GB1155478A

GB1155478A – Process for the manufacture of Olefin Polymers
– Google Patents

GB1155478A – Process for the manufacture of Olefin Polymers
– Google Patents
Process for the manufacture of Olefin Polymers

Info

Publication number
GB1155478A

GB1155478A
GB36518/67A
GB3651867A
GB1155478A
GB 1155478 A
GB1155478 A
GB 1155478A
GB 36518/67 A
GB36518/67 A
GB 36518/67A
GB 3651867 A
GB3651867 A
GB 3651867A
GB 1155478 A
GB1155478 A
GB 1155478A
Authority
GB
United Kingdom
Prior art keywords
compound
aluminium
aug
isoprenyl
carbon atoms
Prior art date
1966-08-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB36518/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Hoechst AG

Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1966-08-09
Filing date
1967-08-09
Publication date
1969-06-18

1967-08-09
Application filed by Hoechst AG, Farbwerke Hoechst AG
filed
Critical
Hoechst AG

1969-06-18
Publication of GB1155478A
publication
Critical
patent/GB1155478A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S526/00—Synthetic resins or natural rubbers — part of the class 520 series

Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen

Abstract

1,155,478. Polymerizing ethylene with Zieglertype catalysts. FARBWERKE HOECHST A.G. 9 Aug., 1967 [9 Aug., 1966], No. 36518/67. Heading C3P. Olefin polymers are made by polymerizing ethylene alone or in admixture with up to 10%, of a higher alpha-olefin having 3 to 15 carbon atoms in solution, suspension, or the gaseous phase, at a temperature in the range of 20 to 250 C., in presence of hydrogen, and under a pressure up to 10 atmospheres and in the presence of as catalyst a mixture of from 0À05 to 0À3 millimole of a trivalent chlorine-containing compound per litre of dispersing agent or solvent, or per half litre of reaction volume, if the polymerization is carried out in the gaseous phase, and an organo-aluminium compound in amount corresponding to from 0À1 to 3À0 millimoles of aluminium equivalent per litre of dispersing agent, solvent, or reaction volume. The organoaluminium compound is selected from, (a) a compound of the formula AlR1 3 where R1 represents a C 4 to C 40 hydrocarbon radical or (b) a reaction product of a trialkylaluminium compound or an alkylaluminium hydride with a diolefin having 4 to 20 carbon atoms, e.g. triisobutyl Al and isoprene (polymeric isoprenyl aluminium). The trivalent chlorine-containing Ti-compound is preferably obtained by reducing a compound of the formula Ti(OR) 4-n Cl n where n is 1 to 4, and R represents a C 2 to C 8 hydrocarbon radical, with an alkyl Al sesquichloride, and/or a dialkyl Al monochloride, and/or isoprenyl Al at a temperature in the range of – 60 to +70C., and if desired heat-treating and washing the product. The monomers polymerized are purified with a copper catalyst. Exemplified polymers are polyethylene, and a copolymer of ethylene and butene-1.

GB36518/67A
1966-08-09
1967-08-09
Process for the manufacture of Olefin Polymers

Expired

GB1155478A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

DEF0049907

1966-08-09

Publications (1)

Publication Number
Publication Date

GB1155478A
true

GB1155478A
(en)

1969-06-18

Family
ID=7103366
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB36518/67A
Expired

GB1155478A
(en)

1966-08-09
1967-08-09
Process for the manufacture of Olefin Polymers

Country Status (17)

Country
Link

US
(1)

US3773735A
(en)

JP
(1)

JPS5318555B1
(en)

AT
(1)

AT287291B
(en)

BE
(1)

BE702473A
(en)

CA
(1)

CA919848A
(en)

CS
(1)

CS155164B2
(en)

DE
(1)

DE1595666C3
(en)

ES
(1)

ES343722A1
(en)

FI
(1)

FI46853C
(en)

FR
(1)

FR1533866A
(en)

GB
(1)

GB1155478A
(en)

NL
(1)

NL153884B
(en)

NO
(1)

NO121751B
(en)

PL
(1)

PL69858B1
(en)

SE
(1)

SE345465B
(en)

SU
(1)

SU404200A3
(en)

YU
(1)

YU31286B
(en)

Cited By (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0370372A3
(en)

*

1988-11-25
1991-10-16
Hoechst Aktiengesellschaft
Process for continuously preparing catalysts for low pressure olefin polymerization

Families Citing this family (10)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

BE757847A
(en)

*

1969-11-08
1971-04-22
Solvay

PROCESS FOR THE POLYMERIZATION OF OLEFINS

DE2361052C2
(en)

*

1973-12-07
1982-12-30
Ruhrchemie Ag, 4200 Oberhausen

Process for the polymerization of alpha-olefins having 2 to 6 carbon atoms

IT1015582B
(en)

*

1974-07-01
1977-05-20
Snam Progetti

PROCESS FOR THE POLYMERIZATION OF ETHYLENE

DE2621404C2
(en)

