AU648887B2 - Creation of Inventions and Patents with Artificial Intelligence

AU648887B2 – Durably hydrophilic, thermoplastic fiber
– Google Patents

AU648887B2 – Durably hydrophilic, thermoplastic fiber
– Google Patents
Durably hydrophilic, thermoplastic fiber

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Publication number
AU648887B2

AU648887B2
AU14970/92A
AU1497092A
AU648887B2
AU 648887 B2
AU648887 B2
AU 648887B2
AU 14970/92 A
AU14970/92 A
AU 14970/92A
AU 1497092 A
AU1497092 A
AU 1497092A
AU 648887 B2
AU648887 B2
AU 648887B2
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AU
Australia
Prior art keywords
fiber
group
compound
thermoplastic
fabric
Prior art date
1991-05-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

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Application number
AU14970/92A
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AU1497092A
(en

Inventor
Robert Archie Gardiner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

3M Co

Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1991-05-02
Filing date
1992-04-15
Publication date
1994-05-05

1992-04-15
Application filed by Minnesota Mining and Manufacturing Co
filed
Critical
Minnesota Mining and Manufacturing Co

1992-11-05
Publication of AU1497092A
publication
Critical
patent/AU1497092A/en

1994-05-05
Application granted
granted
Critical

1994-05-05
Publication of AU648887B2
publication
Critical
patent/AU648887B2/en

2012-04-15
Anticipated expiration
legal-status
Critical

Status
Ceased
legal-status
Critical
Current

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Classifications

D—TEXTILES; PAPER

D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING

D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS

D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof

D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers

D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent

A—HUMAN NECESSITIES

A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE

A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES

A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads

A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons

A61L15/20—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing organic materials

D—TEXTILES; PAPER

D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING

D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS

D01F1/00—General methods for the manufacture of artificial filaments or the like

D01F1/02—Addition of substances to the spinning solution or to the melt

D01F1/10—Other agents for modifying properties

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S428/00—Stock material or miscellaneous articles

Y10S428/903—Microfiber, less than 100 micron diameter

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S428/00—Stock material or miscellaneous articles

Y10S428/913—Material designed to be responsive to temperature, light, moisture

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

Y10T428/00—Stock material or miscellaneous articles

Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof

Y10T428/2913—Rod, strand, filament or fiber

Y10T428/2933—Coated or with bond, impregnation or core

Y10T428/2964—Artificial fiber or filament

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

Y10T428/00—Stock material or miscellaneous articles

Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof

Y10T428/2913—Rod, strand, filament or fiber

Y10T428/2933—Coated or with bond, impregnation or core

Y10T428/2964—Artificial fiber or filament

Y10T428/2967—Synthetic resin or polymer

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]

Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]

Y10T442/608—Including strand or fiber material which is of specific structural definition

Y10T442/614—Strand or fiber material specified as having microdimensions [i.e., microfiber]

Y10T442/626—Microfiber is synthetic polymer

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]

Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]

Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material

Y10T442/642—Strand or fiber material is a blend of polymeric material and a filler material

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]

Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]

Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]

Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]

Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet

Y10T442/675—Ester condensation polymer sheet or film [e.g., polyethylene terephthalate, etc.]

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]

Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]

Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet

Y10T442/678—Olefin polymer or copolymer sheet or film [e.g., polypropylene, polyethylene, ethylene-butylene copolymer, etc.]

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]

Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]

