GB1046512A

GB1046512A – Improvements in and relating to polyurethanes
– Google Patents

GB1046512A – Improvements in and relating to polyurethanes
– Google Patents
Improvements in and relating to polyurethanes

Info

Publication number
GB1046512A

GB1046512A
GB16426/63A
GB1642663A
GB1046512A
GB 1046512 A
GB1046512 A
GB 1046512A
GB 16426/63 A
GB16426/63 A
GB 16426/63A
GB 1642663 A
GB1642663 A
GB 1642663A
GB 1046512 A
GB1046512 A
GB 1046512A
Authority
GB
United Kingdom
Prior art keywords
hydrogen
alkyl
aromatic nucleus
reactive position
moles
Prior art date
1962-05-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB16426/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Carbide Corp

Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1962-05-01
Filing date
1963-04-26
Publication date
1966-10-26

1963-04-26
Application filed by Union Carbide Corp
filed
Critical
Union Carbide Corp

1966-10-26
Publication of GB1046512A
publication
Critical
patent/GB1046512A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G18/00—Polymeric products of isocyanates or isothiocyanates

C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen

C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen

C08G18/40—High-molecular-weight compounds

C08G18/54—Polycondensates of aldehydes

C08G18/546—Oxyalkylated polycondensates of aldehydes

Abstract

A polyurethane is prepared by the reaction of (i) an organic polyisocyanate with (ii) a polyol which comprises a vicinal epoxide adduct of the condensation product of (a) a phenol which has at least one unsubstituted reactive position on the aromatic nucleus, (b) an aromatic amine of the formula ArNHR, wherein Ar is an aryl group which has at least one unsubstituted reactive position on the aromatic nucleus and wherein R is hydrogen or alkyl and (c) an aldehyde. The term reactive position is defined as a position ortho or para to the hydroxyl or amino group. The phenol (a) may have the formula where each R1 is hydrogen, alkyl, hydroxyl, amino, alkylamino or dialkylamino, provided that at least one R1 represents a hydrogen that is bonded to a reactive position on the aromatic nucleus. The amine (b) may have the formula where R is hydrogen or alkyl and wherein each R2 is hydrogen, hydroxyl, amino, alkyl, alkylamino or dialkylamino, provided that at least one R2 is a hydrogen that is bonded to a reactive position on the aromatic nucleus. Foams may be prepared by incorporating water or a blowing agent into the reaction mixture. An organotin catalyst and a polysiloxane polyoxyalkylene copolymer may also be present. In a typical Example (1) a polyol prepared by oxypropylation of the condensation product of pheno(10.62 moles), aniline (10.62 moles) and aqueous formaldehyde (11.8 moles), the propylene oxide being in such amount as to provide an average polyoxyalkylene chain length of 1.98 oxypropylene units, was mixed with tolylene diisocyanate, Cl3CF, silicone surfactant and dibutyltin dilaurate and allowed to foam.

GB16426/63A
1962-05-01
1963-04-26
Improvements in and relating to polyurethanes

Expired

GB1046512A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US191425A

US3245924A
(en)

1962-05-01
1962-05-01
Polyurethane compositions

Publications (1)

Publication Number
Publication Date

GB1046512A
true

GB1046512A
(en)

1966-10-26

Family
ID=22705460
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB16426/63A
Expired

GB1046512A
(en)

1962-05-01
1963-04-26
Improvements in and relating to polyurethanes

Country Status (6)

Country
Link

US
(1)

US3245924A
(en)

AT
(1)

AT264848B
(en)

DE
(1)

DE1286752B
(en)

GB
(1)

GB1046512A
(en)

NL
(2)

NL292107A
(en)

SE
(1)

SE307013B
(en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

NL133349C
(en)

*

1963-12-30

US3436373A
(en)

*

1965-04-16
1969-04-01
Union Carbide Corp
Phenol-formaldehyde-aliphatic amine condensation products

US3450653A
(en)

*

1965-12-10
1969-06-17
Upjohn Co
Polyurethane elastomeric sealants

US3470118A
(en)

*

1966-05-20
1969-09-30
Reichhold Chemicals Inc
Flame-resistant polyol urethane foam composition and process of producing the same

