AU4500599A - Creación de Inventos y Patentes con Inteligencia Artificial

AU4500599A – Thickening agent based on homogenized vegetable puree, its preparation and its use in foodstuffs
– Google Patents

AU4500599A – Thickening agent based on homogenized vegetable puree, its preparation and its use in foodstuffs
– Google Patents
Thickening agent based on homogenized vegetable puree, its preparation and its use in foodstuffs

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Publication number
AU4500599A

AU4500599A
AU45005/99A
AU4500599A
AU4500599A
AU 4500599 A
AU4500599 A
AU 4500599A
AU 45005/99 A
AU45005/99 A
AU 45005/99A
AU 4500599 A
AU4500599 A
AU 4500599A
AU 4500599 A
AU4500599 A
AU 4500599A
Authority
AU
Australia
Prior art keywords
vegetable
homogenised
process according
puree
food product
Prior art date
1998-06-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Granted

Application number
AU45005/99A
Other versions

AU750191B2
(en

Inventor
Maria Teresa Belmar
Michela Tamai
Eric William Thompson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee
Unilever PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1998-06-15
Filing date
1999-05-21
Publication date
2000-01-05

1999-05-21
Application filed by Unilever PLC
filed
Critical
Unilever PLC

2000-01-05
Publication of AU4500599A
publication
Critical
patent/AU4500599A/en

2002-07-11
Application granted
granted
Critical

2002-07-11
Publication of AU750191B2
publication
Critical
patent/AU750191B2/en

2019-05-21
Anticipated expiration
legal-status
Critical

Status
Ceased
legal-status
Critical
Current

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Classifications

A—HUMAN NECESSITIES

A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES

A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL

A23L23/00—Soups; Sauces; Preparation or treatment thereof

A—HUMAN NECESSITIES

A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES

A23L19/00—Products from fruits or vegetables; Preparation or treatment thereof

A23L19/09—Mashed or comminuted products, e.g. pulp, purée, sauce, or products made therefrom, e.g. snacks