*

1976-05-14
1982-09-23
Ruhrchemie Ag, 4200 Oberhausen

Process for the production of high molecular weight copolymers of ethylene

DE2837481C2
(en)

*

1978-08-28
1983-08-04
Ruhrchemie Ag, 4200 Oberhausen

Process for the production of polymers of ethylene

FR2521148A1
(en)

*

1982-02-11
1983-08-12
Raffinage Cie Francaise

PROCESS FOR THE PREPARATION OF OLEFIN POLYMERIZATION CATALYSTS, CATALYSTS PREPARED BY SAID METHOD AND APPLICATION OF SAID CATALYSTS

US4593010A
(en)

*

1983-08-31
1986-06-03
Exxon Research & Engineering Co.
Polyethylene with broad molecular weight distribution

JPS60228504A
(en)

*

1984-04-26
1985-11-13
Sumitomo Chem Co Ltd
Production of olefin polymer

FR2571728B1
(en)

*

1984-10-16
1987-01-23
Atochem

TIME-IMPROVED ACTIVITY-CATALYST FOR PROPYLENE POLYMERIZATION – POLYMERIZATION PROCESS

US5206315A
(en)

*

1989-04-10
1993-04-27
Phillips Petroleum Company
Process for polymerizing 1-olefins and catalyst therefor

Family Cites Families (7)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3058963A
(en)

*

1955-04-07
1962-10-16
Hercules Powder Co Ltd
Process for polymerizing olefins

IN57789B
(en)

*

1955-07-29

DE1049584B
(en)

*

1955-07-29
1959-01-29
Hercules Powder Company,Wilmington, Del. (V. St. A.)

Process for the polymerization of olefinically unsaturated hydrocarbons

BE587292A
(en)

*

1959-02-04

AT239523B
(en)

*

1961-05-25
1965-04-12
Hibernia Chemie Ges Mit Beschr

Process for polymerizing olefins

FR1448179A
(en)

*

1964-06-23
1966-01-28
Shell Int Research

Polyolefin products and their preparation

GB1059864A
(en)

*

1964-06-23
1967-02-22
Shell Int Research
Polyolefin products and their manufacture

1966

1966-08-09
DE
DE1595666A
patent/DE1595666C3/en
not_active
Expired

1967

1967-07-25
YU
YU1484/67A
patent/YU31286B/en
unknown

1967-07-28
PL
PL1967121949A
patent/PL69858B1/en
unknown

1967-08-01
NL
NL676710626A
patent/NL153884B/en
not_active
IP Right Cessation

1967-08-02
ES
ES343722A
patent/ES343722A1/en
not_active
Expired

1967-08-05
NO
NO169272A
patent/NO121751B/no
unknown

1967-08-07
AT
AT730567A
patent/AT287291B/en
not_active
IP Right Cessation

1967-08-08
CA
CA997278A
patent/CA919848A/en
not_active
Expired

1967-08-08
FI
FI672141A
patent/FI46853C/en
active

1967-08-08
SE
SE11261/67A
patent/SE345465B/xx
unknown

1967-08-09
BE
BE702473D
patent/BE702473A/xx
not_active
IP Right Cessation

1967-08-09
FR
FR117401A
patent/FR1533866A/en
not_active
Expired

1967-08-09
CS
CS573967A
patent/CS155164B2/cs
unknown

1967-08-09
GB
GB36518/67A
patent/GB1155478A/en
not_active
Expired

1967-08-09
JP
JP5079067A
patent/JPS5318555B1/ja
active
Pending

1968

1968-12-06
SU
SU681418946A
patent/SU404200A3/ru
active

1971

1971-08-26
US
US00175319A
patent/US3773735A/en
not_active
Expired – Lifetime

Cited By (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0370372A3
(en)

*

1988-11-25
1991-10-16
Hoechst Aktiengesellschaft
Process for continuously preparing catalysts for low pressure olefin polymerization

Also Published As

Publication number
Publication date

NL153884B
(en)

1977-07-15

YU31286B
(en)

1973-02-28

FI46853C
(en)

1973-07-10

PL69858B1
(en)

1973-10-31

CS155164B2
(en)

1974-05-30

DE1595666C3
(en)

1982-06-16

SE345465B
(en)

1972-05-29

US3773735A
(en)

1973-11-20

AT287291B
(en)

1971-01-11

ES343722A1
(en)

1968-12-01

DE1595666B2
(en)

1975-06-26

FR1533866A
(en)

1968-07-19

SU404200A3
(en)

1973-10-26

JPS5318555B1
(en)

1978-06-15

NL6710626A
(en)

1968-02-12

NO121751B
(en)

1971-04-05

DE1595666A1
(en)

1970-04-30

FI46853B
(en)

1973-04-02

CA919848A
(en)

1973-01-23

BE702473A
(en)

1968-02-09

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