GB1442290A

GB1442290A – Process for the hydroxylation of phenols and phenol ethers in the nucleus
– Google Patents

GB1442290A – Process for the hydroxylation of phenols and phenol ethers in the nucleus
– Google Patents
Process for the hydroxylation of phenols and phenol ethers in the nucleus

Info

Publication number
GB1442290A

GB1442290A
GB934575A
GB934575A
GB1442290A
GB 1442290 A
GB1442290 A
GB 1442290A
GB 934575 A
GB934575 A
GB 934575A
GB 934575 A
GB934575 A
GB 934575A
GB 1442290 A
GB1442290 A
GB 1442290A
Authority
GB
United Kingdom
Prior art keywords
phenol
hydroxylation
nucleus
phenols
carried out
Prior art date
1974-03-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB934575A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer AG

Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1974-03-06
Filing date
1975-03-06
Publication date
1976-07-14

1975-03-06
Application filed by Bayer AG
filed
Critical
Bayer AG

1976-07-14
Publication of GB1442290A
publication
Critical
patent/GB1442290A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring

C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups

C07C41/01—Preparation of ethers

C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds

C07C41/26—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of hydroxy or O-metal groups

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE

Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

Y02P20/00—Technologies relating to chemical industry

Y02P20/50—Improvements relating to the production of bulk chemicals

Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

1442290 Hydroxylation of phenols and phenol ethers BAYER AG 6 March 1975 [6 March 1974] 9345/75 Heading C2C The invention comprises a process for the hydroxylation in the nucleus of a phenol (excluding unsubstituted phenol itself) or a phenol ether wherein a phenol (excluding unsubstituted phenol itself) or a phenol ether is reacted initially with substantially anhydrous hydrogen peroxide, wherein the reaction is carried out in the presence of an acid having a pKa value of #4À76 at 25‹ C. and wherein the resulting phenol or phenol ether hydroxylated in the nucleus is recovered. The acid is preferably one which is inert under the reaction conditions. The hydrogen peroxide may be dissolved in an anhydrous solvent. The reaction is preferably carried out at from 20‹ to 150‹ C. and may be carried out in the presence of a stabilizer.

GB934575A
1974-03-06
1975-03-06
Process for the hydroxylation of phenols and phenol ethers in the nucleus

Expired

GB1442290A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

DE2410758A

DE2410758C3
(en)

1974-03-06
1974-03-06

Process for the production of polyhydric substituted phenols or monoethers of polyhydric phenols by nuclear hydroxylation of phenols or phenol ethers

Publications (1)

Publication Number
Publication Date

GB1442290A
true

GB1442290A
(en)

1976-07-14

Family
ID=5909276
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB934575A
Expired

GB1442290A
(en)

1974-03-06
1975-03-06
Process for the hydroxylation of phenols and phenol ethers in the nucleus

Country Status (8)

Country
Link

US
(1)

US4045496A
(en)

JP
(1)

JPS5753330B2
(en)

BE
(1)

BE826244A
(en)

DE
(1)

DE2410758C3
(en)

FR
(1)

FR2263217B1
(en)

GB
(1)

GB1442290A
(en)

IT
(1)

IT1029935B
(en)

LU
(1)

LU71960A1
(en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US4174460A
(en)

*

1974-03-06
1979-11-13
Bayer Aktiengesellschaft
Process for the hydroxylation of phenols and phenol ethers in the nucleus

FR2318851A1
(en)

*

1975-07-25
1977-02-18
Rhone Poulenc Ind

PROCESS FOR HYDROXYLATION OF AROMATIC COMPOUNDS

FR2392939A1
(en)

*

1977-06-01
1978-12-29
Midi Salines Est Cie Salins
Sterilising ion exchange resins using bactericidal salt soln. – prepd. from salt pastilles contg. isolated bactericide inside

US4258219A
(en)

*

1978-10-27
1981-03-24
Mitsui Toatsu Chemicals, Inc.
Process for producing hydroquinone

US4419528A
(en)

*

1979-10-05
1983-12-06
Pcuk – Produits Chimiques Ugine Kuhlmann
Regioselective preparation of α- or β-naphthol

DE2942366A1
(en)

