GB1467693A - Creación de Inventos y Patentes con Inteligencia Artificial

GB1467693A – Polymerization process
– Google Patents

GB1467693A – Polymerization process
– Google Patents
Polymerization process

Info

Publication number
GB1467693A

GB1467693A
GB4063174A
GB4063174A
GB1467693A
GB 1467693 A
GB1467693 A
GB 1467693A
GB 4063174 A
GB4063174 A
GB 4063174A
GB 4063174 A
GB4063174 A
GB 4063174A
GB 1467693 A
GB1467693 A
GB 1467693A
Authority
GB
United Kingdom
Prior art keywords
monomer
mixture
rubber
polymer
isobaric
Prior art date
1973-09-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB4063174A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Monsanto Co

Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1973-09-19
Filing date
1974-09-18
Publication date
1977-03-16

1974-09-18
Application filed by Monsanto Co
filed
Critical
Monsanto Co

1977-03-16
Publication of GB1467693A
publication
Critical
patent/GB1467693A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00

C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes

Abstract

1467693 Graft polymerization process MONSANTO CO 18 Sept 1974 [19 Sept 1973] 40631/74 Heading C3G A bulk graft polymerization process comprises the steps: (A) charging continuously to an initial stirred isothermal reaction zone a monoalkenyl aromatic monomer having 2 to 15% by weight of a rubber dissolved therein, (B) maintaining reaction conditions in said zone having a constant fillage of from 10 to 100% of its volume with said monomer/rubber composition such as to produce a steady state polymerization of said monomer at a temperature of 110 to 140 C. under a pressure of 1À03 to 11À5 kg./cm.2 wherein 10 to 50% by weight of the monomer is polymerized to a first polymer, at least a portion of said first polymer being grafted to said rubber and the remainder being dissolved in said monomer as a monomer-polymer phase, said rubber and grafted rubber being uniformly dispersed under shearing agitation in said phase as rubber-monomer particles having a weight average diameter of 0À5 to 10 microns and having occluded therein a portion of said monomer-polymer phase, (C) withdrawing continuously from said initial reaction zone said monomer-polymer phase having rubber-monomer particles dispersed therein as a first mixture, (D) charging continuously said first mixture to the first stage of a continuous staged isobaric reaction zone having a plurality of stages so as to produce linear flow through said stages downstream to a final stage, each of said stages operating at constant gravimetric fillage of 10 to 90% of its volume of polymerizing first mixture, (E) maintaining conditions in said isobaric zone so as to polymerize said first mixture by progressive multistage linear flow polymerization, all said stages operating with shearing agitation and common evaporative vapour phase cooling under isobaric conditions in said isobaric zone, providing each said stage with steady state polymerization at controlled temperature and interfacial liquid contact, stage to stage establishing a pressure gradient from the first stage downstream to the final stage causing substantially linear flow through said isobaric zone, all said stages operating at predetermined conversion levels producing a composite polymer as a second polymer in said isobaric zone having a predetermined molecular weight distribution and average molecular weight, thereby maintaining the structural integrity of said rubbermonomer particles, said second zone producing a second mixture having a second polymer solids content determined by said multistage steady state polymerization and evaporation of said monomer, (F) withdrawing continuously said second mixture from said final stage, said second mixture comprising first and second polymer as a combined polymer, at least a portion of said first and second polymer being grafted to said diene rubber and the remainder being dissolved in said monomer-polymer phase, having 2 to 15% by weight based on the second mixture of said rubber moiety dispersed therein as grafted rubber-monomer particles having a weight average diameter of 0À5 to 10 microns and having occluded therein a portion of said monomer-polymer phase, (G) removing continuously a vapour phase evolved from said polymerizing first mixture in said isobaric zone at a rate sufficient to maintain the temperature of said first mixture at a predetermined temperature of from 130 to 180 C. and under a predetermined isobaric pressure of 0À42 to 2À04 kg./cm.2, (H) withdrawing said second mixture from said final stage at a rate approximating the total rate at which all additions are made to all stages of said continuous staged isobaric stirred reaction zone, (I) heating the said second mixture at sufficiently elevated temperatures of from 200 to 250 C. until the said grafted rubber-monomer particles are crosslinked to a predetermined swelling index of from 7 to 20 and (J) separating said polymeric solids from said second mixture volatile phase, wherein said polymeric solids comprise a polyblend of said combined polymers having dispersed therein crosslinked rubber particles having occluded and grafted first and second polymers and a weight average diameter of 0À5 to 10 microns. Examples are given in which the alkenyl aromatic monomer is styrene and the rubber is polybutadiene.

