AU6367380A

AU6367380A – Hydroformylation of olefins using rhodium catalyst
– Google Patents

AU6367380A – Hydroformylation of olefins using rhodium catalyst
– Google Patents
Hydroformylation of olefins using rhodium catalyst

Info

Publication number
AU6367380A

AU6367380A
AU63673/80A
AU6367380A
AU6367380A
AU 6367380 A
AU6367380 A
AU 6367380A
AU 63673/80 A
AU63673/80 A
AU 63673/80A
AU 6367380 A
AU6367380 A
AU 6367380A
AU 6367380 A
AU6367380 A
AU 6367380A
Authority
AU
Australia
Prior art keywords
hydroformylation
olefins
rhodium catalyst
rhodium
catalyst
Prior art date
1979-10-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Granted

Application number
AU63673/80A
Other versions

AU538456B2
(en

Inventor
Ernst Billig
Donald Leroy Bunning
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Carbide Corp

Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1979-10-26
Filing date
1980-10-24
Publication date
1981-04-30

1980-10-24
Application filed by Union Carbide Corp
filed
Critical
Union Carbide Corp

1981-04-30
Publication of AU6367380A
publication
Critical
patent/AU6367380A/en

1984-08-16
Application granted
granted
Critical

1984-08-16
Publication of AU538456B2
publication
Critical
patent/AU538456B2/en

2000-10-24
Anticipated expiration
legal-status
Critical

Status
Ceased
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands

B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/20—Carbonyls

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds

C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide

C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00

B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds

B01J2231/32—Addition reactions to C=C or C-C triple bonds

B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00

B01J2531/80—Complexes comprising metals of Group VIII as the central metal

B01J2531/82—Metals of the platinum group

B01J2531/822—Rhodium

AU63673/80A
1979-10-26
1980-10-24
Hydroformylation of olefins using rhodium catalyst

Ceased

AU538456B2
(en)

Applications Claiming Priority (2)

Application Number
Priority Date
Filing Date
Title

US088827

1979-10-26

US06/088,827

US4283562A
(en)

1979-10-26
1979-10-26
Hydroformylation process using stable rhodium catalyst

Publications (2)

Publication Number
Publication Date

AU6367380A
true

AU6367380A
(en)

1981-04-30

AU538456B2

AU538456B2
(en)

1984-08-16

Family
ID=22213740
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

AU63673/80A
Ceased

AU538456B2
(en)

1979-10-26
1980-10-24
Hydroformylation of olefins using rhodium catalyst

Country Status (14)

Country
Link

US
(1)

US4283562A
(en)

EP
(1)

EP0028378B1
(en)

JP
(1)

JPS5671032A
(en)

KR
(1)

KR840000212B1
(en)

AU
(1)

AU538456B2
(en)

BR
(1)

BR8006845A
(en)

CA
(1)

CA1137998A
(en)

DE
(1)

DE3069950D1
(en)

IN
(1)

IN154537B
(en)

MX
(1)

MX155379A
(en)

PL
(1)

PL129099B1
(en)

SU
(1)

SU1678201A3
(en)

YU
(1)

YU42711B
(en)

ZA
(1)

ZA806160B
(en)

Families Citing this family (60)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US4593141A
(en)

*

1979-02-12
1986-06-03
Exxon Research And Engineering Co.
Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes

US4450299A
(en)

*

1980-10-01
1984-05-22
Exxon Research And Engineering Co.
Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes

US4687874A
(en)

*

1980-02-12
1987-08-18
Exxon Research And Engineering Company
Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts

US4687866A
(en)

*

1980-02-12
1987-08-18
Exxon Research And Engineering Company
Ligand exchange process for producing alkyl diaryl phosphine rhodium carbonyl hydrides

US4522933A
(en)

*

1981-08-17
1985-06-11
Union Carbide Corporation
Hydroformylation catalyst containing bisphosphine monooxide ligands

US4593011A
(en)

*

1981-08-17
1986-06-03
Union Carbide Corporation
Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands

US4491675A
(en)

