GB1175023A – Hydrogenation of Residuum
– Google Patents
GB1175023A – Hydrogenation of Residuum
– Google Patents
Hydrogenation of Residuum
Info
Publication number
GB1175023A
GB1175023A
GB30778/68A
GB3077868A
GB1175023A
GB 1175023 A
GB1175023 A
GB 1175023A
GB 30778/68 A
GB30778/68 A
GB 30778/68A
GB 3077868 A
GB3077868 A
GB 3077868A
GB 1175023 A
GB1175023 A
GB 1175023A
Authority
GB
United Kingdom
Prior art keywords
catalyst
liquid
range
reaction zone
phase
Prior art date
1967-11-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30778/68A
Inventor
Seymour Bernard Alpert
Ronald Howard Wolk
Michael Christopher Chervenak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hydrocarbon Research Inc
Original Assignee
Hydrocarbon Research Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1967-11-21
Filing date
1968-06-27
Publication date
1969-12-23
1967-11-21
Priority to US684700A
priority
Critical
patent/US3412010A/en
1968-06-27
Application filed by Hydrocarbon Research Inc
filed
Critical
Hydrocarbon Research Inc
1968-06-27
Priority to GB30778/68A
priority
patent/GB1175023A/en
1969-12-23
Publication of GB1175023A
publication
Critical
patent/GB1175023A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
C10G45/20—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles according to the «fluidised-bed» technique
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
C—CHEMISTRY; METALLURGY
C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
C10G45/16—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles suspended in the oil, e.g. slurries
C—CHEMISTRY; METALLURGY
C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
C10G47/26—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles suspended in the oil, e.g. slurries
C—CHEMISTRY; METALLURGY
C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
C10G47/30—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles according to the «fluidised-bed» technique
Abstract
1,175,023. Hydrocracking HYDROCARBON RESEARCH Inc. 27 June, 1968, No. 30778/68. Heading C5E. A process of hydrogenating and hydrocracking a reduced crude having at least 25 volume per cent boiling above 975‹ F. comprises (a) passing said crude at a temperature in the range of 750‹ to 900‹ F. and at a pressure in the range of 1000 to 5000 p.s.i.g. together with at least 2500 SCF/BBL of hydrogen upwardly through a reaction zone in the presence of a hydrogenation type catalyst having a narrow size range, said range falling between # inch and 325 mesh (USS), whilst (b) the flow velocities of liquid and hydrogen upwardly through the catalyst are such as to expand the bed of catalyst at least 10% over the settled state volume and to maintain the catalyst in random motion in the liquid, and (c) the space velocity of the liquid is such as to accomplish more than 50% conversion of the 975‹ F. plus boiling components in the feed and to partially remove sulphur, (d) separating the effluent from the reaction zone into a gas phase and a liquid phase, (e) fractionating the vapour phase and the liquid phase to separate out fractions boiling above 680‹ F., and (f) recycling one of said fractions to the reaction zone at a rate equivalent to at least 25 volume per cent of the feed. The catalyst may be cobalt molybdate or nickel molybdate on alumina or alumina-silica. The fraction recycled may be a 975‹ F. plus fraction or a 680‹ to 975‹ F. cut.
GB30778/68A
1967-11-21
1968-06-27
Hydrogenation of Residuum
Expired
GB1175023A
(en)
Priority Applications (2)
Application Number
Priority Date
Filing Date
Title
US684700A
US3412010A
(en)
1967-11-21
1967-11-21
High conversion level hydrogenation of residuum
GB30778/68A
GB1175023A
(en)
1967-11-21
1968-06-27
Hydrogenation of Residuum
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
US684700A
US3412010A
(en)
1967-11-21
1967-11-21
High conversion level hydrogenation of residuum
GB30778/68A
GB1175023A
(en)
1967-11-21
1968-06-27
Hydrogenation of Residuum
Publications (1)
Publication Number
Publication Date
GB1175023A
true
GB1175023A
(en)
1969-12-23
Family
ID=30117150
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB30778/68A
Expired
GB1175023A
(en)
1967-11-21
1968-06-27
Hydrogenation of Residuum
Country Status (2)
Country
Link
US
(1)
US3412010A
(en)
GB
(1)
GB1175023A
(en)
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
FR2515681A1
(en)
*
1981-11-02
1983-05-06
Hydrocarbon Research Inc
PROCESS FOR CATALYTIC HYDROGENATION CONVERSION OF CERTAIN HEAVY PETROLETS
Families Citing this family (22)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3477944A
(en)
*
1967-12-26
1969-11-11
Cities Service Res & Dev Co
Maintenance of fluid flow in heavy hydrocarbon oil hydrogenation
US3549517A
(en)
*
1968-07-23
1970-12-22
Hydrocarbon Research Inc
High conversion level hydrogenation of residuum
CA934685A
(en)
*
1969-03-19
1973-10-02
Hydrocarbon Research
High conversion hydrogenation
US3622500A
(en)
*
1970-04-21
1971-11-23
Hydrocarbon Research Inc
Hydrogenation of hydrocarbons with catalytic microspheres
US3888761A
(en)
*
1970-11-12
1975-06-10
Cities Service Res & Dev Co
H-oil process
US3862108A
(en)
*
1973-01-02
1975-01-21
Hydrocarbon Research Inc
Hydrogenation of residuum
US3972803A
(en)
*
1974-02-15
1976-08-03
Hydrocarbon Research, Inc.