A—HUMAN NECESSITIES

A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES

A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof

A23L27/60—Salad dressings; Mayonnaise; Ketchup

Description

WO 99/65328 PCT/EP99/03593 THICKENING AGENT BASED ON HOMOGENIZED VEGETABLE PUREE, ITS PREPARATION AND ITS USE IN FOODSTUFFS Field of the invention 5 The present invention relates to a process for thickening foodstuffs, in particular thickening liquid, pourable or squeezable or spoonable foodstuffs, as well as to a thickening agent and the preparation thereof. 10 Background of the invention A broad range of thickeners is conventionally employed to 15 achieve the desired thickness and consistency of various (liquid, pourable or squeezable) foodstuffs. Well-known in this respect are the use of starch and gellable biopolymers or gums. Examples of the latter group are gelatin, agar, carrageenans, pectins, alginates, xanthan, locust bean gum 20 etcetera. The application of (native) starch, however, may result in a sticky mouthfeel and/or characteristic smell or flavour of starch, which is less desirable. Also, the use of starch 25 as a thickener may result in less heat stability of the thickened foodstuff and/or retrogradation upon cooling. The use of native starch as a thickener without gums will generally result in a gelled consistency when cooling as a 30 result of a network formed by the amylose when leached out from the starch granules during processing, which is undesirable for preparing pourable foodstuffs such as e.g. sauces.
WO99/65328 PCT/EP99/03593 2 The disadvantage of reduced heat stability and/or retrogradation may be overcome by the application of (chemically) modified starches, which are in many countries to be labeled as such on the packaging of the foodstuff 5 concerned, and are as such less attractive. The use of native starch mixed in combination with certain gums may overcome some of the disadvantages of using native starch alone: applying heat will result in amylose leaching 10 out of the starch granules, but phase separation occurs due to the presence of the gums. The application of gums has its disadvantages as well, ranging from a tendency to produce slimy or slightly 15 gellified foodstuffs to non-vegetable origin (e.g. gelatin) to high costs (most gums). Additional disadvantages include reduced heat-stability for many gums similar to that of starch. 20 Various solutions have been proposed in the past in order to overcome the disadvantages mentioned above. A solution w.r.t. the heat stability has been proposed in WO 95/12323. Herein it is disclosed that such problems may be overcome by application of a non-pre-gelatinised starch that is 25 present in the foodstuff as a dispersed phase in a gum. Another attempt to overcome some of the problems as set out above is presented in JP 57/202257 (Yakult Honsha KK). Herein it is disclosed that soups, curry’s, stews, sauces 30 and the like may be thickened by the incorporation of smashed, steamed and homogenised vegetables which are rich in starch. Rich in starch is reported in this reference to mean vegetable containing about 70% or more starch in the dry vegetable, such as potato, sweet potato, taro, cassava, 35 and pumpkin. The homogenisation is according to this WO99/65328 PCT/EP99/03593 3 reference to be carried out at pressures between 30-150 bar, with 50-80 bar being preferred. The pressures actually used are 75 and 80 bar. 5 Summary of the invention Although the solutions given above may be sufficient for some applications, it has been found that for others these are not sufficient. For example, the solutions as proposed 10 by JP 57/202257 still give rise to undesired starchy flavours. Additionally, the homogenised vegetables as disclosed in that reference lead to the formation of gelled compositions upon cooling, unless gums such as gelatins (e.g. in the form of bouillons) are also included in the 15 application. Hence, there was a need for a process for thickening liquid, pourable or squeezable foodproducts without the disadvantages as mentioned above, preferably independent 20 upon temperature during manufacture or use. In other words, the so obtained thickened food products should be thickened but preferably not gelled, be free of a starchy flavor or smell, be at least reasonably stable under heating and cooling conditions, and preferably provide a thickening 25 effect both in hot (e.g. sauces, soups) or cold (e.g. sauces, dressings, mayonnaise) applications. Furthermore, the thickened foodstuff should preferably be free of gums from non-vegetable origin (such as gelatin). 30 Preferably, the foodstuff so prepared should also be free of other gums or thicking biopolymers. Additionally, the thickened foodstuff should be free of any grainy or sandy texture resulting from the thickener.
WO99/65328 PCT/EP99/03593 4 It has now been found that the above can be achieved by a process for thickening a liquid, pourable or squeezable foodproduct by adding to said foodproduct a vegetable homogenate obtained by subjecting a comminuted vegetable to 5 a homogenisation treatment, wherein the vegetable contains less then 70% starch, based on dry matter. The thickening effect can be obtained both in hot and cold preparations, and compositions can be reheated without substantial change in thickening effect. 10 Detailed description of the invention The prior art in JP 57/202257 seems to rely on a thickening effect by liberating starch that is available in starch 15 rich vegetables as are exemplified therein. This still does not solve a number of the problems as set out above. For example a gum (e.g. gelatin, either added as such or in the form of a bouillon) will still be needed in order to avoid the formation of a gelled foodstuff upon cooling. This is 20 due to the presence of starch, although now originating from starch-rich vegetables instead of a different source. The product prepared according to this reference will also result in some starchy flavour or smell being present. Also, retrogradation may occur. 