GB4063174A
1973-09-19
1974-09-18
Polymerization process

Expired

GB1467693A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US398721A

US3903202A
(en)

1973-09-19
1973-09-19
Continuous mass polymerization process for polyblends

Publications (1)

Publication Number
Publication Date

GB1467693A
true

GB1467693A
(en)

1977-03-16

Family
ID=23576532
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB4063174A
Expired

GB1467693A
(en)

1973-09-19
1974-09-18
Polymerization process

Country Status (10)

Country
Link

US
(1)

US3903202A
(en)

JP
(1)

JPS5818362B2
(en)

BE
(1)

BE820079A
(en)

CA
(1)

CA1039437A
(en)

DE
(1)

DE2444650A1
(en)

ES
(1)

ES430168A1
(en)

FR
(1)

FR2243968B1
(en)

GB
(1)

GB1467693A
(en)

IL
(1)

IL45679A
(en)

IT
(1)

IT1022089B
(en)

Families Citing this family (67)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

BE830308A
(en)

1974-06-25
1975-12-17

PROCESS FOR PREPARING AN IMPACT-RESISTANT POLYMER OF A VINYLAROMATIC COMPOUND

US4097549A
(en)

1975-12-29
1978-06-27
Monsanto Company
Polymer polyblend composition

US4125573A
(en)

1976-03-26
1978-11-14
Monsanto Company
Polymer polyblend composition

DE2613352B2
(en)

1976-03-29
1980-08-07
Basf Ag, 6700 Ludwigshafen

Process for the production of impact-resistant modified styrene polymers

US4097555A
(en)

1976-05-11
1978-06-27
Monsanto Company
Transparent polymeric polyblend

ES459128A1
(en)

1976-05-28
1978-04-01
Monsanto Co
Continuous mass polymerization process

US4185049A
(en)

1976-07-01
1980-01-22
Monsanto Company
Mass polymerization process for polyblends

US4100227A
(en)

1977-04-04
1978-07-11
The Dow Chemical Company
Transparent impact-resistant polystyrene structure

US4214056A
(en)

1978-05-19
1980-07-22
Monsanto Company
Method for preparing a monoalkenyl aromatic polyblend having a dispersed rubber phase as particles with a bimodal particle size distribution

US4146589A
(en)

1978-05-19
1979-03-27
Monsanto Company
Method for preparing a monoalkenyl aromatic polyblend having a dispersed rubber phase as particles with a bimodal particle size distribution

US4187261A
(en)

1978-05-23
1980-02-05
Standard Oil Company (Indiana)
Vinyl aromatic polymerization process

US4198383A
(en)

1978-08-21
1980-04-15
Deryagina Galina M
Apparatus for continuous preparation of acrylonitrilebutadienstyrene copolymer

DE2839563A1
(en)

1978-09-12
1980-03-27
Hoechst Ag

METHOD FOR CONTINUOUS MASS POLYMERIZATION OF ALKENYL FLAVORS

ES8103120A1
(en)

1979-03-07
1981-02-16
Monsanto Co
Process for the continuous production of polyblends derived from an alkenyl aromatic monomer and a diene rubber.

US4362850A
(en)

1979-03-07
1982-12-07
Monsanto Company
Process for the continuous polymerization of polyblends

US4254236A
(en)

1979-03-07
1981-03-03
Monsanto Company
Process for the continuous mass polymerization of polyblends having a bimodal rubber particle size

ZA803162B
(en)

1979-06-01
1981-05-27
Mobil Oil Corp
A continuous process for the preparation of rubber modified polymers

US4252911A
(en)

1979-10-17
1981-02-24
Monsanto Company
Mass polymerization process for ABS polyblends

JPS5919576B2
(en)

1979-11-01
1984-05-07
三井東圧化学株式会社

Manufacturing method of rubber modified styrenic resin

JPS56115351A
(en)

1980-02-14
1981-09-10
Mitsui Toatsu Chem Inc
Polyphenylene ether resin composition having excellent appearance

US4315083A
(en)

1980-05-15
1982-02-09
Monsanto Company
Process for the continuous mass polymerization of polyblends

DE3018643C2
(en)

1980-05-16
1982-07-08
Chemische Werke Hüls AG, 4370 Marl

Process for the production of impact-resistant modified styrene polymers

DE3023721A1
(en)

