GB1226493A – – Google Patents
GB1226493A – – Google Patents
Info
Publication number
GB1226493A
GB1226493A
GB1226493DA
GB1226493A
GB 1226493 A
GB1226493 A
GB 1226493A
GB 1226493D A
GB1226493D A
GB 1226493DA
GB 1226493 A
GB1226493 A
GB 1226493A
Authority
GB
United Kingdom
Prior art keywords
enzyme
composition
acid
hydantoin
wash water
Prior art date
1968-03-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1968-03-07
Filing date
1969-03-03
Publication date
1971-03-31
1969-03-03
Application filed
filed
Critical
1971-03-31
Publication of GB1226493A
publication
Critical
patent/GB1226493A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
C11D3/39—Organic or inorganic per-compounds
C11D3/3942—Inorganic per-compounds
C—CHEMISTRY; METALLURGY
C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
C11D3/02—Inorganic compounds ; Elemental compounds
C11D3/04—Water-soluble compounds
C11D3/046—Salts
C—CHEMISTRY; METALLURGY
C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
C11D3/16—Organic compounds
C11D3/38—Products with no well-defined composition, e.g. natural products
C11D3/386—Preparations containing enzymes, e.g. protease or amylase
C11D3/38609—Protease or amylase in solid compositions only
C—CHEMISTRY; METALLURGY
C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
C11D3/39—Organic or inorganic per-compounds
C11D3/3902—Organic or inorganic per-compounds combined with specific additives
C11D3/3905—Bleach activators or bleach catalysts
C11D3/3907—Organic compounds
Abstract
1,226,493. An enzyme cleaning composition. COLGATE-PALMOLIVE CO. 3 March, 1969 [7 March, 1968; 3 May, 1968], No. 11161/69. Heading C3D. A composition for use in washing stains from fabrics comprises an enzyme and a material which supplies a percarboxylic acid or salt thereof when the composition is added to the wash water. This material may comprise a persalt and an activator therefor. A suitable persalt is a perborate such as sodium perborate whilst the activators include carboxylic esters and anhydrides and carboxylic acyl amides, e.g. N-acetyl succinimide, trisacetyl cyanurate, phenyl acetate, N-benzoyl glutarimide, N-pchlorobenzoyl-5,5-dimethyl hydantoin, cyclic and aliphatic imides, e.g. N-methoxycarbonyl phthalimide, 1,3 – di – (N – methoxycarbonyl)- hydantoin, compounds of the general Formula (I): where X is halogen and Z represents the atoms necessary to complete a hydantoin or succinimide ring, e.g. N-m-chlorobenzylsuccinimide, N-sulphonated cyclic imides, e.g. N-benzenesulphonyl phthalimide or an alkyl or aryl chloroformate. Alternatively, a solid percarboxylic acid or a salt of such an acid may be used, e.g. peroxybenzoic acids, particularly those having chloro or nitro substituents such as m-chloroperoxybenzoic acid and 2,4-dichloroperoxybenzoic acid. These acids may be protected against deterioration on storage by pelletizing them, preferably with a coating or agglomerating agent such as paraffin wax. The enzyme may be a proteolytic enzyme, e.g. pepsin, keratinase, metalloproteases. Other enzymes employed are amylases, carbohydrases or lipases. The enzyme preparation may be in the form of a powder or as spray-dried granules, and may contain calcium sulphate as a diluent. The percompound is preferably present in an amount such that it provides a concentration of percompound in the wash water equivalent to 1- 40 p.p.m. of available oxygen. A preferred detergent formulation containing sodium perborate tetrahydrate to be used at 0À15% concentration in the wash water contains 5-15% of that compound, corresponding to 8-20 p.p.m. of available oxygen. Typically the enzyme is present in an amount 0À001-4% of the total detergent formulation. The enzyme composition may be used in water as a pre-rinse or mixed into a surface-active detergent composition. The conventional anionic, cationic and non- ionic surface-active agents may be employed. The detergent may also contain inorganic builder salts, sequestering agents, polymeric additives, e.g. CMC and PVA, optical brighteners, e.g. stilbene derivatives and phenolic antioxidants.