25 In contrast to this, in the present invention the thickening effect is obtained also from homogenised vegetables, but now from vegetables which do not need to be high in starch content. In fact, the thickening effect is 30 more or less independent upon the content of starch of the vegetable used, and in order to overcome some of the disadvantages related to the use of starch as a thickener (as set out above), the content of starch of the vegetable used is preferably low. For the person of average skill in 35 the art, it is surprising that, when confronted with the WO99/65328 PCT/EP99/03593 5 disclosure as mentioned above, a thickening effect can achieved without much starch being present. Without wishing to be bound by any theory, it is believed 5 that in the present invention the tickening effect is obtained by the presence of a mixture of intact vegetable cells, cell debris, cell wall fragments, etcetera. In the process according to this invention and as set out 10 above it is preferred that the starch content of the vegetables used for preparing the homogenised vegetable puree is less than 50% based on the dry vegetable, more preferably even lower than 35%. 15 Preferred vegetables for this invention are (apart from the above mentioned requirements) vegetables of white or pale colour, e.g. parsnips, mushrooms, cauliflower, swede, and turnips. For specific foodstuffs vegetables having a green or orange color, like carrots, broccoli, may also be used. 20 Needless to say, mixtures may also be used. Particularly preferred vegetables are plants of the genus Brassica oleracea and also roots or root-like vegetables, all preferably being low in starch. 25 Less suitable (following their high starch content) are the vegetables as mentioned in JP 57/202257: potato, sweet potato, taro, cassava and pumpkin. Also less suitable for the purpose of the invention are tomatoes. 30 In the process according to the present invention the homogenisation treatment can be effected by any homogeniser suitable for application to foodstuffs. As various types of homogenisers operate following different principles, homogenisation pressures from one type of homogeniser to 35 another type of homogeniser cannot be compared directly. It WO99/65328 PCT/EP99/03593 6 was found in the present case that homogenisation of the vegetables is preferably carried out by a high pressure homogeniser at a pressure of 100-200 bar or any equivalent treatment (in terms of results) by a different type of 5 homogeniser, such as an ultrasonic homogeniser. For some purposes, pressures higher than 150 bar may be preferred. In the process according to the invention, it is preferred that prior to the homogenisation step the vegetables are 10 cooked. Preferably, the homogenisation operation is also preceded by a comminuting (including chopping, slicing, etcetera) operation, leading e.g. to a puree. Depending e.g. on the vegetables chosen, they may be peeled and/or parts of the vegetable (e.g. leaf, stem, bruised spots) may 15 be removed first. It was found that the homogenised vegetable puree according to the invention shows very good (physical) stability, without substantial phase separation, thinning, syneresis 20 over periods of up to 6 weeks or more. It was also found that the homogenised vegetable compositions prepared according to the invention are free of sandy or grainy texture, and provide a smooth mouthfeel, 25 both in pure form and upon usage in diluted form. The homogenised vegetable prepared along the lines as set out above may be applied to a given foodstuff in any desired quantity, e.g. in an amount of 5 to 80% by weight, 30 based on the final formulation. However, for obtaining the desired thickening effect for liquid, pourable or squeezable foodstuffs it may be preferred to incorporate the homogenised vegetable puree in the foodstuff in an amount of between 10 and 60%, more preferably 20-45% by 35 weight based on the final food product. The amount also WO99/65328 PCT/EP99/03593 7 depends on the vegetable used and the desired thickness. The right amount needed can readily be determined by the person of average skill in the art. 5 The material according to the invention can most suitable be added to foodstuffs which need to be liquid, pourable, squeezable or spoonable, such as soups, sauces, simmer sauces, sauce base products, dressings, mayonnaise, etcetera. 10 The homogenised vegetable puree is suitable for application to aqueous foodstuffs, in particular suitable for thickening sauces, simmer sauces, sauce base products (which are to be diluted by an aqueous liquid prior to 15 consumption) and the like. Also, the homogenised vegetable puree can be incorporated into emulsified foodstuffs, like mayonnaise, dressings or fat/oil-containing sauces. The thickened foodstuffs according to the invention can be consumed both cold and hot, without substantial change in 20 thickness. Depending upon the intended use of the thickened foodstuff it may further contain water, organic acids, oil, fat, herbs, spices, comminuted vegetables, or mixtures thereof. 