GB1177095A – New Asymmetric Oxalic Acid Diaryl Amides
– Google Patents
GB1177095A – New Asymmetric Oxalic Acid Diaryl Amides
– Google Patents
New Asymmetric Oxalic Acid Diaryl Amides
Info
Publication number
GB1177095A
GB1177095A
GB28783/68A
GB2878368A
GB1177095A
GB 1177095 A
GB1177095 A
GB 1177095A
GB 28783/68 A
GB28783/68 A
GB 28783/68A
GB 2878368 A
GB2878368 A
GB 2878368A
GB 1177095 A
GB1177095 A
GB 1177095A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
alkyl
substituted
compounds
oxalic acid
Prior art date
1966-02-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28783/68A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1966-02-07
Filing date
1967-02-07
Publication date
1970-01-07
1966-02-07
Priority claimed from CH167966A
external-priority
patent/CH480867A/en
1966-02-07
Priority claimed from CH168066A
external-priority
patent/CH512933A/en
1967-02-07
Application filed by Ciba AG
filed
Critical
Ciba AG
1970-01-07
Publication of GB1177095A
publication
Critical
patent/GB1177095A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
G—PHYSICS
G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
G03C1/00—Photosensitive materials
G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
G03C1/815—Photosensitive materials characterised by the base or auxiliary layers characterised by means for filtering or absorbing ultraviolet light, e.g. optical bleaching
G03C1/8155—Organic compounds therefor
A—HUMAN NECESSITIES
A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
A61K8/00—Cosmetics or similar toiletry preparations
A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
A61K8/42—Amides
A—HUMAN NECESSITIES
A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C233/00—Carboxylic acid amides
C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
C08K5/00—Use of organic ingredients
C08K5/16—Nitrogen-containing compounds
C08K5/20—Carboxylic acid amides
C—CHEMISTRY; METALLURGY
C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
C09K15/22—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen containing an amide or imide moiety
Abstract
1,177,095. Oxalic acid diarylamides. CIBA Ltd. 7 Feb., 1967 [7 Feb., 1966], No. 28783/68. Divided out of 1,177,094. Heading C2C. The invention comprises compounds of the formula where R 1 and R 2 are alkyl of 1-18 carbon atoms which may be substituted by Cl, OH, alkoxy of 1-4 carbon atoms, carboxy, CN, carboxylic acid amide or carboxylic acid alkyl ester of up to 12 carbon atoms in the alkyl moiety, alkenyl of 3-4 carbon atoms, benzyl which may be substituted by Cl or alkyl, aliphatic acyl of up to 18 carbon atoms or benzoyl which may be substituted by Cl or alkyl of 1-4 carbon atoms, R 3 and R 4 are alkyl of 1-12 carbon atoms, halogen, haloalkyl, sulphonic acid, phenyl or phenylalkyl whose alkyl residue contains 1-4 carbon atoms, or two orthopositioned residues R 3 and/or R 4 together form a fused-on six-membered aromatic carbocyclic ring, m and n are 1 or 2, p and q are 1-3, m+(n-1) = or 2, each of the two ring systems containing at most 3 substituents apart from the amide group, the substitutents being so constituted that the molecule is asymmetrical. The compounds are prepared by condensing compounds of the formulµ where A 1 is hydroxy, halogen, alkoxy of 1-12 carbon atoms, benzyloxy or phenoxy and 2 is H or R 2 at 50-250 C. and the free hydroxy groups are blocked by subsequent etherification or acylation.