Y10T442/68—Melt-blown nonwoven fabric

Description

648887
AUSTRALIA
PATENTS ACT 1990 COMPLETE SPECIFICATION FOR A STANDARD PATENT
ORIGINAL
S F Ref: 208056 Name and Address of Applicant: Actual Inventor(s): Address for Service: Minnesota Mining and Manufacturing Company 3M Center Saint Paul Minnesota 55144-1000 UNITED STATES OF AMERICA Robert Archie Gardiner Spruson Ferguson, Patent Attorneys Level 33 St Martins Tower, 31 Market Street Sydney, New South Wales, 2000, Australia Durably Hydrophilic, Thermoplastic Fiber Invention i’tle: The following statement is a full description of this invention, including the best method of performing it known to me/us:- R4R9 q 45848AUS3A 1 DURABLY HYDROPHILIC, THERMOPLASTIC FIBER This invention relates to fiber comprising thermoplastic polymer, such as polypropylene. In another aspect it relates to methods of preparation of durably hydrophilic fiber from normally hydrophobic thermoplastic polymer. In another aspect it relates to fabrics comprising durably hydrophilic fiber, useful, for example, as liners for diapers, and methods of making such fabric.
.Thermoplastic polymers are widely used to make a variety of products, including for example, blown and cast films, extruded sheets, foams, woven and knitted fabrics, and non-woven fibrous webs. Many thermoplastic polymers, such as polyolefins, are normally hydrophobic. There are a number of uses for thermoplastic polymers where their hydrophobic nature either limits their use or requires some effort to 20 modify the’surface of the shaped articles made .therefrom. For example, polyolefins are used to manufacture nonwoven webs which are employed in the construction of absorbent articles such as diapers, feminine care products, and incontinence products, the use of such articles being limited due to their .hydrophobic nature.
When fiber, and the fabric made therefrom, is still hydrophilic after contact with deionized water and drying, such fiber and fabric is said to have S 30 durable hydrophilicity. Hydrophilic fiber can be obtained by spraying or coating the fiber with surfactant followed by drying. Typically, the surfactant which remains on the fiber is diminished or completely lost upon contact with aqueous media, e.g.
water, and thus the hydrophilirity of the fibers has poor durability. Hydrophilicity, or the lack thereof, can be measured in a variety of ways, for example, when water contacts a nonwoven web that has lost its 2 hydrophilicity, the water does not flow through, or flows undesirably slow through, the web.
U.S. Pat. No. 4,328,279 (Meitner et al.) describes a wettable nonwoven wiper which is provided through the treatment of nonwoven material with a mixture of wetting agents. Mixtures of sodium dioctyl sulfosuccinate and a non-ionic surfactant, such as alkyl phenoxy ethanol, were used to treat nonwoven materials made from normally hydrophobic thermoplastic fibers. The nonwoven materials can be treated with the surfactant mixture by conventional techniques such as spraying, dipping, coating, impregnating, and printing.
U.S. Pat. No. 3,870,567 (Palmer et al.) describes a method for producing wettable nonwoven fibers from normally hydrophobic thermoplastic resins.
These fibers are prepared from mixtures of thermoplastic resin, such as polypropylene, and internal wetting agent. It is very important to develop the wetting agent after the fiber has been 20 cooled. Developing usually includes both heating and compression.
U.S. Pat. Nos. 4,857,251 (Nohr et al.) and 4,920,168 (Nohr et al.) describe a method of forming fibers by melt-extrusion of a surface segregatable thermoplastic composition which comprises thermoplastic polymer and siloxane-containing additive having certain moieties. After the fiber is formed, it is heated from 27 0 C to 95 0 C for a period of time sufficient to increase the amount of additive at the fiber surface. The 30 resulting fiber has increased surface hydrophilicity compared to fibers prepared from the thermoplastic Sresin alone.
Fluoroalpihatic groups are generally *hydrophobic, and the use of various fluorochemical compositions on fibers or fibrous substrates, such as textiles, paper, and leather, to impart water repellency is known. See, for example, Banks, Ed., 3 Organofluorine Chemicals and Their Industrial Applications, Elis Horwood Ltd., Chichester, England, 1979, pp 226-234. Such fluorochemical compositions include, for example, fluorochemical guanidines (U.S.
Pat. No. 4,540,497, Chang), compositions of cationic and non-cationic fluorochemicals Pat. No.
4,566,981, Howells), compositions containing fluorochemical carboxylic acid and epoxidic cationic resin Pat. No. 4,426,466, Schwartz), fluoroaliphatic carbodiimides Pat. No. 4,215,205, Landucci), and fluoroaliphatic alcohols Pat. No.
4,468,527, Patel).
Fluorochemical compositions can be applied to various substrates by methods which include, for example, spraying, padding, and finish bath immersion.
Textile fibers and yarns can also be treated by incorporation of the fluorochemical in fiber spin finishes and by melt extrusion of a blend of a synthetic fiber-forming polymer and a fluorochemical composition. Such melt extrusion is described, for example, by Mares, F. et al., “Modification of Fiber Surfaces by Monomeric Additives, Part I: Extrusion Techniques,” Textile Research Journal, Vol. 48, No. 4, pp 218-229, and in U.S. Pat. No. 3,899,563 (Oxenrider et Compounds may be incorporated into polymer melts by injection of the compound into the molten polymer stream immediately on exiting the extruder barrel according to the procedure described in U.S.
Pat. No. 4,933,229 (Insley et al.).
I 30 European Pat. Pub. No. 0 260 011 (Crater et al.) discloses certain fluoroaliphatic group-containing oxazolidinone compositions. The Crater application also discloses fibers, films, and molded articles prepared, for example, by injection molding a blend or mixture of fiber- or film-forming synthetic organic polymers and certain fluorochemical oxazolidinones. The resulting fibers, films, and 4 molded articles are said to have low surface energy, oil and water repellency, and anti-soiling properties.
U.S. Pat. No. 3,787,351 (Olson) discloses reinforced resin composite compositions wherein the wetting of the surface of particulate reinforcing material by resins is improved by the use of certain fluoroaliphatic radical-containing oligomers.
Particular oligomers are copolymers of fluoroaliphatic radical-containing monomers and monomers with moieties that solubilize the resin. Useful solubilizing moieties include poly(oxyalkylene) moieties.