25 In the present invention, the use of thickeners based on non-starch like biopolymers like gelatin, agar, alginate, carrageenans, xanthan, pectins and pect(in)ic substances, CMC and the like can be dispensed with. Hence, a foodstuff 30 thickened according to this invention preferably does not contain substantial amounts of thickeners or gellable compounds from animal origin (e.g. gelatin). The present invention further relates to a liquid, pourable 35 or squeezable foodproduct containing 5-80% by weight WO99/65328 PCTIEP99/03593 8 (preferably 10-60%) of a vegetable puree, wherein the vegetable puree has been homogenised, and wherein the starch content of the vegetable is less than 70%, based on the or vegetable. It is preferred that the vegetable in the 5 above has been homogenised by a high-pressure homogeniser at a pressure of 100-200 bar, or any equivalent (in terms of results obtained) homogenising treatment. The invention further relates to the use of vegetable 10 puree, wherein the vegetable puree has been homogenised, and wherein the starch content of the vegetable is less than 70%, based on the dry vegetable for thickening liquid, pourable or squeezable foodstuffs. It is preferred that the vegetable in the above has been homogenised by a high 15 pressure homogeniser at a pressure of 100-200 bar, or any equivalent (in terms of results obtained) homogenising treatment. The invention is further exemplified by the following 20 examples, which are to be understood as to be non-limiting. Examples Examples 1-7 25 Seven sauces have been prepared with different homogenised vegetables as thickener, homogenisation pressures of the vegetables, and amounts of homogenised vegetable, as set out in table 1.
WO99/65328 PCT/EP99/03593 9 For the eight examples various sauces were prepared, in which was present (percentage by weight): sunflower oil 10 % modified egg-yolk 0.5% 5 salt 0.4% sugar 0.6% homogenised vegetable: see table 1 for amount water: to the balance 10 Table 1: vegetable type, amount and homogenisation pressures. Example Vegetable used amount of Homogenisation homogenised pressure (bar) vegetable (wt %) 1 Parsnips 45% 150 2 Parsnips 45% 200 3 Parsnips 45% 100 4 Parsnips 60% 150 5 Parsnips 45% 150 6 Carrots 75% 150 7 Broccoli 45% 150 Processing examples 1-4 15 The vegetables were peeled, sliced and cooked in deionized boiling water for 15 minutes. Thereafter, they were pureed in an industrial food processor (Robocoup Juicer) with a 0.5 mm sieve. The so-obtained vegetable purees were added to a pre 20 emulsion, which was prepared by mixing water, modified egg yolk, and oil in the amounts given above, after which salt and sugar were added.
WO99/65328 PCT/EP99/03593 10 The so-prepared mixture was passed through a high-pressure homogeniser (type Niro Soavi Pand lab Bench Model, at pressures indicated in table 1) to obtain the sauce (appearance: smooth and creamy) 5 The cold, emulsified sauce was heated to boiling, hot filled in glass jars and pasteurised. The pasteurised samples were stored for 6 weeks (chilled), opened and reheated, which resulted in a smooth, thick, sauce having good mouthfeel and appearance. 10 Processing example 5 Example 1 (45% parsnips, homogenised at 150 bar) was repeated, apart from that the pureed vegetable (and part of the water) and the rest of the sauce ingredients were 15 passed through the high-pressure homogeniser (type Niro Soavi Pand lab Bench Model, at 150 bar) separately, and then mixed. In order to homogenise the vegetable puree, part of the water (30%) was added to the vegetable puree to be homogenised. The rest of the processing was the same. 20 The resulting product was not distinguishable from the product from example 1. Processing example 6 25 Identical to example 1, apart from that carrots were used, in an amount of 75% (wt), and the amount of added water was less as a consequence of the increased amount of vegetable matter. The appearance was the same as for example 1, apart from 30 the color (being yellowish/orange for the carrots). A slight carrot taste could be detected.
WO99/65328 PCTIEP99/03593 11 Processing example 7 Broccoli florets were cut into pieces, 2-3 cm in length and the majority of the stalk discarded. They were then treated as the parsnips in example 5. The resulting product had an 5 appearance as the product in example 1, apart from the color (green). Mouthfeel was very much similar. Example 8 In this example homogenised carrots have been used to 10 thicken a tomato sauce. Carrots were peeled, sliced and cooked in deionized boiling water for 15 minutes. The vegetables were pureed using an industrial food processor (Robocoup Juicer) with a 0.5 mm sieve. The so-obtained vegetable puree was mixed with 30% 15 of water and passed through a high pressure homogeniser (type Niro Soavi Pand Lab Bench Model, at a pressure of 150 bar) to obtain the carrot homogenate. Remainder of the water (see table below), tomato paste (Brix 28), oil and salt were mixed together. 20 The carrot homogenate was added to the tomato sauce to obtain a thick, smooth tomato sauce having the following final composition: WO99/65328 PCTIEP99/03593 12 Ingredients % Homogenised carrot 20 tomato paste 7.3 Soybean oil 1.6 Salt 0.8 Water 70.3 100 The cold sauce was heated to boiling, hot filled in glass 5 jars and pasteurised. The pasteurised samples were stored for 6 weeks (chilled), opened and reheated, which resulted in a smooth, thick, tomato sauce having good mouthfeel and appearance. 10 Example 9 A basic sauce was prepared from homogenised parsnip-puree. The parsnips were peeled, sliced and cooked in deionized boiling water for 15 minutes. Thereafter, they were pureed 15 in an industrial food processor (Robocoup Juicer) with a 0.5 mm sieve. The so-obtained parsnip puree was mixed with 30% of water and passed through a high-pressure homogeniser (type Niro Soavi Pand lab Bench Model, at 150 bar) to obtain a basic 20 sauce (appearance: smooth, thick and non-gritty). After chilled storage for 6 weeks the physical appearance (thick, smooth, non-gritty) was not changed.