GB28783/68A
1966-02-07
1967-02-07
New Asymmetric Oxalic Acid Diaryl Amides
Expired
GB1177095A
(en)
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
CH167966A
CH480867A
(en)
1966-02-07
1966-02-07
Use of asymmetric oxalic acid diarylamides as ultraviolet absorbers
CH168066A
CH512933A
(en)
1966-02-07
1966-02-07
Asymmetric oxalic acid diarylamides as uv protectors
Publications (1)
Publication Number
Publication Date
GB1177095A
true
GB1177095A
(en)
1970-01-07
Family
ID=25688360
Family Applications (2)
Application Number
Title
Priority Date
Filing Date
GB28783/68A
Expired
GB1177095A
(en)
1966-02-07
1967-02-07
New Asymmetric Oxalic Acid Diaryl Amides
GB5725/67A
Expired
GB1177094A
(en)
1966-02-07
1967-02-07
Asymmetrical Oxalic Acid Diarylamides
Family Applications After (1)
Application Number
Title
Priority Date
Filing Date
GB5725/67A
Expired
GB1177094A
(en)
1966-02-07
1967-02-07
Asymmetrical Oxalic Acid Diarylamides
Country Status (7)
Country
Link
US
(2)
US3529982A
(en)
BE
(1)
BE693605A
(en)
DE
(2)
DE1618197B1
(en)
FR
(1)
FR1516276A
(en)
GB
(2)
GB1177095A
(en)
NL
(2)
NL153595B
(en)
SE
(2)
SE346103B
(en)
Cited By (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2145716A
(en)
*
1983-08-26
1985-04-03
Ciba Geigy Ag
Pesticidal oxalyl anilides
FR2596757A1
(en)
*
1986-04-04
1987-10-09
Sandoz Sa
NOVEL DERIVATIVES OF OXALANILIDE, THEIR PREPARATION AND THEIR USE AS STABILIZERS OF POLYMERIC MATERIALS
Families Citing this family (27)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
DE1618197B1
(en)
*
1966-02-07
1971-12-09
Ciba Geigy
Use of asymmetric oxalic acid diarylamides as ultraviolet protective agents for organic materials
US3906041A
(en)
*
1968-02-19
1975-09-16
Sandoz Ltd
Oxalic acid derivatives
US3906029A
(en)
*
1969-08-28
1975-09-16
Noury & Van Der Lande
N,N{40 -bis(p-phenoxycarbophenyl)sulfondiamide
US3886117A
(en)
*
1969-08-28
1975-05-27
Koninkl Ind Mij Noury And Van
Ultraviolet light stabilizers
US3856748A
(en)
*
1971-03-18
1974-12-24
Ciba Geigy Corp
Compositions stabilized with hydroxyphenyl acylamides
IE39205B1
(en)
*
1973-04-19
1978-08-30
Ciba Geigy Ag
New stabiliser system and its use for stabilising styrene polymers
DE2516684A1
(en)
*
1975-04-16
1976-10-28
Bayer Ag
POLYARYLAMIDES, THEIR PRODUCTION AND USE AS ABSORPTION AGENTS FOR ULTRAVIOLET RAYS
DE3135810A1
(en)
*
1980-09-20
1982-04-22
Sandoz-Patent-GmbH, 7850 Lörrach
Oxamide solutions of high concentration
CH656874A5
(en)
*
1980-09-20
1986-07-31
Sandoz Ag
OXAMIDE COMPOUNDS, HIGHLY CONCENTRATED SOLUTIONS THEREOF AND THEIR USE AS STABILIZERS IN POLYMERIC ORGANIC COMPOUNDS.
US4412024A
(en)
*
1981-09-14
1983-10-25
Sandoz Ltd.
Concentrated solutions of aromatic oxamide stabilizers
JPS596254A
(en)
*
1982-07-05
1984-01-13
Mitsubishi Gas Chem Co Inc
Polyphenylene ether resin composition
US4507497A
(en)
*
1983-03-03
1985-03-26
Minnesota Mining And Manufacturing Company
Water soluble michlers ketone analogs
US4576975A
(en)
*
1983-03-03
1986-03-18
Minnesota Mining And Manufacturing Company
Water soluble Michler’s ketone analogs in combined photoinitiator composition and polymerizable composition
US4524165A
(en)
*
1983-10-24
1985-06-18
Eastman Kodak Company
Stabilized copolyesterether compositions suitable for outdoor applications
US4525504A
(en)
*
1983-10-24
1985-06-25
Eastman Kodak Company
Stabilized polyester compositions suitable for outdoor applications
US4645853A
(en)
*
1985-08-30
1987-02-24
Ici Americas Inc.
Hindered phenolic oxamide compounds and stabilized compositions
GB8626608D0
(en)
*
1986-11-07
1986-12-10
Sandoz Ltd
Organic compounds
DE3739523A1
(en)
*
1986-12-02
1988-06-16
Sandoz Ag
SUBSTITUTED OXALSAEUREDIANILIDES AND THEIR USE AS LIGHT STABILIZERS
US5085903A
(en)
*
1990-06-11
1992-02-04
Ppg Industries, Inc.
Coatings for the protection of products in light-transmitting containers
US5182148A
(en)
*
1990-06-11
1993-01-26
Ppg Industries, Inc.
Coatings and method for coloring light-transmitting containers
ES2071472T3
(en)
*
1991-04-03
1995-06-16
Ciba Geigy Ag
ASYMMETRIC DIARYLAMIDE OF OXALIC ACID.
