GB1565712A - Creación de Inventos y Patentes con Inteligencia Artificial

GB1565712A – Wall-mounted burner assembly for raising the temperature of an exhaust gas stream
– Google Patents

GB1565712A – Wall-mounted burner assembly for raising the temperature of an exhaust gas stream
– Google Patents
Wall-mounted burner assembly for raising the temperature of an exhaust gas stream

Download PDF
Info

Publication number
GB1565712A

GB1565712A
GB15690/77A
GB1569077A
GB1565712A
GB 1565712 A
GB1565712 A
GB 1565712A
GB 15690/77 A
GB15690/77 A
GB 15690/77A
GB 1569077 A
GB1569077 A
GB 1569077A
GB 1565712 A
GB1565712 A
GB 1565712A
Authority
GB
United Kingdom
Prior art keywords
fuel
inner liner
burner assembly
duct
air
Prior art date
1976-04-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB15690/77A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1976-04-16
Filing date
1977-04-15
Publication date
1980-04-23

1977-04-15
Application filed by General Electric Co
filed
Critical
General Electric Co

1980-04-23
Publication of GB1565712A
publication
Critical
patent/GB1565712A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING

F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES

F23D—BURNERS

F23D17/00—Burners for combustion conjointly or alternatively of gaseous or liquid or pulverulent fuel

F23D17/002—Burners for combustion conjointly or alternatively of gaseous or liquid or pulverulent fuel gaseous or liquid fuel

