GB1331280A – Process for the manufacture of epoxy-modified polyurethene resins
– Google Patents
GB1331280A – Process for the manufacture of epoxy-modified polyurethene resins
– Google Patents
Process for the manufacture of epoxy-modified polyurethene resins
Info
Publication number
GB1331280A
GB1331280A
GB5743970A
GB5743970A
GB1331280A
GB 1331280 A
GB1331280 A
GB 1331280A
GB 5743970 A
GB5743970 A
GB 5743970A
GB 5743970 A
GB5743970 A
GB 5743970A
GB 1331280 A
GB1331280 A
GB 1331280A
Authority
GB
United Kingdom
Prior art keywords
weight
epoxide
unsaturated
product
water
Prior art date
1969-12-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5743970A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reichhold Albert Chemie AG
Original Assignee
Reichhold Albert Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1969-12-08
Filing date
1970-12-03
Publication date
1973-09-26
1970-12-03
Application filed by Reichhold Albert Chemie AG
filed
Critical
Reichhold Albert Chemie AG
1973-09-26
Publication of GB1331280A
publication
Critical
patent/GB1331280A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
C09D5/4465—Polyurethanes
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/08—Processes
C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G18/2805—Compounds having only one group containing active hydrogen
C08G18/2815—Monohydroxy compounds
C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
C08G18/2825—Alkanols, cycloalkanols or arylalkanols including terpenealcohols having at least 6 carbon atoms
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G18/40—High-molecular-weight compounds
C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
C08G18/4252—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G18/40—High-molecular-weight compounds
C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
C08G18/4255—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing oxyalkylated carbocyclic groups and polycarboxylic acids
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G18/40—High-molecular-weight compounds
C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G18/40—High-molecular-weight compounds
C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G18/4294—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from polyester forming components containing polyepoxy compounds
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G18/40—High-molecular-weight compounds
C08G18/48—Polyethers
C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G18/40—High-molecular-weight compounds
C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G18/67—Unsaturated compounds having active hydrogen
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G18/00—Polymeric products of isocyanates or isothiocyanates
C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G18/67—Unsaturated compounds having active hydrogen
C08G18/671—Unsaturated compounds having only one group containing active hydrogen
C08G18/6715—Unsaturated monofunctional alcohols or amines
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
C—CHEMISTRY; METALLURGY
C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
C09D5/4423—Polyesters, esterified polyepoxides
C09D5/4426—Esterified polyepoxides
Abstract
1331280 Epoxide-modified polyurethanes REICHBOLD-ALBERT-CHEMIE AG 3 Dec 1970 [8 Dec 1969] 57439/70 Headings C3B, C3P and C3R Epoxide-modified polyurethanes or polyurethane copolymer resins which can be dissolved or dispersed in water are prepared by reacting I (a) 25 to 70% by weight of unsaturated fatty acids, of which 0 to 25% by weight can be present as drying oils, the unsaturated acids and/or the drying oils, containing up to 6% by weight of maleic anhydride as an adduct, the mixture possessing an iodine number of 130 to 390, (b) 0 to 30% by weight of an aliphatic, cycloaliphatic or aromatic carboxylic acid or hydroxycarboxylic acid or an anhydride thereof, (c) 3 to 35% by weight of monohydric and/or polyhydric organic hydroxy compounds. (d) 0 to 17% by weight of polyoxyalkylene compounds which contain at least one active hydrogen atom and have an average M.W. of the polyoxylalkylene chain of 200 to 50,000, (e) 1 to 50% by weight of a compound which contains at least one epoxide group, (f) 0 to 60% by weight of a copolymerizable ethylenically unsaturated compound, conjointly or stepwise by heating until the reaction product has an acid number of 0 to 300, reacting the resultant ester and/or ester ether with (g) 0 to 65% by weight of an unsaturated monoalcohol and/or polyalcohol and (h) 0À05 to 50% by weight of an isocyanate, the reaction of component (I) with (g) and (h) taking place conjointly or with (g) and (h) having been prereacted to form an intermediate product and the reaction taking place so that the OH/NCO group equivalent ratio is 1À01 to 1À45/1 and optionally where the polyurethane contains carboxyl groups converting it, by the addition of alkali and/or organic strong bases, into the state where it can be dispersed or dissolved in water. The polyurethanes may be used as binders in aqueous solutions or dispersions along with, if desired, addition copolymer dispersions or low M.W. heat-curable aldehyde condensation products. In a typical example, a mixture of linseed oil fatty acid, trimethylolpropane and a bisphenol-A/propylene oxide adduct was esterified, thereafter an epoxide resin was reacted therewith, followed by further esterification with trimellitic anhydride. The resulting product was reacted with toluylene diisocyanate and adjusted to pH 7 with triethylamine. A dispersion of the product in water could be produced and used to produce elastic films.