1980-06-25
1982-01-21
Basf Ag, 6700 Ludwigshafen

METHOD FOR THE CONTINUOUS PRODUCTION OF RUBBER-MODIFIED POLYMERISATS OF VINYL FLAVORS

DE3032260A1
(en)

1980-08-27
1982-04-08
Basf Ag, 6700 Ludwigshafen

PROCESS FOR THE CONTINUOUS PRODUCTION OF RUBBER-MODIFIED POLYMERISATS OF VINYLAROMATS, USE THEREOF FOR INJECTION MOLDING AND MOLDED PARTS FROM THESE POLYMERISATES

US4451612A
(en)

1980-09-22
1984-05-29
Mobil Oil Corporation
Continuous process for the preparation of rubber modified polymers

DE3047303A1
(en)

1980-12-16
1982-07-29
Basf Ag, 6700 Ludwigshafen

PROCESS FOR THE CONTINUOUS PRODUCTION OF RUBBER-MODIFIED POLYMERISATS OF VINYL FLAVORS, USE THEREOF FOR INJECTION MOLDING, AND MOLDED PARTS THEREOF

CA1173585A
(en)

1980-12-31
1984-08-28
Mobil Oil Corporation
Continuous bulk process for producing impact thermoplastics with controlled particle size

US4334039A
(en)

1981-03-23
1982-06-08
Monsanto Company
Process for preparing polymeric polyblends having a rubber phase as particles with a bimodal particle size distribution

JPS57187345A
(en)

1981-05-12
1982-11-18
Mitsui Toatsu Chem Inc
Rubber-modified styrene resin composition

JPS57187346A
(en)

1981-05-14
1982-11-18
Mitsui Toatsu Chem Inc
Improved rubber-modified styrene resin composition

USRE32217E
(en)

1982-11-12
1986-07-29
The Dow Chemical Company
Graft copolymerization process

JPS6042414A
(en)

1983-08-18
1985-03-06
Mitsui Toatsu Chem Inc
Continuous production of rubber-modified, impact-resistant resin

US4594391A
(en)

1984-05-21
1986-06-10
The Dow Chemical Company
Impact-modified monovinylidene aromatic polymer injection molding resins

JPS61109165U
(en)

1984-12-20
1986-07-10

US4680337A
(en)

1985-12-23
1987-07-14
Polysar Financial Services S.A.
Transparent impact polymers

US4772667A
(en)

1985-12-23
1988-09-20
Polysar Financial Services S.A.
Transparent impact polymers

US4777210A
(en)

1986-07-25
1988-10-11
Cosden Technology, Inc.
Continuous production of high impact polystyrene

US4857587A
(en)

1987-12-24
1989-08-15
Fina Technology, Inc.
Continuous process including recycle stream treatment for the production of high impact polystyrene

DE3844490A1
(en)

1988-12-31
1990-07-05
Basf Ag

IMPACT RESISTANT THERMOPLASTIC MOLDS AND THEIR USE

GB8918157D0
(en)

1989-08-09
1989-09-20
Dow Benelux
A process for the preparation of rubber-reinforced monovinylidene aromatic polymers

JPH0436208U
(en)

1990-07-20
1992-03-26

DE4110009A1
(en)

1991-03-27
1992-10-01
Basf Ag

METHOD FOR PRODUCING ABS COMPOSITIONS

JP2563033B2
(en)

1992-04-09
1996-12-11
三洋化成工業株式会社

Manufacturing method of composite resin

US5380822A
(en)

1992-07-27
1995-01-10
Novacor Chemicals (International) S.A.
Water assisted devolatilization

US5272231A
(en)

1992-07-28
1993-12-21
General Electric Company
Nitric oxide for vapor phase elimination of styrene and acrylonitrile popcorn polymer in bulk SAN production

US5399644A
(en)

1992-07-28
1995-03-21
General Electric Company
Sulfur dioxide for vapor phase elimination of styrene and acrylonitrile popcorn polymer in bulk san production

CA2127141A1
(en)

1993-07-19
1995-01-20
James E. Cantrill
Particle sizing

US5551859A
(en)

1993-07-19
1996-09-03
Novacor Chemicals (International) S.A.
Particulator

CA2127140A1
(en)

1993-07-19
1995-01-20
James E. Cantrill
Particulation of a metastable syrup

DE69501584T2
(en)

1994-11-21
1998-09-10
Gen Electric

Impact-modified compositions based on copolymers of alpha-alkyl vinyl aromatics and vinyl cyanide

ES2141896T3
(en)

1994-11-21
2000-04-01
Gen Electric

ALPHA-ALKYLVINYL COMPOSITION AROMATIC / VINYL CYANIDE OF MODIFIED IMPACT.

