GB1048840A – Halogenated derivatives of monoepoxycyclododecadiene and flame retardant materials comprising them
– Google Patents
GB1048840A – Halogenated derivatives of monoepoxycyclododecadiene and flame retardant materials comprising them
– Google Patents
Halogenated derivatives of monoepoxycyclododecadiene and flame retardant materials comprising them
Info
Publication number
GB1048840A
GB1048840A
GB48195/63A
GB4819563A
GB1048840A
GB 1048840 A
GB1048840 A
GB 1048840A
GB 48195/63 A
GB48195/63 A
GB 48195/63A
GB 4819563 A
GB4819563 A
GB 4819563A
GB 1048840 A
GB1048840 A
GB 1048840A
Authority
GB
United Kingdom
Prior art keywords
flame
diene
monoepoxycyclododeca
resin
halogenation
Prior art date
1963-12-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB48195/63A
Inventor
David George Hare
Robert James Stephenson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Chemicals Ltd
Original Assignee
Monsanto Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1963-12-06
Filing date
1963-12-06
Publication date
1966-11-23
1963-12-06
Application filed by Monsanto Chemicals Ltd
filed
Critical
Monsanto Chemicals Ltd
1963-12-06
Priority to GB48195/63A
priority
Critical
patent/GB1048840A/en
1964-11-30
Priority to US414887A
priority
patent/US3374187A/en
1966-11-23
Publication of GB1048840A
publication
Critical
patent/GB1048840A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
C08K5/00—Use of organic ingredients
C08K5/04—Oxygen-containing compounds
C08K5/15—Heterocyclic compounds having oxygen in the ring
C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
C08K5/1515—Three-membered rings
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07D—HETEROCYCLIC COMPOUNDS
C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
C07D303/02—Compounds containing oxirane rings
C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
C08J9/0014—Use of organic additives
C08J9/0038—Use of organic additives containing phosphorus
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
C08K5/00—Use of organic ingredients
C08K5/04—Oxygen-containing compounds
C08K5/15—Heterocyclic compounds having oxygen in the ring
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
C08K5/00—Use of organic ingredients
C08K5/49—Phosphorus-containing compounds
C08K5/51—Phosphorus bound to oxygen
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S521/00—Synthetic resins or natural rubbers — part of the class 520 series
Y10S521/907—Nonurethane flameproofed cellular product
Abstract
The invention comprises halogenation products of 1,2-monoepoxycyclododeca-5,9-diene and halogenation products of adducts of 1,2-monoepoxycyclododeca – 5,9 – diene with a phosphorus halide and/or with a compound containing a hydroxylic group. Specified phosphorus halides are those of the formulae PX3, PX5 and POX3 where X is a halogen. The compound containing a hydroxylic group may contain a simple hydroxyl group, as in water or an alcohol or phenol, or a hydroxyl group forming part of a carboxyl, sulphonic or organic phosphonic radical. The compounds of the invention are prepared by treating the epoxycyclododecadiene or its adduct with a halogenating agent. The adducts are generally prepared by heating the components together.ALSO:A flame-retardant synthetic resin material comprises a synthetic resin and, as a flame-retarding agent, a halogenation product of 1,2 – monoepoxy – cyclododeca – 5,9 – diene or a halogenation product of an adduct of 1,2-monoepoxycyclododeca-5,9-diene with a phosphorus halide and/or with a compound containing a hydroxylic group. The resin materials specified are polymers or copolymers of ethylenically unsaturated monomers, for example, hydrocarbons, acrylates, vinyl esters and acrylonitrile. The resin materials may be foamable or foamed, polystyrene resins being preferred. In Example 3, polystyrene is dissolved in benzene, a flame-retarding additive is added, and a film is then cast from the solution; the composition is stated to be suitable for the production of a self-extinguishing foamed resin.ALSO:Resin particles may be coated with a flame-retarding agent which is a halogenation product of 1, 2-monoepoxycyclododeca-5, 9-diene or a halogenation product of an adduct of 1, 2-monoepoxycyclododeca-5, 9-diene with a phosphorus halide and/or with a compound containing a hydroxylic group. Foamable polystyrene heads are especially suitable for treatment. In a first process, the particles of resin are coated by “tumbling” them in a drum with an appropriate quantity of flame-retarding agent and if desired an adhesive such as an oil or wax. In a second process, the resin particles are treated with an aqueous dispersion of the flame-retarding agent so that a surface coating is applied, for instance by coagulating the dispersion.
