GB1087337A – Alkylbenzene sulphonate detergent compositions
– Google Patents
GB1087337A – Alkylbenzene sulphonate detergent compositions
– Google Patents
Alkylbenzene sulphonate detergent compositions
Info
Publication number
GB1087337A
GB1087337A
GB10707/65A
GB1070765A
GB1087337A
GB 1087337 A
GB1087337 A
GB 1087337A
GB 10707/65 A
GB10707/65 A
GB 10707/65A
GB 1070765 A
GB1070765 A
GB 1070765A
GB 1087337 A
GB1087337 A
GB 1087337A
Authority
GB
United Kingdom
Prior art keywords
phenylalkanes
sulphonates
chains
alkylbenzene
mixture
Prior art date
1964-04-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB10707/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-04-20
Filing date
1965-03-12
Publication date
1967-10-18
1965-03-12
Application filed by Colgate Palmolive Co
filed
Critical
Colgate Palmolive Co
1967-10-18
Publication of GB1087337A
publication
Critical
patent/GB1087337A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
C—CHEMISTRY; METALLURGY
C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
C11D1/02—Anionic compounds
C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Abstract
A detergent composition comprises a mixture of alkylbenzenesulphonates [e.g. of Li, Na, K, NH3, Ca, Mg, NH2C2H4OH or N(C2 H4OH)3] in which the alkylbenzene portion has an average mol. wt. 250-270, the alkyl groups are linear and contain at least 85% C12- 14 and at least 10% each C12, C13 and C14 chains, the sulphonates having at least 37% 5-(or higher) phenylalkanes and at most 27% 2-phenylalkanes. Other ingredients specified are Na2SO4, Na2CO3, K2CO3, Na4P2O7, Na3PO4, Na5P3O10, K5\P3O10, (NaPO3)6, Na- and K-silicates (e.g. Na2O + 1-3 SiO2), Nacarboxymethylcellulose, persulphates, perborates, percarbonates, lauric or coconut diethanolamide, monoethanolamide, isopropanolamide and their oxyethylated derivatives, lauryl and cetyl alcohols, dodecyldimethylamine oxide, Na- and K-xylene- and toluene-sulphonates, C8- 20 alkyl sulphates and sulphonates, sulphated alkylphenol- and alkanol-ethylene oxide condensates, polyethylene glycol ethers and esters, polyvinyl alcohol, Na salt of 85:15 tallow-coconut fatty acids, silica, trichlorocyanuric acid, chlorinated Na3PO4 and oxalic acid. A suitable starting material is an unbranched C11- 15 paraffin mixture, containing 34% C12, 43% C13 and 17% C14, prepared by selective absorption on molecular sieves of kerosene, followed by fractionation of the desorbed linear hydrocarbon. The product is monohalogenated and reacted with benzene (+ AlCl/HCl). The undesired 2-phenylalkane is separated by distillation from the desired 5-(or higher)phenylalkane and recycled to the alkylation reactor. The alkylation of benzene with alphaolefins having at least 85% C12- 14 chains, in presence of HF, is also mentioned.ALSO:The invention comprises a mixture of alkyl-benzenesulphonates [e.g. of Li, Na, K, NH3, Ca, Mg, NH2C2H4OH or N(C2H4OH)3] i which the alkylbenzene portion has an average mol. wt. 250-270, the alkyl groups are linear and contain at least 85% C12- 14 and at least 10% each C12, C13 and C14 chains, the sulphonates having at least 37% 5 (or higher)-phenylalkanes and at most 27% 2-phenylalkanes. The alkylbenzene having the specified properties is sulphonated by a standard procedure. A suitable starting material is an unbranched C11- 15 paraffin mixture containing 34% C12, 43% C13 and 17% C14, which is monohalogenated by reaction with one third mol. Cl2 to give internally chlorinated hydrocarbons.
GB10707/65A
1964-04-20
1965-03-12
Alkylbenzene sulphonate detergent compositions
Expired
GB1087337A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US361289A
US3320174A
(en)
1964-04-20
1964-04-20
Detergent composition
Publications (1)
Publication Number
Publication Date
GB1087337A
true
GB1087337A
(en)
1967-10-18
Family
ID=23421431
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB10707/65A
Expired
GB1087337A
(en)
1964-04-20
1965-03-12
Alkylbenzene sulphonate detergent compositions
Country Status (10)
Country
Link
US
(1)
US3320174A
(en)
BE
(1)
BE662407A
(en)
CH
(1)
CH481213A
(en)
DE
(1)
DE1281087B
(en)
DK
(1)
DK117311B
(en)
ES
(1)
ES310058A1
(en)
GB
(1)
GB1087337A
(en)
NL
(1)
NL6504957A
(en)
OA
(1)
OA01693A
(en)
SE
(1)
SE303168B
(en)
Cited By (1)
* Cited by examiner, † Cited by third party
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Priority date
Publication date
Assignee
Title
WO2000037775A1
(en)
*
1998-12-22
2000-06-29
Chevron U.S.A. Inc.
