AU8143487A – New derivatives of 2,2-dimethyl cyclopropane carboxylic acid having a saturated halogenated chain in position 3, the process and the intermediates for their preparation, their use as pesticides and the compositions containing them
– Google Patents
AU8143487A – New derivatives of 2,2-dimethyl cyclopropane carboxylic acid having a saturated halogenated chain in position 3, the process and the intermediates for their preparation, their use as pesticides and the compositions containing them
– Google Patents
New derivatives of 2,2-dimethyl cyclopropane carboxylic acid having a saturated halogenated chain in position 3, the process and the intermediates for their preparation, their use as pesticides and the compositions containing them
Info
Publication number
AU8143487A
AU8143487A
AU81434/87A
AU8143487A
AU8143487A
AU 8143487 A
AU8143487 A
AU 8143487A
AU 81434/87 A
AU81434/87 A
AU 81434/87A
AU 8143487 A
AU8143487 A
AU 8143487A
AU 8143487 A
AU8143487 A
AU 8143487A
Authority
AU
Australia
Prior art keywords
pesticides
intermediates
preparation
carboxylic acid
compositions containing
Prior art date
1986-11-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
AU81434/87A
Other versions
AU593955B2
(en
Inventor
Joseph Cadiergue
Jean-Pierre Demoute
Jean Tessier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1986-11-20
Filing date
1987-11-20
Publication date
1988-08-04
1987-11-20
Application filed by Roussel Uclaf SA
filed
Critical
Roussel Uclaf SA
1988-08-04
Publication of AU8143487A
publication
Critical
patent/AU8143487A/en
1990-02-22
Application granted
granted
Critical
1990-02-22
Publication of AU593955B2
publication
Critical
patent/AU593955B2/en
2007-11-20
Anticipated expiration
legal-status
Critical
Status
Ceased
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
BFNMOMYTTGHNGJ-UHFFFAOYSA-N
2,2-dimethylcyclopropane-1-carboxylic acid
Chemical class
CC1(C)CC1C(O)=O
BFNMOMYTTGHNGJ-UHFFFAOYSA-N
0.000
title
1
239000000543
intermediate
Substances
0.000
title
1
239000000203
mixture
Substances
0.000
title
1
239000000575
pesticide
Substances
0.000
title
1
229920006395
saturated elastomer
Polymers
0.000
title
1
125000000217
alkyl group
Chemical group
0.000
abstract
2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
Ethanol
Chemical compound
CCO
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
0.000
abstract
1
125000003118
aryl group
Chemical group
0.000
abstract
1
230000015572
biosynthetic process
Effects
0.000
abstract
1
150000001875
compounds
Chemical class
0.000
abstract
1
150000002148
esters
Chemical class
0.000
abstract
1
125000005010
perfluoroalkyl group
Chemical group
0.000
abstract
1
238000003786
synthesis reaction
Methods
0.000
abstract
1
Classifications
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07D—HETEROCYCLIC COMPOUNDS
C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
C07D213/62—Oxygen or sulfur atoms
C07D213/63—One oxygen atom
C07D213/64—One oxygen atom attached in position 2 or 6
C07D213/647—One oxygen atom attached in position 2 or 6 and having in the molecule an acyl radical containing a saturated three-membered ring, e.g. chrysanthemumic acid esters
A—HUMAN NECESSITIES
A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
A—HUMAN NECESSITIES
A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
A—HUMAN NECESSITIES
A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
A—HUMAN NECESSITIES
A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
A01N57/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus as a ring member
A—HUMAN NECESSITIES
A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
A23K—FODDER
A23K20/00—Accessory food factors for animal feeding-stuffs
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
C07C309/01—Sulfonic acids
C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
C07C309/41—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
C07C309/42—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton having the sulfo groups bound to carbon atoms of non-condensed six-membered aromatic rings
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
C07C309/63—Esters of sulfonic acids
C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
C07C309/63—Esters of sulfonic acids
C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
C07C309/66—Methanesulfonates
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
C07C309/63—Esters of sulfonic acids
C07C309/72—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
C07C61/16—Unsaturated compounds
C07C61/40—Unsaturated compounds containing halogen
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
C07C69/757—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07D—HETEROCYCLIC COMPOUNDS
