GB1197168A

GB1197168A – Trycylic Ketones and a Process for the Manufacture Thereof
– Google Patents

GB1197168A – Trycylic Ketones and a Process for the Manufacture Thereof
– Google Patents
Trycylic Ketones and a Process for the Manufacture Thereof

Info

Publication number
GB1197168A

GB1197168A
GB11865/69A
GB1186569A
GB1197168A
GB 1197168 A
GB1197168 A
GB 1197168A
GB 11865/69 A
GB11865/69 A
GB 11865/69A
GB 1186569 A
GB1186569 A
GB 1186569A
GB 1197168 A
GB1197168 A
GB 1197168A
Authority
GB
United Kingdom
Prior art keywords
alkyl
formula
alkoxy
compounds
preparation
Prior art date
1968-03-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB11865/69A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

F Hoffmann La Roche AG

Original Assignee
F Hoffmann La Roche AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1968-03-15
Filing date
1969-03-06
Publication date
1970-07-01

1969-03-06
Application filed by F Hoffmann La Roche AG
filed
Critical
F Hoffmann La Roche AG

1970-07-01
Publication of GB1197168A
publication
Critical
patent/GB1197168A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES

C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES

C11B9/00—Essential oils; Perfumes

C11B9/0042—Essential oils; Perfumes compounds containing condensed hydrocarbon rings

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds

C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition

C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups

C07C45/512—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being a free hydroxyl group

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates

C07C49/587—Unsaturated compounds containing a keto groups being part of a ring

C07C49/647—Unsaturated compounds containing a keto groups being part of a ring having unsaturation outside the ring

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates

C07C49/587—Unsaturated compounds containing a keto groups being part of a ring

C07C49/647—Unsaturated compounds containing a keto groups being part of a ring having unsaturation outside the ring

C07C49/653—Unsaturated compounds containing a keto groups being part of a ring having unsaturation outside the ring polycyclic

Abstract

1,197,168. Tricyclic ketones. F. HOFFMANN-LA ROCHE & CO., A.G. 6 March, 1969 [15 March, 1968], No. 11865/69. Heading C2C. The invention comprises tricyclic ketones of the formula wherein R 1 , R 2 and R 3 represent H, halogen, OH, C 1-7 alkyl, C 1-7 alkoxy, C 1-7 alkylamino, NH 2 , di-(C 1-7 alkyl) amino, SH or C 1-7 alkylmercapto; R 4 and R 5 represent H, C 1-7 alkyl or alkoxy; R 6 represents H or C 1-7 alkyl, and R 7 and R 8 represent H or C 1-7 alkyl or alkoxy with the proviso that at least one of R 7 and R 8 is C 1-7 alkyl or alkoxy; and acid addition salts thereof. They may be obtained by heating a compound of the formula or a compound of the formula wherein R1 2 represents halogen, OH, NH 2 , SH, C 1-7 alkyl, alkoxy, alkylamino or alkylmercapto, or di-(C 1-7 alkyl) amino; to a temperature of from 50 C. to 200 C. and, if desired, converting the product into an acid addition salt. Examples are given for the preparation of the compounds. They are useful in the preparation of perfumes and other scented compositions. Compounds of Formulµ II and III are obtained by reacting a phenol of formula with a propargyl halide of the formula wherein X represents a halogen atom in the presence of an inorganic base, an inert organic solvent and in the case of the preparation of compounds of Formula III in the presence of Cu powder. Examples are given of the preparation of these compounds.

GB11865/69A
1968-03-15
1969-03-06
Trycylic Ketones and a Process for the Manufacture Thereof

Expired

GB1197168A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

CH389968A

CH507186A
(en)

1968-03-15
1968-03-15

Process for the preparation of tricyclic ketones

Publications (1)

Publication Number
Publication Date

GB1197168A
true

GB1197168A
(en)

1970-07-01

Family
ID=4265889
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB11865/69A
Expired

GB1197168A
(en)

1968-03-15
1969-03-06
Trycylic Ketones and a Process for the Manufacture Thereof

Country Status (7)

Country
Link

US
(1)

US3711553A
(en)

BE
(1)

BE729787A
(en)

CH
(1)

CH507186A
(en)

DE
(1)

DE1910931A1
(en)

FR
(1)

FR2003993A1
(en)

GB
(1)

GB1197168A
(en)

NL
(1)

NL6901683A
(en)

Cited By (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0073837A1
(en)

*

1981-03-09
1983-03-16
Asahi Kasei Kogyo Kabushiki Kaisha
Process for selectively producing para-substituted derivatives of phenols

Families Citing this family (7)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3925479A
(en)

*

1971-11-05
1975-12-09
Hoffmann La Roche
Tricyclo (5,4,0,0{hu 3,9{b )undecan-2-ones

US3923899A
(en)

*

1971-11-12
1975-12-02
Hoffmann La Roche
Tricyclo(5,3,1,0{hu 3.8{b )undeca-5,9-dien-2-ones

US3925477A
(en)

*

1971-11-12
1975-12-09
Hoffmann La Roche
Tricyclo{8 5,3,1,0{hu 3,8{b {9 undecan-2-ones and the corresponding mono- and di-unsaturated derivatives

US3957878A
(en)

*

1971-11-12
1976-05-18
Hoffmann-La Roche Inc.
Tricyclic ketones

JPS5530687B2
(en)

*

1974-01-11
1980-08-13

US3907908A
(en)

*

1974-01-28
1975-09-23
Int Flavors & Fragrances Inc
Novel tricyclic alcohols, novel uses of tricyclic alcohols and processes for preparing same

JPS5530688B2
(en)

*

1974-04-01
1980-08-13

1968

1968-03-15
CH
CH389968A
patent/CH507186A/en
not_active
IP Right Cessation

1969

1969-02-03
NL
NL6901683A
patent/NL6901683A/xx
unknown

1969-02-24
US
US00801796A
patent/US3711553A/en
not_active
Expired – Lifetime

1969-03-04
DE
DE19691910931
patent/DE1910931A1/en
active
Pending

1969-03-06
GB
GB11865/69A
patent/GB1197168A/en
not_active
Expired

1969-03-13
BE
BE729787D
patent/BE729787A/xx
unknown

1969-03-14
FR
FR6907255A
patent/FR2003993A1/fr
not_active
Withdrawn

Cited By (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0073837A1
(en)

*

1981-03-09
1983-03-16
Asahi Kasei Kogyo Kabushiki Kaisha
Process for selectively producing para-substituted derivatives of phenols

EP0073837A4
(en)

*

1981-03-09
1983-08-01
Asahi Chemical Ind
Process for selectively producing para-substituted derivatives of phenols.

Also Published As

Publication number
Publication date

DE1910931A1
(en)

1970-09-03

CH507186A
(en)

1971-05-15

BE729787A
(en)

1969-09-15

FR2003993A1
(en)

1969-11-14

NL6901683A
(en)

1969-09-17

US3711553A
(en)

1973-01-16

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Legal Events

Date
Code
Title
Description

1970-11-11
PS
Patent sealed [section 19, patents act 1949]

1973-10-03
PLNP
Patent lapsed through nonpayment of renewal fees

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