GB1177095A - Creation of Inventions and Patents with Artificial Intelligence

GB1177095A – New Asymmetric Oxalic Acid Diaryl Amides
– Google Patents

GB1177095A – New Asymmetric Oxalic Acid Diaryl Amides
– Google Patents
New Asymmetric Oxalic Acid Diaryl Amides

Info

Publication number
GB1177095A

GB1177095A
GB28783/68A
GB2878368A
GB1177095A
GB 1177095 A
GB1177095 A
GB 1177095A
GB 28783/68 A
GB28783/68 A
GB 28783/68A
GB 2878368 A
GB2878368 A
GB 2878368A
GB 1177095 A
GB1177095 A
GB 1177095A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
alkyl
substituted
compounds
oxalic acid
Prior art date
1966-02-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB28783/68A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Schweiz AG

Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1966-02-07
Filing date
1967-02-07
Publication date
1970-01-07

1966-02-07
Priority claimed from CH167966A
external-priority
patent/CH480867A/en

1966-02-07
Priority claimed from CH168066A
external-priority
patent/CH512933A/en

1967-02-07
Application filed by Ciba AG
filed
Critical
Ciba AG

1970-01-07
Publication of GB1177095A
publication
Critical
patent/GB1177095A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

G—PHYSICS

G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY

G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY

G03C1/00—Photosensitive materials

G03C1/76—Photosensitive materials characterised by the base or auxiliary layers

G03C1/815—Photosensitive materials characterised by the base or auxiliary layers characterised by means for filtering or absorbing ultraviolet light, e.g. optical bleaching

G03C1/8155—Organic compounds therefor

A—HUMAN NECESSITIES

A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE

A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES

A61K8/00—Cosmetics or similar toiletry preparations

A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition

A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds

A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen

A61K8/42—Amides

A—HUMAN NECESSITIES

A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE

A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS

A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings

A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C233/00—Carboxylic acid amides

C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms

C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K5/00—Use of organic ingredients

C08K5/16—Nitrogen-containing compounds

C08K5/20—Carboxylic acid amides

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change

C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds

C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen

C09K15/22—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen containing an amide or imide moiety

Abstract

1,177,095. Oxalic acid diarylamides. CIBA Ltd. 7 Feb., 1967 [7 Feb., 1966], No. 28783/68. Divided out of 1,177,094. Heading C2C. The invention comprises compounds of the formula where R 1 and R 2 are alkyl of 1-18 carbon atoms which may be substituted by Cl, OH, alkoxy of 1-4 carbon atoms, carboxy, CN, carboxylic acid amide or carboxylic acid alkyl ester of up to 12 carbon atoms in the alkyl moiety, alkenyl of 3-4 carbon atoms, benzyl which may be substituted by Cl or alkyl, aliphatic acyl of up to 18 carbon atoms or benzoyl which may be substituted by Cl or alkyl of 1-4 carbon atoms, R 3 and R 4 are alkyl of 1-12 carbon atoms, halogen, haloalkyl, sulphonic acid, phenyl or phenylalkyl whose alkyl residue contains 1-4 carbon atoms, or two orthopositioned residues R 3 and/or R 4 together form a fused-on six-membered aromatic carbocyclic ring, m and n are 1 or 2, p and q are 1-3, m+(n-1) = or 2, each of the two ring systems containing at most 3 substituents apart from the amide group, the substitutents being so constituted that the molecule is asymmetrical. The compounds are prepared by condensing compounds of the formulµ where A 1 is hydroxy, halogen, alkoxy of 1-12 carbon atoms, benzyloxy or phenoxy and 2 is H or R 2 at 50-250 C. and the free hydroxy groups are blocked by subsequent etherification or acylation.

GB28783/68A
1966-02-07
1967-02-07
New Asymmetric Oxalic Acid Diaryl Amides

Expired

GB1177095A
(en)

Applications Claiming Priority (2)

Application Number
Priority Date
Filing Date
Title

CH167966A

CH480867A
(en)

1966-02-07
1966-02-07

Use of asymmetric oxalic acid diarylamides as ultraviolet absorbers

CH168066A

CH512933A
(en)

1966-02-07
1966-02-07
Asymmetric oxalic acid diarylamides as uv protectors

Publications (1)

Publication Number
Publication Date

GB1177095A
true

GB1177095A
(en)

1970-01-07

Family
ID=25688360
Family Applications (2)

Application Number
Title
Priority Date
Filing Date

GB28783/68A
Expired

GB1177095A
(en)

1966-02-07
1967-02-07
New Asymmetric Oxalic Acid Diaryl Amides

GB5725/67A
Expired

GB1177094A
(en)

