GB1346856A – Regeneration of dehydrogenation catalysts
– Google Patents
GB1346856A – Regeneration of dehydrogenation catalysts
– Google Patents
Regeneration of dehydrogenation catalysts
Info
Publication number
GB1346856A
GB1346856A
GB1795871A
GB1795871A
GB1346856A
GB 1346856 A
GB1346856 A
GB 1346856A
GB 1795871 A
GB1795871 A
GB 1795871A
GB 1795871 A
GB1795871 A
GB 1795871A
GB 1346856 A
GB1346856 A
GB 1346856A
Authority
GB
United Kingdom
Prior art keywords
tin
catalyst
deactivated
platinum
catalysts
Prior art date
1970-06-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1795871A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1970-06-03
Filing date
1971-05-28
Publication date
1974-02-13
1971-05-28
Application filed by Phillips Petroleum Co
filed
Critical
Phillips Petroleum Co
1974-02-13
Publication of GB1346856A
publication
Critical
patent/GB1346856A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36 with germanium, tin or lead
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/56—Platinum group metals
B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
B01J23/90—Regeneration or reactivation
B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
B01J23/90—Regeneration or reactivation
B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
C07C5/321—Catalytic processes
C07C5/324—Catalytic processes with metals
C07C5/325—Catalytic processes with metals of the platinum group
C—CHEMISTRY; METALLURGY
C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
C10G35/00—Reforming naphtha
C10G35/04—Catalytic reforming
C10G35/06—Catalytic reforming characterised by the catalyst used
C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/00—Technologies relating to chemical industry
Y02P20/50—Improvements relating to the production of bulk chemicals
Y02P20/584—Recycling of catalysts
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S585/00—Chemistry of hydrocarbon compounds
Y10S585/8995—Catalyst and recycle considerations
Y10S585/901—Catalyst and recycle considerations with recycle, rehabilitation, or preservation of solvent, diluent, or mass action agent
Abstract
1346856 Dehydrogenation catalysts PHILLIPS PETROLEUM CO 28 May 1971 [3 June 1970] 17958/71 Heading B1E [Also in Division C5] The activity of deactivated dehydrogenation catalyst comprising Group VIII metal selected for example from nickel, ruthenium, rhodium, palladium, osmium, iridium and platinum and, optionally, activator material, for example selected from compounds of alkali metals, alkaline earth metals, germanium, tin and lead, and/or support material, for example selected from alumina (including HF-treated alumina and flame-hydrolyzed alumina), magnesia, silica, zirconia, aluminosilicates and Group II metal aluminate spinels, is restored by a process wherein the deactivated catalyst is impregnated, optionally after oxidative burnoff to remove carbonaceous deposit, with tin or a compound thereof in an amount sufficient to provide that the reactivated catalyst contains, additional to any tin present in the deactivated catalyst, from 0.01 to 2 weight per cent of tin. The impregnated catalyst may be dried, for example at a temperature of from 100 to 400‹F, and calcined, for example at a temperature of from 800 to 1200‹F. Impregnation may be effected either by vaporization of tin or a compound thereof in the presence of the catalyst or by the use of solution; the specification discloses many suitable solvents for use in preparing such solution, water being preferred, and many suitable tin compounds which must be convertible to tin or tin oxide, must be silicon-free and preferably contain no metal other than tin and alkali metal. As exemplified, deactivated catalysts comprising platinum and tin supported on zinc aluminate spinel are immersed in aqueous stannous chloride solution and subsequently dried and, optionally, calcined at 1050‹F in air; details relating to the initial preparation of such catalysts are given in the specification. Reference also is made to impregnating with platinum a deactivated catalyst comprising platinum and tin supported on zinc aluminate spinel.
GB1795871A
1970-06-03
1971-05-28
Regeneration of dehydrogenation catalysts
Expired
GB1346856A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US4320270A
1970-06-03
1970-06-03
Publications (1)
Publication Number
Publication Date
GB1346856A
true
GB1346856A
(en)
1974-02-13
Family
ID=21926008
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB1795871A
Expired
GB1346856A
(en)
1970-06-03
1971-05-28
Regeneration of dehydrogenation catalysts
Country Status (6)
Country
Link
US
(1)
US3674706A
(en)
BE
(1)
BE768047A
(en)
CA
(1)
CA977327A
(en)
DE
(1)
DE2127353C3
(en)
FR
(1)
FR2095869A5
(en)
GB
(1)
GB1346856A
(en)
Cited By (5)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
WO2010069548A1
(en)
2008-12-18
2010-06-24
Uhde Gmbh
Variation of the tin impregnation of a catalyst for the dehydrogenation of alkanes
DE102008062782A1
(en)
2008-12-18
2010-07-01
Uhde Gmbh
Catalyst, useful to dehydrogenate alkane or alkyl substituent of hydrocarbon, comprises molding body containing oxide of group II-IV elements as base material, and platinum compound and compound of element of group IV as surface component
DE102009056539A1
