GB1117481A – Electrically conductive synthetic polymers
– Google Patents
GB1117481A – Electrically conductive synthetic polymers
– Google Patents
Electrically conductive synthetic polymers
Info
Publication number
GB1117481A
GB1117481A
GB3607165A
GB3607165A
GB1117481A
GB 1117481 A
GB1117481 A
GB 1117481A
GB 3607165 A
GB3607165 A
GB 3607165A
GB 3607165 A
GB3607165 A
GB 3607165A
GB 1117481 A
GB1117481 A
GB 1117481A
Authority
GB
United Kingdom
Prior art keywords
tcnq
salt
free
lithium
quaternized
Prior art date
1964-08-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3607165A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-08-24
Filing date
1965-08-23
Publication date
1968-06-19
1965-08-23
Application filed by General Electric Co
filed
Critical
General Electric Co
1968-06-19
Publication of GB1117481A
publication
Critical
patent/GB1117481A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
H—ELECTRICITY
H01—ELECTRIC ELEMENTS
H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
H01B1/121—Charge-transfer complexes
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F8/00—Chemical modification by after-treatment
C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F8/00—Chemical modification by after-treatment
C08F8/44—Preparation of metal salts or ammonium salts
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
C08G65/48—Polymers modified by chemical after-treatment
C08G65/485—Polyphenylene oxides
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 – C08G71/00
C08G73/02—Polyamines
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
C08K5/00—Use of organic ingredients
C08K5/16—Nitrogen-containing compounds
C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
C08K5/00—Use of organic ingredients
C08K5/16—Nitrogen-containing compounds
C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
H—ELECTRICITY
H01—ELECTRIC ELEMENTS
H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/00—Stock material or miscellaneous articles
Y10T428/31504—Composite [nonstructural laminate]
Y10T428/31678—Of metal
Y10T428/31692—Next to addition polymer from unsaturated monomers
Abstract
A composition comprises a salt of a polymer having quaternary nitrogen groups and of 7,7,8,8 – tetracyano – quinodimethan (TCNQ), said salt containing a sufficient quantity of additional TCNQ to give the composition, when in the form of a solid, a conductivity greater than 10-10 mho per centimetre. The salts may be obtained by (1) polymerizing a monvinyl monomer containing a tertiary nitrogen atom, or (2) polymerizing a monomer having a primary or secondary amine group, e.g. ethylene imine, and subsequently alkylating, or (3) reaction of a tertiary amine with a polymer containing halomethyl groups, e.g. halomethylated polystyrene and polyphenylene ethers, followed by quaternization and reaction with a simple TCNQ salt. The compositions may also include thermoplastics and elastomers such as polyurethane. In the examples: (1) polyvinylpyridine is quaternized with dimethyl sulphate, reacted with the lithium salt of TCNQ, and mixed in dimethyl formamide with free TCNQ, (2) and (3) the procedure of (1) is followed but the quaternization is with methyl iodide followed by conversion to the chloride form using an anion exchange column, (4) a styrene-2-vinylpyridine copolymer is quaternized using n-butyl iodide and converted to the TCNQ salt by reaction with the lithium salt of TCNQ, followed by addition of free TCNQ, (5) poly-(4-dimethylamino styrene) was quaternized with methyl iodide, treated with lithium TCNQ and free TCNQ added, (6) poly – (2,6 – dimethyl – phenylene) ether was chlorinated, reacted with (CH3)3N, treated with lithium TCNQ, and free TCNQ added, (7) polyethyleneimine was quaternized with dimethyl sulphate, reacted with lithium TCNQ and free TCNQ added, and (8) polyvinylimidazole was quaternized with methyl iodide, reacted with lithium TCNQ, and free TCNQ added.ALSO:Films are formed by coating glass slides with a composition comprising a salt of a polymer having quaternary nitrogen cationic groups and of 7, 7, 8, 8-tetracyanoquinodimethane (TCNQ), said salt containing a sufficient quantity of additional TCNQ to give the composition a conductivity greater than 10-10 mho per cm.. Exemplified polymers are those of vinyl pyridine, vinyl pyridine and styrene, aminostyrene, ethyleneimine, N-vinyl-imidazole and a polyphenylene ether.
