GB1183397A

GB1183397A – Improved Mordenite Catalyst Compositions
– Google Patents

GB1183397A – Improved Mordenite Catalyst Compositions
– Google Patents
Improved Mordenite Catalyst Compositions

Info

Publication number
GB1183397A

GB1183397A
GB44239/67A
GB4423967A
GB1183397A
GB 1183397 A
GB1183397 A
GB 1183397A
GB 44239/67 A
GB44239/67 A
GB 44239/67A
GB 4423967 A
GB4423967 A
GB 4423967A
GB 1183397 A
GB1183397 A
GB 1183397A
Authority
GB
United Kingdom
Prior art keywords
mordenite
catalyst
catalyst compositions
mordenite catalyst
platinum
Prior art date
1966-10-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB44239/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Technology and Engineering Co

Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1966-10-14
Filing date
1967-09-28
Publication date
1970-03-04

1967-09-28
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co
filed
Critical
Exxon Research and Engineering Co

1970-03-04
Publication of GB1183397A
publication
Critical
patent/GB1183397A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions

C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used

C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier

C10G47/12—Inorganic carriers

C10G47/16—Crystalline alumino-silicate carriers

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof

B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material

B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate

B01J20/16—Alumino-silicates

B01J20/18—Synthetic zeolitic molecular sieves

B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J29/00—Catalysts comprising molecular sieves

B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites

B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms

C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction

C07C4/06—Catalytic processes

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms

C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation

C07C5/2206—Catalytic processes not covered by C07C5/23 – C07C5/31

C07C5/226—Catalytic processes not covered by C07C5/23 – C07C5/31 with metals

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils

C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used

C10G11/04—Oxides

C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2529/00—Catalysts comprising molecular sieves

C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays

C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type

C07C2529/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper

C07C2529/22—Noble metals

Abstract

1,183,397. Mordenite zeolite. ESSO RESEARCH & ENG. CO. 28 Sept., 1967 [14 Oct., 19661, No. 44239/67. Heading B1E. [Also in Divisions C1 and C5] A mordenite catalyst having a SiO 2 /Al 2 O 3 molar ratio of at least 55 is prepared by treating a natural or synthetic mordenite with at least 1 N acid solution at a temperature not exceeding 220‹F for at least 1 hour. The catalyst may be impregnated with a platinum group metal, i.e. Pd, Pt, Ru, Rh, Os or Ir, preferably palladium or platinum, or may be used in a matrix of clay or an inorganic oxide gel. At least part of the hydrogen content may be replaced by metal cations having properties for the catalysing of hydrocarbon conversion reactions, these include Al, Be, Ca, Ce, Cr, Mg, Mn, Sr, Zn, Ag, Au, Cu, Fe, Ni, Sb and the rare earth metals either individually or, preferably, mixed. The mordenite has large pore diameters of 6.6A and smaller ones of 2.8A.

GB44239/67A
1966-10-14
1967-09-28
Improved Mordenite Catalyst Compositions

Expired

GB1183397A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US58669566A

1966-10-14
1966-10-14

Publications (1)

Publication Number
Publication Date

GB1183397A
true

GB1183397A
(en)

1970-03-04

Family
ID=24346788
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB44239/67A
Expired

GB1183397A
(en)

1966-10-14
1967-09-28
Improved Mordenite Catalyst Compositions

Country Status (4)

Country
Link

US
(1)

US3480539A
(en)

DE
(1)

DE1667479C3
(en)

GB
(1)

GB1183397A
(en)

NL
(1)

NL160736C
(en)

Cited By (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2167430A
(en)

*

1984-11-22
1986-05-29
Intevep Sa
Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content

EP0372471A1
(en)

*

1988-12-05
1990-06-13
Research Association For Utilization Of Light Oil
Process for preparation of lower aliphatic hydrocarbons

Families Citing this family (29)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3673267A
(en)

*

1970-10-19
1972-06-27
Mobil Oil Corp
Isomerization of cyclohexane in the presence of a mordenite catalyst

US3730876A
(en)

*

1970-12-18
1973-05-01
A Sequeira
Production of naphthenic oils

US4018711A
(en)

*

1971-07-29
1977-04-19
Standard Oil Company (Indiana)
Catalytic composition

US4182692A
(en)

*

1973-12-03
1980-01-08
Norton Company
Mordenite catalyst

FR2314906A1
(en)

*

1975-06-17
1977-01-14
Erap

CATALYTIC TRANSFORMATION PROCESS OF BUTANE

FR2529100B1
(en)

*

1982-06-23
1986-10-03
Inst Francais Du Petrole

NEW HIGHLY DESALUMINATED MORDENITE-BASED CATALYST

US4500417A
(en)

*

1982-12-28
1985-02-19
Mobil Oil Corporation
Conversion of Fischer-Tropsch products

US4575417A
(en)

*

1983-03-31
1986-03-11
Texaco Inc.
Process for catalytic dewaxing with mordenite

US4536486A
(en)

*

1983-03-31
1985-08-20
Texaco Inc.
Process for dewaxing with mordenite

FR2593084B1
(en)

*

1986-01-22
1990-09-28
Inst Francais Du Petrole

CATALYST CONTAINING MORDENITY, ITS PREPARATION AND ITS APPLICATION TO THE ISOMERIZATION OF NORMAL PARAFFIN RICH CUTS.

