GB1094724A

GB1094724A – N-vinyl-2-piperazinones and polymers thereof
– Google Patents

GB1094724A – N-vinyl-2-piperazinones and polymers thereof
– Google Patents
N-vinyl-2-piperazinones and polymers thereof

Info

Publication number
GB1094724A

GB1094724A
GB8875/65A
GB887565A
GB1094724A
GB 1094724 A
GB1094724 A
GB 1094724A
GB 8875/65 A
GB8875/65 A
GB 8875/65A
GB 887565 A
GB887565 A
GB 887565A
GB 1094724 A
GB1094724 A
GB 1094724A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
alkyl
hydrogen
individually
alkaralkyl
Prior art date
1964-03-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB8875/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rohm and Haas Co

Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-03-04
Filing date
1965-03-02
Publication date
1967-12-13

1965-03-02
Application filed by Rohm and Haas Co
filed
Critical
Rohm and Haas Co

1967-12-13
Publication of GB1094724A
publication
Critical
patent/GB1094724A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

229920000642
polymer
Polymers

0.000
title
abstract
3

FRDAFUHMWZDCKM-UHFFFAOYSA-N
1-ethenylpiperazin-2-one
Chemical class

C=CN1CCNCC1=O
FRDAFUHMWZDCKM-UHFFFAOYSA-N
0.000
title
abstract
2

125000004432
carbon atom
Chemical group

C*

0.000
abstract
27

229910052739
hydrogen
Inorganic materials

0.000
abstract
16

239000001257
hydrogen
Substances

0.000
abstract
16

125000000217
alkyl group
Chemical group

0.000
abstract
14

UFHFLCQGNIYNRP-UHFFFAOYSA-N
Hydrogen
Chemical compound

[H][H]
UFHFLCQGNIYNRP-UHFFFAOYSA-N
0.000
abstract
13

125000004178
(C1-C4) alkyl group
Chemical group

0.000
abstract
6

125000002947
alkylene group
Chemical group

0.000
abstract
6

125000003710
aryl alkyl group
Chemical group

0.000
abstract
6

229910052799
carbon
Inorganic materials

0.000
abstract
6

125000001624
naphthyl group
Chemical group

0.000
abstract
6

125000001997
phenyl group
Chemical group

[H]C1=C([H])C([H])=C(*)C([H])=C1[H]

0.000
abstract
6

125000006702
(C1-C18) alkyl group
Chemical group

0.000
abstract
5

125000002496
methyl group
Chemical group

[H]C([H])([H])*

0.000
abstract
4

125000002941
2-furyl group
Chemical group

O1C([*])=C([H])C([H])=C1[H]

0.000
abstract
3

125000003545
alkoxy group
Chemical group

0.000
abstract
3

125000000000
cycloalkoxy group
Chemical group

0.000
abstract
3

125000000753
cycloalkyl group
Chemical group

0.000
abstract
3

125000004985
dialkyl amino alkyl group
Chemical group

0.000
abstract
3

125000004435
hydrogen atom
Chemical group

[H]*

0.000
abstract
3

239000000203
mixture
Substances

0.000
abstract
2

125000003011
styrenyl group
Chemical class

[H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H]

