GB1501459A

GB1501459A – Production of basic copper carbonate
– Google Patents

GB1501459A – Production of basic copper carbonate
– Google Patents
Production of basic copper carbonate

Info

Publication number
GB1501459A

GB1501459A
GB787775A
GB787775A
GB1501459A
GB 1501459 A
GB1501459 A
GB 1501459A
GB 787775 A
GB787775 A
GB 787775A
GB 787775 A
GB787775 A
GB 787775A
GB 1501459 A
GB1501459 A
GB 1501459A
Authority
GB
United Kingdom
Prior art keywords
carbonate
copper carbonate
reaction mixture
basic copper
basic
Prior art date
1974-02-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB787775A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EIDP Inc

Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1974-02-25
Filing date
1975-02-25
Publication date
1978-02-15

1975-02-25
Application filed by EI Du Pont de Nemours and Co
filed
Critical
EI Du Pont de Nemours and Co

1978-02-15
Publication of GB1501459A
publication
Critical
patent/GB1501459A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System

C07F9/94—Bismuth compounds

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds

B01J27/20—Carbon compounds

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/22—Organic complexes

B01J31/2282—Unsaturated compounds used as ligands

B01J31/2286—Alkynes, e.g. acetylides

C—CHEMISTRY; METALLURGY

C01—INORGANIC CHEMISTRY

C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F

C01G3/00—Compounds of copper

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms

C07C33/04—Acyclic alcohols with carbon-to-carbon triple bonds

C07C33/042—Acyclic alcohols with carbon-to-carbon triple bonds with only one triple bond

C07C33/044—Alkynediols

C07C33/046—Butynediols

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System

C07F1/08—Copper compounds

Abstract

1501459 Basic copper carbonate EI DU PONT DE NEMOURS & CO 25 Feb 1975 [25 Feb 1974] 7877/75 Heading C1A [Also in Divisions Bl and C2] Agglomerates of crystalline particles of basic copper carbonate having uniformly dispersed therein bismuth in amounts in the range of 1-5% by weight based on the amount of copper present are prepared by a process comprising the following steps: precipitating hydrated copper carbonate particles by the simultaneous addition to water of solutions of cupric salts and alkali metal carbonate or bicarbonate to form a reaction mixture, said solutions being in such proportions as to maintain the pH in the range of 5À0 to 8À0, nucleating and converting the hydrated copper carbonate to basic copper carbonate in the reaction mixture at a temperature of at least 60‹ C., and growing agglomerates of the nucleated crystalline particles by precipitating basic copper carbonate containing bismuth by the addition to the reaction mixture of solutions of cupric salts, bismuth salts and alkali metal carbonate or bicarbonate in such proportions as to maintain the pH in the range 5À0 to 8À0 with the reaction mixture at a temperature of at least 60‹ C. until the average cross-sectional dimension of the agglomerate of crystallites is at least 10 microns. A particulate cuprous acetylide complex having the general formula wherein w=4, x = 0À24-4À0, y=0À24-2À40 and z = 0À67-2À80 and the Bi is present in an amount of 2-5% by weight based on the amount of copper present, and having a total surface area of at least 5 m.2/g. and average particle size of at least 10 Á is produced by subjecting the basic carbonate as a slurry in aqueous medium at 50-120‹ C. to the simultaneous action of formaldehyde and acetylene at a partial pressure of not more than 2 atmospheres, the aqueous medium having a pH of 3-10 at the start of the reaction.

GB787775A
1974-02-25
1975-02-25
Production of basic copper carbonate

Expired

GB1501459A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US44547674A

1974-02-25
1974-02-25

Publications (1)

Publication Number
Publication Date

GB1501459A
true

GB1501459A
(en)

1978-02-15

Family
ID=23769056
Family Applications (2)

Application Number
Title
Priority Date
Filing Date

GB787775A
Expired

GB1501459A
(en)

1974-02-25
1975-02-25
Production of basic copper carbonate

GB1296178A
Expired

GB1555297A
(en)

1974-02-25
1978-04-03
Production of basic copper carbonate

Family Applications After (1)

Application Number
Title
Priority Date
Filing Date

GB1296178A
Expired

GB1555297A
(en)

1974-02-25
1978-04-03
Production of basic copper carbonate

Country Status (7)

Country
Link

JP
(2)

JPS594380B2
(en)

BE
(1)

BE825446A
(en)

DE
(2)

DE2560545C2
(en)

FR
(2)

FR2264034B1
(en)

GB
(2)

GB1501459A
(en)

IT
(1)

IT1033129B
(en)

NL
(1)

NL183087C
(en)

Cited By (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US4406865A
(en)

1978-12-15
1983-09-27
Exxon Research And Engineering Co.
Metal extraction by solid-liquid agglomerates

CN111589836A
(en)

*

2019-09-16
2020-08-28
徐光耀
Method for treating waste containing acetylides

CN111747439A
(en)