GB5743970A
1969-12-08
1970-12-03
Process for the manufacture of epoxy-modified polyurethene resins
Expired
GB1331280A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
CH1822569A
CH537432A
(en)
1969-12-08
1969-12-08
Process for the production of water-thinnable or water-dispersible, expoxy-modified polyurethane resins
Publications (1)
Publication Number
Publication Date
GB1331280A
true
GB1331280A
(en)
1973-09-26
Family
ID=4431440
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB5743970A
Expired
GB1331280A
(en)
1969-12-08
1970-12-03
Process for the manufacture of epoxy-modified polyurethene resins
Country Status (12)
Country
Link
US
(1)
US3758427A
(en)
JP
(1)
JPS4914876B1
(en)
AT
(1)
AT314202B
(en)
BE
(1)
BE759939A
(en)
CA
(1)
CA960795A
(en)
CH
(3)
CH537434A
(en)
DE
(2)
DE2065637A1
(en)
ES
(1)
ES386085A1
(en)
FR
(1)
FR2073755A5
(en)
GB
(1)
GB1331280A
(en)
NL
(1)
NL7017587A
(en)
SE
(1)
SE377943B
(en)
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2247683A
(en)
*
1990-08-22
1992-03-11
Kansai Paint Co Ltd
Aqueous coating composition and coating method with use of the composition
Families Citing this family (9)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
BE791977A
(en)
*
1971-11-29
1973-05-28
Montedison Spa
WATER SOLUBLE RESINS
US3878148A
(en)
*
1972-09-28
1975-04-15
Delux Australia Ltd
Film-farming compositions comprising autoxidizable material
GB1484514A
(en)
*
1974-05-22
1977-09-01
Hoechst Ag
Heat-curable pulverulent coating composition of a mixture of copolymers containing glycidyl groups and an adduct of aliphatic dicarboxylic acid and 2,4,6-tris(n’,n”,n”‘-dimethylaminomethyl)-phenol
US4036800A
(en)
*
1975-06-04
1977-07-19
Desoto, Inc.
Electrodeposition of aqueous dispersions of amine functional urethane copolymers
US4222911A
(en)
*
1978-08-07
1980-09-16
Ppg Industries, Inc.
Polyester diol extended uralkyd resin and coating compositions containing the same
DE3366096D1
(en)
*
1982-09-09
1986-10-16
Akzo Nv
Process for coating an electrically conductive substrate and an aqueous composition containing a cationic binder
DE4004651A1
(en)
*
1990-02-15
1991-08-22
Hoechst Ag
AIR DRYING POLYURETHANE RESINS, THEIR PRODUCTION AND USE
US5912299A
(en)
*
1995-06-07
1999-06-15
The Sherwin-Williams Company
Coating compositions from oil modified polyurethane dispersions
US7462679B1
(en)
*
2002-11-27
2008-12-09
Han Xiong Xiao
Process for preparing functionalized oils; adhesives and coatings and interpenetrating polymer networks prepared from the functionalized oils
0
BE
BE759939D
patent/BE759939A/en
unknown
1969
1969-12-08
CH
CH146972A
patent/CH537434A/en
not_active
IP Right Cessation
1969-12-08
CH
CH146872A
patent/CH537433A/en
not_active
IP Right Cessation
1969-12-08
CH
CH1822569A
patent/CH537432A/en
not_active
IP Right Cessation
1970
1970-11-05
DE
DE2065637*A
patent/DE2065637A1/en
active
Pending
1970-11-05
DE
DE19702054467
patent/DE2054467A1/en
active
Pending
1970-11-17
AT
AT1036370A
patent/AT314202B/en
not_active
IP Right Cessation
1970-12-02
NL
NL7017587A
patent/NL7017587A/xx
unknown
1970-12-02
ES
ES386085A
patent/ES386085A1/en
not_active
Expired
1970-12-03
CA
CA099,737A
patent/CA960795A/en
not_active
Expired
1970-12-03
GB
GB5743970A
patent/GB1331280A/en
not_active
Expired
1970-12-07
JP
JP45107673A
patent/JPS4914876B1/ja
active
Pending
1970-12-07
US
US00095921A
patent/US3758427A/en
not_active
Expired – Lifetime
1970-12-07
SE
SE7016499A
patent/SE377943B/xx
unknown
1970-12-08
FR
FR7045077A
patent/FR2073755A5/fr
not_active
Expired
Cited By (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2247683A
(en)
*
1990-08-22
1992-03-11
Kansai Paint Co Ltd
Aqueous coating composition and coating method with use of the composition
GB2247683B
(en)
*
1990-08-22
1994-02-02
Kansai Paint Co Ltd
Novel aqueous coating composition and coating method with use of the composition
Also Published As
Publication number
Publication date
DE2054467A1
(en)
1971-06-16
CH537432A
(en)
1973-05-31
JPS4914876B1
(en)
1974-04-10
BE759939A
(en)
1971-05-17
FR2073755A5
(en)
1971-10-01
CH537434A
(en)
1973-05-31
AT314202B
(en)
1974-03-25
DE2065637A1
(en)
1974-10-03
ES386085A1
(en)
1973-03-16
NL7017587A
(en)
1971-06-10
CA960795A
(en)
1975-01-07
SE377943B
(en)
1975-08-04
US3758427A
(en)
1973-09-11
CH537433A
(en)
1973-05-31
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Legal Events
Date
Code
Title
Description
1974-02-06
PS
Patent sealed [section 19, patents act 1949]
1977-07-06
PLNP
Patent lapsed through nonpayment of renewal fees
