AU3642797A

AU3642797A – Bridged metallocene compounds
– Google Patents

AU3642797A – Bridged metallocene compounds
– Google Patents
Bridged metallocene compounds

Info

Publication number
AU3642797A

AU3642797A
AU36427/97A
AU3642797A
AU3642797A
AU 3642797 A
AU3642797 A
AU 3642797A
AU 36427/97 A
AU36427/97 A
AU 36427/97A
AU 3642797 A
AU3642797 A
AU 3642797A
AU 3642797 A
AU3642797 A
AU 3642797A
Authority
AU
Australia
Prior art keywords
metallocene compounds
bridged metallocene
bridged
compounds
metallocene
Prior art date
1996-07-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Granted

Application number
AU36427/97A
Other versions

AU716491B2
(en

Inventor
James M. Boncella
David E. Richardson
Faisal A. Shafiq
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

University of Florida

Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1996-07-10
Filing date
1997-06-25
Publication date
1998-02-02

1997-06-25
Application filed by Mobil Oil Corp
filed
Critical
Mobil Oil Corp

1998-02-02
Publication of AU3642797A
publication
Critical
patent/AU3642797A/en

1999-05-27
Assigned to UNIVERSITY OF FLORIDA
reassignment
UNIVERSITY OF FLORIDA
Alteration of Name(s) of Applicant(s) under S113
Assignors: MOBIL OIL CORPORATION

2000-02-24
Application granted
granted
Critical

2000-02-24
Publication of AU716491B2
publication
Critical
patent/AU716491B2/en

2017-06-25
Anticipated expiration
legal-status
Critical

Status
Ceased
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides

B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides

B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/22—Organic complexes

B01J31/2282—Unsaturated compounds used as ligands

B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

C07F17/00—Metallocenes

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System

C07F7/02—Silicon compounds

C07F7/08—Compounds having one or more C—Si linkages

C07F7/0803—Compounds with Si-C or Si-Si linkages

C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F4/00—Polymerisation catalysts

C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen

C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00

B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal

B01J2531/46—Titanium

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00

B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal

B01J2531/48—Zirconium

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00

B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal

B01J2531/49—Hafnium

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F4/00—Polymerisation catalysts

C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors

C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides

C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof

C08F4/62—Refractory metals or compounds thereof

C08F4/64—Titanium, zirconium, hafnium or compounds thereof

C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond

C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F4/00—Polymerisation catalysts

C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors

C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides

C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof

C08F4/62—Refractory metals or compounds thereof

C08F4/64—Titanium, zirconium, hafnium or compounds thereof

C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond

C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S526/00—Synthetic resins or natural rubbers — part of the class 520 series

Y10S526/943—Polymerization with metallocene catalysts

AU36427/97A
1996-07-10
1997-06-25
Bridged metallocene compounds

Ceased

AU716491B2
(en)

Applications Claiming Priority (3)

Application Number
Priority Date
Filing Date
Title

US08677800

1996-07-10

US08/677,800

US5712354A
(en)

1996-07-10
1996-07-10
Bridged metallocene compounds

PCT/US1997/011074

WO1998001456A1
(en)

1996-07-10
1997-06-25
Bridged metallocene compounds

Publications (2)

Publication Number
Publication Date

AU3642797A
true

AU3642797A
(en)

1998-02-02

AU716491B2

AU716491B2
(en)

2000-02-24

Family
ID=24720169
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

AU36427/97A
Ceased

AU716491B2
(en)

1996-07-10
1997-06-25
Bridged metallocene compounds

Country Status (8)

Country
Link

US
(1)

US5712354A
(en)

EP
(1)

EP0977762A4
(en)

JP
(1)

JP2001513074A
(en)

KR
(1)

KR20000023612A
(en)

AU
(1)

AU716491B2
(en)

CA
(1)

CA2260174A1
(en)

TW
(1)

TW380144B
(en)

WO
(1)

WO1998001456A1
(en)

Families Citing this family (39)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US6117659A
(en)

*

1997-04-30
2000-09-12
Kosan Biosciences, Inc.
Recombinant narbonolide polyketide synthase