GB1226493D
1968-03-07
1969-03-03
Expired
GB1226493A
(en)
Applications Claiming Priority (4)
Application Number
Priority Date
Filing Date
Title
US71120368A
1968-03-07
1968-03-07
US72657168A
1968-05-03
1968-05-03
US82910469A
1969-05-29
1969-05-29
US00164463A
US3840466A
(en)
1968-03-07
1971-07-20
Stain removal
Publications (1)
Publication Number
Publication Date
GB1226493A
true
GB1226493A
(en)
1971-03-31
Family
ID=27496600
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB1226493D
Expired
GB1226493A
(en)
1968-03-07
1969-03-03
Country Status (8)
Country
Link
US
(3)
US3637339A
(en)
BE
(1)
BE729544A
(en)
CA
(1)
CA943891A
(en)
CH
(1)
CH506617A
(en)
DE
(1)
DE1908905A1
(en)
FR
(1)
FR2003378A1
(en)
GB
(1)
GB1226493A
(en)
NL
(3)
NL6903616A
(en)
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4422950A
(en)
1980-12-09
1983-12-27
Lever Brothers Company
Bleach activator granules and preparation thereof
Families Citing this family (80)
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Publication number
Priority date
Publication date
Assignee
Title
US3982891A
(en)
*
1967-10-24
1976-09-28
Colgate-Palmolive Company
Bleaching and detergent compositions having imide activator and peroxygen bleach
DK128287A
(en)
*
1967-10-24
GB1355795A
(en)
*
1970-05-01
1974-06-05
Colgate Palmolive Co
Process and composition for cleaning fabrics
US4003700A
(en)
*
1970-05-01
1977-01-18
Colgate-Palmolive Company
Cleaning fabrics
DE2060762A1
(en)
*
1970-12-10
1972-06-22
Henkel & Cie Gmbh
Preparations for the production of cold bleach liquors, in particular washing liquors with a cold bleaching effect
US4009113A
(en)
*
1971-04-30
1977-02-22
Lever Brothers Company
Protection of materials
US3894960A
(en)
*
1972-05-22
1975-07-15
Colgate Palmolive Co
Activated peroxygen detergent
AT326611B
(en)
*
1972-07-31
1975-12-29
Henkel & Cie Gmbh
BLEACHING AID SUITABLE AS A COMPONENT OF POWDERED DETERGENTS AND BLEACHING AGENTS
US3974082A
(en)
*
1972-08-21
1976-08-10
Colgate-Palmolive Company
Bleaching compositions
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(en)
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1972-09-14
1977-02-25
BE789286A
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1972-09-14
1973-01-15
Tukovy Prumysl Oborone Reditel
DETERGENT PRODUCT CONTAINING A TENSIO-ACTIVE AGENT WITH ACTIVATION FACULTIES.
DE2422691A1
(en)
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1973-05-14
1974-12-05
Procter & Gamble
STABLE BLEACHING AGENTS
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1973-07-24
1978-10-17
Colgate-Palmolive Company
Washing and bleaching with composition containing bleach activator and a nitrilotricarboxylic acid compound
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1973-08-24
1981-11-17
Colgate-Palmolive Company
Method for bleaching with peroxymonosulfate-based compositions
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1974-03-06
1978-05-09
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1974-03-21
1975-10-02
Henkel & Cie Gmbh
STORAGE-RESISTANT, EASILY-RELEASE DETERGENT ADDITIVE AND METHOD FOR MANUFACTURING IT
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1975-11-25
1976-10-19
American Cyanamid Company
Aroyl-n-hydroxyformimidoyl halides as bleach activators
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1977-10-03
1978-09-19
Fmc Corporation
N-sulfonylimidazoles as peroxygen activators
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1977-10-03
1979-10-02
Fmc Corporation
Sulfonic anhydrides as peroxygen activators
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Aromatic sulfonic anhydrides as peroxygen activators
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1980-05-10
1984-07-13
Procter & Gamble
US4405482A
(en)
*
1980-09-01
1983-09-20
Richardson-Vicks Pty. Limited
Sanitizing formulation
US4489574A
(en)
*
1981-11-10
1984-12-25
The Procter & Gamble Company
Apparatus for highly efficient laundering of textiles
DE3264685D1
(en)
*
1981-11-13
1985-08-14
Unilever Nv
Enzymatic liquid cleaning composition
US4430244A
(en)
1982-03-04
1984-02-07
Colgate-Palmolive Company
Silicate-free bleaching and laundering composition
US4443352A
(en)
*
1982-03-04
1984-04-17
Colgate-Palmolive Company
Silicate-free bleaching and laundering composition
DE3218889A1
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*
1982-05-19
1983-11-24
Hoechst Ag, 6230 Frankfurt
METHOD FOR SIMULTANEOUSLY DECOLIFYING AND BLEACHING TEXTILE MATERIAL FROM CELLULOSE FIBERS
GR79703B
(en)
*
1982-10-04
1984-10-31
Colgate Palmolive Co
FR2535341B1
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1982-10-29
1986-08-14
Ugine Kuhlmann
LAUNDRY COMPOSITION FOR LOW TEMPERATURE LAUNDRY AND CLEANING OF PROTEIN FOULS
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(en)
*
1983-03-07
1985-06-25
Cushman Mark E
Bleaching detergent compositions comprising sulfosuccinate bleach promoters
GB8321924D0
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1983-08-15
1983-09-14
Unilever Plc
Enzymatic machine-dishwashing compositions
GB8321923D0
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1983-08-15