The use of certain fluorochemical compositions as processing aids in the extrusion of synthetic resins into fibers and films is also known.
See for example, Rudkin et al., “Fluorocarbon Elastomer Aids Polyolefin Extrusion,” Plastics Enqineerin March 1986. pp 83-86 and U.S. Pat. No. 4,855,360 (Duchesne et al.).
U.S. Pat. No. 4,093,775 (Szur) discloses applying directly to a polymer shape, such as nylon S^ films and filaments, or compounding with the polymeric material prior to shaping, or incorporating internally in the polymeric shape, non-ionic surfactants made from the reaction of 6-hydroxyhexyl perfluoroisopropylether or 2,2,3,4,4,4-hexafluorobutanol with ethylene oxide and/or propylene oxide. These non-ionic surfactants S” are said to be useful as antistatic agents, lubricants and antisoiling agents for polymeric shapes such as nylon films and filaments.
30 U.S. Pat. No. 5,043,195 (Skerivseth) describes flexible sheet material comprising an antistatic layer. Said antistatic layer comprises a polymer having dispersed therein a fluoroaliphatic •sulfonamide polyether.
Briefly, the present invention, in one aspect, provides durably hydrophilic, thermoplastic fiber comprising a mixture of thermoplastic polymer, such as polyamide, polyurethane, or polyolefin, e.g.
5 polypropylene, and fluoroaliphatic group-containing non-ionic compound which imparts durable hydrophilicity to the surface of the fiber. The compound is dispersed within the fiber and is present at the surface of the fiber. The compound is present in an amount sufficient to impart durable hydrophilicity to said surfaces. The fiber cai. be fabricated in the form of a durably hydrophilic nonwoven web.
The fluoroaliphatic group-containing non-ionic compounds useful in the present invention comprise a fluoroaliphatic group and a non-ionic water solubilizing group such as poly(oxyethylene), poly(oxypropylene), or poly(oxyethylene-co-oxypropylene). The fluoroaliphatic group contains sufficient fluorine so that the resulting fibers are durably hydrophilic. The fluoroaliphatic group-containing non-ionic compounds useful in the present invention are preferably those that result in durably hydrophilic fiber when the compounds are incorporated into the fiber at about 2% Sby weight or less, based on weight of the fiber.
Larger amounts, up to 15% by weight can be used, but durable hydrophilicity does not substantially increase and the higher amounts may cause problems during extrusion.
Surprisingly, the compounds of this invention S. must contain at least four, and preferably at least 6, fully-fluorinated carbon atoms in the fluoroaliphatic group, in order to impart durable hydrophilicity to the 30 fiber. Because fluoroaliphatic groups are hydrophobic, it is surprising that compounds with more fluorine impart hydrophilicity while compounds with less fluorine do not.
“i This invention also provides a method of preparation of durably hydrophilic fiber from a mixture or blend of thermoplastic film-forming polymer and fluoroaliphatic group-containing non-ionic compound.
The melt of the mixture or blend is processed or 6 shaped, for example, by extrusion or molding, to produce fibers with the compound dispersed within the fiber and present at the surfaces of the fiber, which surfaces are durably hydrophilic. Because non-ionic compounds demonstrate thermal sensitivity, it is preferred that processing temperatures in the extruder e kept below about 310 0 C, and more prif rably below ibout 30 0 C. The durable hydrophilicity is achieved without requiring post fiber-spinning operations, for example heating, because the fiber is durably hydrophilic as extruded (“as made”).
This invention also provides fabric, e.g.
nonwoven web, comprising the durably hydrophilic fiber of this invention. The fabric of the present invention typically is more durably hydrophilic, including very good in-service durability, than fabric comprising comparable levels of fluorine-free compound.
The fabric of this invention can be prepared by post fiber-formation operations, such as weaving or 20 knitting, or by direct processing, such as melt-blowing or spun-bond processes, of a melt of the thermoplastic polymer and compound mixture into a nonwoven fabric.
The durable hydrophilicity, or lack thereof, of fiber can be determined by subjecting a nonwoven web sample of such fiber to at least two cycles of the flow-rate hydrophilicity test described below. For brevity, the fiber is defined as having a “Hydrophilicity Index” equal to the number of cycles that a nonwoven web sample of such fiber can experience and still be hydrophilic as defined by the test. The higher the Hydrophilicity Index, the more durable is the hydrophilicity of the fiber. Fiber is hydrophilic if it has a Hydrophilicity Index of at least 1, and fiber is durably hydrophilic if it has a Hydrophilicity Intex of at least 2. Hydrophilic fiber can be prepared from normally hydrophobic thermoplastic polymer resins which have a Hydrophilicity Index of zero.
7 This invention also provides aqueous media absorbent articles such as diapers, feminine care products, and adult incontinence products. Such articles comprise the fabric of this invention, which functions as the aqueous media absorbent structure in the articles. Such articles typically include an aqueous media impervious backing sheet, an aqueous media pervious top sheet, and an aqueous media absorbent core positioned between the backing sheet and the top sheet.
A class of fluoroaliphatic group-containing non-ionic compounds useful in the present invention can be represented by Formula I.
R-Q-Z I In Formula I, Rf is a fluoroaliphatic group, which is saturated, and mono-valent, and has at least 4 fully-fluorinated carbon atoms. It can be straight, branched, if sufficiently large, cyclic, or combinatic.is thereof, such as alkylcycloaliphatic radicals. The skeletal chain in the fluoroaliphatic radical can include catenary oxygen, hexavalent sulfur, and/or trivalent nitrogen atoms bonded only to carbon atoms of the skeletal chain, such hetero atoms providing stable linkages between fluorocarbon portions of the Rr radical. A fully fluorinated radical is preferred, but hydrogen or chlorine atoms may be present as substituents provided that not more than one 30 atom of either is present for every two carbon atoms.