US6245868B1
(en)

1998-05-29
2001-06-12
Univation Technologies
Catalyst delivery method, a catalyst feeder and their use in a polymerization process

US20020002256A1
(en)

*

1998-09-16
2002-01-03
Thomas Henry Peterson
Catalyst composition for the polymerization of olefins

AU764177B2
(en)

1998-12-18
2003-08-14
Univation Technologies Llc
Haloaryl containing group 13 substituents on bridged metallocene polyolefin catalysts

DE10114345A1
(en)

*

2001-03-23
2002-09-26
Bayer Ag
Transition metal compound used in olefin polymerization e.g. polyethylene production, with an acceptor with a fluorinated aryl group, has at least two pi-systems and a donor-acceptor exchange between these systems

JP4576126B2
(en)

*

2002-04-12
2010-11-04
ダウ グローバル テクノロジーズ インコーポレイティド

Azaborolyl group 4 metal complex, catalyst and olefin polymerization method

JP4742221B2
(en)

2003-03-21
2011-08-10
ダウ グローバル テクノロジーズ エルエルシー

Morphology controlled olefin polymerization process

ATE464352T1
(en)

2004-12-17
2010-04-15
Dow Global Technologies Inc

RHEOLOGY-MODIFIED POLYETHYLENE COMPOSITIONS

EP1803747A1
(en)

2005-12-30
2007-07-04
Borealis Technology Oy
Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films

RU2008122073A
(en)

*

2006-05-02
2009-12-10
Дау Глобал Текнолоджиз Инк. (Us)

COMPOSITIONS OF HIGH DENSITY POLYETHYLENE, THE METHOD OF PRODUCING THEM, THE WIRING AND CABLES SHAPED, PRODUCED FROM THEM, AND THE METHOD OF PRODUCING SUCH WIRING AND CABLES

US7456244B2
(en)

*

2006-05-23
2008-11-25
Dow Global Technologies
High-density polyethylene compositions and method of making the same

CN103396604B
(en)

*

2007-05-02
2021-05-25
陶氏环球技术有限责任公司
High-density polyethylene composition, method of making the same, injection molded articles made therefrom, and method of making the articles

US7981517B2
(en)

*

2007-08-28
2011-07-19
Dow Global Technologies Inc.
Bituminous compositions and methods of making and using same

WO2010071798A1
(en)

2008-12-18
2010-06-24
Univation Technologies, Llc
Method for seed bed treatment for a polymerization reaction

CN102361925B
(en)

2009-01-30
2013-08-14
陶氏环球技术有限责任公司
High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices

JP2011099091A
(en)

*

2009-09-30
2011-05-19
Sumitomo Chemical Co Ltd
Manufacturing method for ethylenic polymer

JP5900089B2
(en)

2011-03-29
2016-04-06
住友化学株式会社

Transition metal complex, method for producing the transition metal complex, catalyst for trimerization, method for producing 1-hexene, substituted cyclopentadiene compound, and method for producing the substituted cyclopentadiene compound

JP2012214457A
(en)

2011-03-29
2012-11-08
Sumitomo Chemical Co Ltd
Transition metal complex, method for producing the same, catalyst for trimerization, method for producing 1-hexene, substituted cyclopentadiene compound, and method for producing the same

ES2823768T3
(en)

2012-12-28
2021-05-10
Univation Tech Llc

Methods to integrate aluminoxane production into catalyst production

ES2723878T3
(en)

2013-01-14
2019-09-03
Univation Tech Llc

Methods for preparing catalytic systems with increased productivity

JP6621845B2
(en)

2015-05-08
2019-12-18
エクソンモービル ケミカル パテンツ インコーポレイテッド

Polymerization method

WO2018063764A1
(en)

2016-09-27
2018-04-05
Exxonmobil Chemical Patents Inc.
Polymerization process

WO2018063767A1
(en)

2016-09-27
2018-04-05
Exxonmobil Chemical Patents Inc.
Polymerization process

WO2018063765A1
(en)

2016-09-27
2018-04-05
Exxonmobil Chemical Patents Inc.
Polymerization process

WO2018118155A1
(en)