1983-09-14
Unilever Plc
Machine-dishwashing compositions
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1983-12-22
1984-12-04
The Procter & Gamble Company
Bodies containing stabilized bleach activators
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(en)
*
1983-12-22
1984-11-20
The Procter & Gamble Company
Peroxygen bleach activators and bleaching compositions
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1983-12-22
1985-09-03
The Procter & Gamble Company
Peroxygen bleach activators and bleaching compositions
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1985-07-19
1987-07-07
Colgate-Palmolive Company
Method of encapsulating a bleach and activator therefor in a binder
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*
1985-08-21
1989-09-05
The Clorox Company
Encapsulated enzyme in dry bleach composition
US5093021A
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1985-08-21
1992-03-03
The Clorox Company
Encapsulated enzyme in dry bleach composition
US5254287A
(en)
*
1985-08-21
1993-10-19
The Clorox Company
Encapsulated enzyme in dry bleach composition
US5167854A
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*
1985-08-21
1992-12-01
The Clorox Company
Encapsulated enzyme in dry bleach composition
ATE72579T1
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*
1985-08-21
1992-02-15
Clorox Co
STABLE PERSACID BLEACH.
USRE32672E
(en)
*
1985-09-09
1988-05-24
Allergan, Inc.
Method for simultaneously cleaning and disinfecting contact lenses using a mixture of peroxide and proteolytic enzyme
US5296161A
(en)
*
1986-06-09
1994-03-22
The Clorox Company
Enzymatic perhydrolysis system and method of use for bleaching
AU603101B2
(en)
*
1986-06-09
1990-11-08
Clorox Company, The
Enzymatic perhydrolysis system and method of use for bleaching
US5364554A
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*
1986-06-09
1994-11-15
The Clorox Company
Proteolytic perhydrolysis system and method of use for bleaching
US5087385A
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*
1986-11-06
1992-02-11
The Clorox Company
Acyloxynitrogen peracid precursors
US4859800A
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1986-11-06
1989-08-22
The Clorox Company
Phenoxyacetate peracid precursors
US4956117A
(en)
*
1986-11-06
1990-09-11
The Clorox Company
Phenoxyacetate peracid precursors and perhydrolysis systems therewith
US4957647A
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1986-11-06
1990-09-18
The Clorox Company
Acyloxynitrogen peracid precursors
US5049305A
(en)
*
1986-11-06
1991-09-17
Zielske Alfred G
Phenoxyacetate peracid precursors and perhydrolysis systems therewith
US5130045A
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1992-07-14
The Clorox Company
Delayed onset active oxygen bleach composition
US5234616A
(en)
*
1987-10-30
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The Clorox Company
Method of laundering clothes using a delayed onset active oxygen bleach composition
GB8803114D0
(en)
*
1988-02-11
1988-03-09
Bp Chem Int Ltd
Bleach activators in detergent compositions
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Bp Chem Int Ltd
Anhydrides in detergent compositions
US4906399A
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1988-08-19
1990-03-06
Dow Corning Corporation
Organosilicon oxygen bleach activator compositions
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(en)
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1989-03-08
Procter & Gamble
Liquid detergent composition containing enzyme and enzyme stabilization system
US5232620A
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1991-02-28
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Fmc Corporation
Sodium tripolyphosphate composition and method of producing it
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The Procter & Gamble Company
Stable liquid detergent compositions inhibiting dye transfer
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1998-07-21
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Stable liquid detergent compositions inhibiting dye transfer
US5302375A
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Colgate-Palmolive Company
Oral composition having improved tooth whitening effect
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1998-07-29
The Procter & Gamble Company
Bleaching compounds comprising substituted benzoyl caprolactam bleach activators
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1998-05-19
The Procter & Gamble Company
Bleaching detergent compositions comprising bleach activators effective at low perhydroxyl concentrations
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The Procter & Gamble Company
Bleaching solutions and method utilizing selected bleach activators effective at low perhydroxyl concentrations
EP0736085B2
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2009-12-16
The Procter & Gamble Company
Detergent compositions containing percarbonate, amylase and protease
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2000-02-16
Procter & Gamble
BLEACHING COMPOSITIONS INCLUDING A PROTEASE ENZYME.