*

1981-08-17
1985-01-01
Union Carbide Corporation
Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands

US4400548A
(en)

*

1981-08-17
1983-08-23
Union Carbide Corporation
Hydroformylation process using bisphosphine monooxide ligands

IT1140319B
(en)

*

1981-12-04
1986-09-24
Consiglio Nazionale Ricerche

CATALYST CONTAINING CHIRAL STEROID PHOSPHINS ASYMMETRICAL CATALYTIC PRECESSES THAT USE THEM

US4668809A
(en)

*

1982-05-03
1987-05-26
Exxon Research And Engineering
Transition metal complex catalysts

US4595753A
(en)

*

1982-05-03
1986-06-17
Exxon Research And Engineering Co.
Heterocycle-substituted alkyl diaryl phosphine rhodium caronyl hydride complex hydroformylation catalyst compositions

DE3372361D1
(en)

*

1982-06-11
1987-08-13
Davy Mckee London
Hydroformylation process

US4668823A
(en)

*

1983-12-30
1987-05-26
Union Carbide Corporation
Process for the preparation of bulky alkyldiarylphosphines and unsymmetrical aryldialkyl phosphines

US4599206A
(en)

1984-02-17
1986-07-08
Union Carbide Corporation
Transition metal complex catalyzed reactions

US5110990A
(en)

*

1984-03-30
1992-05-05
Union Carbide Chemicals & Plastics Technology Corporation
Process for recovery of phosphorus ligand from vaporized aldehyde

US4737588A
(en)

*

1984-12-28
1988-04-12
Union Carbide Corporation
Transition metal complex catalyzed reactions

US4593127A
(en)

*

1985-01-11
1986-06-03
Union Carbide Corporation
Hydroformylation process

US4625068A
(en)

*

1985-03-20
1986-11-25
Exxon Chemical Patents Inc.
Rhodium catalyzed hydroformylation of internal olefins

US4642388A
(en)

*

1985-08-30
1987-02-10
Exxon Chemical Patents Inc.
Rhodium catalyzed hydroformylation of alpha-substituted alpha-olefins

ATE66668T1
(en)

*

1986-07-01
1991-09-15
Davy Mckee London

PROCESS FOR THE PRODUCTION OF ALDEHYDES BY HYDROFORMYLATION.

US4716250A
(en)

*

1986-07-10
1987-12-29
Union Carbide Corporation
Hydroformylation using low volatile/organic soluble phosphine ligands

US4731486A
(en)

*

1986-11-18
1988-03-15
Union Carbide Corporation
Hydroformylation using low volatile phosphine ligands

US5113022A
(en)

*

1988-08-05
1992-05-12
Union Carbide Chemicals & Plastics Technology Corporation
Ionic phosphites used in homogeneous transition metal catalyzed processes

US5059710A
(en)

*

1988-08-05
1991-10-22
Union Carbide Chemicals And Plastics Technology Corporation
Ionic phosphites and their use in homogeneous transition metal catalyzed processes

JPH031927U
(en)

*

1989-05-26
1991-01-10

US5001274A
(en)

*

1989-06-23
1991-03-19
Union Carbide Chemicals And Plastics Company Inc.
Hydroformylation process

US5516965A
(en)

*

1995-01-18
1996-05-14
Exxon Research And Engineering Company
Unsaturates recovery and recycle process

US5675041A
(en)

*

1995-01-18
1997-10-07
Exxon Research & Engineering Company
Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene

US5520722A
(en)

*

1995-01-18
1996-05-28
Exxon Research And Engineering Company
Multiunsaturates removal process

US5763679A
(en)

*

1995-12-06
1998-06-09
Union Carbide Chemicals & Plastics Technology Corporation
Metal-ligand complex catalyzed processes

US6265619B1
(en)

1996-01-17
2001-07-24
Exxon Chemical Patents Inc.
Oxygenates and processes for their manufacture

US5892119A
(en)

*

1996-11-26
1999-04-06
Union Carbide Chemicals & Plastics Technology Corporation
Metal-ligand complex catalyzed processes

JP3864669B2
(en)