0.000
abstract
2

KGIGUEBEKRSTEW-UHFFFAOYSA-N
2-vinylpyridine
Chemical class

C=CC1=CC=CC=N1
KGIGUEBEKRSTEW-UHFFFAOYSA-N
0.000
abstract
1

NIXOWILDQLNWCW-UHFFFAOYSA-N
Acrylic acid
Chemical class

OC(=O)C=C
NIXOWILDQLNWCW-UHFFFAOYSA-N
0.000
abstract
1

NLHHRLWOUZZQLW-UHFFFAOYSA-N
Acrylonitrile
Chemical compound

C=CC#N
NLHHRLWOUZZQLW-UHFFFAOYSA-N
0.000
abstract
1

GYCMBHHDWRMZGG-UHFFFAOYSA-N
Methylacrylonitrile
Chemical compound

CC(=C)C#N
GYCMBHHDWRMZGG-UHFFFAOYSA-N
0.000
abstract
1

239000002253
acid
Substances

0.000
abstract
1

150000003926
acrylamides
Chemical class

0.000
abstract
1

239000012190
activator
Substances

0.000
abstract
1

239000000561
aggregant
Substances

0.000
abstract
1

HSFWRNGVRCDJHI-UHFFFAOYSA-N
alpha-acetylene
Natural products

C#C
HSFWRNGVRCDJHI-UHFFFAOYSA-N
0.000
abstract
1

239000003429
antifungal agent
Substances

0.000
abstract
1

239000007900
aqueous suspension
Substances

0.000
abstract
1

239000000022
bacteriostatic agent
Substances

0.000
abstract
1

239000008364
bulk solution
Substances

0.000
abstract
1

239000003795
chemical substances by application
Substances

0.000
abstract
1

239000008199
coating composition
Substances

0.000
abstract
1

150000001875
compounds
Chemical class

0.000
abstract
1

229920001577
copolymer
Polymers

0.000
abstract
1

230000007797
corrosion
Effects

0.000
abstract
1

238000005260
corrosion
Methods

0.000
abstract
1

239000000839
emulsion
Substances

0.000
abstract
1

150000002148
esters
Chemical class

0.000
abstract
1

150000002170
ethers
Chemical class

0.000
abstract
1

125000005677
ethinylene group
Chemical group

[*:2]C#C[*:1]

0.000
abstract
1

239000004744
fabric
Substances

0.000
abstract
1

239000011953
free-radical catalyst
Substances

0.000
abstract
1

230000001408
fungistatic effect
Effects

0.000
abstract
1

239000003254
gasoline additive
Substances

0.000
abstract
1

239000003112
inhibitor
Substances

0.000
abstract
1

239000010985
leather
Substances

0.000
abstract
1

239000003879
lubricant additive
Substances

0.000
abstract
1

239000010687
lubricating oil
Substances

0.000
abstract
1

FQPSGWSUVKBHSU-UHFFFAOYSA-N
methacrylamide
Chemical class

CC(=C)C(N)=O
FQPSGWSUVKBHSU-UHFFFAOYSA-N
0.000
abstract
1

125000005395
methacrylic acid group
Chemical group

0.000
abstract
1

238000005554
pickling
Methods

0.000
abstract
1

IWELDVXSEVIIGI-UHFFFAOYSA-N
piperazin-2-one
Chemical class

O=C1CNCCN1
IWELDVXSEVIIGI-UHFFFAOYSA-N
0.000
abstract
1

238000006116
polymerization reaction
Methods

0.000
abstract
1

125000001453
quaternary ammonium group
Chemical group

0.000
abstract
1

230000005855
radiation
Effects

0.000
abstract
1

239000002689
soil
Substances

0.000
abstract
1

125000001174
sulfone group
Chemical group

0.000
abstract
1

239000000725
suspension
Substances

0.000
abstract
1

150000003568
thioethers
Chemical class

0.000
abstract
1

229920002554
vinyl polymer
Polymers

0.000
abstract
1

XLYOFNOQVPJJNP-UHFFFAOYSA-N
water
Substances

O
XLYOFNOQVPJJNP-UHFFFAOYSA-N
0.000
abstract
1

Classifications

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07D—HETEROCYCLIC COMPOUNDS

C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings

C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings

C07D241/06—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having one or two double bonds between ring members or between ring members and non-ring members

C07D241/08—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having one or two double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms

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C10L1/00—Liquid carbonaceous fuels

C10L1/10—Liquid carbonaceous fuels containing additives

C10L1/14—Organic compounds

C10L1/146—Macromolecular compounds according to different macromolecular groups, mixtures thereof

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C10L1/00—Liquid carbonaceous fuels

C10L1/10—Liquid carbonaceous fuels containing additives

C10L1/14—Organic compounds

C10L1/22—Organic compounds containing nitrogen

C10L1/234—Macromolecular compounds

C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof

C10L1/2368—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing heterocyclic compounds containing nitrogen in the ring

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C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen

C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

C10M149/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring

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C10M159/005—Macromolecular compounds, e.g. macromolecular compounds composed of alternatively specified monomers not covered by the same main group

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C10L1/00—Liquid carbonaceous fuels

