GB1183397A – Improved Mordenite Catalyst Compositions
– Google Patents
GB1183397A – Improved Mordenite Catalyst Compositions
– Google Patents
Improved Mordenite Catalyst Compositions
Info
Publication number
GB1183397A
GB1183397A
GB44239/67A
GB4423967A
GB1183397A
GB 1183397 A
GB1183397 A
GB 1183397A
GB 44239/67 A
GB44239/67 A
GB 44239/67A
GB 4423967 A
GB4423967 A
GB 4423967A
GB 1183397 A
GB1183397 A
GB 1183397A
Authority
GB
United Kingdom
Prior art keywords
mordenite
catalyst
catalyst compositions
mordenite catalyst
platinum
Prior art date
1966-10-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB44239/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1966-10-14
Filing date
1967-09-28
Publication date
1970-03-04
1967-09-28
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co
filed
Critical
Exxon Research and Engineering Co
1970-03-04
Publication of GB1183397A
publication
Critical
patent/GB1183397A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
C10G47/12—Inorganic carriers
C10G47/16—Crystalline alumino-silicate carriers
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
B01J20/16—Alumino-silicates
B01J20/18—Synthetic zeolitic molecular sieves
B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J29/00—Catalysts comprising molecular sieves
B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
C07C4/06—Catalytic processes
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
C07C5/2206—Catalytic processes not covered by C07C5/23 – C07C5/31
C07C5/226—Catalytic processes not covered by C07C5/23 – C07C5/31 with metals
C—CHEMISTRY; METALLURGY
C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
C10G11/04—Oxides
C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2529/00—Catalysts comprising molecular sieves
C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
C07C2529/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
C07C2529/22—Noble metals
Abstract
1,183,397. Mordenite zeolite. ESSO RESEARCH & ENG. CO. 28 Sept., 1967 [14 Oct., 19661, No. 44239/67. Heading B1E. [Also in Divisions C1 and C5] A mordenite catalyst having a SiO 2 /Al 2 O 3 molar ratio of at least 55 is prepared by treating a natural or synthetic mordenite with at least 1 N acid solution at a temperature not exceeding 220‹F for at least 1 hour. The catalyst may be impregnated with a platinum group metal, i.e. Pd, Pt, Ru, Rh, Os or Ir, preferably palladium or platinum, or may be used in a matrix of clay or an inorganic oxide gel. At least part of the hydrogen content may be replaced by metal cations having properties for the catalysing of hydrocarbon conversion reactions, these include Al, Be, Ca, Ce, Cr, Mg, Mn, Sr, Zn, Ag, Au, Cu, Fe, Ni, Sb and the rare earth metals either individually or, preferably, mixed. The mordenite has large pore diameters of 6.6A and smaller ones of 2.8A.
GB44239/67A
1966-10-14
1967-09-28
Improved Mordenite Catalyst Compositions
Expired
GB1183397A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US58669566A
1966-10-14
1966-10-14
Publications (1)
Publication Number
Publication Date
GB1183397A
true
GB1183397A
(en)
1970-03-04
Family
ID=24346788
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB44239/67A
Expired
GB1183397A
(en)
1966-10-14
1967-09-28
Improved Mordenite Catalyst Compositions
Country Status (4)
Country
Link
US
(1)
US3480539A
(en)
DE
(1)
DE1667479C3
(en)
GB
(1)
GB1183397A
(en)
NL
(1)
NL160736C
(en)
Cited By (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2167430A
(en)
*
1984-11-22
1986-05-29
Intevep Sa
Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content
EP0372471A1
(en)
*
1988-12-05
1990-06-13
Research Association For Utilization Of Light Oil
Process for preparation of lower aliphatic hydrocarbons
Families Citing this family (29)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3673267A
(en)
*
1970-10-19
1972-06-27
Mobil Oil Corp
Isomerization of cyclohexane in the presence of a mordenite catalyst
US3730876A
(en)
*
1970-12-18
1973-05-01
A Sequeira
Production of naphthenic oils
US4018711A
(en)
*
1971-07-29
1977-04-19
Standard Oil Company (Indiana)
Catalytic composition
US4182692A
(en)
*
1973-12-03
1980-01-08
Norton Company
Mordenite catalyst
FR2314906A1
(en)
*
1975-06-17
1977-01-14
Erap
CATALYTIC TRANSFORMATION PROCESS OF BUTANE
FR2529100B1
(en)
*
1982-06-23
1986-10-03
Inst Francais Du Petrole
NEW HIGHLY DESALUMINATED MORDENITE-BASED CATALYST
US4500417A
(en)
*
1982-12-28
1985-02-19
Mobil Oil Corporation
Conversion of Fischer-Tropsch products
US4575417A
(en)
*
1983-03-31
1986-03-11
Texaco Inc.
Process for catalytic dewaxing with mordenite
US4536486A
(en)
*
1983-03-31
1985-08-20
Texaco Inc.
