GB1365589A – Epoxidation of unsaturated compounds
– Google Patents
GB1365589A – Epoxidation of unsaturated compounds
– Google Patents
Epoxidation of unsaturated compounds
Info
Publication number
GB1365589A
GB1365589A
GB743172A
GB743172A
GB1365589A
GB 1365589 A
GB1365589 A
GB 1365589A
GB 743172 A
GB743172 A
GB 743172A
GB 743172 A
GB743172 A
GB 743172A
GB 1365589 A
GB1365589 A
GB 1365589A
Authority
GB
United Kingdom
Prior art keywords
epoxidized
feb
catalyst
alkyl radical
hydroperoxide
Prior art date
1971-02-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB743172A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe Nationale des Petroles dAquitaine SA
Original Assignee
Societe Nationale des Petroles dAquitaine SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1971-02-18
Filing date
1972-02-17
Publication date
1974-09-04
1971-04-02
Priority claimed from IT2269071A
external-priority
patent/IT984547B/en
1972-02-17
Application filed by Societe Nationale des Petroles dAquitaine SA
filed
Critical
Societe Nationale des Petroles dAquitaine SA
1974-09-04
Publication of GB1365589A
publication
Critical
patent/GB1365589A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07D—HETEROCYCLIC COMPOUNDS
C07D301/00—Preparation of oxiranes
C07D301/02—Synthesis of the oxirane ring
C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07D—HETEROCYCLIC COMPOUNDS
C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
C07D303/02—Compounds containing oxirane rings
C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
B01J2231/72—Epoxidation
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
B01J2531/64—Molybdenum
Abstract
1365589 Epoxidation of unsaturated compounds SOC NATIONALE DES PETROLES D’AQUITAINE 17 Feb 1972 [18 Feb 1971 2 April 1971] 7431/72 Heading C2C Olefinically unsaturated hydrocarbons are epoxidized in the liquid phase with a hydroperoxide and a catalyst comprising an organometallic chelate complex of a Group V or VI metal oxide and a nitrogenous bidendatechelate forming ligand. Cyclohexene and propylene are epoxidized in examples using catalysts from molybdenum, vanadium and tungsten oxides. The chelate forming ligand may be 8- hydroxy quinoline, substituted mono- or dicarboxylic pyridine acids, compounds of formula where R 1 is an alkyl radical or aromatic nucleus, R 2 is hydrogen, alkyl radical or aromatic nucleus, e.g. benzohydroxamic or salicylhydroxamic acids, substituted or unsubstituted hexahydrobenzo-hydroxamic acid, N-benzoyl N- phenyl hydroxylamine and N-furfuryl N-phenyl hydroxylamine. The reaction mixture may include solvents and the catalyst may be activated by reacting separately with a solution of hydroperoxide before being added to the olefine.
GB743172A
1971-02-18
1972-02-17
Epoxidation of unsaturated compounds
Expired
GB1365589A
(en)
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
IT2073571
1971-02-18
IT2269071A
IT984547B
(en)
1971-04-02
1971-04-02
IMPROVEMENT TO SELECTIVE CATALYTIC SYSTEMS FOR OLEFIN EPOXY PROCESSES WITH HYDROPEROXIDES AND RELATED PERFECTED CATALYTIC SYSTEMS
Publications (1)
Publication Number
Publication Date
GB1365589A
true
GB1365589A
(en)
1974-09-04
Family
ID=26327639
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB743172A
Expired
GB1365589A
(en)
1971-02-18
1972-02-17
Epoxidation of unsaturated compounds
Country Status (7)
Country
Link
BE
(1)
BE779477A
(en)
DE
(1)
DE2207506A1
(en)
FR
(1)
FR2125327B1
(en)
GB
(1)
GB1365589A
(en)
LU
(1)
LU64789A1
(en)
NL
(1)
NL7202143A
(en)
SU
(1)
SU475767A3
(en)
Cited By (4)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
EP0138624A2
(en)
*
1983-10-18
1985-04-24
BP Chemicals Limited
Organo metallic complexes and the use thereof in epoxidation of olefins
US5017712A
(en)
*
1984-03-09
1991-05-21
Arco Chemical Technology, Inc.
