GB1117319A – Hydrogenation process
– Google Patents
GB1117319A – Hydrogenation process
– Google Patents
Hydrogenation process
Info
Publication number
GB1117319A
GB1117319A
GB5488267A
GB5488267A
GB1117319A
GB 1117319 A
GB1117319 A
GB 1117319A
GB 5488267 A
GB5488267 A
GB 5488267A
GB 5488267 A
GB5488267 A
GB 5488267A
GB 1117319 A
GB1117319 A
GB 1117319A
Authority
GB
United Kingdom
Prior art keywords
transition metal
range
hydrogen
solid catalyst
ethoxide
Prior art date
1965-06-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5488267A
Inventor
Wolfram R Kroll
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1965-06-21
Filing date
1965-06-21
Publication date
1968-06-19
1965-06-21
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co
filed
Critical
Exxon Research and Engineering Co
1965-06-21
Priority to GB5488267A
priority
Critical
patent/GB1117319A/en
1968-06-19
Publication of GB1117319A
publication
Critical
patent/GB1117319A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
B01J2231/60—Reduction reactions, e.g. hydrogenation
B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
B01J2531/64—Molybdenum
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/80—Complexes comprising metals of Group VIII as the central metal
B01J2531/82—Metals of the platinum group
B01J2531/828—Platinum
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/80—Complexes comprising metals of Group VIII as the central metal
B01J2531/84—Metals of the iron group
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/22—Organic complexes
B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
B01J31/2208—Oxygen, e.g. acetylacetonates
B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
Abstract
C2 to C30 hydrocarbons containing at least one double bond, C2 to C30 acetylenic compounds and C8 to C30 aromatic compounds may be hydrogenated in the liquid or gas phase at a temperature in the range -50 DEG to +500 DEG C. and a pressure in the range 0 to 1000 p.s.i.g. in the presence of a solid catalyst prepared by reaction of a transition metal salt (as defined) with an organic aluminium compound Al(CH3)2Y, where Y is halogen, hydrogen, methyl, methoxide, ethoxide, cyano or azide, in the presence of a hydrocarbon or Lewis base solvent, the transition metal and aluminum being in atomic ratio 1:1 to 1:30 (see Division B1). The catalyst may be mixed with a porous support material. Examples relate to the complete hydrogenation of cyclohexene, benzene, para-xylene. There is reference also to butene, octene, cyclododecatriene, norbornylene, acetylene, octyne-4, hexyne-3, phenyl acetylene, toluene, xylene, naphthalene and anthracene.ALSO:Unsaturated compounds are hydrogenated in liquid or gas phase by a process comprising contacting them with hydrogen at a temperature in the range -50 DEG to 500 DEG C and a pressure in the range 0 to 1000 psig in the presence of a solid catalyst prepared by the reaction of a transition metal salt with an organo aluminium compound of formula Al(CH3)2Y, where Y is halogen, hydrogen, methyl, methoxide, ethoxide, cyano or azide, in the presence of a hydrocarbon or Lewis base solvent, the transition metal and aluminium being in atomic ratio 1:1 to 1:30. The transition metal salts are reducible salts of Pt, Ru, Rh, Pd, Os, Ir, Au, Ag, Fe, Co, Ni, Mn, Re, Mo, W, Cu, Zn, Cr, Ti, V and are preferably chelates of cobalt, iron, nickel and platinum, for example the acetyl acetonates. The solid catalyst may be diluted with alumina, silica-alumina, activated carbon, titanium dioxides, zirconium dioxides, magnesia, clay, synthetic and natural zeolites such as faujasites and mordenites.
GB5488267A
1965-06-21
1965-06-21
Hydrogenation process
Expired
GB1117319A
(en)
Priority Applications (1)
Application Number
Priority Date
Filing Date
Title
GB5488267A
GB1117319A
(en)
1965-06-21
1965-06-21
Hydrogenation process
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
GB5488267A
GB1117319A
(en)
1965-06-21
1965-06-21
Hydrogenation process
Publications (1)
Publication Number
Publication Date
GB1117319A
true
GB1117319A
(en)
1968-06-19
Family
ID=10472345
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB5488267A
Expired
GB1117319A
(en)
1965-06-21
1965-06-21
Hydrogenation process
Country Status (1)
Country
Link
GB
(1)
GB1117319A
(en)
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
CN110560086A
(en)
*
2019-08-30
2019-12-13
浙江工业大学
High-dispersion palladium-sulfur-doped active carbon catalyst and preparation and application thereof
1965
1965-06-21
GB
GB5488267A
patent/GB1117319A/en
not_active
Expired
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
CN110560086A
(en)
*
2019-08-30
2019-12-13
浙江工业大学
High-dispersion palladium-sulfur-doped active carbon catalyst and preparation and application thereof
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