C10L1/10—Liquid carbonaceous fuels containing additives

C10L1/14—Organic compounds

C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium

C10L1/2462—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds

C10L1/2468—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds obtained by reactions involving only carbon to carbon unsaturated bonds; derivatives thereof

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C10M2203/108—Residual fractions, e.g. bright stocks

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C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions

C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers

C10M2205/026—Butene

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C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings

C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring

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C10M2207/02—Hydroxy compounds

C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings

C10M2207/027—Neutral salts thereof

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C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates

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C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions

C10M2207/10—Carboxylix acids; Neutral salts thereof

C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms

C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms

C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic

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C10M2207/10—Carboxylix acids; Neutral salts thereof

C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms

C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids

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C10M2207/10—Carboxylix acids; Neutral salts thereof

C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms

C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms

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C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions

C10M2207/10—Carboxylix acids; Neutral salts thereof

C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings

C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups

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C10M2207/10—Carboxylix acids; Neutral salts thereof

C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings

C10M2207/146—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings having carboxyl groups bound to carbon atoms of six-membeered aromatic rings having a hydrocarbon substituent of thirty or more carbon atoms

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C10M2207/22—Acids obtained from polymerised unsaturated acids

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C10M2207/26—Overbased carboxylic acid salts

C10M2207/262—Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates

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C10M2207/28—Esters

C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids

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C10M2207/28—Esters

C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids

C10M2207/304—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids derived from the combination of monohydroxy compounds, dihydroxy compounds and dicarboxylic acids only and having no free hydroxy or carboxyl groups

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C10M2207/28—Esters

C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives

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C10M2223/042—Metal salts thereof

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C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION

C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions

C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds

C10M2223/04—Phosphate esters

C10M2223/045—Metal containing thio derivatives

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION

C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions

C10M2227/06—Organic compounds derived from inorganic acids or metal salts

C10M2227/061—Esters derived from boron

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION

C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions

C10M2227/06—Organic compounds derived from inorganic acids or metal salts

C10M2227/063—Complexes of boron halides

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION

C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions

C10M2229/02—Unspecified siloxanes; Silicones

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION

C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions

C10M2229/04—Siloxanes with specific structure

C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2010/00—Metal present as such or in compounds

C10N2010/04—Groups 2 or 12

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2010/00—Metal present as such or in compounds

C10N2010/14—Group 7

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2010/00—Metal present as such or in compounds

C10N2010/16—Groups 8, 9, or 10

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives

C10N2030/08—Resistance to extreme temperature

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2040/00—Specified use or application for which the lubricating composition is intended

C10N2040/02—Bearings

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2040/00—Specified use or application for which the lubricating composition is intended

C10N2040/08—Hydraulic fluids, e.g. brake-fluids

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2040/00—Specified use or application for which the lubricating composition is intended

C10N2040/12—Gas-turbines

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2040/00—Specified use or application for which the lubricating composition is intended

C10N2040/12—Gas-turbines

C10N2040/13—Aircraft turbines

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2050/00—Form in which the lubricant is applied to the material being lubricated