Claims (14)

1. Process for thickening a liquid, pourable or squeezable foodproduct by incorporating in said foodstuff in an amount of between 5 and 80% by weight a homogenised vegetable puree obtained by subjecting a vegetable to a homogenisation treatment wherein the vegetable has a starch content of less than 70 wt% based on the dry vegetable.

2. Process according to claim 1, wherein the starch content of the vegetable is less than 50% based on the dry vegetable.

3. Process according to claim 1 or 2, wherein the vegetable used for preparing the homogenised vegetable puree is one of roots, root-like vegetables, or plants of the genus Brassica oleracea, all preferably being low in starch.

4. Process according to claim 1, wherein the vegetable used for preparing the homogenised vegetable puree is selected from parsnips, turnips, mushrooms, cauliflower, swede, carrots, broccoli and mixtures thereof.

5. Process according to claim 1, wherein the homogenisation treatment is carried out by a high pressure homogeniser at a pressure of 100-200 bar or any equivalent treatment using an ultrasonic homogeniser or other homogenisation treatment. WO99/65328 PCTIEP99/03593 14

6. Process according to claim 1, wherein the homogenised vegetable puree is incorporated in the food product in an amount of between 10 and 60% by weight based on the final food product.

7. Process according to claim 6, wherein the homogenised vegetable puree is incorporated in the food product in an amount of between 20 and 45% by weight based on the final food product.

8. Process according to claim 1, wherein the food product further comprises water and optionally oil, fat, herbs, spices, comminuted vegetables, or mixtures thereof.

9. Process according to claim 1, wherein the food product is a dressing, mayonnaise, soup, sauce, simmer sauce or sauce base product.

10. Process according to any of claims 1-9, wherein further is incorporated in the liquid, pourable or squeezable foodproduct one or more of salt, herbs, spices, comminuted vegetable particles, water, organic acids, meat, vegetable oils or fats or mixtures thereof.

11. Liquid, pourable or squeezable foodproduct containing 5-80% by weight of a vegetable puree, wherein the vegetable puree has been homogenised, characterized in that the starch content of the vegetable is less than 70%, based on the dry vegetable.

12. Foodproduct according to claim 11, wherein the vegetable has been homogenised by an high pressure WO99/65328 PCT/EP99/03593 15 homogeniser at a pressure of 100-200 bar, or any equivalent homogenising treatment.

13. Foodproduct according to claim 11 or 12, wherein the homogenised vegetable puree is present in an amount of 10-60% by weight.

14. Use of a vegetable puree, wherein the vegetable puree has been homogenised, and wherein the starch content of the vegetable is less than 70%, based on the dry vegetable, for thickening a liquid, pourable or squeezable foodstuff.

AU45005/99A
1998-06-15
1999-05-21
Thickening agent based on homogenized vegetable puree, its preparation and its use in foodstuffs

Ceased

AU750191B2
(en)

Applications Claiming Priority (3)

Application Number
Priority Date
Filing Date
Title

EP98304724

1998-06-15

EP98304724

1998-06-15

PCT/EP1999/003593

WO1999065328A1
(en)

1998-06-15
1999-05-21
Thickening agent based on homogenized vegetable puree, its preparation and its use in foodstuffs

Publications (2)

Publication Number
Publication Date

AU4500599A
true

AU4500599A
(en)

2000-01-05

AU750191B2

AU750191B2
(en)

2002-07-11

Family
ID=8234876
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

AU45005/99A
Ceased

AU750191B2
(en)

