GB1572463A - Creación de Inventos y Patentes con Inteligencia Artificial

GB1572463A – Flatness control of thermoplastic film
– Google Patents

GB1572463A – Flatness control of thermoplastic film
– Google Patents
Flatness control of thermoplastic film

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Publication number
GB1572463A

GB1572463A
GB15602/76A
GB1560276A
GB1572463A
GB 1572463 A
GB1572463 A
GB 1572463A
GB 15602/76 A
GB15602/76 A
GB 15602/76A
GB 1560276 A
GB1560276 A
GB 1560276A
GB 1572463 A
GB1572463 A
GB 1572463A
Authority
GB
United Kingdom
Prior art keywords
film
subjected
tensioning force
longitudinal
heat
Prior art date
1976-04-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB15602/76A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Agfa Gevaert AG

Original Assignee
Agfa Gevaert AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1976-04-15
Filing date
1976-04-15
Publication date
1980-07-30

1976-04-15
Application filed by Agfa Gevaert AG
filed
Critical
Agfa Gevaert AG

1976-04-15
Priority to GB15602/76A
priority
Critical
patent/GB1572463A/en

1976-07-01
Priority to FR7620413A
priority
patent/FR2360402A1/en

1977-03-18
Priority to LU76969A
priority
patent/LU76969A1/xx

1977-03-22
Priority to DE19772712436
priority
patent/DE2712436A1/en

1977-03-29
Priority to IT48702/77A
priority
patent/IT1080443B/en

1977-04-01
Priority to BE1008059A
priority
patent/BE853148A/en

1977-04-08
Priority to JP4088277A
priority
patent/JPS52126476A/en

1977-04-13
Priority to US05/787,051
priority
patent/US4140740A/en

1980-07-30
Publication of GB1572463A
publication
Critical
patent/GB1572463A/en

Status
Expired
legal-status
Critical
Current

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Classifications

B—PERFORMING OPERATIONS; TRANSPORTING

B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL

B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE

B29D7/00—Producing flat articles, e.g. films or sheets

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S428/00—Stock material or miscellaneous articles