GB48195/63A
1963-12-06
1963-12-06
Halogenated derivatives of monoepoxycyclododecadiene and flame retardant materials comprising them
Expired
GB1048840A
(en)
Priority Applications (2)
Application Number
Priority Date
Filing Date
Title
GB48195/63A
GB1048840A
(en)
1963-12-06
1963-12-06
Halogenated derivatives of monoepoxycyclododecadiene and flame retardant materials comprising them
US414887A
US3374187A
(en)
1963-12-06
1964-11-30
Flame retardant compositions prepared from halogenated 1, 2-monoepoxycyclododeca-5, 9 -diene and adducts thereof
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
GB48195/63A
GB1048840A
(en)
1963-12-06
1963-12-06
Halogenated derivatives of monoepoxycyclododecadiene and flame retardant materials comprising them
Publications (1)
Publication Number
Publication Date
GB1048840A
true
GB1048840A
(en)
1966-11-23
Family
ID=10447719
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB48195/63A
Expired
GB1048840A
(en)
1963-12-06
1963-12-06
Halogenated derivatives of monoepoxycyclododecadiene and flame retardant materials comprising them
Country Status (2)
Country
Link
US
(1)
US3374187A
(en)
GB
(1)
GB1048840A
(en)
Families Citing this family (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4699734A
(en)
*
1985-11-06
1987-10-13
A. Schulman, Inc.
Flame-retardant polyolefin compositions containing exudation inhibitor and process for producing same
US5290835A
(en)
*
1991-10-01
1994-03-01
Teijin Limited
Electrical and electronic parts formed of polybutylene naphthalenedicarboxylate
Family Cites Families (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
DE1058987B
(en)
*
1957-04-26
1959-06-11
Studiengesellschaft Kohle Mbh
Preparation of cyclododecadiene monoepoxide from cyclododecatrienes
DE1218149C2
(en)
*
1959-08-22
1974-12-19
Basf Ag
FLAME RETARDANT FOR PLASTICS
US3039977A
(en)
*
1959-12-03
1962-06-19
Koppers Co Inc
Method of producing self-extinguishing foamable polystyrene by brominating foamable polystyrene in aqueous suspension
1963
1963-12-06
GB
GB48195/63A
patent/GB1048840A/en
not_active
Expired
1964
1964-11-30
US
US414887A
patent/US3374187A/en
not_active
Expired – Lifetime
Also Published As
Publication number
Publication date
US3374187A
(en)
1968-03-19
Similar Documents
Publication
Publication Date
Title
EP0898593B1
(en)
2002-02-13
Expandable polystyrene particles
DE1218149C2
(en)
1974-12-19
FLAME RETARDANT FOR PLASTICS
US3326832A
(en)
1967-06-20
Self-extinguishing plastics compositions
US2307157A
(en)
1943-01-05
Stabilized vinyl resin
GB1044680A
(en)
1966-10-05
Expandable thermoplastic polymer particles containing volatile fluid foaming agent and method of making the same
GB466879A
(en)
1937-06-07
Improvements relating to photographic materials
GB1117038A
(en)
1968-06-12
Improvements in or relating to polymerising or co-polymerising organosilicon compounds
GB1270990A
(en)
1972-04-19
Preparation of flameproof self-extinguishing moulding materials, moulded components, lacquers, films, sheets and coatings from plastics which are in themselves combustible
DE2205660B2
(en)
1978-03-16
Method for rendering a plastic film or a plastic sheet antistatic
US2789053A
(en)
1957-04-16
Photographic process using a light sensitive resin composition
US2317725A
(en)
1943-04-27
Coating agent
GB1048840A
(en)
1966-11-23
Halogenated derivatives of monoepoxycyclododecadiene and flame retardant materials comprising them
US2394418A
(en)
1946-02-05
Reduction of color in vinyl resins
DE2339863A1
(en)
1975-03-06
BROMINOUS CYCLIC PHOSPHONIC ACID ESTERS
US3697575A
(en)
1972-10-10
Boric acid esters of 2-vinylthioethanol
DE1182810B
(en)
1964-12-03
Process for making styrene polymers flame retardant
GB1005045A
(en)
1965-09-22
Process for preparing foamed polymeric materials
EP0027609B1
(en)
1982-12-22
Particulate styrene polymers containing an expanding agent, and their use
US2758984A
(en)
1956-08-14
Process for making destaticized plastic
DE19828250A1
(en)
1999-12-30
Polystyrene foam beads, useful for the production of drainage sheets for cellar and structural walls
US3111417A
(en)
1963-11-19
New ultra-violet light stabilized compositions, processes for preparing same, and uses thereof
GB1119829A
(en)
1968-07-17
Adhesive compositions
DE1067586B
(en)
1959-10-22
Process for the production of flame-retardant foam compounds or bodies from flammable, thermoplastic plastics
US1765015A
(en)
1930-06-17
Process for treating rubber latex, composition and article formed thereby
US3553114A
(en)
1971-01-05
Method of coating a deliquescent substance onto the surface of foamable beads and foaming the beads; the foamable and foamed products obtained therefrom
None