GB1457528A

GB1457528A – Extracrion of heavy metals from industrial waste waters
– Google Patents

GB1457528A – Extracrion of heavy metals from industrial waste waters
– Google Patents
Extracrion of heavy metals from industrial waste waters

Info

Publication number
GB1457528A

GB1457528A
GB5862073A
GB5862073A
GB1457528A
GB 1457528 A
GB1457528 A
GB 1457528A
GB 5862073 A
GB5862073 A
GB 5862073A
GB 5862073 A
GB5862073 A
GB 5862073A
GB 1457528 A
GB1457528 A
GB 1457528A
Authority
GB
United Kingdom
Prior art keywords
heavy metals
waste water
dec
suspension
ferrous ions
Prior art date
1972-12-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB5862073A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

NEC Corp

Original Assignee
Nippon Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1972-12-19
Filing date
1973-12-18
Publication date
1976-12-01

1972-12-19
Priority claimed from JP12781672A
external-priority
patent/JPS5122307B2/ja

1972-12-20
Priority claimed from JP12866672A
external-priority
patent/JPS5139940B2/ja

1973-04-10
Priority claimed from JP4117273A
external-priority
patent/JPS5336712B2/ja

1973-12-18
Application filed by Nippon Electric Co Ltd
filed
Critical
Nippon Electric Co Ltd

1976-12-01
Publication of GB1457528A
publication
Critical
patent/GB1457528A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F1/00—Treatment of water, waste water, or sewage

C02F1/72—Treatment of water, waste water, or sewage by oxidation

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01D—SEPARATION

B01D21/00—Separation of suspended solid particles from liquids by sedimentation

B01D21/0009—Settling tanks making use of electricity or magnetism

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof

B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material

B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04

B—PERFORMING OPERATIONS; TRANSPORTING

B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS

B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS

B03C1/00—Magnetic separation

B03C1/005—Pretreatment specially adapted for magnetic separation

B03C1/015—Pretreatment specially adapted for magnetic separation by chemical treatment imparting magnetic properties to the material to be separated, e.g. roasting, reduction, oxidation

C—CHEMISTRY; METALLURGY

C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F1/00—Treatment of water, waste water, or sewage

C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities

C—CHEMISTRY; METALLURGY

C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F1/00—Treatment of water, waste water, or sewage

C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities

C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents

C—CHEMISTRY; METALLURGY

C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F1/00—Treatment of water, waste water, or sewage

C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields

C02F1/488—Treatment of water, waste water, or sewage with magnetic or electric fields for separation of magnetic materials, e.g. magnetic flocculation

C—CHEMISTRY; METALLURGY

C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

C02F2101/00—Nature of the contaminant

C02F2101/10—Inorganic compounds

C02F2101/20—Heavy metals or heavy metal compounds

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S210/00—Liquid purification or separation

Y10S210/902—Materials removed

Y10S210/911—Cumulative poison

Y10S210/912—Heavy metal

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S210/00—Liquid purification or separation

Y10S210/902—Materials removed

Y10S210/911—Cumulative poison

Y10S210/912—Heavy metal

Y10S210/913—Chromium

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S210/00—Liquid purification or separation

Y10S210/902—Materials removed

Y10S210/911—Cumulative poison

Y10S210/912—Heavy metal

Y10S210/914—Mercury

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S423/00—Chemistry of inorganic compounds

Y10S423/01—Waste acid containing iron

Abstract

1457528 Removing heavy metals from waste water NIPPON ELECTRIC CO Ltd 18 Dec 1973 [19 Dec 1972 20 Dec 1972 10 April 1973] 58620/73 Headings C1A and C1C A method of extracting heavy metals from waste water containing ferrous ions in an amount of at least twice the molar amount of all heavy metals other than iron, comprises the steps of adding alkali to the waste water in an amount of 0À9-1À2 equivalents of acid radical contained in the waste water to form a suspension of hydroxides of ferrous ions and/or the other heavy metals, bubbling an oxidizing gas into the suspension to stir up and at the same time to oxidize the suspension, whereby crystals containing ferric ions and further containing and/or adsorbing the heavy metal ions originally contained in the waste water are precipitated and separating the precipitated crystals to obtain clear water from which heavy metals have been extracted. An initial addition of ferrous ions may be made to waste water which contains no or insufficient ferrous ions. Alkaline waste water is treated without the step of alkali addition. The precipitated crystals may include ferromagnetic crystals which may be separated with a magnet. Heavy metals having a smaller ionization potential than iron may be removed by plating metallic iron added to the waste water. The heavy metals exemplified include Cr, Cd Pb Cu, Ni, Bi and Hg.