Y10S428/91—Product with molecular orientation

Description

PATENT SPECIFICATION ( 11) 1 572 463
F ( 21) Application No 15602/76 ( 22) Filed 15 Apr 1976 ( 19) ( 23) Complete Specification Filed 30 Mar 1977 ( 44) Complete Specification Published 30 Jul 1980 ( 51) INT CL 3 B 29 D 7/24 n ( 52) Index at Acceptance B 5 B 352 360 363 368 902 CL ( 72) Inventors: FELIX FREDERICK DE SMEDT CHARLES ARSENE GILLES ( 54) FLATNESS CONTROL OF THERMOPLASTIC FILM ( 71) We, AGFA-GEVAERT, a naamloze vennootschap organised under the laws of Belgium, of Septestraat 27, B 2510 Mortsel, Belgium, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:
The present invention relates to a method for the production of biaxially molecularly 5 oriented polymeric film with improved flatness.
A great many linear, synthetic, organic polymers such as polyethylene terephthalate, are capable of being transformed into translucent or transparent films having excellent physical properties Some of these properties e g tensile strength, impact strength and flexural strength can be further improved by molecular orientation For instance, a polyethylene 10 terephthalate film that has been stretched biaxially, for instance stretched in two directions perpendicular to each other, is a material offering many possibilities of industrial application owing to its excellent physical properties When such oriented films are submitted to a heat treatment at high temperatures, say above 100 ‘C, they show a high degree of dimensional stability and tensile strength at elevated temperatures up to the temperature of heat 15 treatment.
In the customary process for the production of a biaxially oriented crystallizable, thermoplastic, organic polymer film, such as a polyethylene terephthalate film, the polymer is extruded as a molten film on a quenching drum where it is rapidly cooled to be in a substantially amorphous state, and the quenched film is stretched longitudinally (that is in 20 the direction of extrusion) to the desired extent between rollers rotating at different speeds.
Thereafter the film is stretched transversely in a transverse stretching device comprising jaws for engaging the film edges and making them follow diverging paths After biaxial stretching, the film is passed through a heat setting station which is maintained at a temperature which is within a range from about 250 C above the second order transition tempera 25 ture to below the crystalline melting temperature range of the film and wherein the dimensions of the film are held substantially constant The mentioned heat setting of the film improves the dimensional stability of the film at temperatures above the temperatures of biaxial stretching, while at the same time considerably increasing the crystallinity of the film 30 Finally, the film is passed through a heat relaxing zone which is maintained at a temperature which is slightly above that in the transverse stretching zone, and wherein the film is maintained under only a slight longitudinal tension to still further improve the dimensional stability of the film An additional advantage of the heat relaxing of a film is the improvement of the overall flatness of the manufactured film 35 The factors influencing the overall flatness of a manufactured film are not known with any degree of certainty because the film may become less flat in an unpredictable fashion, even when it appears that all of the important processing conditions are being maintained practically constant Possible causes of unflatness may include different orientation, thickness and rates of heating or cooling 40 The occurrence of less flat film may give rise to considerable production losses, especially in the production of graphic film, that is light-sensitive photographic material used for graphic reproduction purposes It may also lead to complete interruptions of a production process in those cases where, prior to the heat relaxing of the film, one or more layers are being coated on the film by means of modern coaters that are closely spaced from the film, 45 I,5724 b 3 such as cascade or extrusion coaters so that, even if the film is sufficiently flat upon leaving the heat relaxing station, its insufficient flatness on passing through of the coating station may cause a rupturing of the coating bead or a soiling of the lips of the coater owing to contact of the film with the coater.
R The present invention aims to provide a method for improving the flatness of a film, independent from, and as the case may be in addition to, the heat relaxing of the film.
In accordance with the present invention there is provided a method of continuously producing molecularly oriented heat set polymer film by extruding a linear organic, crystallizable polymer to form a molten layer, quenching said layer to obtain a substantially amorphous film, biaxially molecularly orienting said film by longitudinally and transversely lo stretching the film at a film temperature above the second order transition temperature of the polymer and heat setting the oriented film by heating it to a temperature above the second order transition temperature and below the crystalline melting temperature range of the film while restricting dimensional change of the film, characterised in that before and or after the heat setting the film is subjected while at a temperature between 20 C and l 5 the second order transition temperature to a longitudinal tensioning force of at least 60 kgf cm 2 but insufficient to cause permanent stretching of the film, which improves the flatness of the film.
