GB1297331A – – Google Patents
GB1297331A – – Google Patents
Info
Publication number
GB1297331A
GB1297331A
GB1297331DA
GB1297331A
GB 1297331 A
GB1297331 A
GB 1297331A
GB 1297331D A
GB1297331D A
GB 1297331DA
GB 1297331 A
GB1297331 A
GB 1297331A
Authority
GB
United Kingdom
Prior art keywords
styrene
substituted
isoprene
alkoxy
vinyl
Prior art date
1970-01-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1970-01-19
Filing date
1971-01-04
Publication date
1972-11-22
1971-01-04
Application filed
filed
Critical
1972-11-22
Publication of GB1297331A
publication
Critical
patent/GB1297331A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J29/00—Catalysts comprising molecular sieves
B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
B01J29/068—Noble metals
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System
C07F1/02—Lithium compounds
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
C08F12/02—Monomers containing only one unsaturated aliphatic radical
C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F2/00—Processes of polymerisation
C08F2/36—Polymerisation in solid state
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S585/00—Chemistry of hydrocarbon compounds
Y10S585/8995—Catalyst and recycle considerations
Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use
Abstract
1297331 Organolithium polymerization initiators LITHIUM CORP OF AMERICA 4 Jan 1971 [19 Jan 1970] 232/71 Heading C3P [Also in Division C2] Polymers, copolymers or block copolymers of C 4 -C 12 conjugated dienes and/or vinyl-substituted aromatic compounds are prepared by contacting the monomers in a predominantly liquid hydrocarbon medium with an initiator comprising an adduct of 1 to 100 moles of the above diene or vinyl-aromatic with 1 mole of a C 2 -C 12 alkyllithium dissolved in at least one of (a) aliphatic, cycloaliphatic and aromatic hydrocarbons, (b) aliphatic or arylalkyl tertiary monoamines and (c) aryl ethers. The adduct may particularly be of formula other adducts also being specified. The diene monomer may be halo- or alkoxy-substituted and is especially 1,3-butadiene, isoprene or piperylene. It may be block-copolymerized with vinylpyridines or vinylquinolines which may be substituted by alkyl, cycloalkyl, aryl, alkaryl, aralkyl, alkoxy, aryloxy and dialkylamino groups or with methyl acrylate, methyl methacrylate, butyl methacrylate, acrylonitrile, methacrylonitrile, N,N – dimethylacrylamide, N,N-diethylmethacrylamide, vinylfuran or N- vinylcarbazole. The vinyl-aromatic monomer may be substituted by alkyl, cycloalkyl, aryl, alkaryl, aralkyl, alkoxy, aryloxy or dialkylamino groups, many compounds being specified. It may especially be styrene, m-divinylbenzene, or 1- or 2-vinylnaphthalene and may be copolymerized with the conjugated diene to give random or block copolymers. The polymers and copolymers produced have a high proportion of 1,4 links. Polymers of styrene, butadiene and isoprene and styrene-isoprene-styrene block copolymers are included in the examples.
GB1297331D
1970-01-19
1971-01-04
Expired
GB1297331A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US412670A
1970-01-19
1970-01-19
Publications (1)
Publication Number
Publication Date
GB1297331A
true
GB1297331A
(en)
1972-11-22
Family
ID=21709291
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB1297331D
Expired
GB1297331A
(en)
1970-01-19
1971-01-04
Country Status (9)
Country
Link
US
(1)
US3668263A
(en)
AU
(1)
AU2398771A
(en)
BE
(1)
BE761691A
(en)
CA
(1)
CA987332A
(en)
DE
(1)
DE2063642A1
(en)
FR
(1)
FR2075655A5
(en)
GB
(1)
GB1297331A
(en)
NL
(1)
NL7100697A
(en)
ZA
(1)
ZA708708B
(en)
