GB1232831A

GB1232831A – – Google Patents

GB1232831A – – Google Patents

Info

Publication number
GB1232831A

GB1232831A

GB1232831DA
GB1232831A
GB 1232831 A
GB1232831 A
GB 1232831A

GB 1232831D A
GB1232831D A
GB 1232831DA
GB 1232831 A
GB1232831 A
GB 1232831A
Authority
GB
United Kingdom
Prior art keywords
alx
moo
catalysts
sio
complex
Prior art date
1967-05-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1967-05-03
Filing date
1968-05-02
Publication date
1971-05-19

1968-05-02
Application filed
filed
Critical

1971-05-19
Publication of GB1232831A
publication
Critical
patent/GB1232831A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/22—Organic complexes

B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms

B01J31/2208—Oxygen, e.g. acetylacetonates

B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides

B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides

B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms

B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/20—Carbonyls

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands

B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 – B01J31/24

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions

C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond

C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions

C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond

C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond

C07C6/06—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond at a cyclic carbon-to-carbon double bond

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00

B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds

B01J2231/54—Metathesis reactions, e.g. olefin metathesis

B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00

B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal

B01J2531/64—Molybdenum

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00

B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal

B01J2531/66—Tungsten

Abstract

1,232,831. Olefine catalysts. PHILLIPS PETROLEUM CO. 2 May, 1968 [3 May, 1967; 28 March, 1968], No. 20830/68. Heading B1E. [Also in Divisions C3 and C5] Catalyst compositions comprise the admixture of (a) a complex of formula [(L) a M b Z c ] x where M is Mo, W, MoO, MoO 2 , WO, WO 2 , (L) is CO, R 3 Q, R 3 QO, R 2 Q-QR 2 , or R2(COO-) m where Q=P, As or Sb; Z is halogen, CN, SCN, OCN or SnCl 3 ; a is 1-6, b is 1 or 2, c is 0-5 m is 1 or 2 and x is integer representing polymeric state of the complex; a+b+c= coordination state of the metal; R is a saturated hydrocarbon optionally containing alkoxy and halo of up to 20 carbon atoms, R2 is saturated or ethenically unsaturated hydrocarbon up to 30 carbon atoms and (b) an Al containing adjuvant selected from (1) one or more of R e AlX f , (2) one or more of R’ g M’X h , (3) AlX 3 , or (4) a mixture of (1) or (3) with (2), wherein R’ is R or H, M’ is metal of Group IA, IIA, IIIA or IIB, e is 1-2, f is 1-2, e+f=3, g is 1-3, h is 0-2, g+h= valence of M’. Many examples of complexing agents, starting compounds of Mo and W (usually halides) and Al containing compounds of (b). Catalysts may be used in vapour phase on supports such as SiO 2 , Al 2 O 3 , SiO 2 -A 2 O 3 , TiO 2 , B 2 O 3 , zeolites, ion exchange resins or solid polymers.

GB1232831D
1967-05-03
1968-05-02

Expired

GB1232831A
(en)

Applications Claiming Priority (2)

Application Number
Priority Date
Filing Date
Title

US63564967A

1967-05-03
1967-05-03

US71702868A

1968-03-28
1968-03-28

Publications (1)

Publication Number
Publication Date

GB1232831A
true

GB1232831A
(en)

1971-05-19

Family
ID=27092418
Family Applications (2)

Application Number
Title
Priority Date
Filing Date

GB1232831D
Expired

GB1232831A
(en)

1967-05-03
1968-05-02

GB1232832D
Expired

GB1232832A
(en)

1967-05-03
1968-05-02

Family Applications After (1)

Application Number
Title
Priority Date
Filing Date

GB1232832D
Expired

GB1232832A
(en)

1967-05-03
1968-05-02

Country Status (7)

Country
Link

JP
(1)

JPS5018040B1
(en)

BE
(1)

BE714621A
(en)

CA
(1)

CA925882A
(en)

DE
(1)

DE1767377A1
(en)

FR
(1)

FR1561026A
(en)

GB
(2)

GB1232831A
(en)

NL
(2)

NL6806208A
(en)

Cited By (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0283400A1
(en)

*

1987-03-20
1988-09-21
Societe Nationale Elf Aquitaine
Catalytic system with a prolonged life span and preservation for the metathesis of olefins

Families Citing this family (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US11192975B2
(en)

2016-08-17
2021-12-07
Zeon Corporation
Crosslinked rubber

JP6878786B2
(en)

*

2016-08-17
2021-06-02
日本ゼオン株式会社

Rubber cross-linked product

0

NL
NL135284D
patent/NL135284C/xx
active

1968

1968-04-30
CA
CA018801A
patent/CA925882A/en
not_active
Expired

1968-05-02
GB
GB1232831D
patent/GB1232831A/en
not_active
Expired

1968-05-02
NL
NL6806208A
patent/NL6806208A/xx
unknown

1968-05-02
JP
JP2914468A
patent/JPS5018040B1/ja
active
Pending

1968-05-02
GB
GB1232832D
patent/GB1232832A/en
not_active
Expired

1968-05-03
FR
FR1561026D
patent/FR1561026A/fr
not_active
Expired

1968-05-03
DE
DE19681767377
patent/DE1767377A1/en
active
Pending

1968-05-03
BE
BE714621D
patent/BE714621A/xx
unknown

Cited By (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0283400A1
(en)

*

1987-03-20
1988-09-21
Societe Nationale Elf Aquitaine
Catalytic system with a prolonged life span and preservation for the metathesis of olefins

FR2612422A1
(en)

*

1987-03-20
1988-09-23
Elf Aquitaine

ADVANCED CATALYTIC SYSTEMS WITH EXTENDED LIFE AND CONSERVATION PERIOD FOR OLEFIN METATHESIS

Also Published As

Publication number
Publication date

DE1767377A1
(en)

1972-04-20

FR1561026A
(en)

1969-03-21

BE714621A
(en)

1968-11-04

GB1232832A
(en)

1971-05-19

CA925882A
(en)

1973-05-08

JPS5018040B1
(en)

1975-06-25

NL6806208A
(en)

1968-11-04

NL135284C
(en)

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Legal Events

Date
Code
Title
Description

1971-09-29
PS
Patent sealed

1978-12-06
PCNP
Patent ceased through non-payment of renewal fee

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