*

1979-10-19
1981-04-30
Bayer Ag, 5090 Leverkusen

METHOD FOR PRODUCING MULTIPLE PHENOLES

FR2483403A1
(en)

*

1980-06-03
1981-12-04
Ugine Kuhlmann

PROCESS FOR THE META-HYDROXYLATION OF ALKYL-PHENOLS AND THEIR ETHERS IN A SUPERACID MEDIUM

DE3308769C2
(en)

*

1983-03-11
1985-01-24
Degussa Ag, 6000 Frankfurt

Process for the preparation of dihydroxybenzenes

DE3308726C2
(en)

*

1983-03-11
1991-01-24
Degussa Ag, 6000 Frankfurt

Process for the preparation of dihydroxybenzenes

DE3308763C2
(en)

*

1983-03-11
1985-01-24
Degussa Ag, 6000 Frankfurt

Process for the preparation of dihydroxybenzenes

DE3334854A1
(en)

*

1983-09-27
1985-04-11
Degussa Ag, 6000 Frankfurt

METHOD FOR PRODUCING NON-AQUEOUS HYDROGEN PEROXIDE SOLUTIONS AND USE THEREOF

US4814521A
(en)

*

1985-06-07
1989-03-21
Kureha Kagaku Kogyo Kabushiki Kaisha
Process for producing 2,6-dihydroxynaphthalene and 2,6-diacetoxynaphthalene

DE3607923A1
(en)

*

1986-03-11
1987-09-17
Degussa

METHOD FOR PRODUCING SUBSTITUTED TRIHYDROXYBENZOLES

DE3643206C1
(en)

*

1986-12-18
1988-03-24
Degussa

Process for the preparation of substituted dihydroxybenzenes

FR2649695A1
(en)

*

1989-07-11
1991-01-18
Rhone Poulenc Chimie

PROCESS FOR HYDROXYLATION OF PHENOLS AND PHENOL ETHERS

FR2655332A1
(en)

*

1989-12-05
1991-06-07
Rhone Poulenc Chimie

PROCESS FOR HYDROXYLATION OF PHENOLS AND ETHERS OF PHENOLS

Family Cites Families (3)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

NL130076C
(en)

*

1965-06-30

FR2071464A5
(en)

*

1969-12-30
1971-09-17
Rhone Poulenc Sa

DE2150657C3
(en)

*

1971-07-17
1978-10-26
Brichima S.P.A., Mailand (Italien)

Process for the preparation of a mixture of catechol and hydroquinone

1974

1974-03-06
DE
DE2410758A
patent/DE2410758C3/en
not_active
Expired

1975

1975-02-28
US
US05/553,939
patent/US4045496A/en
not_active
Expired – Lifetime

1975-03-04
LU
LU71960A
patent/LU71960A1/xx
unknown

1975-03-04
BE
BE153959A
patent/BE826244A/en
not_active
IP Right Cessation

1975-03-04
IT
IT48438/75A
patent/IT1029935B/en
active

1975-03-04
JP
JP50025712A
patent/JPS5753330B2/ja
not_active
Expired

1975-03-06
GB
GB934575A
patent/GB1442290A/en
not_active
Expired

1975-03-06
FR
FR757507047A
patent/FR2263217B1/fr
not_active
Expired

Also Published As

Publication number
Publication date

BE826244A
(en)

1975-09-04

US4045496A
(en)

1977-08-30

DE2410758B2
(en)

1980-04-30

IT1029935B
(en)

1979-03-20

DE2410758C3
(en)

1981-01-08

FR2263217A1
(en)

1975-10-03

JPS5753330B2
(en)

1982-11-12

FR2263217B1
(en)

1979-02-09

LU71960A1
(en)

1976-02-04

DE2410758A1
(en)

1975-09-18

JPS50121236A
(en)

1975-09-23

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(en)

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(en)

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Process for recovery of naphthalene from crude naphthalene

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(en)

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(en)

1988-01-21

Process for oxidizing 2,6-diisopropylnaphthalene.

Legal Events

Date
Code
Title
Description

1976-11-24
PS
Patent sealed [section 19, patents act 1949]

1987-10-21
PCNP
Patent ceased through non-payment of renewal fee

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