DE4445141A1
(en)

1994-12-17
1996-06-20
Basf Ag

Process for the production of impact modified polystyrene molding compounds

DE4445139A1
(en)

1994-12-17
1996-06-20
Basf Ag

Process for the production of impact modified polystyrene molding compounds

US5691445A
(en)

1996-03-28
1997-11-25
Novacor Chemicals (International) S.A.
Devolatilization

US5629383A
(en)

1996-05-10
1997-05-13
Novacor Chemicals (Internatioanal) Sa
Departiculation

US5874525A
(en)

1997-01-24
1999-02-23
Nova Chemicals Inc.
Devolatilizer tray array

US6011117A
(en)

1997-02-11
2000-01-04
Basf Corporation
High gloss, high impact polystyrene composition

US6080796A
(en)

1998-08-19
2000-06-27
Nova Chemicals Inc.
Dissolving insecticide in monomer

GB0018162D0
(en)

2000-07-26
2000-09-13
Dow Corning Sa
Polymerisation reactor and process

DE102004018283A1
(en)

2004-04-15
2005-11-03
Wacker-Chemie Gmbh

Process for the continuous production of silicone emulsions

US7615596B2
(en)

2005-09-30
2009-11-10
Chevron Phillips Chemical Company Lp
Multiple component feed methods and systems

US7488774B2
(en)

2005-12-21
2009-02-10
Fina Technology, Inc.
Reactor system for the production of high impact polystyrene

US20070142594A1
(en)

2005-12-21
2007-06-21
Fina Technology, Inc.
Horizontal boiling plug flow reactor

CA2642953A1
(en)

2006-03-20
2007-09-27
Fina Technology, Inc.
Reactor system for the production of high impact polystyrene

US20110054123A1
(en)

2009-08-26
2011-03-03
Fina Technology, Inc.
High Impact Polymers and Methods of Making and Using Same

CN110809938B
(en)

2019-11-18
2021-06-22
湖南省中医药研究院
Device and method for rapid germination of polygonatum sibiricum seeds

IT202100017519A1
(en)

2021-07-02
2023-01-02
Versalis Spa

PROCEDURE FOR THE PREPARATION OF VINYL AROMATIC POLYMERS.

Family Cites Families (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3439065A
(en)

1961-03-15
1969-04-15
Shell Oil Co
Bulk polymerization of vinyl aromatic compounds in presence of a minor amount of water

US3243481A
(en)

1962-01-08
1966-03-29
Dow Chemical Co
Process for making graft copolymers of vinyl aromatic compounds and stereospecific rubbers

US3513145A
(en)

1966-02-25
1970-05-19
Crawford & Russell Inc
Continuous mass polymerization processes

DE1770392B2
(en)

1968-05-11
1980-07-03
Basf Ag, 6700 Ludwigshafen

Process for the production of impact-resistant rubber-containing polymers

1973

1973-09-19
US
US398721A
patent/US3903202A/en
not_active
Expired – Lifetime

1974

1974-09-16
IL
IL45679A
patent/IL45679A/en
unknown

1974-09-18
GB
GB4063174A
patent/GB1467693A/en
not_active
Expired

1974-09-18
JP
JP49106818A
patent/JPS5818362B2/en
not_active
Expired

1974-09-18
ES
ES430168A
patent/ES430168A1/en
not_active
Expired

1974-09-18
CA
CA209,633A
patent/CA1039437A/en
not_active
Expired

1974-09-18
IT
IT27442/74A
patent/IT1022089B/en
active

1974-09-18
DE
DE19742444650
patent/DE2444650A1/en
not_active
Withdrawn

1974-09-18
FR
FR7431596A
patent/FR2243968B1/fr
not_active
Expired

1974-09-18
BE
BE148673A
patent/BE820079A/en
not_active
IP Right Cessation

Also Published As

Publication number
Publication date

IL45679A
(en)

1977-03-31

DE2444650A1
(en)

1975-03-20

JPS5818362B2
(en)

1983-04-12

BE820079A
(en)

1975-03-18

IT1022089B
(en)

1978-03-20

FR2243968B1
(en)

1980-11-07

CA1039437A
(en)

1978-09-26

US3903202A
(en)

1975-09-02

IL45679A0
(en)

1974-11-29

JPS5058189A
(en)

1975-05-20

AU7342874A
(en)

1976-03-25

ES430168A1
(en)

1976-10-16

FR2243968A1
(en)

1975-04-11

Información de contacto