1966-02-07
1967-02-07
Asymmetrical Oxalic Acid Diarylamides

Family Applications After (1)

Application Number
Title
Priority Date
Filing Date

GB5725/67A
Expired

GB1177094A
(en)

1966-02-07
1967-02-07
Asymmetrical Oxalic Acid Diarylamides

Country Status (7)

Country
Link

US
(2)

US3529982A
(en)

BE
(1)

BE693605A
(en)

DE
(2)

DE1618197B1
(en)

FR
(1)

FR1516276A
(en)

GB
(2)

GB1177095A
(en)

NL
(2)

NL153595B
(en)

SE
(2)

SE346103B
(en)

Cited By (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2145716A
(en)

1983-08-26
1985-04-03
Ciba Geigy Ag
Pesticidal oxalyl anilides

FR2596757A1
(en)

1986-04-04
1987-10-09
Sandoz Sa

NOVEL DERIVATIVES OF OXALANILIDE, THEIR PREPARATION AND THEIR USE AS STABILIZERS OF POLYMERIC MATERIALS

Families Citing this family (27)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE1618197B1
(en)

1966-02-07
1971-12-09
Ciba Geigy

Use of asymmetric oxalic acid diarylamides as ultraviolet protective agents for organic materials

US3906041A
(en)

1968-02-19
1975-09-16
Sandoz Ltd
Oxalic acid derivatives

US3906029A
(en)

1969-08-28
1975-09-16
Noury & Van Der Lande
N,N{40 -bis(p-phenoxycarbophenyl)sulfondiamide

US3886117A
(en)

1969-08-28
1975-05-27
Koninkl Ind Mij Noury And Van
Ultraviolet light stabilizers

US3856748A
(en)

1971-03-18
1974-12-24
Ciba Geigy Corp
Compositions stabilized with hydroxyphenyl acylamides

IE39205B1
(en)

1973-04-19
1978-08-30
Ciba Geigy Ag
New stabiliser system and its use for stabilising styrene polymers

DE2516684A1
(en)

1975-04-16
1976-10-28
Bayer Ag

POLYARYLAMIDES, THEIR PRODUCTION AND USE AS ABSORPTION AGENTS FOR ULTRAVIOLET RAYS

DE3135810A1
(en)

1980-09-20
1982-04-22
Sandoz-Patent-GmbH, 7850 Lörrach
Oxamide solutions of high concentration

CH656874A5
(en)

1980-09-20
1986-07-31
Sandoz Ag

OXAMIDE COMPOUNDS, HIGHLY CONCENTRATED SOLUTIONS THEREOF AND THEIR USE AS STABILIZERS IN POLYMERIC ORGANIC COMPOUNDS.

US4412024A
(en)

1981-09-14
1983-10-25
Sandoz Ltd.
Concentrated solutions of aromatic oxamide stabilizers

JPS596254A
(en)

1982-07-05
1984-01-13
Mitsubishi Gas Chem Co Inc
Polyphenylene ether resin composition

US4507497A
(en)

1983-03-03
1985-03-26
Minnesota Mining And Manufacturing Company
Water soluble michlers ketone analogs

US4576975A
(en)

1983-03-03
1986-03-18
Minnesota Mining And Manufacturing Company
Water soluble Michler’s ketone analogs in combined photoinitiator composition and polymerizable composition

US4524165A
(en)

1983-10-24
1985-06-18
Eastman Kodak Company
Stabilized copolyesterether compositions suitable for outdoor applications

US4525504A
(en)

1983-10-24
1985-06-25
Eastman Kodak Company
Stabilized polyester compositions suitable for outdoor applications

US4645853A
(en)

1985-08-30
1987-02-24
Ici Americas Inc.
Hindered phenolic oxamide compounds and stabilized compositions

GB8626608D0
(en)

1986-11-07
1986-12-10
Sandoz Ltd
Organic compounds

DE3739523A1
(en)

1986-12-02
1988-06-16
Sandoz Ag

SUBSTITUTED OXALSAEUREDIANILIDES AND THEIR USE AS LIGHT STABILIZERS

US5085903A
(en)

1990-06-11
1992-02-04
Ppg Industries, Inc.
Coatings for the protection of products in light-transmitting containers

US5182148A
(en)

1990-06-11
1993-01-26
Ppg Industries, Inc.
Coatings and method for coloring light-transmitting containers

ES2071472T3
(en)

1991-04-03
1995-06-16
Ciba Geigy Ag

ASYMMETRIC DIARYLAMIDE OF OXALIC ACID.