Description

PATENT SPECIFICATION ( 11) 1 565 712
e ( 21) Application No 15690/77 ( 22) Filed 15 Apr1977 ( 19) A b ( 31) Convention Application No 677723 ( 32) Filed 16 Apr 1976 in ( 33) United States of America (US)
Q ( 44) Complete Specification Published 23 Apr 1980
0 ( 51) INT CL F 23 D 17/00 ( 52) Index at Acceptance F 4 T AL ( 72) Inventor: SOTIRIS LAMBIRIS ( 54) WALL-MOUNTED BURNER ASSEMBLY FOR RAISING THE TEMPERATURE OF AN EXHAUST GAS STREAM ( 71) We, GENERAL ELECTRIC COMPANY, a corporation organized and existing under the laws of the State of New York, United States of America, of 1 River Road, Schenectady 12305, State of New York, United States of America, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement: 5
This invention relates to a wall-mounted burner assembly raising the temperature of an exhaust gas stream.
One particular application for the present invention is found in that portion of a combined cycle power plant referred to as a heat recovery steam, generator (HRSG) A HRSG is a generally vertical free standing duct which envelops a boiler tube bundle whereby gas turbine 10 exhaust gases are channeled through the duct in a heat exchange relationship with fluid in the tube bundle in order to raise the temperature of the tube bundle fluid to generate steam for driving a steam turbine It is sometimes desirable to raise the temperature of the exhaust gas flow upstream from the tube bundle by using burners in which case the HRSG is referred to as being «fired» One example of a fired HRSG is given in U S Patent 3,830, 620 to Frederick J 15 Martin issued August 20, 1974 The Martin patent shows a grid burner system which includes a network of fuel supplied burner pipes which are disposed within and across the cross-section area of the HRSG duct Each pipe includes a plurality of fuel outlet ports on the downstream (with respect to the exhaust gas flow) surfaces of the pipes Fuel is delivered to the outlet ports through the grid pipes and ignited by pilot burners mounted transversely to the grid pipes and 20 downstream therefrom.
One inherent limitation in grid burner systems is the type of fuels which can be burned in order to avoid pipe clogging Grid burner systems, in general, require natural gas or distillate fuels for operation Grid burner systems are expensive to manufacture and install Moreover, grid burner systems are also difficult to maintain 25 A contributing factor to the aforementioned grid burner disadvantages is that the grid system is disposed within the HRSG where the hot flowing gases may cause decomposition of liquid fuels An alternative solution to the grid burner system is a wall mounted burner which is located outside the exhaust gas duct A wall burner shoots its flame into the duct through a port formed in one of the duct walls Hence, the wall burner is not subject to clogging and is 30 available for easy maintenance One example of a prior art wall burner is given in U S Patent
3,367,384 to Voorheis issued February 6, 1968 The Voorheis burner is a liquid fuel burner wherein the totality of the fuel is supplied from a liquid fuel nozzle located upstream from a pre-main combustion chamber.
According to the invention, there is provided a wall-mounted burner assembly for raising 35 the temperature of an exhaust gas stream flowing through a duct, the burner assembly being arranged to be mounted substantially transverse to the exhaust gas flow outside the duct for communication with the exhaust gas stream through a porthole in the duct, the burner assembly comprising:
a substantially cylindrical outer casing having a downstream end arranged to be mounted 40 adjacent the duct; a substantially cylindrical perforate inner liner disposed within the outer casing; the inner liner and the outer casing having an annular chamber therebetween; means providing pressurized air into the inner liner; means providing a relatively small amount of fuel into the inner liner for mixing with the air 45 2 1,565,712 2 to form a combustible mixture; means for igniting the fuel and air mixture in said inner liner; accelerator means at the downstream end of the inner liner for accelerating the fuel and air mixture; and; 5 fuel ports on the downstream side of the accelerator means for supplying a relatively large amount of fuel into the ignited mixture so as to cause the combustion process to be continued in the exhaust gas duct when the apparatus is mounted on the duct.
Such a burner may be in the form of a dual fuel universal burner capable of operating efficiently on both liquid hydrocarbon fuels including heavier commercial grades (No 6 oil) 10 and gaseous fuels including low calorific content fuels Such a burner assembly is also simple to construct and is capable of being scaled in size to match more efficiently varying system design requirements.
The invention will be further described, by way of example, with reference to the accompanying drawings, in which: 15 Figure 1 is a partially sectioned elevation view of a wall burner constituting a preferred embodiment of the present invention; and Figure 2 is an end view of the wall burner of Figure 1 taken at the wall mounting flanges and looking into the burner.
As shown in the appended drawings, a wall mounted burner 11 is arranged to fire into a 20 duct 13 through a port-hole 15 formed in the duct wall 17 The duct may be part of a Heat Recovery Steam Generator (HRSG) wherein a gas stream flowing through the duct is heated by one or more wall burners in order to provide heat to a boiler tube section (not shown) disposed downstream from the burners with respect to the gas stream flow and in the heated gas flow path Such an arrangement is shown, for example, in U S Patent 3, 934,553 to 25 Freeman et al issued January 27, 1976 A frustro-conical diffuser and heat shield 19 is fixed to the duct wall immediately downstream from the porthole 15 and a suitable heat insulation 21 is supplied between the heat shield 19 and the duct wall 17.