Families Citing this family (46)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3862251A
(en)
*
1970-02-11
1975-01-21
Us Navy
Organo-dilithium initiator for anionic polymerization, a novel polyisoprene, and processes for production thereof
US3954894A
(en)
*
1973-05-18
1976-05-04
Lithium Corporation Of America
Organotrilithium polymerization initiators
US3931107A
(en)
*
1973-06-21
1976-01-06
Phillips Petroleum Company
Polyalkoxy monovinylaromatic compound in copolymerization of a conjugated diene with a monovinyl-substituted aromatic compound
FR2313389A1
(en)
*
1975-06-06
1976-12-31
Anvar
NEW BI-FUNCTIONAL ORGANOLITHIAN POLYMERIZATION INITIALS AND THEIR APPLICATIONS, IN PARTICULAR FOR THE OBTAINING OF THERMOPLASTIC ELASTOMERS
US4205016A
(en)
*
1975-08-01
1980-05-27
The Dow Chemical Company
Multifunctional lithium containing initiator
CA1098913A
(en)
*
1975-08-01
1981-04-07
Lu H. Tung
Multifunctional lithium containing initiator
GB1555729A
(en)
*
1976-06-17
1979-11-14
Charbonnages Ste Chimique
Bifunctional and trifunctional organo-lithium initiators and their use
US4311818A
(en)
*
1976-06-17
1982-01-19
Societe Chimique Des Charbonnages-Cdf. Chimie
Bi- and Trifunctional organolithium initiators and applications thereof
US4179480A
(en)
*
1976-11-05
1979-12-18
Phillips Petroleum Company
Blends of cyclodiene-containing copolymers and block copolymers having improved high temperature green tensile strength
US4138536A
(en)
*
1976-12-20
1979-02-06
Phillips Petroleum Company
Polymerization of 1,3-cyclodiene with vinylaromatic hydrocarbon
US4311803A
(en)
*
1979-05-01
1982-01-19
Phillips Petroleum Company
Continuous solution polymerization process
US4297451A
(en)
*
1979-07-10
1981-10-27
Phillips Petroleum Company
Dienyllithium initiated polymers
DE2938658A1
(en)
*
1979-09-25
1981-04-09
Basf Ag, 6700 Ludwigshafen
SOLUTIONS OF BIFUNCTIONAL ORGANOLITHIUM COMPOUNDS IN NON-POLAR ORGANIC HYDROCARBONS AS SOLVENTS, METHOD FOR THE PRODUCTION OF SUCH SOLUTIONS AND THE USE THEREOF
IT1195303B
(en)
*
1981-12-22
1988-10-12
Anic Spa
MULTIFUNCTIONAL ANIONIC INITIATORS AND THEIR USE
JPS58154703A
(en)
*
1982-03-09
1983-09-14
Daicel Chem Ind Ltd
Optically active polymerization catalyst and synthesis of optically active polymer
DE3309748A1
(en)
*
1982-07-23
1984-03-01
Veb Chemische Werke Buna, Ddr 4212 Schkopau
METHOD FOR PRODUCING MULTIFUNCTIONAL POLYMERIZATION INITIATORS
US4713424A
(en)
*
1984-11-05
1987-12-15
Phillips Petroleum Company
Polymerization of olefinic hydrocarbons and complex-initiator therefor
US5780540A
(en)
*
1990-01-16
1998-07-14
Mobil Oil Corporation
Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5210359A
(en)
*
1990-01-16
1993-05-11
Mobil Oil Corporation
Vulcanizable liquid compositions
US5637783A
(en)
*
1990-01-16
1997-06-10
Mobil Oil Corporation
Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5149895A
(en)
*
1990-01-16
1992-09-22
Mobil Oil Corporation
Vulcanizable liquid compositions
US5633415A
(en)
*
1990-01-16
1997-05-27
Mobil Oil Corporation
Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5260370A
(en)
*
1990-09-21
1993-11-09
Bridgestone Corporation
Oil extended ultra high molecular weight elastomers
US5147951A
(en)
*
1990-09-21
1992-09-15
Bridgestone/Firestone, Inc.
Method for preparing ultra high molecular weight copolymers of conjugated dienes and aromatic vinyl compounds
US5080835A
(en)
*
1990-09-21
1992-01-14
Bridgestone/Firestone, Inc.
Polymetalated 1-alkyne compositions
US5272203A
(en)
*
1990-09-21
1993-12-21
Bridgestone/Firestone, Inc.
High performance tire treads and tires
EP0690075B1
(en)
1994-06-27
1999-05-06
Shell Internationale Researchmaatschappij B.V.