While Rf can contain a large number of carbon atoms, compounds where Rr is not more than 20 carbon atoms will be adequate and preferred since larger radicals usually represent a less efficient utilization of the fluorine than is possible with shorter chains. Fluoroaliphatic radicals containing from about 6 to about 12 carbon atoms are most preferred. Generally R, will contain to 78 weight percent fluorine. The terminal portion of 8 the Rf group preferably has at least four fully fluorinated carbon atoms, CF 3
CF
2
CF
2
CF
2 and the preferred compounds are those in which the Rf group is fully or substantially completely fluorinated, as in the case where Rf is perfluoroalkyl, e.g. CF 3
(CF
2 Suitable R, groups include for example, CFnI 7
C
6
F
3
CH
2
CH
2 and CioF 2 1
-CH
2
CH
2 In the Formula, Q is a linking group, or a covalent bond, which provides a means to link Rf with the depicted group Z, which is a non-ionic water-solubilizing group. The linking group, Q, can comprise a hetero atom-containing group, a group-containing and/or or a combination of such groups, for example -CONR-, -SOz-, -SO 2
N(CH
3
-C
3 HC1-, -OCH 4 -CnH 2 where n is 1 to 6.
The non-ionic water-solubilizing group Z comprises a poly(oxyalkylene) group, (OR’) x where R’ is an alkylene group having 2 to 4 carbon atoms, such as S 20 -CH2CH 2
-CHCH
2
CH
2
-CH(CH
3 )CH2-, and -CH(CH 3
)CH(CH
3 and x is from about 6 to about 20. The oxyalkylene units in said poly(oxyalkylene) being the same, as in poly(oxypropylene), or present as a mixture, such as in a heteric straight or branched chain of randomly distributed oxyethylene and oxypropylene units poly(oxyethylene-co-oxypropylene), or as in a straight or branched chain of blocks of oxyethylene units and Sblocks of oxypropylene units. The poly(oxyalkylene) chain can be interrupted by or include one or more 30 catenary linkages, providing such linkages do not substantially alter the water-solubilizing character of the poly(oxyalkylene) chain. The Z group is terminated with hydroxyl or lower alkyl ether for example, -OCH 3 or
-OCH
2
CH
3 Examples of suitable Z groups include,
-(CH
2
CH
2 0)g-H
-(CH
2 CH20) 6
-H
(CH
2
CH
2 O) E-CH 3 9
(CH
2 CH20) 6
-CH
3
(CH
2 CHO) 8
-H
I
CH
3
(CH
2 CHO) 8
-CH
3 i
CH
3
-CH
2 CH20- (CH 2 CHO) 8-H
I
CH
3
-CH
2 CH20- (CH 2
CH
O
g-CH 3
CH
3 Compounds useful as fluoroaliphatic group-containing non-ionic compounds in the present invention can be prepared using known methods such as those described in U.S. Pat. No. 2,915,554 (Albrecht et al.) The Albrecht patent discloses the preparation of fluoroaliphatic group-containing non-ionic compounds from active hydrogen containing fluorochemical intermediates, such as fluoroaliphatic alcohols, e.g., RfC 2
H
4 0H, acids, RSO 2
CH
2
CO
2 H, and sulfonamides, RfSO 2 by reaction of the intermediates 30 with, for example, ethylene oxide to yield, respectively, RC 2
H
4 0(C 2
H
4 RfSO 2
CH
2
CO
2
(C
2 H4O),H, and
RSO
2
(C
2
H
4 0)nH, where n is a number greater than about 3, and R’ is a :ydrogen or lower alkyl 1 to 6 carbons). Analogous compounds can be prepared by treating the intermediates with propylene oxide or a mixture of ethylene oxide and propylene oxide. See also the fluoroaliphatic oligomers disclosed in U.S.
Pat. No. 3,787,351 (Olson), and certain fluorinated O.o” alcohol-ethylene oxide condensates described in U.S.
40 Pat. No. 2,723,999 (Cowen et which descriptions are hereby incorporated by reference.
“Fiber” and “fibrous” refers to particulate material wherein the length to diameter ratio of such particulate material is greater than about 10. The 10 term “fiber” includes fiber sizes ranging from about micron diameters to diameters in excess of millimeter. The term includes textile materials in the form of a mass, aggregation, or collection of fibers, continuous fibers of indeterminant length, spun yarns, filaments, rovings, slivers, tows and the like. Fiber may have a variety of cross-sectional geometries, and may be solid or hollow. Fiber may optionally be colored by, incorporating soluble dye in the polymer melt.
The fiber of this invention, in addition to having modified surface characteristics, also contains said fluoroaliphitic compound within the fiber. The compound within the fiber is believed to act as a reservoir of internal wetting agent to resupply the surface upon removal of the compound already present on the surface. When the fiber and fabric of this invention are exposed to water, they retain their hydrophilic nature after repeated exposures to deionized water. This durable hydrophilicity is obtained at much lower levels than with fluorine-free compounds within the fiber. Thus the fiber of the present invention is durably hydrophilic. The S” fluoroaliphatic group-containing compound contained within the fiber is distributed or dispersed within the fiber such that there is no visible difference, as viewed with a microscope, between fiber containing the compound and fiber without the compound.
The fabrics of this invention possess much greater surface area per weight then would films of the thermoplastic polymer and non-ionic compound and thus are useful for absorption applications. The fabrics are also better than the films would be in removing S’ liquid fro- the skin surface.
The fabrics of the present invention are readily prepared by processes used in the manufacture of melt-blown or spun-bonded webs. For example, a process similar to that described in Wente, “_’uperfine 11 Thermoplastic Fibers,” in Industrial Engineering Chemistry, Vol. 48, pages 1342 et seq. (1956), or in Report No. 4364 of the Naval Research Laboratories, published May 25, 1954, entitled “Manufacture of Superfine Organic Fibers” by Wente, Boone, and Fluharty, can be used for the preparation of the fabrics of the present invention.
Thermoplastic polymers useful in the present invention are generally normally hydrophobic polymers and include fiber-forming polyolefins such as polyethylene, polypropylene, polybutylene, and blends.
Other useful fiber-forming thermoplastic polymirs include thermoplastic polyesters, polyurethanes and polyamides.
The amount of fluoroaliphatic group-containing non-ionic compound incorporated in the thermoplastic polymer can vary. The amount to be used will be that amount sufficient to improve the wetting of the surface of the resulting fiber. Compounds that are effective at lower levels are more economical and are easier to process. The fluoroaliphatic compounds Suseful in this invention are preferably those that are effective when incorporated within the thermoplastic polymer at up to 2 weight percent and more preferably at up to 1 weight percenc.
