GB1065425A - Creation of Inventions and Patents with Artificial Intelligence

GB1065425A – New hydroxyphenyl-1,3,5-triazine, processes for its production and its uses
– Google Patents

GB1065425A – New hydroxyphenyl-1,3,5-triazine, processes for its production and its uses
– Google Patents
New hydroxyphenyl-1,3,5-triazine, processes for its production and its uses

Info

Publication number
GB1065425A

GB1065425A
GB30827/64A
GB3082764A
GB1065425A
GB 1065425 A
GB1065425 A
GB 1065425A
GB 30827/64 A
GB30827/64 A
GB 30827/64A
GB 3082764 A
GB3082764 A
GB 3082764A
GB 1065425 A
GB1065425 A
GB 1065425A
Authority
GB
United Kingdom
Prior art keywords
residue
formula
benzene
triazines
triazine
Prior art date
1963-07-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB30827/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Schweiz AG

Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1963-07-26
Filing date
1964-08-04
Publication date
1967-04-12

1964-08-04
Application filed by Ciba AG
filed
Critical
Ciba AG

1967-04-12
Publication of GB1065425A
publication
Critical
patent/GB1065425A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES

C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES

C11B5/00—Preserving by using additives, e.g. anti-oxidants

C11B5/0042—Preserving by using additives, e.g. anti-oxidants containing nitrogen

C11B5/0064—Heterocyclic compounds containing nitrogen in the ring

A—HUMAN NECESSITIES

A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE

A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES

A61K8/00—Cosmetics or similar toiletry preparations

A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition

A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds

A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds

A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom

A61K8/4966—Triazines or their condensed derivatives

A—HUMAN NECESSITIES

A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE

A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS

A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings

A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K5/00—Use of organic ingredients

C08K5/16—Nitrogen-containing compounds

C08K5/34—Heterocyclic compounds having nitrogen in the ring

C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring

C08K5/3477—Six-membered rings

C08K5/3492—Triazines

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS

C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers

C08L67/06—Unsaturated polyesters

D—TEXTILES; PAPER

D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING

D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS

D01F1/00—General methods for the manufacture of artificial filaments or the like

D01F1/02—Addition of substances to the spinning solution or to the melt

D01F1/10—Other agents for modifying properties

Abstract

The invention comprises hydroxyphenyl-1,3,5-triazines of the formula where R represents a hydroxybenzene residue which contains in the o-position to the triazine ring a hydroxyl group and in the p-position a residue of formula where D represents an organic residue and N = 1 or 2, A represents a benzene residue and X a halogen atom or benzene residue, which are prepared by the reaction of 21,41-dihydroxyphenyl-triazine compounds in the presence of a tert-amine and, if desired, an inert organic solvent, with an isocyanate D-N = C = O or an acid halide or an acid anhydride D-C = O > O D-C = O and many examples are given. The compounds are used for protecting organic materials from the effects of heat, air, and ultra-violet rays. Particularly valuable compounds are those in which R represents a residue in which n = 2 or especially 1, and D1 stands for an alkyl (1-18 C) or benzene residue which maybe substituted by halogen, hydroxyl, alkyl (1-4 C), alkoxy (up to 8 C); A1 the residue above or The compounds of formula are of especial value and examples of the preparation and use are given.ALSO:Stabilizers against heat, air, and especially ultra-violet light, comprise hydroxyphenyl-1,3,5-triazines of formula where R represents a hydroxybenzene residue with a hydroxy group in the ortho position to the triazine, and in the para position a residue where D represents an organic residue and n = 1 or 2, A represents a benzene residue and X a halogen atom or a benzene residue (see Division C2), and are used to protect polymers and copolymers such as polyethylene, polypropylene polyvinyl chloride, polyacrylonitrile, polyvinylidene chloride, vinyl chloride-vinylidene chloride copolymers, polystyrene, polychloroprene, polysulphides, polybutadiene, copolymers of butadiene and styrene, and butadiene-acrylonitrile, polyesters, and polyamides, alkyd lacquers, epoxy resins, phenol-, urea- and melamine-formaldehyde resins, natural rubber, and cellulose derivatives. The stabilizers may be incorporated in the material before or after polymerization or used as a filter layer. Examples describe the preparation of foils of polyvinyl chloride plasticized with dioctyl phthalate, polyethylene, and polypropylene; polyester sheets prepared from phthalic acid-maleic acid-ethylene glycol in monostyrene; filaments prepared from polyamide chips pigmented with titanium dioxide; all stabilized by the addition of hydroxyphenyl-1,3,5-triazines of above formula.ALSO:Stabilisers against heat, air, and especially ultraviolet light for textiles which may be of animal or vegetable origin and which may be in any form, e.g. fibres, filaments, yarns, woven or knitted fabrics or felt, or paper cardboard or paper pulp, comprise hydroxy phenol-1, 3, 5-triazines of formula:- where R represents a hydroxybenzene residue with a hydroxy group in the ortho position to the triazine, and the the para position a residue. where D represents or organic residue and n= 1 or 2, A represents a benzene residue and X a halogen atom or a benzene residue (see Division C2). The compounds may also be included in coating or dressing agents for the above based on the starch, casein, or synthetic resins.ALSO:Hydroxyphenyl-1,3,5-triazines of formula where R represents a hydroxybenzene residue which contains in the ortho-position to the bond to the triazine ring a hydroxyl group and in the para-position to that bond a residue of the formula where D represents an organic residue and n = 1 or 2, A represents a benzene residue and X a halogen atom or a benzene residue (see Division C2) are used as stabilisers against heat, air and ultra-violet rays in perfumes, dyed or undyed soaps and bath salts, skin and face creams, powders repellants and sunburn oil and creams.