The minimum longitudinal tensioning force of 60 kgf/ cm 2 to be applied when carrying out the present invention is very considerably in excess of the longitudinal tensioning force 20 normally applied to a film during its transportation by transporting rollers These normally exert a tensioning force of from 10 to ‘5 kgf/cm 2.
In a method according to the invention, the longitudinal stretching of the film preferably precedes the transverse stretching thereof In these circumstances the devices for longitudi,1 nallv stretching the film may be accommodated in a considerably smaller width than if they were disposed downstream from the devices for transversely stretching the film This advantage of width reduction also applies to any coating installation which may be provided between the longitudinal and transverse stretching stations for applying a subbing or other laver to the film Another advantage is the fact that the operations of transverse stretching anid of heat setting the film may be carried out in direct succession by means of one jaw-and-chain mechanism comprising two series of jaws which grip the opposed margins of the film and make them first follow diverging paths to trasversely stretch the film, and then follow parallel paths through a zone where the required processing temperature is maintained to heat set the film.
3 ‘ In preferred embodiments of the invention, the film is subjected to a said longitudinal 3 ‘ tensioning force of at least 60 kgf Icm 2 immediately after heat setting of the film For example such tensioning force may be applied between the exit end of the tenter of a heat setting station and a film pull roller disposed downstream from said station, such force being applied by such pull roller against a restraining force applied at the heat setting station.
Preferably the longitudinal tensioning force is at least 100 kgf/cm 2 and most preferably it 4 ( is not less than 180 kgf ‘cm 2, particularly in the case that the said tensioning force is applied after heat setting of the film.
The values for the longitudinal film tensioning force given in this specification are the quotient resulting from the division of the pulling force exerted on the film by the cross 45 sectional area of the film.
In case the longitudinal tensioning force is established by a dancer roller, said pulling force is determined by the mass of the dancer roller increased, as the case may be, by the biasing of said roller.
Since in a conventional installation for the production of a biaxially molecularly oriented, heat set and heat released polymer film, there are mostly several dancer rollers provided at 5 ( several places in order to control the film tension and the proper film transport at such places, it will be understood that the present invention can be carried out merely by increasing the masses of iron, lead or other material that determine the biasing force of a particular dancer roller.
In case the longitudinal tensioning force is established by one or more driven rollers 55 about which the film is angularly wrapped in order to obtain the desired pulling, the pulling force may be measured by means of transducers mounted between the roller bearings and the machine frame, said transducers providing an electric output signal as a function of their distortion under the influence of the film tension An alternative method for measuring the film pulling force in such case, is to measure the electric current in the supply circuit of the 60 motor(s) driving such rollers.
In certain embodiments of the invention film is subjected to a said high longitudinal tensioning force of at least 60 kgf/cm 2 at most preferably at least l O Okgf/cm 2 immediately after its longitudinal stretching During the application of such tensioning force the temperature of the film is preferably in the range of 25 to 450 C 65 3 1,572,463 3 The invention includes methods wherein the film is twice subjected to a said high longitudinal tensioning force, namely a first time between its longitudinal and transverse stretching, and a second time after its heat setting subsequent to its transverse stretching.
The film may be heat relaxed prior to being wound up The time during which the film is subjected to a said high longitudinal tensioning force in accordance with the present inven 5 tion is not critical, and may e g be between 1 second or even less, and a much longer time of some tens of seconds.
An embodiment of the invention will now be described, by way of example, with reference to the accompanying drawings wherein:
Fig 1 is a diagrammatic illustration of an installation for carrying out the method accord 10 ing to the present invention, Fig 2 is a diagrammatic top view of the transverse stretching and of the heat setting station of the installation of fig 1, and Fig 3 is a diagrammatic view illustrating the measurement of the flatness of a strip of film 15 Referring to Fig 1, a molten thermoplastic film forming polymeric material is extruded through an extrusion die 10 as a molten film curtain onto driven quenching drums 11 and 12 The function of the quenching drums is to sufficiently rapidly lower the temperature of the film to below the second order transition temperature of the polymer, so that the solidified film 13 is in a substantially amorphous state as it leaves the quenching drum 12 A 20 dancer roller 14, which is in fact a free vertically movable roller which, by its vertical position, controls the motor means (not shown) driving the rollers downstream of its position, determines the longitudinal film tension by its mass, and as the case may be by means of ballast masses added thereto.