*

2000-05-08
2007-01-10
三菱化学株式会社

Hydroformylation process

CN101654462B
(en)

2003-07-03
2013-05-29
陶氏技术投资有限责任公司
Minimization of ligand degradation products, or reversion of same to useful phosphine ligands

DE10349343A1
(en)

*

2003-10-23
2005-06-02
Basf Ag

Stabilization of hydroformylation catalysts based on phosphoramidite ligands

DE10352261B4
(en)

*

2003-11-08
2006-08-24
Celanese Chemicals Europe Gmbh

Process for the preparation of TCD-dialdehyde

CN1993311B
(en)

*

2004-08-02
2010-06-23
陶氏技术投资有限责任公司
Stabilization of a hydroformylation process

PL1863747T3
(en)

*

2005-03-16
2017-06-30
Perstorp Specialty Chemicals Ab
Hydroformylation process with improved iso-selectivity

WO2009091669A1
(en)

2008-01-15
2009-07-23
Dow Global Technologies Inc.
Sulfonated organophosphine compounds and use in hydroformylation processes

DE102009004655B4
(en)

2009-01-15
2013-02-14
Oxea Gmbh

Process for the preparation of aldehydes

DE102009016652A1
(en)

2009-04-07
2010-10-14
Oxea Gmbh

Process for working up a liquid hydroformylation discharge

DE102009016651B4
(en)

2009-04-07
2011-11-17
Oxea Gmbh

Process for the preparation of aldehydes

WO2013048701A1
(en)

2011-09-30
2013-04-04
Dow Technology Investments Llc
Purification process

CA2858351C
(en)

2011-12-20
2016-11-22
Dow Technology Investments Llc
A hydroformylation process

US8710276B2
(en)

*

2012-05-24
2014-04-29
Lg Chem, Ltd.
Catalyst compositions for hydroformylation reaction and hydroformylation process using the same

DE102012105878A1
(en)

2012-07-02
2014-01-02
Oxea Gmbh

Process for the preparation of isopentane derivatives

DE102012014396B4
(en)

2012-07-13
2018-01-11
Oxea Gmbh

Process for the preparation of a vinyl ester mixture from a mixture of positionally isomeric aliphatic Isononansäuren starting from 2-ethylhexanol

DE102012014395B3
(en)

2012-07-13
2013-08-22
Oxea Gmbh

Isononylamines starting from 2-ethylhexanol, process for their preparation and their use

DE102012013969B4
(en)

2012-07-13
2017-09-14
Oxea Gmbh

Process for the preparation of a mixture of positionally isomeric aliphatic isononanoic acids starting from 2-ethylhexanol

DE102012013968A1
(en)

2012-07-13
2014-04-03
Oxea Gmbh

Carboxylic acid ester of isononanoic acid starting from 2-ethylhexanol, process for their preparation and their use

CN104248860A
(en)

2013-06-27
2014-12-31
陶氏技术投资有限责任公司
Heat management process

DE102013113724A1
(en)

2013-12-09
2015-06-11
Oxea Gmbh

Process for the preparation of pentane derivatives and derivatives of alpha, beta-unsaturated decenals from propylene

MX2018009690A
(en)

2016-02-11
2018-09-11
Dow Technology Investments Llc
Processes for converting olefins to alcohols, ethers, or combinations thereof.

TWI788364B
(en)

2017-06-23
2023-01-01
美商陶氏科技投資有限公司
Hydroformylation reaction processes

US20210114010A1
(en)

2018-05-30
2021-04-22
Dow Technology Investments Llc
Catalyst compositions and hydroformylation processes

EP3802476B1
(en)

2018-05-30
2022-04-13
Dow Technology Investments LLC
Methods of controlling hydroformylation processes

KR20210013702A
(en)

2018-05-30
2021-02-05
다우 테크놀로지 인베스트먼츠 엘엘씨.