GB5862073A
1972-12-19
1973-12-18
Extracrion of heavy metals from industrial waste waters

Expired

GB1457528A
(en)

Applications Claiming Priority (3)

Application Number
Priority Date
Filing Date
Title

JP12781672A

JPS5122307B2
(en)

1972-12-19
1972-12-19

JP12866672A

JPS5139940B2
(en)

1972-12-20
1972-12-20

JP4117273A

JPS5336712B2
(en)

1973-04-10
1973-04-10

Publications (1)

Publication Number
Publication Date

GB1457528A
true

GB1457528A
(en)

1976-12-01

Family
ID=27290739
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB5862073A
Expired

GB1457528A
(en)

1972-12-19
1973-12-18
Extracrion of heavy metals from industrial waste waters

Country Status (5)

Country
Link

US
(1)

US3931007A
(en)

CA
(1)

CA1017083A
(en)

DE
(1)

DE2363291A1
(en)

FR
(1)

FR2210574B1
(en)

GB
(1)

GB1457528A
(en)

Cited By (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2206342A
(en)

*

1987-06-30
1989-01-05
Raymond Leonard Sukovieff
Process and apparatus for the purification of water

Families Citing this family (65)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

IT1008297B
(en)

*

1974-02-25
1976-11-10
Montedison Spa

PROCEDURE FOR OBTAINING MAGNETITE FROM FERROUS SULPHATE SOLUTIONS

US4169053A
(en)

*

1975-08-08
1979-09-25
Nippon Electric Co., Ltd.
Method of treating waste waters containing solid-phase difficultly-soluble compounds

IT1064085B
(en)

*

1976-07-02
1985-02-18
Anic Spa

METHOD FOR THE THICKENING OF MERCURY PARTICLES

DE2642198C3
(en)

*

1976-09-20
1980-01-17
Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt

Process for the separation of Cd + + ions from waste water and aqueous solutions

DE2642238C3
(en)

*

1976-09-20
1980-01-17
Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt

Process for the separation of Cu + + ions from wastewater and aqueous solutions

JPS5452862A
(en)

*

1977-08-25
1979-04-25
Blue Circle Ind Ltd
Method of removing heavy metal by silicate

US4211646A
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1977-10-31
1980-07-08
Texaco Inc.
Waste water process

US4137293A
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*

1977-12-16
1979-01-30
Ishihara Sangyo Kaisha, Ltd.
Producing gypsum and magnetite from ferrous sulfate and separating

NL7802123A
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*

1978-02-25
1979-08-28
Akzo Nv

PROCEDURE FOR REMOVING HEAVY METALS FROM Aqueous SUBSTANCES.

US4197117A
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1978-11-20
1980-04-08
Kennecott Copper Corporation
Recovery of copper by ferrous ion precipitation

FR2466282A1
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1979-10-02
1981-04-10
Commissariat Energie Atomique

METHOD FOR REMOVING HEAVY METALLIC ELEMENTS SUSPENDED IN A LIQUID USING A FINALLY DIVIDED FERROMAGNETIC ADJUVANT

US4330511A
(en)

*

1980-03-17
1982-05-18
Peter F. Loftus Corporation (Illinois)
Treatment of blast furnace off-gas

US4465597B2
(en)

*

1981-08-10
1997-07-01
Tetra Tech
Treatment of industrial wastewaters

DE3380033D1
(en)

*

1982-06-22
1989-07-13
Seitetsu Kagaku Co Ltd
Process for removal and recovery of mercury from waste water

US4525254A
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1982-10-07
1985-06-25
Gosudarstvenny Nauchno-Issledovatelsky I Proektny Institut Po Obogascheniju Rud Tsvetnykh Metallov “Kazmekhanobr”
Process and apparatus for purifying effluents and liquors

CA1223375A
(en)

*

1982-10-13
1987-06-23
Colin W.A. Muir
Treating cyanide-containing effluents

WO1984003692A1
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*

1983-03-21
1984-09-27
Union Oil Co
Method for removing heavy metals from aqueous solutions by coprecipitation