The wall burner 11 includes a substantially cylindrical outer casing 23 A substantially cylindrical inner liner 25 is mounted within the outer casing having a centerline axis which is 30 approximately coincident with the centerline axis of the outer casing The inner liner volume 31 constitutes a pre-main combustion chamber The inner liner is spaced from the outer liner so as to define an annular chamber 33 there between The inner liner is perforate, that is, formed with a plurality of ports 35 which may be arranged in circular rows along the length of the inner liner The outer casing further includes an air inlet conduit 37 which may be 35 connected to a source of pressurized air The air inlet conduit, the annular chamber and the perforated inner liner comprise a means for providing pressurized air into the premain combustion chamber The source of pressurized air may be any air compressor well known in the art.
The wall burner further includes means providing a relatively small amount of fuel, 40 optimally one to two percent of the total fuel requirement, into the inner liner or pre-main combustion chamber The means for providing fuel into the inner liner may be a gaseous fuel nozzle, a liquid fuel nozzle or a dual fuel nozzle In a preferred embodiment shown, the fuel providing means is a dual fuel nozzle 41 The dual fuel nozzle 41 comprises a liquid fuel pipe 43 concentrically mounted within an outer pipe 45 to form an annular space 47 therebet 45 ween Annular space 47 may be supplied with either gaseous fuel during gaseous fuel operation or atomizing air during liquid fuel operation Inlet boss 49 is formed on the outer pipe to provide fluid communication into annular space 47 A swirler ring 51 is provided at the outlet end of the dual fuel nozzle having an outer circumference attached to the outer pipe and an inner circumference attached to the inner or liquid fuel pipe 43 A liquid fuel nozzle 53 50 is screwed into the outlet end of the liquid fuel pipe whereas the swirler ring includes a plurality (only one shown) of ports 55 Ports 55 are directed radially inwardly toward the burner centerline axis, and tangentially sidewise to induce swirl within the through flowing gases (air or gaseous fuel).
An ignitor in the form of a spark plug 61 is screwed into the inner liner 25 through an 55 opening 65 formed in the outer casing The spark plug and its associated electrical lead 67 provides a means for igniting a combustible mixture comprising gaseous fuel and air or liquid fuel and air formed in the pre-main combustion chamber 31.
An accelerator means is disposed at the downstream end of the pre-main combustion chamber between the duct wall and the outer casing and inner liner The accelerator means 60 comprises an accelerator ring 71 which includes a hyperbolic nozzle at its inner circumference The accelerator ring is attached to the wall of the HRSG in approximate register with port 15 by means of mounting bracket lugs 73 A mounting ring 75 is used for attaching the outer casing to mounting bracket lugs 73 whereas the downstream end of the inner liner is attached to the accelerator ring by means of screws 77 65 3 1,565,712 3 The burner further includes main fuel ports on the downstream side of the accelerator ring.
Referring to Figure 2, taken in connection with Figure 1, and according to a preferred embodiment of the invention, a first set of fuel ports 81 is arranged in a circular pattern on the downstream side of the accelerator ring for injecting gaseous fuel into the accelerating combusting mixture being diffused from the accelerator ring The gaseous fuel is delivered to 5 fuel ports 81 from a gas manifold 83 through conduits 85 The gaseous fuel ports 81 are directed inwardly toward the centerline axis of the burner Further, according to a preferred embodiment of the invention, a second set of fuel ports 91 is arranged in a circular pattern on the downstream side of the accelerator ring Fuel ports 91 are liquid fuel ports for injecting liquid fuel into the accelerating combusting mixture being diffused from the accelerator ring 10 The liquid fuel is delivered to fuel ports 91 from a liquid fuel manifold 93 through conduits The liquid fuel ports 91 are directed inwardly toward the centerline axis of the burner.
While the foregoing described embodiment shows the most universal aspect of the invention, it should be clear that either the gaseous fuel ports and associated fuel delivery apparatus or the liquid fuel ports and associated fuel delivery apparatus could be eliminated to convert the 15 preferred dual fuel burner into either a liquid fuel burner or a gaseous fuel burner Optimally about ninety-nine or ninety-eight percent of the total fuel requirement is delivered through these main fuel ports.
The nozzle portion of the accelerator ring is air cooled by means of a plurality (only one shown) of cooling holes 99 which communicate the annular chamber 33, filled with compres 20 sed air, with the nozzle surface of the accelerator ring Moreover, the accelerator ring is further air cooled by passages 97 which pass through the accelerator ring to the downstream side of the ring in communication with annular chamber 33 This air also purges the downstream side of the accelerator ring and eliminates any stagnation of recirculation gases in that region Also, the injection of the main fuel (gaseous or liquid) through the accelerator 25 ring provides additional cooling of the nozzle ring.
