GB1197265A

GB1197265A – Improvements relating to Chromium Complex Dyestuffs and their use
– Google Patents

GB1197265A – Improvements relating to Chromium Complex Dyestuffs and their use
– Google Patents
Improvements relating to Chromium Complex Dyestuffs and their use

Info

Publication number
GB1197265A

GB1197265A
GB5646268A
GB5646268A
GB1197265A
GB 1197265 A
GB1197265 A
GB 1197265A
GB 5646268 A
GB5646268 A
GB 5646268A
GB 5646268 A
GB5646268 A
GB 5646268A
GB 1197265 A
GB1197265 A
GB 1197265A
Authority
GB
United Kingdom
Prior art keywords
alkyl
alkylsulphamoyl
halogen
hydroxy
appropriate
Prior art date
1967-11-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB5646268A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Novartis AG

Original Assignee
JR Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1967-11-29
Filing date
1968-11-28
Publication date
1970-07-01

1968-11-28
Application filed by JR Geigy AG
filed
Critical
JR Geigy AG

1970-07-01
Publication of GB1197265A
publication
Critical
patent/GB1197265A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES

C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves

C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring

C09B62/465—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an acryloyl group, a quaternised or non-quaternised aminoalkyl carbonyl group or a (—N)n—CO—A—O—X or (—N)n—CO—A—Hal group, wherein A is an alkylene or alkylidene group, X is hydrogen or an acyl radical of an organic or inorganic acid, Hal is a halogen atom, and n is 0 or 1

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES

C09B45/00—Complex metal compounds of azo dyes

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES

C09B45/00—Complex metal compounds of azo dyes

C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o’-position hydroxy, alkoxy, carboxyl, amino or keto groups

C09B45/04—Azo compounds in general

C09B45/06—Chromium compounds

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES

C09B55/00—Azomethine dyes

C09B55/001—Azomethine dyes forming a 1,2 complex metal compound, e.g. with Co or Cr, with an other dye, e.g. with an azo or azomethine dye

Abstract

1,197,265. Chromium complex dyes. J. R. GEIGY A.G. 28 Nov., 1968 [29 Nov., 1967], No. 56462/68. Heading C4P. The invention comprises dyes of formula wherein Y is phenyl (optionally substituted by halogen, CN, lower-alkyl, lower-alkoxy, NO 2 , halo-lower-alkanoylamino or halo-lower-alkenoylamino), naphthyl, loweralkyl, benzyl (optionally ring-substituted by Cl, lower-alkyl, loweralkoxy or NO 2 ), C-phenyl-hydroxy-lower-alkyl, phenylsulphonyl, halophenylsulphonyl, lower alkylphenylsulphonyl, lower – alkoxypheny sulphonyl, nitrophenylsulphonyl, naphthylsulphonyl or lower-alkylsulphonyl; X is H, halogen, NO 2 or lower-alkyl; Ar is phenyl (optionally substituted by halogen, NO 2 , loweralkyl, CF 3 , lower-alkoxy, phenoxy, loweralkylphenoxy, lower – alkylsulphonyl, sulphamoyl, N – lower – alkylsulphamoyl or N,N – di – lower – alkylsulphamoyl) or naphthyl; M+ is one equivalent of a cation; and n is 1 or 2; wherein rings A and B may be substituted by halogen, NO 2 , lower-alkyl, phenylsulphonyl, lower – alkylsulphonyl, sulphamoyl, N – lower – alkylsulphamoyl or N,N – di – lower – alkylsulphamoyl, and wherein the group -N=N-Ar is linked to ring A or B or both para to the metal-binding oxygen atom. The term ” lower ” denotes a carbon content of up to five atoms. These dyes are prepared by reacting, in any sequence, an appropriate o – (hydroxy or alkoxy) – o1– hydroxy azo dye, an appropriate o-hydroxyo1-hydroxy azomethine dye and an agent capable of yielding chromium. The azomethine dye may be prepared in situ by condensing an appropriate o-hydroxybenzaldehyde with an appropriate o-hydroxyaniline. Intermediate 1 : 1 chromium complexes of the azo dye starting materials may be isolated. The dyes of the invention may be used to imbue polyamide-containing materials with red to orange shades. Reference has been directed by the Comptroller to Specification 887,461.