Oil recovery method for waxy crude oil using alkylaryl sulfonate surfactants derived from alpha-olefins
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US3433846A
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*
1964-05-07
1969-03-18
Chevron Res
Biodegradable detergent alkylate having improved detergent properties
US3391210A
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1968-07-02
Continental Oil Co
Process for the preparation of detergent alkylate
US3342888A
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1965-02-17
1967-09-19
Atlantic Refining Co
Production of low 2-phenyl isomer content monoalkylbenzene fractions
US3352933A
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*
1965-12-07
1967-11-14
Atlantic Refining Co
Isomerization of 2-phenyl alkanes
US3538006A
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1966-07-27
1970-11-03
Witco Chemical Corp
Emulsion cleaner
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*
1969-08-25
1972-02-01
Monsanto Co
Surfactant composition and liquid detergent formulations containing same
US3970596A
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1973-11-26
1976-07-20
Colgate-Palmolive Company
Non-gelling alpha-olefin sulfonate liquid detergent
US3951879A
(en)
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1973-12-14
1976-04-20
Colgate-Palmolive Company
Detergent that reduces electrostatic cling of synthetic fabrics
US4162236A
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*
1978-01-05
1979-07-24
Monsanto Company
Detergent compositions containing mixtures of alkylbenzene sulfonates as the detergent active
US4486329A
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*
1983-10-17
1984-12-04
Colgate-Palmolive Company
Liquid all-purpose cleaner
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1986-09-10
1989-06-27
Colgate-Palmolive Company
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US5236614A
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1990-09-25
1993-08-17
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Basf Ag
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Oral care products comprising zinc oxide and trimethylglycine.
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Composition with halide precursors of amino acid / zinc trimethylglycine
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Antiperspirant products with protein and antiperspirant salts
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Zinc-amino acid cysteine complex
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Oral care products comprising a tetrabasic zinc – amino acid – halide complex
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Steel surface cleaning agent and preparation method and application thereof
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Assignee
Title
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(en)
*
1950-03-31
1955-07-05
Exxon Research Engineering Co
Sulfonate detergent blend
US2944028A
(en)
*
1956-09-12
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California Research Corp
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(en)
*
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Colgate Palmolive Co
Detergent bar
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(en)
*
1960-12-30
1965-02-16
Universal Oil Prod Co
Alkaryl sulfonate production via n-olefin isomerization
1964
1964-04-20
US
US361289A
patent/US3320174A/en
not_active
Expired – Lifetime
1965
1965-03-03
ES
ES0310058A
patent/ES310058A1/en
not_active
Expired
1965-03-10
DE
DEC35269A
patent/DE1281087B/en
active
Pending
1965-03-11
SE
SE3220/65A
patent/SE303168B/xx
unknown
1965-03-12
GB
GB10707/65A
patent/GB1087337A/en
not_active
Expired
1965-03-12
CH
CH346465A
patent/CH481213A/en
not_active
IP Right Cessation
1965-04-12
BE
BE662407D
patent/BE662407A/xx
unknown
1965-04-15
OA
OA51591A
patent/OA01693A/en
unknown
1965-04-20
DK
DK198265AA
patent/DK117311B/en
unknown
1965-04-20
NL
NL6504957A
patent/NL6504957A/xx
unknown
Cited By (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
WO2000037775A1
(en)
*
1998-12-22
2000-06-29
Chevron U.S.A. Inc.
Oil recovery method for waxy crude oil using alkylaryl sulfonate surfactants derived from alpha-olefins
US6269881B1
(en)
1998-12-22
2001-08-07
Chevron U.S.A. Inc
Oil recovery method for waxy crude oil using alkylaryl sulfonate surfactants derived from alpha-olefins and the alpha-olefin compositions
CN1306145C
(en)
*
1998-12-22
2007-03-21
切夫里昂奥罗尼特有限责任公司
Oil recovery method for waxy crude oil using alkylaryl sulfonate surfactants derived from alpha-olefins
Also Published As
Publication number
Publication date
CH481213A
(en)
1969-11-15
SE303168B
(en)
1968-08-19
OA01693A
(en)
1969-12-15
DK117311B
(en)
1970-04-13
US3320174A
(en)
1967-05-16
NL6504957A
(en)
1965-10-21
ES310058A1
(en)
1965-06-01
DE1281087B
(en)
1968-10-24
BE662407A
(en)
1965-08-02
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