The film is longitudinally molecularly oriented by means of a longitudinal stretcher 15 25 which comprises a series of slowly driven, heated rollers 16, a series of rapidly driven, cooled rollers 17, and two rod-like IR-heaters 18 and 19 for heating the film to a temperature above the second order transition temperature of the polymer.
The film is thereafter transversely molecularly oriented in a transverse stretcher 20 where the film edges are gripped by a plurality of successive jaws which are made to follow 30 diverging paths thereby to increase the width of the film while the film is being heated to a temperature above the second order transition temperature In a heat setting station 21 the jaws remain engaged with the film edges while following, however, parallel paths, thereby to constrain the film against lateral shrinkage while the film is being heated to a temperature within a range of 250 C above the second order transition temperature of the film and 35 below the crystalline melting temperature range of the film, in order to heat stabilise the film.
A dancer roller 22 determines the film tension between the longitudinal and the transverse stretcher.
Upon leaving the heat setting station 21, the film is engaged by a driven so-called vacuum 40 roller 23 which, in accordance with the invention, is so adjusted that an increased longitudinal tensioning force is exerted on the film A vacuum roller is, as known in the art, a roller having a perforated mantle over a certain angular extent of which there may be established a vacuum at the innerside of the roller by means of an appropriately shaped and sealed member which is stationarily disposed within the roller 45 The film 13 is conveyed over a number of idler rollers 24 to a first coating station 25, where a first subbing layer is applied to the film, the film tension being controlled by a dancer roller 26 The film web 13 is then conveyed through a drying section 27, next transported through a second coating station 28, where the film web is provided at its opposite side with a subbing layer, and thereupon the film web is passed again through the 50 drying section 27.
Finally, the film is heat relaxed in the station 29, and wound onto a roll 30 at a longitudinal tension which is determined by the dancer roller 31 The means within the heat relaxing station 29 for keeping the film at a reduced longitudinal tension are known in the art and have therefore not been shown in the drawing 55 As the film leaves the heat setting station 21, the margins of the film are trimmed by rotatable circular blades 32 and 33, so that a smooth flat film which is free of wrinkled and corrugated margins as a consequence of the gripping by the jaws, is obtained The trimmed marginal film bands, such as the band 34 shown, are conveyed to a collector such as 35.
The following tests illustrate the improvements attainable by the invention 60 A polyethylene terephthalate polymer having an inherent viscosity of 0 57 dl gt is extruded at a rate of 750 kg h land at a temperature of 290 WC through a conventional flat extrusion die having an orifice of 535 x 2 5 mm The molten polymer is received on the quenching drums 11 and 12 which are driven at a rate of 10 m mini l The film temperature amounts to about 50 WC as the film leaves the drum 12 65 A 1,572,463 The film is stretched longitudinally to a ratio of 3 8 and while at a temperature of 220 WC for 2 seconds.
The film receives thereafter a subbing layer at both its surfaces by means of an appropriate coating installation, for instance an extrusion or a cascade coater Finally the film is heat relaxed at a longitudinal tension of 10 kp/sq cm and while at a temperature of 130 WC for a period of 30 seconds.
In a first test, the production of the film occurred under the following conditions Film tension established by the roller 14: 4 5 kp/sq cm, by the roller 22: 20 kp/sq cm, by the roller 23: 24 kp/sq cm, by the roller 26: 27 kp/sq cm and by the roller 31: 24 kp/sq cm 10 The film was not heat relaxed.
A second test occurred under the same working conditions, but in addition the film was heat relaxed.
In a third test the film was subjected by the roller 23 to an increased longitudinal tensioning force of 250 kgf/ cm 2 During said increased longitudinal tensioning, the film had 15 a temperature of 400 C The final film ws not heat relaxed.
In a fourth test, the film was treated according to the conditions of the third test, except for the fact that the film was now heat relaxed.
In a fifth test, the film was subjected to an increased longitudinal tensioning force, after its longitudinal stretching, of 140 kgf/cm 2 by increasing the mass of the roller 22 while the 20 film was at a temperature of approximately 40 WC The film was not heat relaxed.
In a sixth test, the film was treated according to the fifth test, except for the fact that the film was now heat relaxed.
In a seventh test, the film was subjected to the increased longitudinal tensioning force of the third and fifth tests, without heat relaxing.
Finally, in an eighth test, the film was treated according to the seventh test, except for the 25 fact that the film was now heat relaxed.
The following table summarizes the different conditions of the eight tests, and the measured flatness of the film.
Table 30