1998-06-15
1999-05-21
Thickening agent based on homogenized vegetable puree, its preparation and its use in foodstuffs

Country Status (8)

Country
Link

US
(1)

US20020160094A1
(en)

EP
(1)

EP1087670B1
(en)

AR
(1)

AR018665A1
(en)

AU
(1)

AU750191B2
(en)

BR
(1)

BR9911261A
(en)

DE
(1)

DE69902389T2
(en)

WO
(1)

WO1999065328A1
(en)

ZA
(1)

ZA200006603B
(en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP1538928B1
(en)

2002-09-16
2007-01-03
Unilever N.V.
Thickening agent and process for thickening

RU2384253C2
(en)

2005-12-12
2010-03-20
Юнилевер Н.В.
Concentrate for making broth, soup, sauce, gravy or for using it as seasoning and that contains particles, gelatin and starch, method of its production and application

US8795749B2
(en)

2010-03-26
2014-08-05
Conopco, Inc.
Process for preparing a heat processed blend from two or more fresh plant materials

GB2486465B
(en)

2010-12-16
2017-01-11
Singh Lalvani Kartar
Novel substitutes as food additives

EP3639678B1
(en)

2017-08-24
2021-08-04
Mizkan Holdings Co., Ltd.
Liquid or semisolid emulsion seasoning, method for manufacturing same and flavor improving method

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Priority date
Publication date
Assignee
Title

GB732983A
(en)

1952-07-25
1955-07-06
William Evans & Co Hereford An
Manufacture of a base material for thick sauces

US3745020A
(en)

1971-05-05
1973-07-10
Us Agriculture
Process for preparing citrus puree

FR2331293A1
(en)

1975-11-17
1977-06-10
Roquette Freres

NEW APPLICATIONS OF THE POTATO PULP AND CORRESPONDING NEW PRODUCTS

JPS57202257A
(en)

1981-06-09
1982-12-11
Yakult Honsha Co Ltd
Production of liquid food with comfortably smooth and thick texture

US4413017A
(en)

1981-06-11
1983-11-01
General Mills, Inc.
Food product containing juice pulp and acidified milk components

US4931321A
(en)

1987-03-03
1990-06-05
John Harra
Frozen food composition

US5248515A
(en)

1992-02-04
1993-09-28
Gerber Products Company
Processing method using entire peeled vegetable in a fruit juice/vegetable puree beverage

IT1275904B1
(en)

1995-03-14
1997-10-24
Deve S R L

PROCEDURE FOR THE PREPARATION OF FOOD PRODUCTS CONTAINING CONCENTRATED VEGETABLES AND VEGETABLES

US5849350A
(en)

1995-08-07
1998-12-15
Ashourian; Jamshid
Process for producing shelf-stable fruit products by fruit cell fragmentation and products produced thereby

1999

1999-05-21
EP
EP99927753A
patent/EP1087670B1/en
not_active
Expired – Lifetime

1999-05-21
DE
DE69902389T
patent/DE69902389T2/en
not_active
Expired – Lifetime

1999-05-21
BR
BR9911261-2A
patent/BR9911261A/en
not_active
Application Discontinuation

1999-05-21
AU
AU45005/99A
patent/AU750191B2/en
not_active
Ceased

1999-05-21
WO
PCT/EP1999/003593
patent/WO1999065328A1/en
active
IP Right Grant

1999-06-11
AR
ARP990102801A
patent/AR018665A1/en
unknown

1999-06-15
US
US09/333,241
patent/US20020160094A1/en
not_active
Abandoned

2000

2000-11-14
ZA
ZA200006603A
patent/ZA200006603B/en
unknown

Also Published As

Publication number
Publication date

US20020160094A1
(en)

2002-10-31

BR9911261A
(en)

2001-03-13

EP1087670B1
(en)

2002-07-31

DE69902389D1
(en)

2002-09-05

ZA200006603B
(en)

2001-11-14

EP1087670A1
(en)

2001-04-04

AR018665A1
(en)

2001-11-28

DE69902389T2
(en)

2003-03-13

WO1999065328A1
(en)

1999-12-23

AU750191B2
(en)

2002-07-11

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