GB30827/64A
1963-07-26
1964-08-04
New hydroxyphenyl-1,3,5-triazine, processes for its production and its uses

Expired

GB1065425A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

CH933063A

CH469053A
(en)

1963-07-26
1963-07-26

Use of new hydroxyphenyl-1,3,5-triazines as protective agents against ultraviolet radiation for non-textile organic materials

Publications (1)

Publication Number
Publication Date

GB1065425A
true

GB1065425A
(en)

1967-04-12

Family
ID=4350824
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB30827/64A
Expired

GB1065425A
(en)

1963-07-26
1964-08-04
New hydroxyphenyl-1,3,5-triazine, processes for its production and its uses

Country Status (9)

Country
Link

US
(1)

US3249608A
(en)

AT
(1)

AT244306B
(en)

BE
(1)

BE650932A
(en)

CH
(1)

CH469053A
(en)

DE
(1)

DE1291511B
(en)

ES
(1)

ES302393A1
(en)

GB
(1)

GB1065425A
(en)

NL
(1)

NL6408514A
(en)

SE
(1)

SE316470B
(en)

Cited By (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

JP2011088885A
(en)

2009-07-29
2011-05-06
Fujifilm Corp
Novel triazine derivative, uv absorber, and resin composition

Families Citing this family (36)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE3206398A1
(en)

1982-02-23
1983-09-01
Basf Ag, 6700 Ludwigshafen

S-TRIAZINE DERIVATIVES AND THEIR USE AS LIGHT PROTECTION AGENTS

US5736597A
(en)

1989-12-05
1998-04-07
Ciba-Geigy Corporation
Stabilized organic material

FR2674850B1
(en)

1991-04-04
1993-07-02
Oreal

S-TRIAZINIC DERIVATIVES CARRYING BENZALMALONATE SUBSTITUTES, FILTERING COSMETIC COMPOSITIONS CONTAINING THEM AND THEIR USE FOR PROTECTING THE SKIN AND HAIR FROM ULTRAVIOLET RADIATION.

DE59208921D1
(en)

1991-06-03
1997-10-30
Ciba Geigy Ag

Photographic material containing UV absorbers

EP0531258B1
(en)

1991-09-05
1997-09-10
Ciba SC Holding AG
Photographic material containing a UV-absorber

US5672704A
(en)

1994-10-04
1997-09-30
Ciba-Geigy Corporation
2-Hydroxyphenyl-s-Triazines substituted with ethylenically unsaturated moieties

AU703967B2
(en)

1994-10-10
1999-04-01
Ciba Specialty Chemicals Holding Inc.
Bisresorcinyltriazines

EP0711804A3
(en)

1994-11-14
1999-09-22
Ciba SC Holding AG
Latent light stabilizers

TW308601B
(en)

1995-01-18
1997-06-21
Ciba Sc Holding Ag

US6255483B1
(en)

1995-03-15
2001-07-03
Ciba Specialty Chemicals Corporation
Biphenyl-substituted triazines

US6013704A
(en)

1996-09-13
2000-01-11
Ciba Specialty Chemicals Corporation
Hydroxyphenyltriazines

BE1012529A3
(en)

1996-09-13
2000-12-05
Ciba Sc Holding Ag
Triaryltriazines mixing and its use for the stabilization of organic materials.