US3857890A
(en)

*

1969-07-25
1974-12-31
Upjohn Co
Process for preparing methylene-di-anilines

US4001329A
(en)

*

1974-02-25
1977-01-04
Owens-Corning Fiberglas Corporation
Aniline based reaction product

US4060439A
(en)

*

1974-05-22
1977-11-29
Union Carbide Corporation
Polyurethane foam composition and method of making same

US4008275A
(en)

*

1975-08-18
1977-02-15
The Upjohn Company
Process for isolating 4,4′-diaminodiphenylmethane

US4107106A
(en)

*

1976-11-22
1978-08-15
Union Carbide Corporation
Phenol-aldehyde-amine resin/glycol curatives for energy absorbing polyurethanes

US4195151A
(en)

*

1976-11-22
1980-03-25
Union Carbide Corporation
Phenol-aldehyde-amine resin/glycol curative compositions

US4436881A
(en)

1983-06-29
1984-03-13
Acme Resin Corporation
Polyurethane binder compositions

US5580651A
(en)

*

1991-08-13
1996-12-03
Woodbridge Foam Corporation
Energy absorbing panel

US5389316A
(en)

*

1991-08-13
1995-02-14
Woodbridge Foam Corporation
Process for producing an energy absorbing panel

DE19916945C1
(en)

*

1999-04-15
2000-10-05
Clariant Gmbh

Aromatic aldehyde resins and their use as emulsion breakers

DE19916946C1
(en)

*

1999-04-15
2000-07-27
Clariant Gmbh
Resins, useful for breaking crude oil emulsions, are prepared by condensation of a disubstituted phenol aromatic amine, benzoic acid or amide with formaldehyde followed by alkoxylation

DE10057043B4
(en)

*

2000-11-17
2004-05-06
Clariant Gmbh

Alkylphenol glyoxal resins and their use as emulsion breakers

JP4484458B2
(en)

*

2002-07-09
2010-06-16
クラリアント・プロドゥクテ・(ドイチュラント)・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング

Oxidation-stable lubricant additive for highly desulfurized fuel oil

US7041738B2
(en)

*

2002-07-09
2006-05-09
Clariant Gmbh
Cold flow improvers for fuel oils of vegetable or animal origin

JP4754773B2
(en)

*

2002-07-09
2011-08-24
クラリアント・プロドゥクテ・(ドイチュラント)・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング

Oily liquids stabilized against oxidation based on vegetable or animal oils

WO2022046581A1
(en)

*

2020-08-31
2022-03-03
Dow Global Technologies Llc
Dimensionally stable polyurethanes and composites

Family Cites Families (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US2349756A
(en)

*

1940-07-25
1944-05-23
Du Pont
Formaldehyde resin modified with a polyiso-or polyisothiocyanate

US2499365A
(en)

*

1947-03-07
1950-03-07
Petrolite Corp
Chemical manufacture

BE596036A
(en)

*

1959-10-15

NL265783A
(en)

*

1960-06-09
1900-01-01

0

NL
NL130122D
patent/NL130122C/xx
active

NL
NL292107D
patent/NL292107A/xx
unknown

1962

1962-05-01
US
US191425A
patent/US3245924A/en
not_active
Expired – Lifetime

1963

1963-04-26
GB
GB16426/63A
patent/GB1046512A/en
not_active
Expired

1963-04-30
SE
SE4768/63A
patent/SE307013B/xx
unknown

1963-04-30
DE
DEU9766A
patent/DE1286752B/en
not_active
Withdrawn

1963-05-02
AT
AT355763A
patent/AT264848B/en
active

Also Published As

Publication number
Publication date

AT264848B
(en)

1968-09-10

US3245924A
(en)

1966-04-12

NL130122C
(en)

DE1286752B
(en)

1969-01-09

NL292107A
(en)

SE307013B
(en)

1968-12-16

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Improvements in and relating to polyurethanes

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(en)

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Improvements in or relating to polyols and polyurethane foams

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(en)

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Method of producing hydrophilic polyurethane foam

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(en)

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(en)

1986-09-02

Preparation of amino polyols

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