2016-12-20
2018-06-28
Exxonmobil Chemical Patents Inc.
Polymerization process

KR102001965B1
(en)

2017-10-12
2019-07-19
롯데케미칼 주식회사
Polyolefin catalyst and preparing method of polyolefin using same

WO2019118073A1
(en)

2017-12-13
2019-06-20
Exxonmobil Chemical Patents Inc.
Deactivation methods for active components from gas phase polyolefin polymerization process

WO2019173030A1
(en)

2018-03-08
2019-09-12
Exxonmobil Chemical Patents Inc.
Methods of preparing and monitoring a seed bed for polymerization reactor startup

CN110272515B
(en)

*

2018-03-15
2021-10-19
中国石油化工股份有限公司
Process for the preparation of ethylene copolymers

US11459408B2
(en)

2018-05-02
2022-10-04
Exxonmobil Chemical Patents Inc.
Methods for scale-up from a pilot plant to a larger production facility

WO2019213227A1
(en)

2018-05-02
2019-11-07
Exxonmobil Chemical Patents Inc.
Methods for scale-up from a pilot plant to a larger production facility

WO2020014138A1
(en)

2018-07-09
2020-01-16
Exxonmobil Chemical Patents Inc.
Polyethylene cast films and methods for making the same

EP3826833A1
(en)

2018-07-26
2021-06-02
ExxonMobil Chemical Patents Inc.
Multilayer foam films and methods for making the same

CN113207293B
(en)

2018-11-13
2023-08-04
埃克森美孚化学专利公司
Polyethylene blends and films

WO2020102385A1
(en)

2018-11-13
2020-05-22
Exxonmobil Chemical Patents Inc.
Polyethylene films

WO2020163079A1
(en)

2019-02-06
2020-08-13
Exxonmobil Chemical Patents Inc.
Films and backsheets for hygiene articles

WO2021126458A1
(en)

2019-12-17
2021-06-24
Exxonmobil Chemical Patents Inc.
Films made of polyethylene blends for improved sealing performance and mechanical properties

US20230097375A1
(en)

2020-03-12
2023-03-30
Exxonmobil Chemical Patents Inc.
Films made of polyethylene blends for improved bending stiffness and high md tear resistance

CN117098785A
(en)

2021-04-30
2023-11-21
埃克森美孚化学专利公司
Method for transitioning between different polymerization catalysts in a polymerization reactor

Family Cites Families (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

JP3850048B2
(en)

*

1994-12-08
2006-11-29
東ソー株式会社

Organic transition metal compound and method for producing polyolefin using the same

DE4446922A1
(en)

*

1994-12-28
1996-07-04
Hoechst Ag

Metallocene compound and its use as a catalyst component

1996

1996-07-10
US
US08/677,800
patent/US5712354A/en
not_active
Expired – Lifetime

1997

1997-06-25
JP
JP50523098A
patent/JP2001513074A/en
not_active
Ceased

1997-06-25
AU
AU36427/97A
patent/AU716491B2/en
not_active
Ceased

1997-06-25
EP
EP97933171A
patent/EP0977762A4/en
not_active
Withdrawn

1997-06-25
WO
PCT/US1997/011074
patent/WO1998001456A1/en
not_active
Application Discontinuation

1997-06-25
CA
CA002260174A
patent/CA2260174A1/en
not_active
Abandoned

1997-07-11
TW
TW086109884A
patent/TW380144B/en
not_active
IP Right Cessation

1999

1999-01-08
KR
KR1019997000060A
patent/KR20000023612A/en
not_active
Application Discontinuation

Also Published As

Publication number
Publication date

TW380144B
(en)

2000-01-21

AU716491B2
(en)

2000-02-24

EP0977762A4
(en)

2000-07-26

KR20000023612A
(en)

2000-04-25

CA2260174A1
(en)

1998-01-15

EP0977762A1
(en)

2000-02-09

WO1998001456A1
(en)

1998-01-15

JP2001513074A
(en)

2001-08-28

US5712354A
(en)

1998-01-27

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Legal Events

Date
Code
Title
Description

2000-06-22
FGA
Letters patent sealed or granted (standard patent)

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