GB1128089A

GB1128089A – Process for the oxidation of cycloalkanes
– Google Patents

GB1128089A – Process for the oxidation of cycloalkanes
– Google Patents
Process for the oxidation of cycloalkanes

Info

Publication number
GB1128089A

GB1128089A
GB54739/66A
GB5473966A
GB1128089A
GB 1128089 A
GB1128089 A
GB 1128089A
GB 54739/66 A
GB54739/66 A
GB 54739/66A
GB 5473966 A
GB5473966 A
GB 5473966A
GB 1128089 A
GB1128089 A
GB 1128089A
Authority
GB
United Kingdom
Prior art keywords
organoperoxy
tri
oxidation
carbon atoms
alkyl
Prior art date
1965-12-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB54739/66A
Inventor
Jean-Claude Brunie
Noel Crenne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rhone Poulenc SA

Original Assignee
Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1965-12-10
Filing date
1966-12-07
Publication date
1968-09-25

1966-12-07
Application filed by Rhone Poulenc SA
filed
Critical
Rhone Poulenc SA

1968-09-25
Publication of GB1128089A
publication
Critical
patent/GB1128089A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds

C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation

C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring

C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring

C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups

C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only

C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2601/00—Systems containing only non-condensed rings

C07C2601/12—Systems containing only non-condensed rings with a six-membered ring

C07C2601/14—The ring being saturated

Abstract

1,128,089. Oxidation of cycloalkanes; tri- (organoperoxy) boranes. RHONE-POULENC S.A. 7 Dec., 1966 [10 Dec., 1965], No. 54739/66. Heading C2C. A cycloalkanol and a cycloalkane are obtained by heating a cycloalkane having 6-12 ring atoms with a tri-(organoperoxy) borane of formula B(OOR1) 3 , in which R1 is a monovalent hydrocarbon radical containing at least 4 carbon atoms. The reaction is preferably carried out at 120-180‹ C. in the presence of an alkyl orthoborate in which the alkyl group has 1-4 carbon atoms. The tri-(organoperoxy) boranes may be obtained by reacting the corresponding organic hydroperoxide with a lower alkyl orthoborate as follows: 3R1OOH + B(OR11) 3 -# B(OOR1) 3 +3R11OH in which R1 is as defined above and R11 is an aliphatic radical having 1-4 carbon atoms. The reaction may be carried out in an excess of the alkyl borate or an inert solvent. Examples are given of the oxidation of cyclohexane to cyclohexanol and cyclohexanone.

GB54739/66A
1965-12-10
1966-12-07
Process for the oxidation of cycloalkanes

Expired

GB1128089A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

FR41807A

FR1466528A
(en)

1965-12-10
1965-12-10

Cycloalkane oxidation process

Publications (1)

Publication Number
Publication Date

GB1128089A
true

GB1128089A
(en)

1968-09-25

Family
ID=8595136
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB54739/66A
Expired

GB1128089A
(en)

1965-12-10
1966-12-07
Process for the oxidation of cycloalkanes

Country Status (8)

Country
Link

US
(1)

US3479394A
(en)

AT
(1)

AT266072B
(en)

BE
(1)

BE690989A
(en)

DE
(1)

DE1593343B1
(en)

FR
(1)

FR1466528A
(en)

GB
(1)

GB1128089A
(en)

LU
(1)

LU52547A1
(en)

NL
(1)

NL6617026A
(en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

FR2953154B1
(en)

2009-11-30
2013-07-12
Rhodia Operations

PROCESS FOR PREPARING A DEPEROXIDATION CATALYST

FR2954314B1
(en)

2009-12-17
2012-01-27
Rhodia Operations

PROCESS FOR HYDROCARBON OXIDATION BY OXYGEN

FR2955321B1
(en)

2010-01-21
2012-02-10
Rhodia Operations

PROCESS FOR HYDROCARBON OXIDATION

FR2955322B1
(en)

2010-01-21
2013-09-06
Rhodia Operations

PROCESS FOR PRODUCING ALKYL HYDROPEROXIDE

US20230029768A1
(en)

2019-12-18
2023-02-02
Basf France Sas
Process for producing cyclohexanol and cyclohexanone

Family Cites Families (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB892723A
(en)

*

1959-11-04
1962-03-28
Distillers Co Yeast Ltd
Production of alkanols

LU41564A1
(en)

*

1961-04-27
1963-10-17

FR1346607A
(en)

*

1963-01-15
1963-12-20
Stamicarbon

Manufacture of cyclic alcohols

FR1361232A
(en)

*

1963-06-28
1964-05-15
Ici Ltd

Process for the catalytic oxidation of hydrocarbons

1965

1965-12-10
FR
FR41807A
patent/FR1466528A/en
not_active
Expired

1966

1966-12-02
NL
NL6617026A
patent/NL6617026A/xx
unknown

1966-12-02
US
US598635A
patent/US3479394A/en
not_active
Expired – Lifetime

1966-12-07
GB
GB54739/66A
patent/GB1128089A/en
not_active
Expired

1966-12-09
AT
AT1138666A
patent/AT266072B/en
active

1966-12-09
LU
LU52547D
patent/LU52547A1/xx
unknown

1966-12-09
DE
DE19661593343
patent/DE1593343B1/en
not_active
Withdrawn

1966-12-09
BE
BE690989D
patent/BE690989A/xx
unknown

Also Published As

Publication number
Publication date

US3479394A
(en)

1969-11-18

DE1593343B1
(en)

1971-09-16

FR1466528A
(en)

1967-01-20

NL6617026A
(en)

1967-06-12

AT266072B
(en)

1968-11-11

LU52547A1
(en)

1967-02-09

BE690989A
(en)

1967-06-09

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