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1996-02-29
Degussa
Activators for inorganic peroxo compounds and agents containing them
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1994-10-11
1998-09-08
The Procter & Gamble Company
Detergent compositions with optimized surfactant systems to provide dye transfer inhibition benefits
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1995-01-20
1997-06-03
The Procter & Gamble Company
Bleaching compositions and additives comprising bleach activators having alpha-modified lactam leaving-groups
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1997-05-13
The Proctor & Gamble Company
Detergent compositions
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1996-02-23
1999-03-09
The Procter & Gamble Company
Bleach additive and bleaching compositions having glycine anhydride activators
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1996-12-04
2003-07-30
诺沃奇梅兹北美公司
Alkaline enzyme scouring of cotton textiles
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The Procter & Gamble Company
Low sudsing granular detergent composition containing optimally selected levels of a foam control agent and enzymes
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1927-05-19
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*
1934-08-22
1936-03-02
Henkel & Cie Gmbh
Improvements in or relating to bleaching, washing, and cleansing agents, particularly for use in water containing iron
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Stable dry compositions useful as bleaching and oxidizing agents
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Product for laundering and method of preparing this product.
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Detergent compositions
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*
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Unilever Ltd
Detergent composition
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(en)
*
1966-12-19
DK130474A
(en)
*
1967-12-30
1968
1968-05-03
US
US726571A
patent/US3637339A/en
not_active
Expired – Lifetime
1969
1969-02-22
DE
DE19691908905
patent/DE1908905A1/de
not_active
Ceased
1969-02-26
CA
CA044,053A
patent/CA943891A/en
not_active
Expired
1969-02-27
CH
CH299069A
patent/CH506617A/en
not_active
IP Right Cessation
1969-02-27
FR
FR6905074A
patent/FR2003378A1/fr
active
Pending
1969-03-03
GB
GB1226493D
patent/GB1226493A/en
not_active
Expired
1969-03-07
BE
BE729544D
patent/BE729544A/xx
not_active
IP Right Cessation
1969-03-07
NL
NL6903616A
patent/NL6903616A/xx
unknown
1969-05-29
US
US00829104A
patent/US3714050A/en
not_active
Expired – Lifetime
1971
1971-07-20
US
US00164463A
patent/US3840466A/en
not_active
Expired – Lifetime
1973
1973-07-17
NL
NL7309966A
patent/NL7309966A/xx
unknown
1973-07-17
NL
NL7309965A
patent/NL7309965A/xx
unknown
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4422950A
(en)
1980-12-09
1983-12-27
Lever Brothers Company
Bleach activator granules and preparation thereof
Also Published As
Publication number
Publication date
US3637339A
(en)
1972-01-25
US3840466A
(en)
1974-10-08
FR2003378A1
(en)
1969-11-07
NL6903616A
(en)
1969-09-09
NL7309966A
(en)
1973-09-25
US3714050A
(en)
1973-01-30
DE1908905A1
(en)
1969-11-27
BE729544A
(en)
1969-08-18
CH506617A
(en)
1971-04-30
CA943891A
(en)
1974-03-19
NL7309965A
(en)
1973-09-25
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Legal Events
Date
Code
Title
Description
1971-08-11
PS
Patent sealed [section 19, patents act 1949]
1989-03-30
PE20
Patent expired after termination of 20 years