C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
C07D213/62—Oxygen or sulfur atoms
C07D213/63—One oxygen atom
C07D213/64—One oxygen atom attached in position 2 or 6
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07D—HETEROCYCLIC COMPOUNDS
C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
C07D317/18—Radicals substituted by singly bound oxygen or sulfur atoms
C07D317/24—Radicals substituted by singly bound oxygen or sulfur atoms esterified
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
C07F9/02—Phosphorus compounds
C07F9/06—Phosphorus compounds without P—C bonds
C07F9/08—Esters of oxyacids of phosphorus
C07F9/09—Esters of phosphoric acids
C07F9/117—Esters of phosphoric acids with cycloaliphatic alcohols
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
C07F9/02—Phosphorus compounds
C07F9/06—Phosphorus compounds without P—C bonds
C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
C07F9/165—Esters of thiophosphoric acids
C07F9/177—Esters of thiophosphoric acids with cycloaliphatic alcohols
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
C07F9/02—Phosphorus compounds
C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
C07F9/576—Six-membered rings
C07F9/58—Pyridine rings
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
C07F9/02—Phosphorus compounds
C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
C07F9/65502—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a three-membered ring
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
C07F9/02—Phosphorus compounds
C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
C07F9/6574—Esters of oxyacids of phosphorus
C07F9/65742—Esters of oxyacids of phosphorus non-condensed with carbocyclic rings or heterocyclic rings or ring systems
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2601/00—Systems containing only non-condensed rings
C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Abstract
Compounds of formula (I):
in which X1 and X2 = Hal, R1 = alkyl, aryl, perfluoroalkyl, C IDENTICAL N,
and R=H, alkyl or the residue of an alcohol employed in the synthesis of the pyrethrinoid esters.
AU81434/87A
1986-11-20
1987-11-20
New derivatives of 2,2-dimethyl cyclopropane carboxylic acid having a saturated halogenated chain in position 3, the process and the intermediates for their preparation, their use as pesticides and the compositions containing them
Ceased
AU593955B2
(en)
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
FR8616155A
FR2607133B1
(en)
1986-11-20
1986-11-20
NOVEL DERIVATIVES OF 2,2-DIMETHYL CARBOXYLIC CYCLOPROPANE CYCLOPROPANE CARRYING IN 3 A SATURATED HALOGENATED CHAIN, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS PESTICIDES
FR8616155
1986-11-20
Publications (2)
Publication Number
Publication Date
AU8143487A
true
AU8143487A
(en)
1988-08-04
AU593955B2
AU593955B2
(en)
1990-02-22
Family
ID=9341015
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
AU81434/87A
Ceased
AU593955B2
(en)
1986-11-20
1987-11-20
New derivatives of 2,2-dimethyl cyclopropane carboxylic acid having a saturated halogenated chain in position 3, the process and the intermediates for their preparation, their use as pesticides and the compositions containing them
Country Status (18)
Country
Link
US
(2)
US4925874A
(en)
EP
(3)
EP0445843B1
(en)
JP
(2)
JP2717787B2
(en)
KR
(1)
KR960010787B1
(en)
CN
(2)
CN1033028C
(en)
AT
(2)
ATE119516T1
(en)
AU
(1)
AU593955B2
(en)
BR
(1)
BR8706250A
(en)
DE
(3)
DE3789064T2
(en)
ES
(3)
ES2062598T3
(en)
FR
(1)
FR2607133B1
(en)
GR
(1)
GR3005520T3
(en)
HU
(1)
HU206075B
(en)
MX
(1)
MX9412A
(en)
OA
(1)
OA08693A
(en)
PT
(1)
PT86171B
(en)
RU
(1)
RU1779242C
(en)
ZA
(1)
ZA878666B
(en)
Families Citing this family (7)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
FR2607133B1
(en)
*
1986-11-20
1989-05-05
Roussel Uclaf
NOVEL DERIVATIVES OF 2,2-DIMETHYL CARBOXYLIC CYCLOPROPANE CYCLOPROPANE CARRYING IN 3 A SATURATED HALOGENATED CHAIN, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS PESTICIDES
KR880007430A
(en)
*
1986-12-11
1988-08-27
허버트 프리텔
Method for preparing pentafluorophenylmethyl 2,2-dimethyl3-formyl cyclopropane carboxylate
DK90688A
(en)
*
1987-02-24
1988-08-25
Sandoz Ag
PROCEDURE FOR PREPARING CYCLOPROPANCARBOXYL ACID ESTERS
FR2636945B1
(en)
*
1988-09-29
1991-04-19
Roussel Uclaf
NOVEL DERIVATIVES OF 2,2-DIMETHYL ACID 3- (1-HYDROXY-2-SULFINO-ETHYL) CYCLOPROPANE CARBOXYLIC, PROCESS FOR THEIR PREPARATION AND THEIR USE AS PESTICIDES
DK171797B1
(en)
*
1995-07-21
1997-06-02
Cheminova Agro As
Cyclopropane derivatives and process for the preparation of cyclopropane carboxylic acids, in which these cyclopropane derivatives are included as intermediates.