GB5646268A
1967-11-29
1968-11-28
Improvements relating to Chromium Complex Dyestuffs and their use

Expired

GB1197265A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

CH1678867A

CH492002A
(en)

1967-11-29
1967-11-29

Process for the production of chromium complex dyes

Publications (1)

Publication Number
Publication Date

GB1197265A
true

GB1197265A
(en)

1970-07-01

Family
ID=4420232
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB5646268A
Expired

GB1197265A
(en)

1967-11-29
1968-11-28
Improvements relating to Chromium Complex Dyestuffs and their use

Country Status (5)

Country
Link

BE
(1)

BE724612A
(en)

CH
(1)

CH492002A
(en)

FR
(1)

FR1599875A
(en)

GB
(1)

GB1197265A
(en)

NL
(1)

NL6817043A
(en)

Cited By (6)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE2457590A1
(en)

*

1973-12-07
1975-06-12
Ciba Geigy Ag

NEW METAL COMPLEXES, THEIR PRODUCTION AND USE

DE2520526A1
(en)

*

1974-05-09
1975-11-20
Ciba Geigy Ag

NEW CHROME COMPLEX DYES, THEIR PRODUCTION AND USE

EP0072501A1
(en)

*

1981-08-17
1983-02-23
Bayer Ag
Asymmetric 1:2 chromium-complex dyestuffs

EP0082117A1
(en)

*

1981-12-15
1983-06-22
Ciba-Geigy Ag
Chromium complexes of polyazo dyestuffs

US4443370A
(en)

*

1980-06-05
1984-04-17
Ciba-Geigy Corporation
Chrome-complex dyes

CN111500117A
(en)

*

2019-01-31
2020-08-07
精工爱普生株式会社
Ink composition for ink jet printing and recording method

Families Citing this family (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE2542707C3
(en)

*

1975-09-25
1978-06-01
Bayer Ag, 5090 Leverkusen

Chromium mixed complex dyes and their use for dyeing and printing nitrogen-containing fiber materials and leather

DE2735287C2
(en)

*

1977-08-05
1985-03-28
Basf Ag, 6700 Ludwigshafen

1: 2 chromium complex dyes, their production and use

1967

1967-11-29
CH
CH1678867A
patent/CH492002A/en
not_active
IP Right Cessation

1968

1968-11-28
GB
GB5646268A
patent/GB1197265A/en
not_active
Expired

1968-11-28
BE
BE724612D
patent/BE724612A/xx
not_active
IP Right Cessation

1968-11-28
NL
NL6817043A
patent/NL6817043A/xx
unknown

1968-11-29
FR
FR1599875D
patent/FR1599875A/fr
not_active
Expired

Cited By (10)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE2457590A1
(en)

*

1973-12-07
1975-06-12
Ciba Geigy Ag

NEW METAL COMPLEXES, THEIR PRODUCTION AND USE

US3978037A
(en)

*

1973-12-07
1976-08-31
Ciba-Geigy Corporation
Azo, azo methine 1:2 chromium complex dyes

DE2520526A1
(en)

*

1974-05-09
1975-11-20
Ciba Geigy Ag

NEW CHROME COMPLEX DYES, THEIR PRODUCTION AND USE

US4443370A
(en)

*

1980-06-05
1984-04-17
Ciba-Geigy Corporation
Chrome-complex dyes

US4486196A
(en)

*

1980-06-05
1984-12-04
Ciba-Geigy Corporation
Chrome-complex dyes and the production and use thereof for dyeing wool, polyamide

EP0072501A1
(en)

*

1981-08-17
1983-02-23
Bayer Ag
Asymmetric 1:2 chromium-complex dyestuffs

EP0082117A1
(en)

*

1981-12-15
1983-06-22
Ciba-Geigy Ag
Chromium complexes of polyazo dyestuffs

CN111500117A
(en)

*

2019-01-31
2020-08-07
精工爱普生株式会社
Ink composition for ink jet printing and recording method

EP3693414A1
(en)

*

2019-01-31
2020-08-12
Seiko Epson Corporation
Ink jet textile printing ink composition and recording method

US11499063B2
(en)

2019-01-31
2022-11-15
Seiko Epson Corporation
Ink jet textile printing ink composition and recording method

Also Published As

Publication number
Publication date

FR1599875A
(en)

1970-07-20

CH492002A
(en)

1970-06-15

NL6817043A
(en)

1969-06-02

BE724612A
(en)

1969-05-28

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(en)

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(en)

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(en)

1974-04-03

Monoazo compounds processes for their production and their use for the dyeing of natural and synthetic polyamide fibres

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(en)

1963-05-15

New chromium and cobalt complexes of monoazo dyestuffs of the benzene-azo-pyrazolone series and their manufacture and use

ES477802A1
(en)

1979-12-16

Iron complex azo dyestuffs

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(en)

1976-02-25

Fibre-reactive metallised idsazo dyestuffs their manufacture and use

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(en)

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Azo dyestuffs process for their manufacture and their use

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(en)

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Legal Events

Date
Code
Title
Description

1970-11-11
PS
Patent sealed

1985-07-24
PCNP
Patent ceased through non-payment of renewal fee

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