The fundamental combustion design of the burner inherently minimizes air pollution emissions during combustion However, the design provides easy access for installation of an auxiliary injection system for air, steam and/or other emission reducing additives For example, cooling air passages 97 may be utilized for providing auxiliary air injection for 30 emission control Alternatively, the gaseous fuel injection system may be used for emission reducing additives for operation with liquid fuels.
With the foregoing description and drawings in mind, the following describes the general principles of operation of the burner:
A small amount of the total required fuel passes into the pre-main combustion chamber 31 35 through dual fuel nozzle 41 The percentage fuel passing into the chamber 31 is preferably in the range of from one to five percent of the total burner fuel requirement The optimum range is one to two percent If the burner is operating on gaseous fuel, the gaseous fuel enters chamber 31 through swirler ports 55 If the burner is operating on liquid (oil) fuel the liquid fuel enters chamber 31 through the liquid fuel nozzle 53 In combination with liquid fuel 40 operation, atomizing air is introduced into the pre-main combustion chamber through swirler ports 55 Although it is not specifically shown, it is well known that either air or gaseous fuel may pass into annular space 47 by providing a three way valve connection upstream from inlet boss 49.
A quantity of oxidizer, proportionate to the inlet fuel through nozzle 41, also passes into 45 chamber 31 as provided from an external source (not shown) through conduit 37, annular chamber 33 and perforated liner 25 The oxidizer may be, for example, air at the same inlet conditions as used for atomizing air in the dual fuel nozzle Since only a small amount of fuel is injected into the pre-main combustion chamber only a correspondingly small amount of auxiliary air is necessary thereby reducing the combustion air requirements heretofore 50 necessary in the prior art.
An energy source as, for example, spark plug 61 supplies a spark for initiating combustion of the combustible mixture formed in chamber 31 The spark plug may be a regular automotive type spark plug and is only required to operate at start-up and the energy supply may be terminated once steadystate combustion is achieved Usually, the desired air-flow is 55 first established through the inner liner volume followed by initiation of the electric spark discharge Immediately thereafter, fuel flow is established in the premain combustion chamber Within the pre-main combustion chamber, fuel and air mix at appropriate rates and the resulting combustible mixture ignites initially by means of the electric spark discharge energy and later by the inherent heat energy contained in the product of combustion 60 recirculating gases adjacent the dual fuel nozzle port of the inner liner.
The ignited combusting mixture expands through the nozzle portion of the accelerator ring 71 which converts the pressure potential energy of the hot combusting mixture within the inner liner into a highly reactive jet with high velocity and momentum Upon formation of the combusting jet, the main fuel injection process is initiated The major portion of the total fuel 65 4 1,565,712 4 required, for example, ninety-five to ninety-nine percent, optimally ninety-nine or ninetyeight percent, may be injected through main fuel ports 81 or 91 on the downstream side of the accelerator ring The gaseous fuel flows through pipes 85 into ports 81 to be injected as high velocity jets towards the combusting mixture exhausting from the accelerator ring If the main fuel is liquid (oil) fuel, the liquid fuel flows through pipes 95 into ports 91 to be injected 5 as high velocity jets towards the combusting mixture exhausting from the accelerator ring.
The main fuel (liquid or gaseous) is blasted into fragments as soon as it is intercepted by the combusting mixture jet.
Heat and momentum are exchanged from the combusting mixture to the main fuel fragments during the time of contact and interaction between these two flowing components 10 As a result of the physical-chemical processes, the fuel fragments ignite and accelerate to a high velocity which carries them into the exhaust gas stream wherein the main combustion takes place Combustion of the fuel fragments continues as they penetrate deeper and deeper into the exhaust gas stream, until all fuel fragments burn out using the oxygen of the exhaust gas stream 15 The combustion system of a fired HRSG may comprise one or more wall burners mounted in various strategic locations on the exterior walls of the HRSG on the basis of size, firing requirements and overall design criteria It is conceivable that flame holding devices may be utilized within the exhaust gas stream to enhace the flame penetration, distribution and stability One example of a suitable flame holder is shown in U S Patent 3, 934,553 to 20 Freeman et al issued January 27, 1976.
Typical operational conditions of the burner may vary depending upon the application.
However, according to tests conducted the following parameters were utilized:
25 Inner Liner: (Pre-Main Combustion Chamber) Ignition: Air Flow Range 30 to 50 SCFM Inlet Air Pressure 1 5 to 3 5 PSIG 30 Fuel Flow 3 to 4 GP Hour Inlet Fuel Pressure 100 to 150 PSIG 35 Regular Operation: Air Flow Range 30 to 350 SCFM Inlet Air Pressure Range 3 to 30 PSIG Fuel Flow 3 to 6 GP Hour 40 Inlet Fuel Pressure 70 to 300 PSIG Main Fuel:
45 Pressure Flow Rate Natural Gas 0 to 25 PSIG 0 to 27,000 SCF/HR #2 Oil O to 300 PSIG O to 6 66 GPM 50 #6 Oil O to 150 PSIG O to 5 5 GPM