US8466096B2
(en)
*
2007-04-26
2013-06-18
Afton Chemical Corporation
1,3,2-dioxaphosphorinane, 2-sulfide derivatives for use as anti-wear additives in lubricant compositions
US20210216996A1
(en)
*
2018-12-11
2021-07-15
Ccs 12
Device and method for securing secure data for a bank payment card
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Publication number
Priority date
Publication date
Assignee
Title
JPS5850209B2
(en)
*
1975-04-15
1983-11-09
住友化学工業株式会社
2 2-dimethyl-3-(2 2-dihalovinyl)-cyclopropanecarbonyl
GB1572183A
(en)
*
1975-09-05
1980-07-23
Wellcome Found
Cyclopropane carboxylic acid ester synthesis and intermediates therefor
FR2396006A1
(en)
*
1977-06-27
1979-01-26
Roussel Uclaf
NEW CYCLOPROPANIC CORE COMPOUNDS, PREPARATION PROCESS AND APPLICATION TO THE PREPARATION OF CYCLOPROPANIC DERIVATIVES WITH DIHALOVINYL CHAIN
EP0021521B1
(en)
*
1979-07-03
1982-12-15
Shell Internationale Researchmaatschappij B.V.
Process for the preparation of dihalovinyl compounds
US4376785A
(en)
*
1980-06-19
1983-03-15
Sumitomo Chemical Company, Limited
Cyclopropanecarboxylates and a low fish toxic insecticide and/or acaricide containing them
DE3037302A1
(en)
*
1980-10-02
1982-05-27
Bayer Ag, 5090 Leverkusen
BISSILYLATED L-HYDROXYCYCLOPROPANCARBONIC ACIDS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS INTERMEDIATE PRODUCTS
GB2099810A
(en)
*
1981-06-09
1982-12-15
Shell Int Research
Cyclopropanecarboxylate esters and their use as pesticides
FR2534252A1
(en)
*
1982-10-12
1984-04-13
Roussel Uclaf
NOVEL 3-SUBSTITUTED CYCLOPROPANE CARBOXYLIC ACID DERIVATIVES FROM A SUBSTITUTED SINGLE-VINYL CHAIN, PROCESS FOR PREPARING THEM AND THEIR APPLICATION AS PESTICIDES
IT1206727B
(en)
*
1985-01-11
1989-05-03
Donegani Guido Ist
PROCESS FOR THE PREPARATION OF POLYALOGENATED CARBINOLS.
