GB1205166A – Process and apparatus for the hydrodesulphurisation of heavy petroleum hydrocarbon oil
– Google Patents
GB1205166A – Process and apparatus for the hydrodesulphurisation of heavy petroleum hydrocarbon oil
– Google Patents
Process and apparatus for the hydrodesulphurisation of heavy petroleum hydrocarbon oil
Info
Publication number
GB1205166A
GB1205166A
GB28004/68A
GB2800468A
GB1205166A
GB 1205166 A
GB1205166 A
GB 1205166A
GB 28004/68 A
GB28004/68 A
GB 28004/68A
GB 2800468 A
GB2800468 A
GB 2800468A
GB 1205166 A
GB1205166 A
GB 1205166A
Authority
GB
United Kingdom
Prior art keywords
zone
catalyst
fluidization
reactor
fluidized
Prior art date
1967-06-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28004/68A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1967-06-12
Filing date
1968-06-12
Publication date
1970-09-16
1968-06-12
Application filed by Nippon Oil Corp
filed
Critical
Nippon Oil Corp
1970-09-16
Publication of GB1205166A
publication
Critical
patent/GB1205166A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
C10G45/16—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles suspended in the oil, e.g. slurries
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to “fluidised-bed” technique
B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to “fluidised-bed” technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
B01J8/384—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to “fluidised-bed” technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only
B01J8/386—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to “fluidised-bed” technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only internally, i.e. the particles rotate within the vessel
Abstract
1,205,166. Hydrodesulphurizing oils. NIPPON OIL CO. Ltd. 12 June, 1968 [12 June, 1967], No. 28004/68. Heading C5E. A process of hydrodesulphurizing heavy petroleum hydrocarbon oil comprises contacting said oil and a hydrogen-containing gas with a hydrodesulphurization catalyst in the fluidized state, in which process (a) said heavy oil and hydrogen-containing gas are introduced into a reactor containing said catalyst; (b) the reaction system consisting of said heavy oil, hydrogen-containing gas and said catalyst is introduced to a fluidization initiating zone located in the reactor at the bottom thereof to initiate the fluidization of the system; (c) the resulting fluidized system is caused to move from said fluidization initiating zone into an adjoining fluidized reaction zone disposed in said reactor above the former zone, and while it is moved upwardly through the fluidized reaction zone substantially all the hydrodesulphurization of the heavy oil is carried out; (d) the hydrodesulphurized product overflowing from said fluidized reaction zone and the catalyst are caused to dwell in a separating zone disposed inside said reactor immediately above the fluidized reaction zone, to separate the hydrodesulphurized product, the catalyst and the hydrogen-containing gas from each other; (e) the catalyst separated in said separating zone is caused to settle to a catalyst settling zone disposed inside said reactor externally of said fluidized reaction zone, the upper part of said catalyst settling zone communicating with said separating zone, the bottom part of said settling zone communicating with said fluidization initiating zone; and (f) the hydrodesulphurized product is withdrawn from the aforesaid separating zone. The catalyst may be any conventional catalyst such as alumina or silica – alumina – supported nickel – molybdenum catalyst, nickel – cobalt – molybdenum catalyst, cobalt-molybdenum catalyst or nickeltungsten catalyst. In a preferred form of apparatus the fluidization initiating zone is indicated by 14, the fluidized reaction zone by 8, and the separating zone by 10. The annular zone 9 functions as catalyst settling zone which is joined by a choked annular passage 11 to the initiating zone 14.
GB28004/68A
1967-06-12
1968-06-12
Process and apparatus for the hydrodesulphurisation of heavy petroleum hydrocarbon oil
Expired
GB1205166A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
JP3713067
1967-06-12
Publications (1)
Publication Number
Publication Date
GB1205166A
true
GB1205166A
(en)
1970-09-16
Family
ID=12489014
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB28004/68A
Expired
GB1205166A
(en)
1967-06-12
1968-06-12
Process and apparatus for the hydrodesulphurisation of heavy petroleum hydrocarbon oil
Country Status (2)
Country
Link
US
(1)
US3583905A
(en)
GB
(1)
GB1205166A
(en)
Families Citing this family (4)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB1331935A
(en)
*
1969-12-12
1973-09-26
Shell Int Research
Peocess for the catalytic hydroconversion of a residual hydroca rbon oil
US3807090A
(en)
*
1970-12-02
1974-04-30
Exxon Research Engineering Co
Purifications of fuels
US4648999A
(en)
*
1985-07-22
1987-03-10
M. W. Kellogg Company
Apparatus for contacting fluid with solid
CN112705118B
(en)
*
2019-10-25
2022-07-12
中国石油化工股份有限公司
Heavy oil hydrogenation reactor and hydrogenation process
1968
1968-06-10
US
US735733A
patent/US3583905A/en
not_active
Expired – Lifetime
1968-06-12
GB
GB28004/68A
patent/GB1205166A/en
not_active
Expired
Also Published As
Publication number
Publication date
DE1770630A1
(en)
1970-04-16
US3583905A
(en)
1971-06-08
DE1770630B2
(en)
1973-01-25
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Legal Events
Date
Code
Title
Description
1971-01-27
PS
Patent sealed [section 19, patents act 1949]
1985-02-06
PCNP
Patent ceased through non-payment of renewal fee