GB3607165A
1964-08-24
1965-08-23
Electrically conductive synthetic polymers
Expired
GB1117481A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US39176464
US3346444A
(en)
1964-08-24
1964-08-24
Electrically conductive polymers and process of producing the same
Publications (1)
Publication Number
Publication Date
GB1117481A
true
GB1117481A
(en)
1968-06-19
Family
ID=23547837
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB3607165A
Expired
GB1117481A
(en)
1964-08-24
1965-08-23
Electrically conductive synthetic polymers
Country Status (8)
Country
Link
US
(1)
US3346444A
(en)
JP
(1)
JPS4415870B1
(en)
DE
(1)
DE1544979A1
(en)
ES
(1)
ES316613A1
(en)
FR
(1)
FR1456735A
(en)
GB
(1)
GB1117481A
(en)
NL
(1)
NL144316B
(en)
SE
(1)
SE331570B
(en)
Cited By (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
DE2838720A1
(en)
*
1978-09-06
1980-03-20
Bbc Brown Boveri & Cie
Electrically insulating resin compsn. with increased conductivity – obtd. by formation of charge transfer complex with added electron acceptor and/or donor
DE3211541A1
(en)
*
1981-03-31
1982-11-04
Rogers Corp., 06263 Rogers, Conn.
HIGH CAPACITY RAIL
CN113368619A
(en)
*
2021-06-23
2021-09-10
深圳市创裕达电子有限公司
Composite air dust removal filter bag and preparation method thereof
Families Citing this family (13)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
ES316614A1
(en)
*
1964-08-24
1966-07-01
Gen Electric
A procedure for preparing an electronically conducting composition. (Machine-translation by Google Translate, not legally binding)
GB1113216A
(en)
*
1965-10-19
1968-05-08
Ici Ltd
Polymer process
US3530007A
(en)
*
1967-12-19
1970-09-22
Us Air Force
Solar cell including aceanthraquinoxaline photosensitive material
JPS5132314B2
(en)
*
1971-08-24
1976-09-11
DE2228702C3
(en)
*
1972-06-13
1985-05-15
TED Bildplatten AG AEG-Telefunken-Teldec, Zug
Record or image record made of thermoplastic polymers based on vinyl chloride with additives for anti-static properties
JPS5741041B2
(en)
*
1974-04-17
1982-09-01
US4116894A
(en)
*
1976-07-01
1978-09-26
Xerox Corporation
Compositions and method for enhancing electrical life of copolymers
JPS56106302A
(en)
*
1980-01-24
1981-08-24
Matsushita Electric Ind Co Ltd
Electrode for conductive high molecular material
US4822638A
(en)
*
1987-02-11
1989-04-18
Lockheed Corporation
Electronic device fabrication on non-conductive polymer substrate
US4861859A
(en)
*
1988-03-28
1989-08-29
The United States Of America As Represented By The Secretary Of The Navy
Conductive polymers of transition-metal complexes coordinated by a diamino-dichalcogen-benzene compound
US7166241B1
(en)
1993-03-03
2007-01-23
International Business Machines Corporation
Water-soluble electrically conducting polymers, their synthesis and use
US5370825A
(en)
*
1993-03-03
1994-12-06
International Business Machines Corporation
Water-soluble electrically conducting polymers, their synthesis and use
CN101136282A
(en)
*
2006-08-31
2008-03-05
Abb研究有限公司
High voltage shield
Family Cites Families (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
BE510386A
(en)
*
1951-04-05
1900-01-01
US3140342A
(en)
*
1963-07-05
1964-07-07
Chomerics Inc
Electrical shielding and sealing gasket
1964
1964-08-24
US
US39176464
patent/US3346444A/en
not_active
Expired – Lifetime
1965
1965-08-18
ES
ES0316613A
patent/ES316613A1/en
not_active
Expired
1965-08-21
DE
DE19651544979
patent/DE1544979A1/en
active
Pending
1965-08-23
GB
GB3607165A
patent/GB1117481A/en
not_active
Expired
1965-08-23
JP
JP5164065A
patent/JPS4415870B1/ja
active
Pending
1965-08-23
NL
NL6510986A
patent/NL144316B/en
unknown
1965-08-24
SE
SE1102765A
patent/SE331570B/xx
unknown
1965-08-24
FR
FR29240A
patent/FR1456735A/en
not_active
Expired
Cited By (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
DE2838720A1
(en)
*
1978-09-06
1980-03-20
Bbc Brown Boveri & Cie
Electrically insulating resin compsn. with increased conductivity – obtd. by formation of charge transfer complex with added electron acceptor and/or donor
DE3211541A1
(en)
*
1981-03-31
1982-11-04
Rogers Corp., 06263 Rogers, Conn.
HIGH CAPACITY RAIL
CN113368619A
(en)
*
2021-06-23
2021-09-10
深圳市创裕达电子有限公司
Composite air dust removal filter bag and preparation method thereof
Also Published As
Publication number
Publication date
DE1544979A1
(en)
1969-08-14
NL6510986A
(en)
1966-02-25
ES316613A1
(en)
1966-07-01
SE331570B
(en)
1971-01-04
NL144316B
(en)
1974-12-16
FR1456735A
(en)
1966-07-08
US3346444A
(en)
1967-10-10
JPS4415870B1
(en)
1969-07-14
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