Claims (1)

WHAT WE CLAIM IS: 55
1 A wall-mounted burner assembly for raising the temperature of an exhaust gas stream flowing through a duct, the burner assembly being arranged to be mounted substantially transverse to the exhaust gas flow outside the duct for communication with the exhaust gas stream through a porthole in the duct, the burner assembly comprising:
a substantially cylindrical outer casing having a downstream end arranged to be mounted 60 adjacent the duct; a substantially cylindrical perforate inner liner disposed within the outer casing; the inner liner and the outer casing having an annular chamber therebetween; means providing pressurized air into the inner liner; means providing a relatively small amount of fuel into the inner liner for mixing with the air 65 1,565,712 5 to form a combustible mixture; means for igniting the fuel and air mixture in said inner liner; accelerator means at the downstream end of the inner liner for accelerating the fuel and air mixture; and; fuel ports on the downstream side of the accelerator means for supplying a relatively large 5 amount of fuel into the ignited mixture so as to cause the combustion process to be continued in the exhaust gas duct when the apparatus is mounted on the duct.
2 A burner assembly according to claim 1, wherein the means providing pressurized air into the inner liner includes a source of pressurized air in fluid communication with said annular chamber; and, 10 a plurality of ports arranged in said inner liner for admitting pressurized air into said inner liner.
3 A burner assembly according to claim 1 or claim 2, wherein the means for supplying a relatively small amount of fuel comprises a dual fuel nozzle at the upstream end of the inner liner 15 4 A burner assembly according to claim 3, wherein the dual fuel nozzle may be selectively operated with gaseous fuel and liquid fuel; said dual fuel nozzle comprising:
a liquid fuel pipe having a liquid fuel nozzle at the downstream end thereof; an outer pipe concentrically mounted about said liquid fuel pipe so as to define an annular space therebetween; 20 a swirler ring mounted at the downstream end of said outer pipe between said liquid fuel pipe and said outer pipe, whereby during gaseous fuel operation, gaseous fuel is supplied to said inner liner through said annular space and said swirler ring; and, during liquid fuel operation, liquid fuel is supplied to said inner liner through said liquid fuel nozzle and pressurized air is supplied to said inner liner through said annular space and said swirler ring 25 A burner assembly according to any one of the preceding claims, wherein the accelerator means comprises a substantially hyperbolic nozzle ring arranged to be disposed between the downstream end of the inner liner and the duct porthole, the centerline axis of the nozzle ring being substantially coincident with the centerline axis of the inner liner.
6 A burner assembly according to claim 5, further comprising a plurality of circumferen 30 tially spaced air holes communicating the annular chamber with the curved inner circumference of the accelerator nozzle ring.
7 A burner assembly according to any one of the preceding claims, further comprising gaseous fuel ports and liquid fuel ports on the downstream side of the accelerator means whereby liquid fuel and gaseous fuel may be selectively injected into the accelerating flow of 35 the combusting fuel and air mixture.
8 A burner assembly according to any one of the preceding claims, further comprising a plurality of air channels interconnecting the annular chamber with the downstream side of said accelerator means, said air channels extending through said accelerator means.
9 A burner assembly according to any one of the preceding claims, wherein the relatively 40 small amount of fuel into the inner liner is in the range of from 1 to 5 percent of the total fuel consumption of the apparatus.
A burner assembly according to any one of the preceding claims, wherein the relatively large amount of fuel from the downstream fuel ports is in the range of from 95 to 99 percent of the total fuel consumption of the apparatus 45 11 A wall-mounted burner assembly for raising the temperature of an exhaust gas stream flowing through a duct, substantially as hereinbefore described with reference to and as shown in the accompanying drawings.
12 A combination of a duct for an exhaust gas stream and a burner assembly according to any one of the preceding claims for raising the temperature of the gas stream 50 J A BLEACH Agent for the Applicants Printed for Her Majesty’s Stationery Office by Croidon Printing Company Limited Croydon, Surrey 1980.
Published by The Patent Office 25 Southampton Bttddings London WC 2 A IA Yfrom which cope, may be obtained.