US4665258A
(en)

*

1986-02-06
1987-05-12
Cosden Technology, Inc.
Toluene disproportionation process

US4723051A
(en)

*

1986-02-06
1988-02-02
Cosden Technology, Inc.
Xylene isomerization process

US4723049A
(en)

*

1987-05-18
1988-02-02
Cosden Technology, Inc.
Toluene disproportionation process

US4761514A
(en)

*

1987-05-18
1988-08-02
Cosden Technology, Inc.
Toluene disproportionation process

US5198595A
(en)

*

1987-11-23
1993-03-30
The Dow Chemical Company
Alkylation of aromatic compounds

US5175135A
(en)

*

1987-11-23
1992-12-29
The Dow Chemical Company
Alkylation of aromatic compounds to alkylates enriched in the linear substituted isomers

US4891448A
(en)

*

1987-11-23
1990-01-02
The Dow Chemical Company
Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers

US5243116A
(en)

*

1987-11-23
1993-09-07
The Dow Chemical Company
Alkylation of aromatic compounds

US4956511A
(en)

*

1989-01-04
1990-09-11
Fina Technology, Inc.
Toluene disproportionation process

US5952535A
(en)

*

1996-09-18
1999-09-14
Catalytica, Inc.
Selective catalytic conversion of a C9 aromatic feedstock containing substantial amounts of ethyl substituted aromatic components to a product rich in toluene and/or xylenes

FR2761905B1
(en)

*

1997-04-09
1999-05-14
Inst Francais Du Petrole

CATALYST BASED ON DEALUMINATED MORDENITY CONTAINING AT LEAST ONE METAL OF GROUPS VI, VII AND VIII, AND ITS USE IN DISMUTATION AND / OR TRANSALKYLATION OF AROMATIC HYDROCARBONS

US6803493B1
(en)

2003-08-15
2004-10-12
Fina Technology, Inc.
Toluene disproportion process

US7576249B2
(en)

*

2005-01-06
2009-08-18
Fina Technology, Inc.
Toluene disproportionation process utilizing mild sulfiding during startup

US20060211902A1
(en)

*

2005-03-16
2006-09-21
Xin Xiao
Palladium modified metal-promoted catalyst

US8349754B2
(en)

2008-03-26
2013-01-08
Council Of Scientific & Industrial Research
Modified zeolite catalyst useful for the conversion of paraffins, olefins and aromatics in a mixed feedstock into isoparaffins and a process thereof

US8063259B2
(en)

*

2008-08-18
2011-11-22
Fina Technology, Inc.
Toluene disproportionation using Nb/mordenite catalyst

US20100185035A1
(en)

*

2008-08-18
2010-07-22
Fin Technology Inc.
Nb/Mordenite Transalkylation Catalyst

US20100041933A1
(en)

*

2008-08-18
2010-02-18
Fina Technology, Inc.
Catalyst and Process for Hydrocarbon Conversions

US8546287B2
(en)

2010-05-31
2013-10-01
Fina Technology, Inc.
Rhenium promoted catalyst

Family Cites Families (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US2253285A
(en)

*

1938-03-29
1941-08-19
Standard Oil Dev Co
Cracking oil by leached zeolites

US2971904A
(en)

*

1957-02-12
1961-02-14
Exxon Research Engineering Co
Petroleum process catalyst supported on a molecular sieve zeolite

IT642040A
(en)

*

1959-12-30
1900-01-01

US3367884A
(en)

*

1965-12-30
1968-02-06
Mobil Oil Corp
Production and use of hydrocarbon conversion catalysts comprising acid treated crystalline aluminosilicates

1966

1966-10-14
US
US586695A
patent/US3480539A/en
not_active
Expired – Lifetime

1967

1967-09-28
GB
GB44239/67A
patent/GB1183397A/en
not_active
Expired

1967-10-13
DE
DE1667479A
patent/DE1667479C3/en
not_active
Expired

1967-10-16
NL
NL6713933.A
patent/NL160736C/en
not_active
IP Right Cessation

Cited By (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2167430A
(en)

*

1984-11-22
1986-05-29
Intevep Sa
Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content

EP0372471A1
(en)

*

1988-12-05
1990-06-13
Research Association For Utilization Of Light Oil
Process for preparation of lower aliphatic hydrocarbons

Also Published As

Publication number
Publication date

DE1667479B2
(en)

1980-08-07

DE1667479C3
(en)

1981-04-02

NL6713933A
(en)

1968-04-16

NL160736B
(en)

1979-07-16

DE1667479A1
(en)

1971-06-16

US3480539A
(en)

1969-11-25

NL160736C
(en)

1979-12-17

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Legal Events

Date
Code
Title
Description

1970-07-15
PS
Patent sealed [section 19, patents act 1949]

1983-04-27
PCNP
Patent ceased through non-payment of renewal fee

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