C10N2050/10—Semi-solids; greasy

F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING

F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS

F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL

F02B3/00—Engines characterised by air compression and subsequent fuel addition

F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition

Abstract

Gasoline and lubricating oil compositions contain polymers or copolymers of N-vinyl-2-piperazinones of formula in which R1 is hydrogen; C1-C18 alkyl; aralkyl or alkaralkyl each containing up to 18 carbon atoms, and in each of which each alkyl group contains up to 8 carbon atoms; dialkylaminoalkyl of up to 12 carbon atoms, and in which each alkyl group contains up to 8 carbon atoms; or furfuryl; R2 individually, is hydrogen or methyl; R3, individually, is hydrogen; C1-C18 alkyl; phenyl; naphthyl; alkyl-, chloro- or alkoxy-substituted phenyl or naphthyl each containing up to 18 alkyl carbon atoms; aralkyl or alkaralkyl of up to 18 carbon atoms; or 2-furyl; R2 and R3 collectively, represent an alkylene group containing up to 18 carbon atoms which together with the carbon atom to which it is attached forms a ring having 5 to 7 cyclic atoms; R4, individually, is hydrogen or C1-C4 alkyl; R, individually, is hydrogen or C1-C4 alkyl and R4 and R5, collectively, represent an alkylene group containing up to 18 carbon atoms which together with the carbon atom to which it is attached forms a ring having 5 to 7 cyclic carbon atoms, the terms “alkyl” and “alkoxy” in the definitions of R1, R3, R4 and R5 including cycloalkyl and cycloalkoxy respectively.ALSO:N-Vinyl-2- piperazinones of the following formula are homopolymerized or copolymerized in which R1 is hydrogen; C1-C18 alkyl; aralkyl or alkaralkyl each containing up to 18 carbon atoms, and in each of which each alkyl group contains up to 8 carbon atoms; dialkylaminoalkyl of up to 12 carbon atoms, and in which each alkyl group contains up to 8 carbon atoms; or furfuryl; R2 individually, is hydrogen or methyl; R3, individually, is hydrogen; C1-C18 alkyl; phenyl; naphthyl; alkyl-, chloro- or alkoxy-substituted phenyl or naphthyl each containing up to 18 alkyl carbon atoms; aralkyl or alkaralkyl of up to 18 carbon atoms; or 2-furyl; R2 and R3 collectively, represent an alkylene group containing up to 18 carbon atoms which together with the carbon atom to which it is attached forms a ring having 5 to 7 cyclic atoms; R4, individually, is hydrogen or C1-C4 alkyl; R, individually, is hydrogen or C1-C4 alkyl and R4 and R5, collectively, represent an alkylene group containing up to 18 carbon atoms which together with the carbon atom to which it is attached forms a ring having 5 to 7 cyclic carbon atoms, the terms “alkyl” and “alkoxy” in the definitions of R1, R3, R4 and R5 including cycloalkyl and cycloalkoxy respectively. Suitable comonomers include alkyl and aminoalkyl acrylic and methacrylic esters, acrylonitrile, methacrylonitrile, acrylamides, methacrylamides, styrenes, vinyl-benzenes, vinyl carboxylates, ethers, sulphides, and sulphones, N-vinyl lactams and alkyleneureas, olefines, fumaric, maleic and itaconic esters, and vinylpyridines. Polymerization may be effected in bulk solution, suspension or emulsion. Conventional free radical catalysts may be used or high energy radiation. Quaternary ammonium activators may be present. The polymers may be used in coating formulations, to form fibres, as gasoline and lubricant additives, to thicken starch-water mixtures for application to paper or cloth, as soil aggregants, as glossing agents for leather, as dye assistants, as corrosion inhibitors in acid pickling baths, to promote settling of clays from aqueous suspensions or as fungistatic or bacteriostatic agents.ALSO:The invention comprises compounds of formula in which R1 is hydrogen; C1- 18 alkyl; aralkyl or alkaralkyl each containing up to 18 carbon atoms, and in each of which each alkyl group contains up to 8 carbon atoms; dialkylaminoalkyl of up to 12 carbon atoms, and in which each alkyl group contains up to 8 carbon atoms; or furfuryl; R2 individually, is hydrogen or methyl; R3, individually, is hydrogen or methyl; R3, individually, is hydrogen; C1-C18 alkyl; phenyl; naphthyl; alkyl-, chloro- or alkoxy-substituted phenyl or naphthyl each containing up to 18 alkyl carbon atoms; aralkyl or alkaralkyl of up to 18 carbon atoms; or 2-furyl; R2 and R3 collectively, represent an alkylene group containing up to 18 carbon atoms which together with the carbon atom to which it is attached forms a ring having 5 to 7 cyclic atoms; R4, individually, is hydrogen or C1-C4 alkyl; R, individually, is hydrogen or C1-C4 alkyl and R4 and R5, collectively, represent an alkylene group containing up to 18 carbon atoms which together with the carbon atom to which it is attached forms a ring having 5 to 7 cyclic carbon atoms, the terms “alkyl” and “alkoxy” in the definitions of R1, R3, R4 and R5 including cycloalkyl and cycloalkoxy respectively. They are prepared by vinylating the corresponding unsubstituted piperazinones with acetylene.