US5045214A
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1983-03-21
1991-09-03
Union Oil Company Of California
Methods for removing substances from aqueous solutions

DE3574165D1
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1984-01-12
1989-12-14
Pelt & Hooykaas
A method of processing waste materials, particularly a sludge containing noxious metals

JPS60206481A
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1984-03-30
1985-10-18
Kawasaki Steel Corp
Recovery treatment of waste stainless steel pickling solution

EP0160496B1
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1984-04-28
1989-09-13
Toda Kogyo Corp.
Magnetic iron oxide particles

DE3417629C1
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1984-05-12
1985-01-24
Th. Goldschmidt Ag, 4300 Essen

Process for the production of basic copper carbonate

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1984-06-13
1985-09-24
Bethlehem Steel Corp.
Removal of complexed zinc-cyanide from wastewater

US4606829A
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1984-06-13
1986-08-19
Bethlehem Steel Corporation
Removal of complexed zinc-cyanide from wastewater with improved sludge stability

US4668124A
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1985-04-22
1987-05-26
Engelhard Corporation
Disposal of material containing vanadium as landfill

US4652381A
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1985-07-22
1987-03-24
Farmland Industries, Inc.
Battery plant waste water treatment process

US4680126A
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*

1986-02-18
1987-07-14
Frankard James M
Separation and recovery of reusable heavy metal hydroxides from metal finishing wastewaters

US4724084A
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*

1986-03-28
1988-02-09
The Boeing Company
System for removing toxic organics and metals from manufacturing wastewater

WO1989009192A1
(en)

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1988-03-31
1989-10-05
Commonwealth Scientific And Industrial Research Or
Hydrometallurgical effluent treatment

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1988-08-19
1992-04-14
Solarchem Enterprises Inc.
Oxidation and photooxidation process

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1989-05-09
1992-02-24
Solvator Process Ab

PROCEDURE FOR PURIFICATION OF ORGANIC MATERIAL

US5106508A
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1990-09-26
1992-04-21
Klaus Schwitzgebel
Integrated process for cyanide and heavy metal removal from plating process waste streams

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1990-12-07
1992-02-11
Clean Harbors, Inc.
Method and apparatus to detoxify aqueous based hazardous waste

FR2688208B1
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1992-03-06
1994-08-26
Promaiga

DEVICE FOR DISCHARGING SLUDGE PRESENT IN A CIRCUIT, ESPECIALLY FOR HEATING.

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1992-09-28
1994-03-08
Klaus Schwitzgebel
Equipment and process for solid waste minimization in chromium and heavy metal removal from groundwater

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1993-02-12
1994-05-17
Clean Harbors, Inc.
Method and apparatus for extracting organic liquids from an organic liquid solute/solvent mixture

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1993-03-17
1994-07-19
Westinghouse Electric Corporation
Solution decontamination method using precipitation and flocculation techniques

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1993-05-25
1994-12-06
Stevenson; Sanford M.
Method for removing metal compounds from waste water

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1993-05-25
2008-02-26
Stevenson Sanford M
Method for removing metal compounds from waste water

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1993-05-25
2000-09-12
Stevenson; Sanford M.
Apparatus for removing metal compounds from waste material

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1994-01-13
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Buckman Laboratories International, Inc.
Process for the treatment of metal-containing water and recovery of metals therefrom

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1994-02-07
1995-12-05
Great Western Chemical Company
Method for recovering metals from solutions

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1995-03-03
1997-06-02
Kemira Kemi Ab

Process for the purification of metal-containing solutions containing iron and zinc salts

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1995-06-30
1997-11-11
Pitts-Mont Environmental Reclamation Corporation
Apparatus and method for ferrite formation and removal of heavy metal ions by ferrite co-precipitation from aqueous solutions

JP3739480B2
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1995-10-31
2006-01-25
栗田工業株式会社

Treatment method of flue gas desulfurization waste water

DE19545660C1
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1995-12-07
1997-04-10
Karlsruhe Forschzent
Removing heavy metals from waste water using ferri- or ferromagnetic particles

DE19641465A1
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1996-10-09
1998-04-16
Schloemann Siemag Ag

Method and device for cleaning and processing of coolants and / or lubricants used in the metallurgical industry