GB2319523B
(en)

1996-11-20
2000-11-08
Ciba Sc Holding Ag
Hydroxyphenyltriazines

US6221342B1
(en)

1997-08-20
2001-04-24
Ciba Specialty Chemicals Corporation
Cosmetic use of Bis(resorcinyl)triazine derivatives

US6117997A
(en)

1997-11-19
2000-09-12
Ciba Specialty Chemicals Corporation
Hydroxyphenyltriazines

ZA9810605B
(en)

1997-11-21
1999-05-25
Cytec Techonoly Corp
Trisaryl-1,3,5-triazine ultraviolet light absorbers

JP2000026435A
(en)

1998-05-07
2000-01-25
Ciba Specialty Chem Holding Inc
Trisresorcinyltriazine

CA2336246A1
(en)

1998-06-22
1999-12-29
Cytec Technology Corp.
Red-shifted trisaryl-1,3,5-triazine ultraviolet light absorbers

WO1999067226A1
(en)

1998-06-22
1999-12-29
Cytec Technology Corp.
Non-yellowing para-tertiary-alkyl phenyl substituted triazine and pyrimidine ultraviolet light absorbers

KR20010053097A
(en)

1998-06-22
2001-06-25
에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러
Poly-trisaryl-1,3,5-triazine carbamate ultraviolet light absorbers

WO2000014074A1
(en)

1998-09-04
2000-03-16
Ciba Specialty Chemicals Holding Inc.
Process for making 2-hydroxy-4-alkoxyphenyl or 2,4-dihydroxyphenyl substituted 1,3,5-triazine uv absorbers

WO2000014077A1
(en)

1998-09-04
2000-03-16
Cytec Technology Corp.
Process for making 2- (2,4- dihydroxyphenyl) or 2- (2,4- dialkoxyphenyl)- 4,6- bisaryl- 1,3,5- triazines

TWI259182B
(en)

1998-11-17
2006-08-01
Cytec Tech Corp
Process for preparing triazines using a combination of Lewis acids with reaction promoters

CA2392889A1
(en)

1999-12-23
2001-07-05
Ciba Specialty Chemicals Holding Inc.
Stabilizer mixture

US7534421B2
(en)

2003-03-03
2009-05-19
L’oreal
s-Triazine compounds bearing at least one para-aminobenzalmalonic salt substituent and photoprotective cosmetic compositions comprised thereof

JP2007269904A
(en)

2006-03-30
2007-10-18
Adeka Corp
Polymeric material composition

JP2007269903A
(en)

2006-03-30
2007-10-18
Adeka Corp
Polymeric material composition

EP2006324A4
(en)

2006-03-30
2010-11-24
Adeka Corp
Polymer material composition

JP5675647B2
(en)

2009-01-19
2015-02-25
ビーエーエスエフソシエタス・ヨーロピアＢａｓｆＳｅ

Organic black pigment and its production

JP5719528B2
(en)

2009-06-09
2015-05-20
富士フイルム株式会社

Novel triazine derivative, ultraviolet absorber and resin composition

JP5613481B2
(en)

2009-07-29
2014-10-22
富士フイルム株式会社

Novel triazine derivative, UV absorber

JP6647023B2
(en)

2014-12-11
2020-02-14
株式会社Adeka

Novel triazine compound and synthetic resin composition using the same

CN110846740B
(en)

2019-11-27
2022-07-15
中原工学院
Method for preparing phenol modified melamine fiber by single-kettle method

CN110846737A
(en)

2019-11-27
2020-02-28
中原工学院
Method for preparing phenolic modified melamine fiber by one-step method

CN110820074B
(en)

2019-11-27
2022-07-15
中原工学院
Method for preparing urea compound modified melamine fiber by base catalysis

CN113214173B
(en)

2021-04-27
2022-08-02
烟台新特路新材料科技有限公司
Multifunctional triazine ultraviolet absorbent with thioether antioxidant structure and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3118887A
(en)

1961-03-06
1964-01-21
American Cyanamid Co
O-hydroxy substituted tris aryl-s-triazines

US3113941A
(en)

1961-07-13
1963-12-10
Monsanto Res Corp
Esters of hydroxyaryltriazines

1963

1963-07-26
CH
CH933063A
patent/CH469053A/en
unknown

1964

1964-07-21
US
US384243A
patent/US3249608A/en
not_active
Expired – Lifetime

1964-07-24
BE
BE650932D
patent/BE650932A/xx
unknown

1964-07-24
AT
AT639764A
patent/AT244306B/en
active

1964-07-24
DE
DEC33495A
patent/DE1291511B/en
active
Pending

1964-07-24
SE
SE9051/64A
patent/SE316470B/xx
unknown

1964-07-24
NL
NL6408514A
patent/NL6408514A/xx
unknown

1964-07-24
ES
ES0302393A
patent/ES302393A1/en
not_active
Expired

1964-08-04
GB
GB30827/64A
patent/GB1065425A/en
not_active
Expired

Cited By (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

JP2011088885A
(en)

2009-07-29
2011-05-06
Fujifilm Corp
Novel triazine derivative, uv absorber, and resin composition

Also Published As

Publication number
Publication date

SE316470B
(en)

1969-10-27

AT244306B
(en)

1965-12-27

DE1291511B
(en)

1969-03-27

ES302393A1
(en)

1965-03-16

NL6408514A
(en)

1965-01-27

US3249608A
(en)

1966-05-03

BE650932A
(en)

1965-01-25

CH469053A
(en)

1969-02-28

Contact information