How to slow the deactivation of the catalyst and/or slow the use of tetraphosphine ligands in the hydroformylation process

CN113698280B
(en)

*

2020-05-21
2023-10-13
中国石油化工股份有限公司
Olefin hydroformylation method

CN114515606A
(en)

*

2020-11-20
2022-05-20
万华化学集团股份有限公司
Hydroformylation reaction catalyst composition and application thereof

EP4267543A1
(en)

2020-12-22
2023-11-01
Dow Technology Investments LLC
Hydroformylation reaction processes

Family Cites Families (10)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3448157A
(en)

*

1965-09-27
1969-06-03
Shell Oil Co
Hydroformylation of olefins

US3487112A
(en)

*

1967-04-27
1969-12-30
Monsanto Co
Vapor phase hydroformylation process

US3527809A
(en)

*

1967-08-03
1970-09-08
Union Carbide Corp
Hydroformylation process

US3644446A
(en)

*

1969-07-01
1972-02-22
Union Oil Co
Preparation of rhodium and iridium hydride carbonyl complexes

CA918673A
(en)

*

1969-12-22
1973-01-09
L. Pruett Roy
Hydroformylation process

US4101588A
(en)

*

1973-04-07
1978-07-18
Basf Aktiengesellschaft
Production of bis-(dimethyl) acetals of hexane dialdehydes

IT1005691B
(en)

*

1973-04-07
1976-09-30
Basf Ag

PROCESS FOR THE PREPARATION OF ALIPHATIC OR CYCLOALIPHATIC DIALDEHYDES AND OF THEIR ACETALS

FR2351077A1
(en)

*

1976-05-13
1977-12-09
Celanese Corp

PERFECTED PROCESS FOR HYDROFORMYLATION OF OLEFINS WITH A COMPLEX RHODIUM CATALYST

ZA78146B
(en)

*

1977-01-25
1978-12-27
Union Carbide Corp
Improved hydroformylation process

US4215077A
(en)

*

1978-02-09
1980-07-29
Kuraray Co., Ltd.
Hydroformylation of olefins

1979

1979-10-26
US
US06/088,827
patent/US4283562A/en
not_active
Expired – Lifetime

1980

1980-10-06
ZA
ZA00806160A
patent/ZA806160B/en
unknown

1980-10-09
CA
CA000362086A
patent/CA1137998A/en
not_active
Expired

1980-10-23
YU
YU2722/80A
patent/YU42711B/en
unknown

1980-10-23
SU
SU803250148A
patent/SU1678201A3/en
active

1980-10-24
KR
KR1019800004078A
patent/KR840000212B1/en
active

1980-10-24
PL
PL1980227478A
patent/PL129099B1/en
unknown

1980-10-24
EP
EP80106539A
patent/EP0028378B1/en
not_active
Expired

1980-10-24
IN
IN1205/CAL/80A
patent/IN154537B/en
unknown

1980-10-24
DE
DE8080106539T
patent/DE3069950D1/en
not_active
Expired

1980-10-24
MX
MX184472A
patent/MX155379A/en
unknown

1980-10-24
AU
AU63673/80A
patent/AU538456B2/en
not_active
Ceased

1980-10-24
JP
JP14823480A
patent/JPS5671032A/en
active
Granted

1980-10-24
BR
BR8006845A
patent/BR8006845A/en
not_active
IP Right Cessation

Also Published As

Publication number
Publication date

CA1137998A
(en)

1982-12-21

DE3069950D1
(en)

1985-02-21

US4283562A
(en)

1981-08-11

PL129099B1
(en)

1984-03-31

SU1678201A3
(en)

1991-09-15

KR830004326A
(en)

1983-07-09

IN154537B
(en)

1984-11-03

BR8006845A
(en)

1981-04-28

EP0028378B1
(en)

1985-01-09

YU42711B
(en)

1988-12-31

YU272280A
(en)

1983-10-31

AU538456B2
(en)

1984-08-16

KR840000212B1
(en)

1984-02-29

PL227478A1
(en)

1981-07-10

EP0028378A1
(en)

1981-05-13

MX155379A
(en)

1988-02-26

JPS5671032A
(en)

1981-06-13

ZA806160B
(en)

1981-09-30

JPH02332B2
(en)

1990-01-08

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