Test Increased longitudinal Heat relaxing Flatness tension L M R after TS after LS I no no no -6 6 6 2 no no yes 4 2 4 3 yes no no 6 6 6 4 yes no yes 2 2 2 no yes no 6 6 6 6 no yes yes 2 2 2 7 yes yes no 5 5 5 8 yes yes yes + 2 2 2 The flatness of the film is expressed by three figures which stand for the left side (L), the middle (M) and the right side (R) of the film respectively A sign (-) indicates that the flatness is slightly less good whereas a sign ( +) indicates that the flatness is slightly better than the mentioned figure The notions TS and LS stand for transverse and longitudinal stretching.
The measurement of the flatness of the film occurred as follows A film strip 35, in the present case a strip of a length of about 5 meters, was cut from a material roll and put on a horizontal flat table 46, see fig 3 The table 46 has a white smooth top surface which is provided with three groups 37, 38 and 39 of each ten equally spaced black lines (ten lines per group) Only some lines in each group are shown in the figure The lines of each group are spaced from each other by about 1 cm The group of lines 38 is drawn centrally of the table whereas the lateral position of the groups 37 and 39 is such that they are situated at a distance of approximately 20 cm from the corresponding film edges Above the table and A 1,572,463 running parallel therewith, there are provided three elongate light sources (not illustrated) that are partially masked so that each of them projects onto the table a line of light of a width of about 5 mm.
The projected lines of light on the table are illustrated by the broken lines 40, 41 and 42.
The table is further provided with a plurality of small bores (not illustrated) so that a length 5 of film which is laid on the table may readily assume a more or less flat position after the air has escaped from its lower surface If now an inspector looks onto the film at three positions indicated by the arrows 43, 44 and 45, then he will notice that the projected lines of light 40, 41 and 42 are no longer straight but, on the contrary, will show a varying course, which is determined by the distortion of the images of the line light sources in dependence on the It) lack of flatness of the film The measurement results are simply the number of lines of one group that are counted by the inspector between the peak to peak deviations of the corresponding projected line of light.
It appears from the table that the results of tests 4, 6 and 8 are very good, and it may be concluded therefrom that the combination of at least one increased longitudinal tensioning 15 force on the film with the step of heat relaxing yields a well flat film Such a film is suitably as a support in the production of graphic film The support of this type of film has in any event to undergo heat relaxation in order to improve its dimensional stability.
If no heat relaxing is carried out, as in the case of a support for the production of X-ray film, then it may be seen from the table that a specification -6,6,6 is obtained if an increased 20 longitudinal tensioning force in accordance with the invention is not applied Although the flatness of such film may still be acceptable for film for radiographic purposes, difficulties may occur if such film is being coated by means of modern coating systems as mentioned in the introduction of the specification It may be seen from the results of tests 3 and 5 that the application of an increased longitudinal tensioning force at one stage is sufficient slightly to 25 improve the flatness of the film, whereas if the film is subjected to a said increased longitudinal tensioning force according to the invention at two distinct stages, see test 7, a more marked improvement of the flatness is achieved.
It will be understood that a film web being made in accordance with the method according to the present invention may undergo other treatments then disclosed in the embodi 30 ment described hereinbefore.
The film may be electrostatically pinned to the quenching drum or drums in order to improve its surface quality and/or accelerating its quenching The film edge may be knurled before the film is wound in order to prevent telescoping deformation of the wound film rolls during the manipulations thereof 35 The film may be provided with a subbing layer, or with a first subbing layer in those cases wherein a substratum layer is composed of two distinct subbing layers, between its longitudinal and transverse stretching, with the advantage mentioned in the introduction of the specification.
The film may be subjected to an intermediate corona discharge treatment for improving 40 the adhesion of its surface(s) for a subbing layer or other layer.
The means for trimming the margins of the film after the heat setting may be so disposed with respect to the exit of the heat setting station 21 that the margins of the film are severed from the film at a point which is upstream of the point where the forces operative to restrict dimensional change of the film cease to exist In practice, this means that the trimming 45 blades such as 32 and 33 are situated on the film path at a point before the point where the jaws which grip the film edges are opened to release the film In doing so, the margins of the film are cut from the film before they are released by the jaws, and thus said margins are free from any stress in the transverse direction at their releasing by the jaws so that the disengagement of the jaws may occur without any problem 50 Finally, the method of the present invention is suitable for use in the production of film from polymers other than polyethylene terephthalate which lend themselves to biaxial molecular orientation and heat setting Some of these polymers are polyvinylidene chloride and copolymers thereof, polyamides, polystyrene and its copolymers, polycarbonates, etc.