Levels of compound higher than 2 weight percent may cause extruder stability problems.
Therefore, when fabrics containing greater than 2 weight percent compound or surfactant are prepared, 30 it is preferable to inject the compound into the molten polymer stream under high pressure either in the extruder barrel or immediately as the melt stream erits the extruder and before it enters the extrusion die.
High pressure injection can be accomplished by using a high pressure metering pump, such as those available from Ruska or Zenith, to pump liquid compound into the molten polymer in the metering or transition zone of the extruder. Alternatively, high pressure injection 12 can be accomplished by means of a cascade extrusion apparatus wherein liquid compound is; introduced into the barrel of a first extruder at the metering section of the screw by means of a Ruska or Zenith pump and the effluent compound stream is subsequently injected into the second extruder at the metering section of the screw. High pressure injection may also be accomplished by injection of the compound into the molten polymer stream immediately on exiting the extruder barrel according to the procedure described in U.S. Pat. No. 4,933,229 (Insley et When fabrics containing less than about 2 weight percent compound are prepared, the compound is conveniently incorporated into the polymer by tumble blending the compound with resin pellets prior to extrusion or by metering liquid compound into the extruder hopper along with the resin pellets during extrusion.
Additionally, fiber of this invention typically can contain at least from two to five times less compound, to develop hydrophilicity of comparable durability, than fibers containing fluorine-free compound. The lower compound levels provide for improved extruder stability and subsequent fiber I uniformity as extruder screw slippage problems are significantly reduced.
The durability of the hydrophilicity of the fiber of the present invention is particularly surprising in view of the significant increase in surface area polymer/air interface) relative to 30 films containing comparable levels of surfactant. For S. example, if a gram of polypropylene resin is converted into fiber having an average diameter of 10 microns, and into a 0.025 mm thick film, the fiber will have approximately five times the surface area of the film.
if the hydrophilicity is indeed produced simply by the migration of the compound to the surface of the fiber, one would reasonably expect a higher surface area would lead to a more rapid depletion of the compound within 13 the fibir and thus, to a less durable hydrophilic treatment.
The fiber and fabrics of this invention can be used to prepare aqueous media absorbent articles such as diapers, feminine care products, and adult incontinence products, which utilize the fabrics of the present invention as at least a portion of their fluid-absorbing “core” element. By “absorbent article” herein is meant a consumer product which is capable of absorbing significant quantities of water and other aqueous fluids liquids), like body fluids.
Examples of aqueous media absorbent articles include disposable diapers, sanitary napkins, tampons, incontinence pads, disposable training pants, paper towels, facial tissues, and the like. The fabrics of the present invention are particularly suitable for use in articles like sanitary napkins, diapers and incontinence pads.
Aqueous media absorbent articles will 20 frequently comprise a substantially aqueous media s impervious backing sheet, an aqueous media pervious top sheet and an aqueous media absorbent core comprising an aqueous media absorbent structure positioned between said backing sheet and said top sheet. Said impervious backing sheets can comprise any material, for example polyethylene or polypropylene having a thickness of about 0.038 mm, which will help retain fluid within the *e e absorbent article. Said pervious top sheets can comprise any material such as polyester, polyolefin, 30 rayon and the like which is substantially porous and permits aqueous media to readily pass therethrough into the underlying absorbent core. Suitable materials for .”*top sheets and bottom sheets are well known in the art.
A more detailed description of sanitary napkins and suitable materials for use therein is found in U.S. Pat. Nos. 3,871,378 (Duncan et 4,324,246 (Smith et and 4,589,876 (Van Tillberg).
14 Disposable diapers comprising the hydrophilic fabrics of the present invention may be made by using conventional diaper making techniques, but by replacing or supplementing the wood pulp fiber web core which is typically used in conventional diapers with the hydrophilic fabrics of the present invention. The hydrophilic fabrics of this invention may thus be used in diapers in single layer or various multiple layer core ionfigurations. Articles in the form of disposable diapers are described in U.S. Pat. Nos.
3,592,194 (Duncan et 3,489,148 (Duncan et al.), and 3,860,003 (Buell).
Objects and advantages of this invention are illustrated in the Examples below.
EXAMPLES
Mixtures of fluoroaliphatic group-containing non-ionic compounds and thermoplastic polymers were prepared. Blown microfiber webs were prepared from 20 fiber of these mixtures. The durability of the hydrophilicity of the fiber was determined by evaluation of the webs made therefrom, and compared to webs prepared from mixtures containing fluorine-free non-ionic surfactants and webs prepared from thermoplastic polymer alone.
Thermoplastic Polymers SPolymer A PP3505, a 400 melt flow index polypropylene resin available from Exxon Corp.
Polymer B PP3435, a 70 melt flow index polypropylene resin available from Exxon Corp.
Polymer C 3860X, a 50 melt flow index polypropylene resin available from Fina Chemicals 15 Polymer D PP3085, a 35 melt flow index polypropylene resin available from Exxon Corp.
Polymer E PF442, an 800 melt flow index polypropylene resin available from Himont.
Polymer F PP3495, an 800 melt flow index polypropylene resin available from Exxon Corp.
Polymer G PS455, a 32 melt flow index poly(ester/urethane) available from Morton Thiokol Corp., Malden, MA.
Polymer H BASF B3F, a 120 melt flow index Nylon 6 resin available from BASF.
Polymer I PE6814, a 125 melt flow index polyethylene available from Dow Corp.
Polymer J PB0400, a 20 melt flow polybutylene available from Shell.