*

2020-07-13
2020-10-09
泰兴冶炼厂有限公司
Preparation process of ultra-pure basic copper carbonate

CN114873653A
(en)

*

2022-05-11
2022-08-09
金驰能源材料有限公司
Basic cobalt carbonate and preparation method thereof

CN115703647A
(en)

*

2021-08-06
2023-02-17
阮氏化工(常熟)有限公司
Method for continuously producing basic copper carbonate by using acidic etching waste liquid

Families Citing this family (7)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

CA1096134A
(en)

*

1976-08-05
1981-02-24
Joseph M. Fremont
Preparation of bismuth-modified spheroidal malachite

DE3417629C1
(en)

*

1984-05-12
1985-01-24
Th. Goldschmidt Ag, 4300 Essen

Process for the production of basic copper carbonate

JPS60252078A
(en)

*

1984-05-30
1985-12-12
Mitsubishi Motors Corp
Device for conveying and positioning vehicle windshield

JPH0311107Y2
(en)

*

1986-02-21
1991-03-18

JPH0447026Y2
(en)

*

1986-03-10
1992-11-06

DE102005042185A1
(en)

*

2005-09-06
2007-03-08
Basf Ag

Process for the separation of polymeric by-products from 1,4-butynediol

CN102171175B
(en)

*

2008-10-07
2014-05-14
日本曹达株式会社
Method for producing tetrafluoro compound

Family Cites Families (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US2300969A
(en)

*

1939-09-07
1942-11-03
Gen Aniline & Film Corp
Production of alkinols

US3650985A
(en)

*

1967-10-23
1972-03-21
Du Pont
Ethynylation catalyst catalyst preparation and process

1975

1975-02-12
BE
BE153285A
patent/BE825446A/en
not_active
IP Right Cessation

1975-02-24
NL
NL7502177A
patent/NL183087C/en
not_active
IP Right Cessation

1975-02-24
IT
IT2058475A
patent/IT1033129B/en
active

1975-02-24
FR
FR7505627A
patent/FR2264034B1/fr
not_active
Expired

1975-02-25
DE
DE19752560545
patent/DE2560545C2/en
not_active
Expired

1975-02-25
JP
JP2250175A
patent/JPS594380B2/en
not_active
Expired

1975-02-25
DE
DE19752508084
patent/DE2508084C2/en
not_active
Expired

1975-02-25
GB
GB787775A
patent/GB1501459A/en
not_active
Expired

1975-07-18
FR
FR7522506A
patent/FR2330647A1/en
active
Granted

1978

1978-04-03
GB
GB1296178A
patent/GB1555297A/en
not_active
Expired

1983

1983-07-15
JP
JP12805183A
patent/JPS5931720A/en
active
Granted

Cited By (7)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US4406865A
(en)

1978-12-15
1983-09-27
Exxon Research And Engineering Co.
Metal extraction by solid-liquid agglomerates

CN111589836A
(en)

*

2019-09-16
2020-08-28
徐光耀
Method for treating waste containing acetylides

CN111747439A
(en)

*

2020-07-13
2020-10-09
泰兴冶炼厂有限公司
Preparation process of ultra-pure basic copper carbonate

CN111747439B
(en)

*

2020-07-13
2023-08-29
泰兴冶炼厂有限公司
Preparation process of ultra-high sodium carbonate copper carbonate

CN115703647A
(en)

*

2021-08-06
2023-02-17
阮氏化工(常熟)有限公司
Method for continuously producing basic copper carbonate by using acidic etching waste liquid

CN114873653A
(en)

*

2022-05-11
2022-08-09
金驰能源材料有限公司
Basic cobalt carbonate and preparation method thereof

CN114873653B
(en)

*

2022-05-11
2023-10-13
金驰能源材料有限公司
Basic cobalt carbonate and preparation method thereof

Also Published As

Publication number
Publication date

NL183087C
(en)

1988-07-18

FR2264034A1
(en)

1975-10-10

NL183087B
(en)

1988-02-16

IT1033129B
(en)

1979-07-10

FR2264034B1
(en)

1981-06-26

JPS594380B2
(en)

1984-01-30

JPS50119797A
(en)

1975-09-19

DE2508084C2
(en)

1984-06-07

GB1555297A
(en)

1979-11-07

NL7502177A
(en)

1975-08-27

JPS6113691B2
(en)

1986-04-15

FR2330647A1
(en)

1977-06-03

FR2330647B1
(en)

1981-06-26

DE2508084A1
(en)

1975-08-28

DE2560545C2
(en)

1986-05-07

JPS5931720A
(en)

1984-02-20

BE825446A
(en)

1975-08-12

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Legal Events

Date
Code
Title
Description

1978-06-28
PS
Patent sealed

1993-10-20
PCNP
Patent ceased through non-payment of renewal fee

Effective date:
19930225

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