Claims (16)

WHAT WE CLAIM IS: 55

1 A method of continuously producing molecularly oriented heat set polymer film by extruding a linear organic, crystallizable polymer to form a molten layer, quenching said layer to obtain a substantially amorphous film, biaxially molecularly orienting said film by longitudinally and transversely stretching the film at a film temperature above the second order transition temperature of the polymer and heat setting the oriented film by heating it 60 to a temperature above the second order transition temperature and below the crystalline melting temperature range of the film while restricting dimensional change of the film, characterised in that before and/or after the heat setting the film is subjected while at a temperature between 20 WC and the second order transition temperature to a longitudinal tensioning force of at least 60 kgf/cm 2 but insufficient to cause permanent stretching of the 65 1,572,463 film, which improves the flatness of the film.

2 A method according to claim 1, wherein the film is subjected to a said longitudinal tensioning force of at least 100 kgf/sq cm.

3 A method according to statement 2 wherein the film is subjected to a said longitudiS nal tensioning force of at least 180 kgf/cm

4 A method according to claim 2 or 3 wherein the film is subjected to a said longitudinal tensioning force of at least 100 kgf/cm immediately after the heat setting of the film.

A method according to claim 4, wherein the film is subjected to a said longitudinal tensioning force immediately after heat setting of the film and while the film is at a tempera 10 ture in the range 200 to 600.

6 A method according to any preceding claim, wherein the film is subjected to a said longitudinal tensioning force at a stage between the longitudinal stretching and heat setting stages.

7 A method according to claim 6, wherein the film is subjected to a said longitudinal tensioning force of at lest 60 kgf/cm’ between the longitudinal stretching and the heat 15 setting stages.

8 A method according to claim 7, wherein the film is subjected to a said longitudinal tensioning force of at least 100 kgf/cm 2 between the longitudinal stretching and heat setting 20stages 2

9 A method according to claim 7 or 8, wherein the film, when subjected to said 20 longitudinal tensioning force between the longitudinal stretching and the heat setting stages, has a temperature in the range 250 to 450 C.

A method according to any of claims 7 to 9, wherein the film is subjected to a said longitudinal tensioning force immediately after being longitudinally stretched.

11 A method according to any preceding claim, wherein marginal portions are severed 25 from the film at a point along its path of travel which is upstream of the point where transverse forces restricting dimensional change of the film during its heat setting are relaxed.

12 A method according to any preceding claim, wherein the longitudinal stretching of 30 the film precedes transverse stretching thereof.

13 A method according to any preceding claim, wherein the biaxially orientated film which has been subjected to a said tensioning force and heat set is heat relaxed.

14 A method according to any of claims wherein at least one coating layer is formed on the film after it has been subjected to a said longitudinal tensioning force.

15 A method according to any preceding claim, wherein said polymeric film is a 35 polyethylene terephthalate film.

16 A method according to claim 1 and substantially as herein described with reference to Fig 1 of the accompanying drawings.
HYDE, HEIDE & O’DONNELL 2 Serjeant’s Inn London EC 4 Y i LL Agents for the Applicants Printed for Her Majesty’s Stationery Office, by Croydon Printing Company Limited, Croydon Surrey, 1979 Published by the Patent Office, 25 Southampton Buildings, London, WC 2 A l AY, from which copies may be obtained.