Process for dewaxing with mordenite
FR2593084B1
(en)
*
1986-01-22
1990-09-28
Inst Francais Du Petrole
CATALYST CONTAINING MORDENITY, ITS PREPARATION AND ITS APPLICATION TO THE ISOMERIZATION OF NORMAL PARAFFIN RICH CUTS.
US4665258A
(en)
*
1986-02-06
1987-05-12
Cosden Technology, Inc.
Toluene disproportionation process
US4723051A
(en)
*
1986-02-06
1988-02-02
Cosden Technology, Inc.
Xylene isomerization process
US4723049A
(en)
*
1987-05-18
1988-02-02
Cosden Technology, Inc.
Toluene disproportionation process
US4761514A
(en)
*
1987-05-18
1988-08-02
Cosden Technology, Inc.
Toluene disproportionation process
US5198595A
(en)
*
1987-11-23
1993-03-30
The Dow Chemical Company
Alkylation of aromatic compounds
US5175135A
(en)
*
1987-11-23
1992-12-29
The Dow Chemical Company
Alkylation of aromatic compounds to alkylates enriched in the linear substituted isomers
US4891448A
(en)
*
1987-11-23
1990-01-02
The Dow Chemical Company
Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers
US5243116A
(en)
*
1987-11-23
1993-09-07
The Dow Chemical Company
Alkylation of aromatic compounds
US4956511A
(en)
*
1989-01-04
1990-09-11
Fina Technology, Inc.
Toluene disproportionation process
US5952535A
(en)
*
1996-09-18
1999-09-14
Catalytica, Inc.
Selective catalytic conversion of a C9 aromatic feedstock containing substantial amounts of ethyl substituted aromatic components to a product rich in toluene and/or xylenes
FR2761905B1
(en)
*
1997-04-09
1999-05-14
Inst Francais Du Petrole
CATALYST BASED ON DEALUMINATED MORDENITY CONTAINING AT LEAST ONE METAL OF GROUPS VI, VII AND VIII, AND ITS USE IN DISMUTATION AND / OR TRANSALKYLATION OF AROMATIC HYDROCARBONS
US6803493B1
(en)
2003-08-15
2004-10-12
Fina Technology, Inc.
Toluene disproportion process
US7576249B2
(en)
*
2005-01-06
2009-08-18
Fina Technology, Inc.
Toluene disproportionation process utilizing mild sulfiding during startup
US20060211902A1
(en)
*
2005-03-16
2006-09-21
Xin Xiao
Palladium modified metal-promoted catalyst
US8349754B2
(en)
2008-03-26
2013-01-08
Council Of Scientific & Industrial Research
Modified zeolite catalyst useful for the conversion of paraffins, olefins and aromatics in a mixed feedstock into isoparaffins and a process thereof
US8063259B2
(en)
*
2008-08-18
2011-11-22
Fina Technology, Inc.
Toluene disproportionation using Nb/mordenite catalyst
US20100185035A1
(en)
*
2008-08-18
2010-07-22
Fin Technology Inc.
Nb/Mordenite Transalkylation Catalyst
US20100041933A1
(en)
*
2008-08-18
2010-02-18
Fina Technology, Inc.
Catalyst and Process for Hydrocarbon Conversions
US8546287B2
(en)
2010-05-31
2013-10-01
Fina Technology, Inc.
Rhenium promoted catalyst
Family Cites Families (4)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US2253285A
(en)
*
1938-03-29
1941-08-19
Standard Oil Dev Co
Cracking oil by leached zeolites
US2971904A
(en)
*
1957-02-12
1961-02-14
Exxon Research Engineering Co
Petroleum process catalyst supported on a molecular sieve zeolite
IT642040A
(en)
*
1959-12-30
1900-01-01
US3367884A
(en)
*
1965-12-30
1968-02-06
Mobil Oil Corp
Production and use of hydrocarbon conversion catalysts comprising acid treated crystalline aluminosilicates
1966
1966-10-14
US
US586695A
patent/US3480539A/en
not_active
Expired – Lifetime
1967
1967-09-28
GB
GB44239/67A
patent/GB1183397A/en
not_active
Expired
1967-10-13
DE
DE1667479A
patent/DE1667479C3/en
not_active
Expired
1967-10-16
NL
NL6713933.A
patent/NL160736C/en
not_active
IP Right Cessation
Cited By (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2167430A
(en)
*
1984-11-22
1986-05-29
Intevep Sa
Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content
EP0372471A1
(en)
*
1988-12-05
1990-06-13
Research Association For Utilization Of Light Oil
Process for preparation of lower aliphatic hydrocarbons
Also Published As
Publication number
Publication date
DE1667479B2
(en)
1980-08-07
DE1667479C3
(en)
1981-04-02
NL6713933A
(en)
1968-04-16
NL160736B
(en)
1979-07-16
DE1667479A1
(en)
1971-06-16
US3480539A
(en)
1969-11-25
NL160736C
(en)
1979-12-17
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Legal Events
Date
Code
Title
Description
1970-07-15
PS
Patent sealed [section 19, patents act 1949]
1983-04-27
PCNP
Patent ceased through non-payment of renewal fee