Production of low sulfur fuel oil and hydrogen from petroleum residium
US4141816A
(en)
*
1977-06-29
1979-02-27
Phillips Petroleum Company
Preventing ammonium chloride deposition in hydrogen recycle stream
US4137149A
(en)
*
1977-06-29
1979-01-30
Exxon Research & Engineering Co.
Slurry hydrogen treating processes
US4433193A
(en)
*
1981-10-16
1984-02-21
Stone & Webster Engineering Corp.
Process for the production of ethane
US4457830A
(en)
*
1981-12-28
1984-07-03
Hri, Inc.
Petroleum hydroconversion using acid precipitation of preasphaltenes in resid recycle
US4457831A
(en)
*
1982-08-18
1984-07-03
Hri, Inc.
Two-stage catalytic hydroconversion of hydrocarbon feedstocks using resid recycle
US4627913A
(en)
*
1985-01-09
1986-12-09
Air Products And Chemicals, Inc.
Catalytic coal liquefaction with treated solvent and SRC recycle
US4615870A
(en)
*
1985-03-11
1986-10-07
The M. W. Kellogg Company
Back-mixed hydrotreating reactor
US4902407A
(en)
*
1988-06-09
1990-02-20
Texaco Inc.
Catalyst inventory control in an ebullated bed process
US5098552A
(en)
*
1988-06-27
1992-03-24
Texaco Inc.
Controlling foam circulation in an ebullated bed process
US5108580A
(en)
*
1989-03-08
1992-04-28
Texaco Inc.
Two catalyst stage hydrocarbon cracking process
US5211839A
(en)
*
1989-07-26
1993-05-18
Texaco Inc.
Controlling hydrogen partial pressure to yield 650 ° F.- boiling range material in an ebullated bed process
US5215653A
(en)
*
1992-03-25
1993-06-01
Texaco Inc.
Catalyst inventory control in an ebullated bed process
US5755955A
(en)
*
1995-12-21
1998-05-26
Petro-Canada
Hydrocracking of heavy hydrocarbon oils with conversion facilitated by control of polar aromatics
US6454932B1
(en)
*
2000-08-15
2002-09-24
Abb Lummus Global Inc.
Multiple stage ebullating bed hydrocracking with interstage stripping and separating
US9869432B2
(en)
2013-01-30
2018-01-16
Cree, Inc.
Luminaires using waveguide bodies and optical elements
Family Cites Families (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3151060A
(en)
*
1961-11-22
1964-09-29
Hydrocarbon Research Inc
Process and apparatus for liquid-gas reactions
US3207688A
(en)
*
1962-06-13
1965-09-21
Cities Service Res & Dev Co
Hydrocracking process in two stages employing finely divided catalyst particles
US3321393A
(en)
*
1965-05-10
1967-05-23
Hydrocarbon Research Inc
Hydrogenation of coal
1967
1967-11-21
US
US684700A
patent/US3412010A/en
not_active
Expired – Lifetime
1968
1968-06-27
GB
GB30778/68A
patent/GB1175023A/en
not_active
Expired
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
FR2515681A1
(en)
*
1981-11-02
1983-05-06
Hydrocarbon Research Inc
PROCESS FOR CATALYTIC HYDROGENATION CONVERSION OF CERTAIN HEAVY PETROLETS
Also Published As
Publication number
Publication date
US3412010A
(en)
1968-11-19
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Legal Events
Date
Code
Title
Description
1970-05-06
PS
Patent sealed [section 19, patents act 1949]
1988-02-10
PCNP
Patent ceased through non-payment of renewal fee