EP0511166A1
(en)
*
1991-04-26
1992-10-28
Ciba-Geigy Ag
Process for photochemical and thermic stabilization of polyamide fibre material with a fiberaffinitive copper complex and an oxalicacid diarylamide
TW383324B
(en)
*
1994-10-13
2000-03-01
Ciba Sc Holding Ag
UV absorbants and the use
GB2361005B
(en)
2000-04-04
2002-08-14
Ciba Sc Holding Ag
Synergistic mixtures of uv-absorbers in polyolefins
EP1395548A1
(en)
*
2001-02-26
2004-03-10
4Sc Ag
Derivatives of diphenylurea, diphenyloxalic acid diamide and diphenylsulfuric acid diamide and their use as medicaments
US7074396B2
(en)
*
2003-10-22
2006-07-11
Access Business Group International Llc
Composition and method for protecting both natural and artificial hair color from ultraviolet light damage
WO2009039943A1
(en)
*
2007-09-21
2009-04-02
Sanofi-Aventis
(carboxylalkylene-phenyl)-phenyl-oxalamides, method for the production thereof, and use of same as a medicament
Family Cites Families (6)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
NL272026A
(en)
*
1960-12-06
BE619816A
(en)
*
1961-07-06
1900-01-01
DE1188080B
(en)
*
1961-07-06
1965-03-04
Ciba Geigy
Use of oxalic acid-bis-oxyarylamides as protective agents against ultraviolet radiation
US3239484A
(en)
*
1962-10-04
1966-03-08
Exxon Research Engineering Co
Stabilization of polyolefins with oxanilide and a crotonaldehyde-phenol condensation product
CH501699A
(en)
*
1965-12-08
1971-02-26
Ciba Geigy Ag
Use of symmetrical oxalic acid diarylamides as ultraviolet protection agents for organic materials outside the textile industry
DE1618197B1
(en)
*
1966-02-07
1971-12-09
Ciba Geigy
Use of asymmetric oxalic acid diarylamides as ultraviolet protective agents for organic materials
1967
1967-01-28
DE
DE1967C0041361
patent/DE1618197B1/en
active
Pending
1967-01-28
DE
DE1967C0041360
patent/DE1618196B1/en
active
Pending
1967-02-02
FR
FR93513A
patent/FR1516276A/en
not_active
Expired
1967-02-03
BE
BE693605D
patent/BE693605A/xx
not_active
IP Right Cessation
1967-02-06
SE
SE1640/67A
patent/SE346103B/xx
unknown
1967-02-06
NL
NL676701776A
patent/NL153595B/en
not_active
IP Right Cessation
1967-02-06
US
US614039A
patent/US3529982A/en
not_active
Expired – Lifetime
1967-02-06
NL
NL6701777.A
patent/NL159955C/en
not_active
IP Right Cessation
1967-02-06
SE
SE01639/67A
patent/SE347959B/xx
unknown
1967-02-07
GB
GB28783/68A
patent/GB1177095A/en
not_active
Expired
1967-02-07
GB
GB5725/67A
patent/GB1177094A/en
not_active
Expired
1970
1970-04-13
US
US28026A
patent/US3661606A/en
not_active
Expired – Lifetime
Cited By (5)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2145716A
(en)
*
1983-08-26
1985-04-03
Ciba Geigy Ag
Pesticidal oxalyl anilides
EP0138757A1
(en)
*
1983-08-26
1985-04-24
Ciba-Geigy Ag
Oxalic-acid anilides
AU583015B2
(en)
*
1983-08-26
1989-04-20
Ciba-Geigy Ag
Oxalyl anilides
TR23746A
(en)
*
1983-08-26
1990-08-01
Ciba Geigy Ag
OXALIC ACID ANILIDES.
FR2596757A1
(en)
*
1986-04-04
1987-10-09
Sandoz Sa
NOVEL DERIVATIVES OF OXALANILIDE, THEIR PREPARATION AND THEIR USE AS STABILIZERS OF POLYMERIC MATERIALS
Also Published As
Publication number
Publication date
US3661606A
(en)
1972-05-09
BE693605A
(en)
1967-08-03
NL6701777A
(en)
1967-08-08
US3529982A
(en)
1970-09-22
NL159955C
(en)
1979-09-17
FR1516276A
(en)
1968-03-08
SE347959B
(en)
1972-08-21
NL153595B
(en)
1977-06-15
NL159955B
(en)
1979-04-17
NL6701776A
(en)
1967-08-08
DE1618196B1
(en)
1971-12-09
GB1177094A
(en)
1970-01-07
SE346103B
(en)
1972-06-26
DE1618197B1
(en)
1971-12-09
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