Polymer K PS440, a polyester-urethane available from Morton Thiokol Corp, Fluoroaliphatic Group-Containing Non-Ionic Compounds Compound I Fluoroaliphatic group-containing non-ionic compound of structure 30 C 8
F
1 7
SO
2
N(C
2
H
5
(CH
2
CH
2 0) 7
CH
3 •was prepared according to U.S. Pat. No. 2,915,554 (Ahlbrecht et al.).
Compound II Fluoroaliphatic group-containing non-ionic compound of structure
C
8
F
17
SO
2 N (C 2 H) CH 2 CH20 (CH 2 CH (CH 3 O) H 16 was prepared according to U.S. Pat. No. 2,915,554 (Ahlbrecht et al.).
Fluorine-Free Non-Ionic Surfactants Comparative fluorine-free non-ionic surfactants which were evaluated include: CA TRITONT” X-100, a poly(ethylene oxide) based surfactant available from Rohm and Haas Corp.
CB EMERESTTM 2620, a polyethylene glycol monolaurate based surfactant available from Emery Industries.
CC SILWETTM L-77, a polyalkylene oxide modified polydimethylsiloxane based surfactant available from Union Carbide.
CD SILWETTM L-720, a polyalkylene oxide modified polydimethylsiloxane based surfactant available from Union Carbide.
CE SILWETTM L-7600, a polyalkylene V oxide modified polydimethylsiloxane based surfactant available from Union Carbide.
S 25 CF SILWETTM L-7602, a polyalkylene oxide modified polydimethylsiloxane based surfactant available from Union Carbide.
Mixing Methods The above compounds or surfactants, and S” polymers were mixed as described below. Because non-ionic compounds and surfactants demonstrate thermal sensitivity it is preferred that processing temperatures in the extr’ider be kept balow about 310 0
C,
and more preferably below about 3000C.
17 Tumble Blending (TB) Compound or surfactant, and thermoplastic polymer mixtures were prepared by tumble blending the compound or surfactant, and the polymer in a plastic bag for about five minutes until a homogeneous mixture was obtained.
Barrel Injection (BI) Compound or surfactant, and thermoplastic polymer mixtures were prepared by pumping the compound or surfactant into the metering section of the extruder by means of a ZENITHTM pump. Compound or surfactant incorporation levels were controlled by adjusting the pump rpm rate.
Cascade Extrusion (CE) Compound or surfactant, and thermoplastic polymer mixtures were prepared by pumping the compound or surfactant into the metering section of a extruder by means of a ZENITH TM pump. The effluent stream from this extruder was then fed into the metering section of a second extruder where the compound or surfactant was mixed with the molten polymer. Compound or surfactant incorporation levels were controlled by adjusting the rpm rate of the first extruder.
Preparation of Blown Microfiber Webs A melt-blowing process is described, for example, in Wente, Van “Superfine Thermoplastic Fibers,” in Industrial Engineering Chemistry, Vol. 48, pages 1342 et seq. (1956), and in Report No. 4364 of the Naval Research Laboratories, published May 1954, entitled “Manufacture of Superfine Organic Fibers” by Wente, Boone, and Fluharty. This process was used to prepare blown microfiber webs, except that the melt blowing die had circular smooth surfaced orifices (10/cm) with a 5:1 length to diameter ratio.
Extrusion was carried out at the temperature indicated -18 1-3, th primary air temperature was maintained at approximately the temperature indicated in Tables 1-3, at a pressure of 124 kPa (18 psi) (0.076 cm air gap width), and the polymer throughput rate was about 180 gm/hr/cm. The resulting average diameter of the small diameter fibers was about 5-18 micrometers and the basis weight of the blown microfiber webs was 55 g/m 2 In the instances where the Barrel Injection or Cascade Extrusion processes were used to incorporate the compound or surfactant into the resin, the melt blowing apparatus was modified by the addition of a ZENITHT high pressure metering pump or a second extruder respectively, which fed into the metering zone of the extruder connected to the die.
Examples 1 28 0. Fluoroaliphatic group-containing non-ionic compound loaded blown microfiber webs were prepared utilizing the above thermoplastic polymers and fluoroaliphatic group-containing non-ionic compounds.
Experimental conditions along with the mixing method used to incorporate the fluoroaliphatic group-containing non-ionic compound into the blown microfiber web are shown in Table 1.
S T S *e Fluoroaliphatic Group-Containing Non-Ionic Compound Loaded Webs Thermoplastic Example Polymer Fluoroaliphatic Non-Ionic Compound Compound Level Mixing Method Extrusion Temp.
Primary Air Temp.
0.4 0.75 11.4 200 200 200 200 200 200 200 200 240 250 260 270 280 290 300 285 290 230 210 210 210 210 210 210 210 210 255 253 253 273 280 285 292 289 295 243 19 F I 1.0 TB 230 242 TABIE I. .4Cohitlifiued) Thermoplastic Example Polymer Fluoroaliphatic Non-Ionic Compound Compound Level mixing Method Extrusion Temp.
(OC)
Primary Air Temp.
(OC)
260 210 280 280 200 300 310 230 266 210 280 290 204 204 310 310 230 21 Comparative Examples Cl C14 Comparative blown microfiber webs were prepared, utilizing commercially available hydrocarbon non-ionic surfactants in place of the fluoroaliphatic group-containing compounds, according to the procedure described above. All used thermoplastic polymer A.
The type and loading level of the surfactant, the extrusion temperature, the mixing method, and the primary air temperature were varied as shown in Table 2.
e S
R
oo* Fluorine-Free Non-Ionic Surfactant Loaded Comparative Webs Primary Comparative Example Surf actant.
Surf actant Level Mixing Extrusion Method Temp. 0
C)
Air Temp.
(OC)
C1 C2 C3 C4 C6 C7 C8 Clo cli C12 C13 C14 1.0 2.0 4.0 4.5 5.0 7.7 11.8 13.6 6.4 1.0 1.0 1.0 1.0 200 200 200 200 200 200 200 200 200 200 270 270 270 270 210 210 210 225 225 225 209 254 209 268 273 273 273 23 Comparative Examples C15-C20 Comparative blown microfiber webs were prepared according to the above described procedure, utilizing thermoplastic polymer alone with no compound or surfactant. The thermoplastic polymer used, the extrusion temperature and the primary air temperature were varied as shown in Table 3.
Table 3 Comparative Webs Without Compound or Surfactant Primary Comparative Extrusicn Air Temp.
Example Polymer Temp. B 280 278 C16 C 285 285 C 17 D 310 305 C18 E 230 243 C19 F 230 241 A 260 266 Comparative Example C21 Comparative Example C21 was prepared with the 25 identical ingredients and procedure as in Example except that the extrusion temperature was 310 0 C instead of 300°C and, the primary air temperature was 288 0
C