Process for the preparation of block copolymers using difunctional anionic polymerisation initiators
TW322493B
(en)
*
1994-06-27
1997-12-11
Shell Int Research
US5464914A
(en)
*
1994-06-29
1995-11-07
The Dow Chemical Company
Preparation of a low polydisperse polymer
DE19516563A1
(en)
*
1995-05-05
1996-11-07
Basf Ag
Process for the preparation of styrene oligomers and their use as lubricants in thermoplastics
US6306962B1
(en)
1999-09-30
2001-10-23
The Dow Chemical Company
Flow carbonate polymer blends
US6380304B1
(en)
1999-09-30
2002-04-30
The Dow Chemical Company
Mass polymerized rubber-modified monovinylidene aromatic copolymer compositions
US6380303B1
(en)
2000-02-24
2002-04-30
The Dow Chemical Company
Flow carbonate polymer blends
US20010046938A1
(en)
*
2000-03-04
2001-11-29
Halasa Adel Farhan
Synthesis of dilithium initiator
CN101045756B
(en)
*
2006-03-30
2011-01-12
北京化工大学
Preparation method of multifunction organic metal initiator for anionic polymerization
EP2158232B1
(en)
*
2007-06-07
2018-08-08
Albemarle Corporation
Low molecular weight brominated polymers and their use in thermoplastic formulations
US8993684B2
(en)
*
2008-06-06
2015-03-31
Albemarle Corporation
Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
BRPI0915818A2
(en)
*
2008-07-09
2015-08-04
Basf Se
Pesticide mixture, pesticide composition, method for controlling phytopathogenic fungi, for protecting plants from phytopathogenic fungi, for controlling insects, arachnids or nematodes, for protecting plants against insect, mite or nematode attack and infestation, and for seed protection, seed, and, use of a mixture.
EP2370383A2
(en)
*
2008-12-02
2011-10-05
Albemarle Corporation
Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom
JO3423B1
(en)
*
2008-12-02
2019-10-20
Albemarle Corp
Brominated Flame Retardants And Precursors Therefor
CN102272176A
(en)
*
2008-12-02
2011-12-07
雅宝公司
Branched and star-branched styrene polymers, telomers, and adducts, their synthesis, their bromination, and their uses
JP2012510539A
(en)
*
2008-12-02
2012-05-10
アルベマール・コーポレーシヨン
Bromination of telomer mixtures derived from toluene and styrene
JO3059B1
(en)
2009-05-01
2017-03-15
Albemarle Corp
Bromination of low molecular weight aromatic polymer compositions
MX2011011302A
(en)
2009-05-01
2011-11-18
Albemarle Corp
Pelletized low molecular weight brominated aromatic polymer compositions.
ES2633097T3
(en)
2009-06-30
2017-09-19
Bridgestone Corporation
Initiators of anionic polymerization and processes
CN104487464A
(en)
*
2012-06-26
2015-04-01
苯领欧洲股份公司
Method for producing polymers of vinyl aromatics, as well as vinyl aromatic-diene block copolymers
Family Cites Families (5)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3308170A
(en)
*
1963-08-28
1967-03-07
Nat Distillers Chem Corp
Substantially linear polydiene alcohols having majority of hydroxy groups terminal by preparing polydiene in hydrocarbon and then using ether medium during epoxide addition
US3402159A
(en)
*
1963-12-20
1968-09-17
Phillips Petroleum Co
Process for polymerizing butadiene and styrene terminated in short blocks of polystyrene
US3301840A
(en)
*
1964-09-17
1967-01-31
Phillips Petroleum Co
Preparation of polymers of conjugated dienes using organolithium/polar compound catalyst systems
US3492369A
(en)
*
1965-05-24
1970-01-27
Phillips Petroleum Co
Graft polymerizing by first lithiating in the presence of polar compounds
US3452111A
(en)
*
1966-12-09
1969-06-24
Lithium Corp
Stabilization of secondary alkyllithiums
1970
1970-01-19
US
US4126A
patent/US3668263A/en
not_active
Expired – Lifetime
1970-12-23
DE
DE19702063642
patent/DE2063642A1/en
active
Pending
1970-12-29
ZA
ZA708708A
patent/ZA708708B/en
unknown
1971
1971-01-04
GB
GB1297331D
patent/GB1297331A/en
not_active
Expired
1971-01-04
AU
AU23987/71A
patent/AU2398771A/en
not_active
Expired
1971-01-18
BE
BE761691A
patent/BE761691A/en
unknown
1971-01-18
FR
FR7101494A
patent/FR2075655A5/fr
not_active
Expired
1971-01-18
CA
CA102,960A
patent/CA987332A/en
not_active
Expired
1971-01-19
NL
NL7100697A
patent/NL7100697A/xx
unknown
Also Published As
Publication number
Publication date
BE761691A
(en)
1971-07-01
AU2398771A
(en)
1972-07-06
CA987332A
(en)
1976-04-13
FR2075655A5
(en)
1971-10-08
ZA708708B
(en)
1971-10-27
NL7100697A
(en)
1971-07-21
US3668263A
(en)
1972-06-06
DE2063642A1
(en)
1971-07-29
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Legal Events
Date
Code
Title
Description
1973-04-04
PS
Patent sealed [section 19, patents act 1949]