GB8875/65A
1964-03-04
1965-03-02
N-vinyl-2-piperazinones and polymers thereof

Expired

GB1094724A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US349485A

US3390139A
(en)

1964-03-04
1964-03-04
Nu-vinyl-2-piperazinones

Publications (1)

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Publication Date

GB1094724A
true

GB1094724A
(en)

1967-12-13

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ID=23372591
Family Applications (1)

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Title
Priority Date
Filing Date

GB8875/65A
Expired

GB1094724A
(en)

1964-03-04
1965-03-02
N-vinyl-2-piperazinones and polymers thereof

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US
(2)

US3390139A
(en)

AT
(2)

AT260936B
(en)

BE
(1)

BE660617A
(en)

BR
(1)

BR6567402D0
(en)

DE
(1)

DE1620149A1
(en)

FR
(1)

FR1431211A
(en)

GB
(1)

GB1094724A
(en)

IL
(1)

IL23092A
(en)

NL
(1)

NL128188C
(en)

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US3386998A
(en)

*

1964-05-19
1968-06-04
Rohm & Haas
Nu-alkenoyloxy-2-morpholinones and their corresponding hydrolysis products

US4123407A
(en)

*

1976-11-26
1978-10-31
American Optical Corporation
Hydrophilic contact lens

US4123408A
(en)

*

1976-11-26
1978-10-31
American Optical Corporation
Hydrogel contact lens

US4190571A
(en)

*

1977-09-21
1980-02-26
The B. F. Goodrich Company
Substituted 2-keto-1,4-diazacycloalkanes and UV-light-stabilized compositions containing them

US4170650A
(en)

*

1978-05-22
1979-10-09
The Dow Chemical Company
Oxopiperazinium salts, their preparation and their use

DE3132882A1
(en)

*

1981-08-20
1983-03-03
Cassella Ag, 6000 Frankfurt

NEW PIPERAZINONE, THEIR PRODUCTION AND USE

DE3817198A1
(en)

*

1988-05-20
1989-11-30
Cassella Ag

THIENYL PIPERAZINONE, THEIR PREPARATION AND USE

US5882799A
(en)

*

1996-12-16
1999-03-16
Vernay Laboratories, Inc.
Polymeric coupling agents for the adhesion of macromolecular materials and metal substrates

US20070122443A1
(en)

*

2005-11-29
2007-05-31
Narayanan Pallassana V
Amphiphilic copolymer compositions

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* Cited by examiner, † Cited by third party

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Priority date
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Title

US2944974A
(en)

*

1956-12-31
1960-07-12
Shell Oil Co
Lubricating oil compositions

NL108929C
(en)

*

1958-05-22

1964

1964-03-04
US
US349485A
patent/US3390139A/en
not_active
Expired – Lifetime

1964-10-02
US
US401236A
patent/US3293182A/en
not_active
Expired – Lifetime

1965

1965-02-23
BR
BR167402/65A
patent/BR6567402D0/en
unknown

1965-02-26
NL
NL6502524A
patent/NL128188C/xx
active

1965-03-01
AT
AT180465A
patent/AT260936B/en
active

1965-03-01
AT
AT779466A
patent/AT261216B/en
active

1965-03-02
GB
GB8875/65A
patent/GB1094724A/en
not_active
Expired

1965-03-03
IL
IL23092A
patent/IL23092A/en
unknown

1965-03-03
DE
DE1965R0040025
patent/DE1620149A1/en
active
Pending

1965-03-04
BE
BE660617D
patent/BE660617A/xx
unknown

1965-03-04
FR
FR7994A
patent/FR1431211A/en
not_active
Expired

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Publication number
Publication date

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(en)

1969-09-15

NL6502524A
(en)

1965-09-06

AT260936B
(en)

1968-03-25

US3293182A
(en)

1966-12-20

AT261216B
(en)

1968-04-10

BR6567402D0
(en)

1973-10-23

IL23092A
(en)

1968-11-27

DE1620149A1
(en)

1970-04-30

FR1431211A
(en)

1966-03-11

BE660617A
(en)

1965-09-06

US3390139A
(en)

1966-03-11

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