EP0511166A1
(en)

1991-04-26
1992-10-28
Ciba-Geigy Ag
Process for photochemical and thermic stabilization of polyamide fibre material with a fiberaffinitive copper complex and an oxalicacid diarylamide

TW383324B
(en)

1994-10-13
2000-03-01
Ciba Sc Holding Ag
UV absorbants and the use

GB2361005B
(en)

2000-04-04
2002-08-14
Ciba Sc Holding Ag
Synergistic mixtures of uv-absorbers in polyolefins

EP1395548A1
(en)

2001-02-26
2004-03-10
4Sc Ag
Derivatives of diphenylurea, diphenyloxalic acid diamide and diphenylsulfuric acid diamide and their use as medicaments

US7074396B2
(en)

2003-10-22
2006-07-11
Access Business Group International Llc
Composition and method for protecting both natural and artificial hair color from ultraviolet light damage

WO2009039943A1
(en)

2007-09-21
2009-04-02
Sanofi-Aventis
(carboxylalkylene-phenyl)-phenyl-oxalamides, method for the production thereof, and use of same as a medicament

Family Cites Families (6)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

NL272026A
(en)

1960-12-06

BE619816A
(en)

1961-07-06
1900-01-01

DE1188080B
(en)

1961-07-06
1965-03-04
Ciba Geigy

Use of oxalic acid-bis-oxyarylamides as protective agents against ultraviolet radiation

US3239484A
(en)

1962-10-04
1966-03-08
Exxon Research Engineering Co
Stabilization of polyolefins with oxanilide and a crotonaldehyde-phenol condensation product

CH501699A
(en)

1965-12-08
1971-02-26
Ciba Geigy Ag

Use of symmetrical oxalic acid diarylamides as ultraviolet protection agents for organic materials outside the textile industry

DE1618197B1
(en)

1966-02-07
1971-12-09
Ciba Geigy

Use of asymmetric oxalic acid diarylamides as ultraviolet protective agents for organic materials

1967

1967-01-28
DE
DE1967C0041361
patent/DE1618197B1/en
active
Pending

1967-01-28
DE
DE1967C0041360
patent/DE1618196B1/en
active
Pending

1967-02-02
FR
FR93513A
patent/FR1516276A/en
not_active
Expired

1967-02-03
BE
BE693605D
patent/BE693605A/xx
not_active
IP Right Cessation

1967-02-06
SE
SE1640/67A
patent/SE346103B/xx
unknown

1967-02-06
NL
NL676701776A
patent/NL153595B/en
not_active
IP Right Cessation

1967-02-06
US
US614039A
patent/US3529982A/en
not_active
Expired – Lifetime

1967-02-06
NL
NL6701777.A
patent/NL159955C/en
not_active
IP Right Cessation

1967-02-06
SE
SE01639/67A
patent/SE347959B/xx
unknown

1967-02-07
GB
GB28783/68A
patent/GB1177095A/en
not_active
Expired

1967-02-07
GB
GB5725/67A
patent/GB1177094A/en
not_active
Expired

1970

1970-04-13
US
US28026A
patent/US3661606A/en
not_active
Expired – Lifetime

Cited By (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2145716A
(en)

1983-08-26
1985-04-03
Ciba Geigy Ag
Pesticidal oxalyl anilides

EP0138757A1
(en)

1983-08-26
1985-04-24
Ciba-Geigy Ag
Oxalic-acid anilides

AU583015B2
(en)

1983-08-26
1989-04-20
Ciba-Geigy Ag
Oxalyl anilides

TR23746A
(en)

1983-08-26
1990-08-01
Ciba Geigy Ag

OXALIC ACID ANILIDES.

FR2596757A1
(en)

1986-04-04
1987-10-09
Sandoz Sa

NOVEL DERIVATIVES OF OXALANILIDE, THEIR PREPARATION AND THEIR USE AS STABILIZERS OF POLYMERIC MATERIALS

Also Published As

Publication number
Publication date

US3661606A
(en)

1972-05-09

BE693605A
(en)

1967-08-03

NL6701777A
(en)

1967-08-08

US3529982A
(en)

1970-09-22

NL159955C
(en)

1979-09-17

FR1516276A
(en)

1968-03-08

SE347959B
(en)

1972-08-21

NL153595B
(en)

1977-06-15

NL159955B
(en)

1979-04-17

NL6701776A
(en)

1967-08-08

DE1618196B1
(en)

1971-12-09

GB1177094A
(en)

1970-01-07

SE346103B
(en)

1972-06-26

DE1618197B1
(en)

1971-12-09

Información de contacto