Production of hydrocarbon-soluble salts of molybdenum for epoxidation of olefins
PT107601A
(en)
*
2014-04-14
2015-10-14
Cofac Cooperativa De Formação E Animação Cultural Crl
OXO-VANADIUM COMPLEXES (IV-V) WITH LIGANDS DERIVED FROM SALICYLALDEHYDE-2-HYDROXYBENZOYL-HYDROZONE AND 8-HYDROXYQUINOLIN OR 1,10-PHENANTROLIN AND ITS APPLICATION AS CATALYSTS FOR PEROXIDATIVE OXIDATION, MICROWAVE ASSISTED AND WITHOUT ADDITION SOLVENT, FROM SECONDARY ALCOHOLS TO CETONAS
CN111704633A
(en)
*
2020-07-08
2020-09-25
万华化学集团股份有限公司
Mo catalyst and application thereof in preparation of 9, 10-epoxy-1, 5-cyclododecadiene
Families Citing this family (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB8307976D0
(en)
*
1983-03-23
1983-04-27
Bp Chem Int Ltd
Epoxidation of olefins
1972
1972-02-08
FR
FR7204106A
patent/FR2125327B1/fr
not_active
Expired
1972-02-16
LU
LU64789D
patent/LU64789A1/xx
unknown
1972-02-17
BE
BE779477A
patent/BE779477A/en
unknown
1972-02-17
GB
GB743172A
patent/GB1365589A/en
not_active
Expired
1972-02-17
DE
DE19722207506
patent/DE2207506A1/en
active
Pending
1972-02-17
SU
SU1747094A
patent/SU475767A3/en
active
1972-02-18
NL
NL7202143A
patent/NL7202143A/xx
unknown
Cited By (5)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
EP0138624A2
(en)
*
1983-10-18
1985-04-24
BP Chemicals Limited
Organo metallic complexes and the use thereof in epoxidation of olefins
EP0138624A3
(en)
*
1983-10-18
1985-06-26
Bp Chemicals Limited
Organo metallic complexes and the use thereof in epoxidation of olefins
US5017712A
(en)
*
1984-03-09
1991-05-21
Arco Chemical Technology, Inc.
Production of hydrocarbon-soluble salts of molybdenum for epoxidation of olefins
PT107601A
(en)
*
2014-04-14
2015-10-14
Cofac Cooperativa De Formação E Animação Cultural Crl
OXO-VANADIUM COMPLEXES (IV-V) WITH LIGANDS DERIVED FROM SALICYLALDEHYDE-2-HYDROXYBENZOYL-HYDROZONE AND 8-HYDROXYQUINOLIN OR 1,10-PHENANTROLIN AND ITS APPLICATION AS CATALYSTS FOR PEROXIDATIVE OXIDATION, MICROWAVE ASSISTED AND WITHOUT ADDITION SOLVENT, FROM SECONDARY ALCOHOLS TO CETONAS
CN111704633A
(en)
*
2020-07-08
2020-09-25
万华化学集团股份有限公司
Mo catalyst and application thereof in preparation of 9, 10-epoxy-1, 5-cyclododecadiene
Also Published As
Publication number
Publication date
SU475767A3
(en)
1975-06-30
FR2125327A1
(en)
1972-09-29
BE779477A
(en)
1972-06-16
NL7202143A
(en)
1972-08-22
DE2207506A1
(en)
1972-09-07
LU64789A1
(en)
1972-07-04
FR2125327B1
(en)
1974-06-28
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Legal Events
Date
Code
Title
Description
1975-01-15
PS
Patent sealed
1977-09-14
PLNP
Patent lapsed through nonpayment of renewal fees
