GB1213538A – New ruthenium complexes and processes for their preparation
– Google Patents
GB1213538A – New ruthenium complexes and processes for their preparation
– Google Patents
New ruthenium complexes and processes for their preparation
Info
Publication number
GB1213538A
GB1213538A
GB5856068A
GB5856068A
GB1213538A
GB 1213538 A
GB1213538 A
GB 1213538A
GB 5856068 A
GB5856068 A
GB 5856068A
GB 5856068 A
GB5856068 A
GB 5856068A
GB 1213538 A
GB1213538 A
GB 1213538A
Authority
GB
United Kingdom
Prior art keywords
diket
ligand
ruthenium complexes
complexes
processes
Prior art date
1967-12-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5856068A
Inventor
Pierre Chabardes
Louis Colevray
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc SA
Original Assignee
Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1967-12-11
Filing date
1968-12-10
Publication date
1970-11-25
1968-12-10
Application filed by Rhone Poulenc SA
filed
Critical
Rhone Poulenc SA
1970-11-25
Publication of GB1213538A
publication
Critical
patent/GB1213538A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/22—Organic complexes
B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
B01J31/2208—Oxygen, e.g. acetylacetonates
B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
C07F15/0046—Ruthenium compounds
C07F15/0053—Ruthenium compounds without a metal-carbon linkage
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
B01J2231/32—Addition reactions to C=C or C-C triple bonds
B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
B01J2231/32—Addition reactions to C=C or C-C triple bonds
B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
B01J2231/52—Isomerisation reactions
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
B01J2231/60—Reduction reactions, e.g. hydrogenation
B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/80—Complexes comprising metals of Group VIII as the central metal
B01J2531/82—Metals of the platinum group
B01J2531/821—Ruthenium
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
Abstract
1,213,538. Ruthenium complexes. RHONEPOULENC S.A. 10 Dec., 1968 [11 Dec., 1967], No. 58560/68. Heading C2C. Ruthenium complexes of the formula where (diket) is a bidentate ligand derived from a #-diketone and has the general formula where R 1 , R 2 and R 3 are alkyl, cycloalkyl, or aryl, which may be substituted by halogen, or R 1 and R 2 or R 2 and R 3 taken together may represent a divalent hydrocarbyl radical which may be substituted by halogen, L is a mono- or bidentate ligand other than CO or a #-diketone and n is 1 or 2, are prepared by reacting a ligand L, in the presence of a hydrogenation catalyst, with a tris-(diket) Ru complex under a hydrogen atmosphere, or by reacting a complex (Ru- (diket) 2 L
GB5856068A
1967-12-11
1968-12-10
New ruthenium complexes and processes for their preparation
Expired
GB1213538A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
FR131734
1967-12-11
Publications (1)
Publication Number
Publication Date
GB1213538A
true
GB1213538A
(en)
1970-11-25
Family
ID=8643035
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB5856068A
Expired
GB1213538A
(en)
1967-12-11
1968-12-10
New ruthenium complexes and processes for their preparation
Country Status (2)
Country
Link
FR
(1)
FR1558416A
(en)
GB
(1)
GB1213538A
(en)
1967
1967-12-11
FR
FR1558416D
patent/FR1558416A/fr
not_active
Expired
1968
1968-12-10
GB
GB5856068A
patent/GB1213538A/en
not_active
Expired
Also Published As
Publication number
Publication date
DE1814026A1
(en)
1969-07-24
FR1558416A
(en)
1969-02-28
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Legal Events
Date
Code
Title
Description
1971-05-19
PS
Patent sealed
1971-09-02
429A
Application made for amendment of specification (sect. 29/1949)
1971-09-08
429H
Application (made) for amendment of specification now open to opposition (sect. 29/1949)
1972-01-19
429D
Case decided by the comptroller ** specification amended (sect. 29/1949)
1972-03-15
429A
Application made for amendment of specification (sect. 29/1949)
1972-03-15
429H
Application (made) for amendment of specification now open to opposition (sect. 29/1949)
1972-07-26
429D
Case decided by the comptroller ** specification amended (sect. 29/1949)
1973-06-06
429A
Application made for amendment of specification (sect. 29/1949)
1973-06-27
429H
Application (made) for amendment of specification now open to opposition (sect. 29/1949)
1973-10-31
429D
Case decided by the comptroller ** specification amended (sect. 29/1949)
1982-07-14
PCNP
Patent ceased through non-payment of renewal fee
