company
Primary alkaline battery containing bismuth metal oxide

US7300722B2
(en)

*

2005-04-11
2007-11-27
The Gillette Company
Lithium battery containing bismuth metal oxide

US7972726B2
(en)

*

2006-07-10
2011-07-05
The Gillette Company
Primary alkaline battery containing bismuth metal oxide

US20130122367A1
(en)

*

2010-11-10
2013-05-16
Panasonic Corporation
Lithium primary cell

JP5987431B2
(en)

*

2011-04-13
2016-09-07
三菱化学株式会社

Lithium fluorosulfonate, non-aqueous electrolyte, and non-aqueous electrolyte secondary battery

CN108011094B
(en)

*

2017-11-10
2020-08-04
上海交通大学
Preparation method of composite positive electrode material of lithium-sulfur battery

Family Cites Families (6)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US2597451A
(en)

*

1948-11-20
1952-05-20
Burgess Battery Co
Primary cell

US2597455A
(en)

*

1948-11-20
1952-05-20
Burgess Battery Co
Primary cell

FR1189268A
(en)

*

1957-11-26
1959-10-01

Improvements to batteries and electric accumulators

US3073884A
(en)

*

1959-08-03
1963-01-15
Ethyl Corp
High energy batteries

FR1320482A
(en)

*

1961-07-29
1963-03-08
Pertrix Union Gmbh

galvanic primary element

US3235408A
(en)

*

1963-10-18
1966-02-15
Corson G & W H
Ammonia electric current-producing cell

1966

1966-03-29
US
US538209A
patent/US3415687A/en
not_active
Expired – Lifetime

1967

1967-03-25
DE
DE19671671804
patent/DE1671804B1/en
active
Pending

1967-03-28
SE
SE4228/67A
patent/SE314723B/xx
unknown

1967-03-28
BE
BE696177D
patent/BE696177A/xx
unknown

1967-03-29
JP
JP1928167A
patent/JPS4634818B1/ja
active
Pending

1967-03-29
FR
FR100597A
patent/FR1515724A/en
not_active
Expired

1967-03-29
NL
NL676704488A
patent/NL138798B/en
not_active
IP Right Cessation

1967-03-29
GB
GB14207/67A
patent/GB1152530A/en
not_active
Expired

Cited By (7)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

FR2461366A1
(en)

*

1979-07-03
1981-01-30
Duracell Int

IMPROVED SALT ELECTROLYTES FOR NON-AQUEOUS ELECTROCHEMICAL CELLS, AND BATTERIES USING SAID ELECTROLYTES

EP0209376A2
(en)

*

1985-07-17
1987-01-21
Nippon Chemi-Con Corporation
An electrolyte for electrolytic capacitor

EP0209376A3
(en)

*

1985-07-17
1987-09-02
Nippon Chemi-Con Corporation
An electrolyte for electrolytic capacitor

EP0228790A2
(en)

*

1985-12-28
1987-07-15
Nippon Chemi-Con Corporation
An electrolyte for electrolytic capacitor

EP0228790A3
(en)

*

1985-12-28
1987-09-02
Nippon Chemi-Con Corporation
An electrolyte for electrolytic capacitor

EP0231114A2
(en)

*

1986-01-24
1987-08-05
Nippon Chemi-Con Corporation
An electrolyte for electrolytic capacitor

EP0231114A3
(en)

*

1986-01-24
1987-09-02
Nippon Chemi-Con Corporation
An electrolyte for electrolytic capacitor

Also Published As

Publication number
Publication date

NL138798B
(en)

1973-05-15

NL6704488A
(en)

1967-10-02

BE696177A
(en)

1967-09-01

JPS4634818B1
(en)

1971-10-12

DE1671804B1
(en)

1971-10-14

SE314723B
(en)

1969-09-15

FR1515724A
(en)

1968-03-01

US3415687A
(en)

1968-12-10

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Legal Events

Date
Code
Title
Description

1969-10-01
PS
Patent sealed [section 19, patents act 1949]

1975-10-22
PLNP
Patent lapsed through nonpayment of renewal fees

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