JPH0674238B2
(en)
*
1985-09-30
1994-09-21
財団法人相模中央化学研究所
2,2-Dimethylcyclopropanecarboxylic acid derivative
FR2607133B1
(en)
*
1986-11-20
1989-05-05
Roussel Uclaf
NOVEL DERIVATIVES OF 2,2-DIMETHYL CARBOXYLIC CYCLOPROPANE CYCLOPROPANE CARRYING IN 3 A SATURATED HALOGENATED CHAIN, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS PESTICIDES
1986
1986-11-20
FR
FR8616155A
patent/FR2607133B1/en
not_active
Expired
1987
1987-11-18
MX
MX941287A
patent/MX9412A/en
unknown
1987-11-18
HU
HU875123A
patent/HU206075B/en
not_active
IP Right Cessation
1987-11-19
DE
DE3789064T
patent/DE3789064T2/en
not_active
Expired – Fee Related
1987-11-19
EP
EP91105956A
patent/EP0445843B1/en
not_active
Expired – Lifetime
1987-11-19
DE
DE8787402605T
patent/DE3781383T2/en
not_active
Expired – Fee Related
1987-11-19
EP
EP91105958A
patent/EP0451873B1/en
not_active
Expired – Lifetime
1987-11-19
AT
AT91105958T
patent/ATE119516T1/en
not_active
IP Right Cessation
1987-11-19
PT
PT86171A
patent/PT86171B/en
not_active
IP Right Cessation
1987-11-19
RU
SU874203815A
patent/RU1779242C/en
active
1987-11-19
ES
ES91105956T
patent/ES2062598T3/en
not_active
Expired – Lifetime
1987-11-19
ES
ES87402605T
patent/ES2051762T3/en
not_active
Expired – Lifetime
1987-11-19
DE
DE3751149T
patent/DE3751149T2/en
not_active
Expired – Fee Related
1987-11-19
BR
BR8706250A
patent/BR8706250A/en
unknown
1987-11-19
ES
ES91105958T
patent/ES2069765T3/en
not_active
Expired – Lifetime
1987-11-19
ZA
ZA878666A
patent/ZA878666B/en
unknown
1987-11-19
EP
EP87402605A
patent/EP0269514B1/en
not_active
Expired – Lifetime
1987-11-20
OA
OA59226A
patent/OA08693A/en
unknown
1987-11-20
AU
AU81434/87A
patent/AU593955B2/en
not_active
Ceased
1987-11-20
US
US07/123,374
patent/US4925874A/en
not_active
Expired – Lifetime
1987-11-20
KR
KR1019870013093A
patent/KR960010787B1/en
active
IP Right Grant
1987-11-20
CN
CN87101182A
patent/CN1033028C/en
not_active
Expired – Fee Related
1987-11-20
JP
JP29224687A
patent/JP2717787B2/en
not_active
Expired – Fee Related
1989
1989-10-18
US
US07/423,803
patent/US5082832A/en
not_active
Expired – Fee Related
1991
1991-04-15
AT
AT91105956T
patent/ATE101391T1/en
active
1992
1992-08-27
GR
GR920400799T
patent/GR3005520T3/el
unknown
1994
1994-11-18
JP
JP30834994A
patent/JP2710097B2/en
not_active
Expired – Fee Related
1995
1995-10-07
CN
CN95115659A
patent/CN1125714A/en
active
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CN1125714A
(en)
1996-07-03
RU1779242C
(en)
1992-11-30
EP0451873A1
(en)
1991-10-16
EP0445843A3
(en)
1991-09-18
EP0451873B1
(en)
1995-03-08
PT86171A
(en)
1987-12-01
DE3789064D1
(en)
1994-03-24
JP2717787B2
(en)
1998-02-25
DE3789064T2
(en)
1994-06-01
MX9412A
(en)
1993-11-01
DE3781383D1
(en)
1992-10-01
DE3751149D1
(en)
1995-04-13
CN87101182A
(en)
1988-07-13
EP0445843A2
(en)
1991-09-11
ES2069765T3
(en)
1995-05-16
HUT47398A
(en)
1989-03-28
EP0269514A3
(en)
1988-09-14
KR960010787B1
(en)
1996-08-08
US4925874A
(en)
1990-05-15
FR2607133B1
(en)
1989-05-05
EP0269514A2
(en)
1988-06-01
EP0269514B1
(en)
1992-08-26
KR880006161A
(en)
1988-07-21
ES2051762T3
(en)
1994-07-01
BR8706250A
(en)
1988-06-21
ZA878666B
(en)
1989-01-25
DE3751149T2
(en)
1995-07-20
OA08693A
(en)
1989-03-31
PT86171B
(en)
1990-11-07
AU593955B2
(en)
1990-02-22
FR2607133A1
(en)
1988-05-27
JPS63150272A
(en)
1988-06-22
DE3781383T2
(en)
1993-03-04
EP0445843B1
(en)
1994-02-09
ES2062598T3
(en)
1994-12-16
US5082832A
(en)
1992-01-21
GR3005520T3
(en)
1993-06-07
ATE101391T1
(en)
1994-02-15
HU206075B
(en)
1992-08-28
CN1033028C
(en)
1996-10-16
JPH0848652A
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1996-02-20
ATE119516T1
(en)
1995-03-15
JP2710097B2
(en)
1998-02-10
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