GB15690/77A
1976-04-16
1977-04-15
Wall-mounted burner assembly for raising the temperature of an exhaust gas stream

Expired

GB1565712A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US05/677,723

US4063872A
(en)

1976-04-16
1976-04-16
Universal burner

Publications (1)

Publication Number
Publication Date

GB1565712A
true

GB1565712A
(en)

1980-04-23

Family
ID=24719870
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB15690/77A
Expired

GB1565712A
(en)

1976-04-16
1977-04-15
Wall-mounted burner assembly for raising the temperature of an exhaust gas stream

Country Status (8)

Country
Link

US
(1)

US4063872A
(en)

JP
(1)

JPS5828490B2
(en)

CA
(1)

CA1061700A
(en)

DE
(1)

DE2716460C2
(en)

FR
(1)

FR2348436A1
(en)

GB
(1)

GB1565712A
(en)

MX
(1)

MX143371A
(en)

NL
(1)

NL179680C
(en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2136553B
(en)

1983-03-11
1986-02-12
British Gas Corp
Burner

AT391195B
(en)

1987-09-21
1990-08-27
Vaillant Gmbh

METHOD FOR BURNING LIQUID OR GASEOUS FUELS AND DEVICE FOR CARRYING OUT THE METHOD

US8955329B2
(en)

2011-10-21
2015-02-17
General Electric Company
Diffusion nozzles for low-oxygen fuel nozzle assembly and method

Family Cites Families (8)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

FR1286095A
(en)

1961-01-21
1962-03-02
Siderurgie Fse Inst Rech

Burner capable of consuming two different fuels to produce a flame with a high calorific concentration stabilized by shock wave

US3179151A
(en)

1962-03-15
1965-04-20
Zink Co John
Fluid fuel burner assembly

DE1401835B2
(en)

1962-11-16
1970-02-19
Dr. Schmitz & Apelt, Industrieofenbau GmbH, 5600 Wuppertal-Langerfeld

Dual fuel burner

US3367384A
(en)

1966-05-09
1968-02-06
James T. Voorheis
Methods for burning fuel, burners and systems for burning fuels and apparatus in which said burners and/or systems are parts thereof

US3376098A
(en)

1966-08-29
1968-04-02
Phillips Petroleum Co
Two-chamber burner and process

US3545918A
(en)

1968-02-21
1970-12-08
Ajem Lab Inc
Afterburner system for cupola furnace

US3929828A
(en)

1974-11-21
1975-12-30
Moore Business Forms Inc
3{40 -Amino-6{40 {0 or 7{40 -(pyrazol-1-yl)fluoran compounds

US3934553A
(en)

1975-01-06
1976-01-27
General Electric Company
Combined wall burner and flameholder for HRSG

1976

1976-04-16
US
US05/677,723
patent/US4063872A/en
not_active
Expired – Lifetime

1977

1977-02-22
NL
NLAANVRAGE7701903,A
patent/NL179680C/en
not_active
IP Right Cessation

1977-03-25
CA
CA274,757A
patent/CA1061700A/en
not_active
Expired

1977-04-08
FR
FR7710769A
patent/FR2348436A1/en
active
Granted

1977-04-14
JP
JP52042097A
patent/JPS5828490B2/en
not_active
Expired

1977-04-14
DE
DE2716460A
patent/DE2716460C2/en
not_active
Expired

1977-04-15
GB
GB15690/77A
patent/GB1565712A/en
not_active
Expired

1977-04-15
MX
MX168771A
patent/MX143371A/en
unknown

Also Published As

Publication number
Publication date

FR2348436B1
(en)

1983-12-30

JPS5828490B2
(en)

1983-06-16

NL179680B
(en)

1986-05-16

DE2716460C2
(en)

1984-01-26

JPS52138729A
(en)

1977-11-19

MX143371A
(en)

1981-04-27

CA1061700A
(en)

1979-09-04

DE2716460A1
(en)

1977-10-27

NL7701903A
(en)

1977-10-18

NL179680C
(en)

1986-10-16

FR2348436A1
(en)

1977-11-10

US4063872A
(en)

1977-12-20

Información de contacto