instead of 292 0
C.
Hydrophilicity Index The durability of the hydrophilicity of the fiber used to prepare the above webs was determined by monitoring the time required for 200 mL of deionized water water) to flow through a sample of the web mounted in a test fixture (“flow-rate test”). The test fixture consisted of two pipe cylinders, each cylinder having a diameter of 10 cm and a height of 12.5 cm.
The two cylinders were abutted together with a sample
A
24 of the web separating the two sections leaving an area of approximately 66 cm 2 of the web exposed for the flow test. The test fixture was mounted in a vertical configuration and 200 mL of D.I. water was poured into the upper cylinder along the inner side of the upper pipe cylinder onto the web so as to avoid a forceful impingement of the D.I. water on the web sample.
The prepared web sample thicknesses were from .036 mm to 0.61 mm as determined by using an ONO SOKKITM Model EG-225 Digital Linear Gauge equipped with a measuring foot diameter of 34.3 mm. Triplicate samples were cut from the substrate to be measured. The digital gauge was zeroed, a sample was centered on the platform under the measuring foot and the measuring foot was lowered on to the sample with a force of 150 g. The reading was allowed to stabilize for about 1 minute and the displayed value was recorded. The Sinstrument was rezeroed and the procedure repeated for each sample. The value reported was the average of the 20 three readings.
S9 Flow-rate test data was reported as the time required (in seconds) for all of the D.I. water (200 ml) to flow through the web. A flow rate of
S*I
Sgreater then 300 seconds is defined as a failure of that cycle and interpreted to mean that the sample is no longer hydrophilic. Subsequent to each test cycle, the web sample was removed from the test fixture, allowed to dry for 24 hrs, and the test procedure repeated. Web samples were subjected to six repeats, 30 or cycles, of the flow test, or until the sample failed a cycle. The results are summarized in Table 4 and Data was recorded as the number of seconds required for the D.I. water to completely flow through the sample. Samples for which D.I. water did not even begin to flow through, were recorded as nonwetting (NW).
The test was stopped after 300 seconds; samples where 25 D.I. water was flowing through were recorded as >300.
Samples that were nonwetting were not subjected to further cycles.
The results are interpreted to mean that flow of water through the sample in less then 300 seconds indicates hydrophilicity. Samples which do not allow water to flow through in 300 seconds of contact are interpreted to no longer be hydrophilic, Durability of hydrophilicity is the retention of hydrophilicity after at least one cycle. The longer (more cycles) that hydrophilicity is retained, the more durable is that sample’s hydrophilicity. For brevity, the fiber is defined as having a “Hydrophilicity Index” equal to the number of cycles that a nonwoven web sample of such fiber can experience and still be hydrophilic.
Hydrophilicity Index equals the number of cycles of the flow-rate test that the sample experiences without a failure. The higher the Hydrophilicity Index, the more Sdurable is the hydrophilicity of the fiber. Fiber is 20 hydrophilic if it has a Hydrophilicity Index of at least 1, and fiber is durably hydrophilic if it has a Hydrophilicity Index of at least 2.
S
T* ‘4.T .4 FLOW TIME (seconds) after after after after after after Initial Cycle Cycle Cycle Cycle Cycle Cycle Example 1 2 3 4 5 6_ 100 160 48 27 2 2 138 87 49 98 186 300 300 300 200 130 45 2 1 1
NW
300 300 300 300 300
NW
>300 200 182 97 2 2 1 1 300 300 300 300 300 >300 270 187 99 2 2 1 1 300
NW
300 300 300 16 10 10 17 8 8 12 57 300 26 89 300 a a *5 S TABLS. 4: (.cbritfnt’ed) FLOW TIME (seconds) after after after after after after Initial Cycle Cycle Cycle Cycle Cycle Cycle Example 1 2 3 4 5 6 18 6 9 52 300 300 300- 19 6 8 21 61 300 300 5 9 15 37 57 57 39 21 10 10 12 17 18 20 22 7 8 8 9 11 15 16 23 3 4 4 6 6 8 84 24 3 3 3 3 3 3 3 3 3 3 3 3 3 3 26 20 55 69 124 >300 >300 >300 27 51 59 68 72 88 102 108 28 6 6 6 7 13 15 18 PLOW TIME (seconds) Initial af ter Cycle after Cycle 2 after Cycle 3 after Cycle 4 after Cycle 5 after Cycle 6 PFY;;nn1 P C1 C2 C3 C4
CS
C6 C7 C8 C9 Cl0 Cli C12 C13 C14 C16 C17 C18 C19 C2 0 C2 1 12 3 3 3 2 2 155 2 71 5 3 3 2 2 191 2 >300 9 36 4 3 2 205 2
NW
14 161 4 3 2 300 2 42 >300 10 3 2 300 2 105 >300 22 4 3 300 2 29 Table 6 summarizes the hydrophilicity, after six cycles, of the fabrics of this invention compared to fabrics comprising hydrocarbon non-ionic surfactants. Each of the samples in Table 6 utilized thermoplastic polymer A. Hydrophilicity is summarized as; “none” where samples required 300 seconds or more, “fair” where samples required 100 seconds or more, and “excellent” where samples required less than 100 seconds. All hydrophilicity data in Table 6 is a summary of the data, in Tables 4 and 5, for hydrophilicity after 6 cycles.
TABLE 6 Comparison of Durability Surfactant TvPTuP fI5\ Hydrophilicity Z-F+*iay (e yExamn l .Sqlm-f (*tan+ gil-L-i-nnt Level ‘~cY~LC~ 1 2 3 4 5 6 7 8 0.4 0.5 0.75 1 2 4 5 11.4 none fair fair excellent excellent excellent excellent excellent Comparative Example C1 C2 C3 C4 C6 C7 40 C8 C9 C11 C12 C13 C14 1 2 4 4.5 5 7.7 11.8 13.6 5 6.4 1 1 1 1 none none none fair none excellent excellent excellent none excellent none none none none none 0.0 none L I 30 Table 6 shows that fibrous webs loaded with fluoroaliphatic group-containing non-ionic con unds of this invention are more hydrophilic than webs loaded with comparable levels of fluorine-free non-ionic surfactants. Durable hydrophilicity is achieved with fluoroaliphatic group-containing non-ionic compounds at lower concentrations than with fluorine-free surfactants. Fibers containing fluoroaliphatic group-containing non-ionic compounds have a Hydrophilicity Index of 6 when they are present in the fiber at levels of about 1 weight percent. That is they give fibrous webs that are still hydrophilic after six cycles at levels of about 1 weight percent, while the comparative examples do not achieve a Hydrophilicity Index of 6 until surfactant levels are at least 4.5 weight percent.
The various modifications and alterations of this invention will be apparent to those skilled in the art without departing from the scope and spirit of this invention and this invention should not be restricted to that set forth herein for illustrative purposes.
.e
I