GB15602/76A
1976-04-15
1976-04-15
Flatness control of thermoplastic film

Expired

GB1572463A
(en)

Priority Applications (8)

Application Number
Priority Date
Filing Date
Title

GB15602/76A

GB1572463A
(en)

1976-04-15
1976-04-15
Flatness control of thermoplastic film

FR7620413A

FR2360402A1
(en)

1976-04-15
1976-07-01

METHOD FOR IMPROVING THE FLAT OF A THERMOPLASTIC FILM

LU76969A

LU76969A1
(en)

1976-04-15
1977-03-18

DE19772712436

DE2712436A1
(en)

1976-04-15
1977-03-22

METHOD FOR MANUFACTURING BIAXIAL MOLECULAR ORIENTED POLYMER FILMS

IT48702/77A

IT1080443B
(en)

1976-04-15
1977-03-29

METHOD FOR THE PRODUCTION OF POLYMER FILMS WITH BLASS MOLECULAR ORIENTATION THAT PRESENT IMPROVED FLATNESS CHARACTERISTICS

BE1008059A

BE853148A
(en)

1976-04-15
1977-04-01

PROCEDURE FOR THE CONTINUOUS MANUFACTURE OF MOLECULAR-ORIENTED, GETHERMOFI-WEATHERED POLYMER FILM

JP4088277A

JPS52126476A
(en)

1976-04-15
1977-04-08
Adjusting of platness of thermplastic film

US05/787,051

US4140740A
(en)

1976-04-15
1977-04-13
Flatness control of thermoplastic film

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

GB15602/76A

GB1572463A
(en)

1976-04-15
1976-04-15
Flatness control of thermoplastic film

Publications (1)

Publication Number
Publication Date

GB1572463A
true

GB1572463A
(en)

1980-07-30

Family
ID=10062091
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB15602/76A
Expired

GB1572463A
(en)

1976-04-15
1976-04-15
Flatness control of thermoplastic film

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US
(1)

US4140740A
(en)

JP
(1)

JPS52126476A
(en)

BE
(1)

BE853148A
(en)

DE
(1)

DE2712436A1
(en)

FR
(1)

FR2360402A1
(en)

GB
(1)

GB1572463A
(en)

IT
(1)

IT1080443B
(en)

LU
(1)

LU76969A1
(en)

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1984-02-20
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1985-02-01
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Process for manufacture of surface-modified oriented polymeric film

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1987-07-14
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Agfa-Gevaert N.V.
Process for making curled photographic film

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(en)

1988-07-05
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Xerox Corporation
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2007-02-23
2008-08-28
Nexcel Synthetics, Llc
Methods and systems for manufacturing yarns for synthetic turf

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* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US2002711A
(en)

1932-05-02
1935-05-28
Fiberloid Corp
Manufacture of thin sheets of cellulose

BE538815A
(en)

1954-06-08
1900-01-01

US2968067A
(en)

1959-02-02
1961-01-17
Du Pont
Process for making oriented films

US3329756A
(en)

1963-03-29
1967-07-04
Burroughs Corp
Sheet processing method

US3663683A
(en)

1969-07-09
1972-05-16
Eastman Kodak Co
Polyester heat relax processes

US3873664A
(en)

1973-08-29
1975-03-25
Celanese Corp
Heat treatment of polyester rolls

1976

1976-04-15
GB
GB15602/76A
patent/GB1572463A/en
not_active
Expired

1976-07-01
FR
FR7620413A
patent/FR2360402A1/en
active
Granted

1977

1977-03-18
LU
LU76969A
patent/LU76969A1/xx
unknown

1977-03-22
DE
DE19772712436
patent/DE2712436A1/en
not_active
Withdrawn

1977-03-29
IT
IT48702/77A
patent/IT1080443B/en
active

1977-04-01
BE
BE1008059A
patent/BE853148A/en
unknown

1977-04-08
JP
JP4088277A
patent/JPS52126476A/en
active
Pending

1977-04-13
US
US05/787,051
patent/US4140740A/en
not_active
Expired – Lifetime

Also Published As

Publication number
Publication date

BE853148A
(en)

1977-10-03

FR2360402A1
(en)

1978-03-03

JPS52126476A
(en)

1977-10-24

US4140740A
(en)

1979-02-20

FR2360402B1
(en)

1978-12-15

DE2712436A1
(en)

1977-10-27

LU76969A1
(en)

1978-06-01

IT1080443B
(en)

1985-05-16

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