US6238571B1
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1998-09-15
2001-05-29
Massachusetts Institute Of Technology
Removal of contaminant metals from waste water

JP2001107258A
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*

1999-10-06
2001-04-17
Hitachi Ltd
Electroless copper plating method, plating device and multilayer wiring board

EP1328477B1
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2000-09-26
2011-03-30
LANXESS Deutschland GmbH
Contact and adsorber granulates

CN1216807C
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2000-09-26
2005-08-31
拜尔公司
Contacting and adsorbent granules

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Lanxess Deutschland Gmbh

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2000-09-26
2002-06-20
Andreas Schlegel
Adsorption vessels

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2001-02-02
2003-07-22
The Regents Of The University Of California
Magnetic process for removing heavy metals from water employing magnetites

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2001-06-20
2006-07-11
Sandia Corporation
Inorganic ion sorbents and methods for using the same

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2002-02-11
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Millennium Inorganic Chemicals, Inc.
Processes for treating iron-containing waste streams

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2003-07-30
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Min-Shing Tsai
Integrated technology in sequential treatment of organics and heavy metal ions wastewater

JP4412936B2
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2003-07-31
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パナソニック株式会社

Cobalt oxyhydroxide, method for producing the same, and alkaline storage battery using the same

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Method for removing trace of heavy metal and nonmetal impurities in waste acid cleaning liquor

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Gopher Resource, LLC
System and method for water treatment

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Pretreatment of produced water to facilitate improved metal extraction

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Detection method for heavy metal in waste soil

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*

1938-07-14
1941-02-18
Charles H Lewis
Process for treating liquids

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*

1965-08-30
1967-10-17
Rhodes John Cecil
Process of purifying or recovering mine drainage waters and the like

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(en)

1966-02-21
1969-02-05
Nippon Electric Co
Improvements in or relating to ferrite particles and process for manufacturing same

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M & T Chemicals Inc
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Neutralization of ferrous iron-containing acid wastes

1973

1973-12-17
US
US05/425,123
patent/US3931007A/en
not_active
Expired – Lifetime

1973-12-18
GB
GB5862073A
patent/GB1457528A/en
not_active
Expired

1973-12-18
CA
CA188,441A
patent/CA1017083A/en
not_active
Expired

1973-12-18
FR
FR7345305A
patent/FR2210574B1/fr
not_active
Expired

1973-12-19
DE
DE2363291A
patent/DE2363291A1/en
not_active
Ceased

Cited By (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2206342A
(en)

*

1987-06-30
1989-01-05
Raymond Leonard Sukovieff
Process and apparatus for the purification of water

GB2206342B
(en)

*

1987-06-30
1992-01-29
Raymond Leonard Sukovieff
Process and apparatus for the purification of water

Also Published As

Publication number
Publication date

US3931007A
(en)

1976-01-06

FR2210574A1
(en)

1974-07-12

FR2210574B1
(en)

1978-11-10

DE2363291A1
(en)

1974-06-27

CA1017083A
(en)

1977-09-06

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1976-11-26

Recovery of heavy metals from sludge after treatment of plating waste

JPS52105573A
(en)

1977-09-05

Treatment of acid washing waste liquid

JPS55128595A
(en)

1980-10-04

Removal of selenium eluted from decoppering liquid of anode slime of copper electrolysis

Mishra et al.

1996

Biosorption of heavy metal ions by penicillium sp. A case study

JPS5231921A
(en)

1977-03-10

Treating method of oxide ore containing iron

JPS5492594A
(en)

1979-07-21

Removing method for heavy metals in aqueous solution of ferrous chloride

FR2447403A1
(en)

1980-08-22

Cobalt recovery from low cobalt, high iron, oxide slag – by mixing with molten ferrous metal to produce ferro-cobalt

JPS5465198A
(en)

1979-05-25

Recovering method for iron ions

JPS5238472A
(en)

1977-03-25

Process for treating sludge of mixed metals

JPS51149189A
(en)

1976-12-21

Process for separation of metallic ions

JPS5788010A
(en)

1982-06-01

Separation of selenium and tellurium from acidic aqueous solution

Legal Events

Date
Code
Title
Description

1977-04-14
PS
Patent sealed [section 19, patents act 1949]

1994-01-19
PE20
Patent expired after termination of 20 years

Effective date:
19931217

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