Claims (17)

1. Durably hydrophilic, thermoplastic fiber comprising thermoplastic polymer and fluoroaliphatic group-containing non-ionic compound, said compound having at least four fully fluorinated carbon atoms in the fluoroaliphatic group, dispersed within said fiber and present at the surface of the fiber.

2. The fiber of Claim 1 wherein said thermoplastic polymer is processable at a temperature below 310oC., and wherein said compound is thermally stable at said temperature.

3. The fiber of Claim I wherein said thermoplastic polymer is normally hydrophobic and is selected from the group consisting of polyolefin, polyamide, polyester, polyurethane, and blends thereof.

4. The fiber of claim 1 wherein said fluoroaliphatic group-containing non-ionic compound is 20 present in an amount sufficient to impart durable hydrophilicity to said surface.

5. The fiber of Claim 4 wherein said fluoroaliphatic group-containing non-ionic compound is present in up to 2 weight percent based on weight of polymer.

6. The fiber of Claim 4 wherein said fiber has a Hydrophilicity Index of at least 2, as described at 30 page 6, lines 23-37 of the specification.

7. The fiber of Claim 1 wherein said fluoroaliphatic group-containing non-ionic compound is represented by the formula R-Q-Z -32- where Rf is a saturated, niono-valent, f luoroaliphatic group comprising an alkyl. group of at least 4 fully- fluorinated carbon atoms; Q is a linking Szoup; and Z ise a non-ionic water-solubiliziig group. S. The fiber of Claim 7 wherein said water- so2.ubilizing group comprises poly (oxyalkylena)

9. The fiber of claim 8 wherein said poly (oxyalkylene) is selected from the group consisting of po2ly (oxyethylene) poly (oxypropylene), and poly( (xyethylene-oo-oxypropylene)

10. The fiber of Claim 7 wherein said Q is -SO 2 N(R)-j where R is an alkyl group of 1 to 4 carbon atoms.

11. The fiber or Claim 7 wherein said polymer is polypropylene, said Rr is CgFr- and said 2 is selected from the group consisting of -(CH 2 CH 2 O) DR’, and -CH 2 CH 2 0(CH2CH(CH3)0),R’, where n is from 6 to 9, and where R is H or CHd 3

12. A fabric comprising fiber of ClaAtm 1.

13. The fabric of Claim 12, wherein the fiber th~ereof is durably hydropilic as made. 30 14. The fabric of claim i2 wherein said fabric comprises a nonwoven web. The hydrophilic fabric of claim 14 wherein said nonwoven web comprises a melt blown web. T 3-

16. The f abric of Claim 15 wherein said melt blown web comprises a blown microf iber web.-

17. A fabric comprising the fiber of Claim 6. 18,~ A Methoa of ‘manufacturing durably hydrophilic fiber comprising the steps of mixing fluoroal1iphatic group-containing non- ionic compounds, said compound having at least four fully fluorinated carbon atoms in the fluoroaliphatic group, with the thermoplastic fiber-forming polymer; and melting a~nd extruding the resulting mixture from step below 3106C. into fiber, said compound imparting duz-able hydrophilicity to the fiber.

19. A method of manufacturing a durably b’ydrophilic fabric comprising the steps of: mixing fluoroaliphatic group-containing non- ionic compound, said compound having at least four fully fluorinated carbon atoms in the fluorodliphatic group, with thermoplastic fiber-forming polymer; and melt spinning the resulting mixture from step into a nonwoven fabric, said compound imparting durable hydrophilicity to the fabric.

20. A multi-layer, aqueous liquid absorbent, article czomprising; an aqueous liquid impervious backing sheet; an aqueous liquid pervious topsheet; and an aqueous liquid absorbent layer positioned between said backi~ng sheet and said topsheet, said absorbent layer comprising a web of C2’L -34- durably hydrophilice thermoplastic fiber, said fiber comprising thermoplastic polymner and fluoroaliphatic group-containing non- ionic compound, said compound having at least four fully fluorinated carbon atoms in the fluoroaliphatic group, dispersed within said fiber and presen6’ at the surface of the fiber. DATED this TWENTY SECOND day of FEBRUARY 1994 Minnesota Mining and manufacturing Company Patent Attorneys for the Applicant SPRUSON FERGUSON S S. S

55.5 S S S *5 *5 I Durably Hydrophilic, Thermoplastic Fiber Abstract of the Disclosure Durably hydrophilic, thermoplastic fibers comprising thermoplastic polymer and fluoroaliphatic group-containing non-ionic compound are provided. Methods of preparation are also disclosed. Compound of the formula Rf-Q-Z Where Rf is a saturated, mono-valent, fluoroaliphatic group comprising an alkyl group of at least 4 fully-fluorinated carbon atoms; Q is a linking group; and Z is a non-ionic water-solubilizing group. *00 0060 0* 0 0 0.. *0 S S Se.. Sr S 0 1600: ied/i634H

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CA2066012A1
(en)

1992-11-03

KR920021758A
(en)

1992-12-18

US5244951A
(en)

1993-09-14

AU1497092A
(en)

1992-11-05

DE69221770T2
(en)

1998-02-26

US5300357A
(en)

1994-04-05

EP0516271A1
(en)

1992-12-02

JPH05186907A
(en)

1993-07-27

JP3135978B2
(en)

2001-02-19

CA2066012C
(en)

2003-01-07

DE69221770D1
(en)

1997-10-02

EP0516271B1
(en)

1997-08-27

KR100230711B1
(en)

1999-11-15

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