(en)
2009-12-03
2011-06-09
Uhde Gmbh
Catalyst, useful to dehydrogenate alkane or alkyl substituent of hydrocarbon, comprises molding body containing oxide of group II-IV elements as base material, and platinum compound and compound of element of group IV as surface component
WO2015022548A1
(en)
*
2013-08-15
2015-02-19
University College Cardiff Consultants Ltd
Catalyst for direct synthesis of hydrogen peroxide
CN114425364A
(en)
*
2020-10-15
2022-05-03
中国石油化工股份有限公司
Catalyst for preparing butadiene by oxidative dehydrogenation of butene, preparation method and application thereof
Families Citing this family (19)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3883418A
(en)
*
1973-01-02
1975-05-13
Phillips Petroleum Co
Lead free motor fuel production
US3894110A
(en)
*
1973-11-15
1975-07-08
Phillips Petroleum Co
Catalytic dehydrogenation process
US4169815A
(en)
*
1973-11-15
1979-10-02
Phillips Petroleum Company
Catalyst for dehydrogenation process
US4268188A
(en)
*
1979-08-06
1981-05-19
Phillips Petroleum Company
Process for reducing possibility of leaching of heavy metals from used petroleum cracking catalyst in land fills
US4348273A
(en)
*
1980-06-25
1982-09-07
Phillips Petroleum Company
Treating cracking catalyst fines containing a passivating material
NL8202647A
(en)
*
1982-07-01
1984-02-01
Shell Int Research
METHOD FOR PREPARING A CATALYST
US4568784A
(en)
*
1985-02-19
1986-02-04
Phillips Petroleum Company
Preparation of polymethylbenzenes
US4692430A
(en)
*
1985-06-17
1987-09-08
Phillips Petroleum Company
Zinc aluminate double bond isomerization catalyst and process for its production
US4620053A
(en)
*
1985-06-17
1986-10-28
Phillips Petroleum Company
Zinc aluminate double bond isomerization catalyst and double bond isomerization of olefins employing said catalyst
US5344805A
(en)
*
1993-05-03
1994-09-06
Phillips Petroleum Company
Platinum and tin-containing catalyst and use thereof in alkane dehydrogenation
US5710091A
(en)
1995-06-07
1998-01-20
Phillips Petroleum Company
Sorbent compositions
US5898011A
(en)
*
1997-08-28
1999-04-27
Phillips Petroleum Company
Hydrocarbon conversion catalyst composition and processes therefor and therewith
US6218328B1
(en)
1998-12-29
2001-04-17
Phillips Petroleum Company
Method of preparing a zeolite based catalyst material
US6740615B2
(en)
*
2000-12-22
2004-05-25
Hydrocarbon Technologies, Inc.
Regeneration of used supported noble metal catalysts
US6908873B2
(en)
*
2000-12-22
2005-06-21
Headwaters Nanokinetix, Inc.
Regeneration of spent supported metal catalysts
US7655137B2
(en)
*
2003-07-14
2010-02-02
Headwaters Technology Innovation, Llc
Reforming catalysts having a controlled coordination structure and methods for preparing such compositions
US7569508B2
(en)
*
2004-11-17
2009-08-04
Headwaters Technology Innovation, Llc
Reforming nanocatalysts and method of making and using such catalysts
US7632775B2
(en)
*
2004-11-17
2009-12-15
Headwaters Technology Innovation, Llc
Multicomponent nanoparticles formed using a dispersing agent
US7541309B2
(en)
*
2006-05-16
2009-06-02
Headwaters Technology Innovation, Llc
Reforming nanocatalysts and methods of making and using such catalysts
1970
1970-06-03
US
US43202A
patent/US3674706A/en
not_active
Expired – Lifetime
1971
1971-02-16
CA
CA105,488A
patent/CA977327A/en
not_active
Expired
1971-05-28
GB
GB1795871A
patent/GB1346856A/en
not_active
Expired
1971-06-02
DE
DE2127353A
patent/DE2127353C3/en
not_active
Expired
1971-06-03
FR
FR7120141A
patent/FR2095869A5/fr
not_active
Expired
1971-06-03
BE
BE768047A
patent/BE768047A/en
unknown
Cited By (6)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
WO2010069548A1
(en)
2008-12-18
2010-06-24
Uhde Gmbh
Variation of the tin impregnation of a catalyst for the dehydrogenation of alkanes
DE102008062782A1
(en)
2008-12-18
2010-07-01
Uhde Gmbh
Catalyst, useful to dehydrogenate alkane or alkyl substituent of hydrocarbon, comprises molding body containing oxide of group II-IV elements as base material, and platinum compound and compound of element of group IV as surface component
DE102009056539A1
(en)
2009-12-03
2011-06-09
Uhde Gmbh
Catalyst, useful to dehydrogenate alkane or alkyl substituent of hydrocarbon, comprises molding body containing oxide of group II-IV elements as base material, and platinum compound and compound of element of group IV as surface component
WO2015022548A1
(en)
*
2013-08-15
2015-02-19
University College Cardiff Consultants Ltd
Catalyst for direct synthesis of hydrogen peroxide
CN105579131A
(en)
*
2013-08-15
2016-05-11
卡迪夫大学顾问有限公司
Catalyst for direct synthesis of hydrogen peroxide
CN114425364A
(en)
*
2020-10-15
2022-05-03
中国石油化工股份有限公司
Catalyst for preparing butadiene by oxidative dehydrogenation of butene, preparation method and application thereof
Also Published As
Publication number
Publication date
BE768047A
(en)
1971-12-03
CA977327A
(en)
1975-11-04
DE2127353C3
(en)
1975-03-20
DE2127353A1
(en)
1971-12-09
FR2095869A5
(en)
1972-02-11
US3674706A
(en)
1972-07-04
DE2127353B2
(en)
1974-07-11
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Legal Events
Date
Code
Title
Description
1974-07-03
PS
Patent sealed [section 19, patents act 1949]
1976-12-22
PLNP
Patent lapsed through nonpayment of renewal fees
