GB1459952A

GB1459952A – Cyclic fluidized catalytic cracking process
– Google Patents

GB1459952A – Cyclic fluidized catalytic cracking process
– Google Patents
Cyclic fluidized catalytic cracking process

Info

Publication number
GB1459952A

GB1459952A
GB2119774A
GB2119774A
GB1459952A
GB 1459952 A
GB1459952 A
GB 1459952A
GB 2119774 A
GB2119774 A
GB 2119774A
GB 2119774 A
GB2119774 A
GB 2119774A
GB 1459952 A
GB1459952 A
GB 1459952A
Authority
GB
United Kingdom
Prior art keywords
sulphur
catalyst
metal
alumina
crystalline aluminosilicate
Prior art date
1973-05-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB2119774A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Standard Oil Co

Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1973-05-23
Filing date
1974-05-14
Publication date
1976-12-31

1974-05-14
Application filed by Standard Oil Co
filed
Critical
Standard Oil Co

1976-12-31
Publication of GB1459952A
publication
Critical
patent/GB1459952A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils

C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used

C10G11/04—Oxides

C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof

B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material

B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate

B01J20/16—Alumino-silicates

B01J20/18—Synthetic zeolitic molecular sieves

B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J29/00—Catalysts comprising molecular sieves

B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites

B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes

B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles

B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to “fluidised-bed” technique

B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to “fluidised-bed” technique with two or more fluidised beds, e.g. reactor and regeneration installations

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00

B01J2229/10—After treatment, characterised by the effect to be obtained

B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making

Y10S502/515—Specific contaminant removal

Y10S502/517—Sulfur or sulfur compound removal

Abstract

1459952 Cracking STANDARD OIL CO 14 May 1974 [23 May 1973] 21197/74 Heading C5E A hydrocarbon feedstock containing sulphur compounds is cracked in the presence of a regenerable fluidized catalyst which has a crystalline aluminosilicate component and has been impregnated with a compound or mixture of compounds of a metal of Group IIa and calcined, the deactivated catalyst is separated and regenerated by burning in a stream of gas containing oxygen. The presence of the Group IIa metal (as oxide) reduces the amount of sulphur oxides in gases from the regenerator; the sulphur held back (as sulphate) on the catalyst is reduced to sulphide in the next cracking step and evolved as H 2 S in the stripper. The preferred metal is magnesium. Suitable feeds include kerosines, gas oils, residuals and cycle oils. The crystalline aluminosilicate may be a natural or synthetic zeolite, ion-exchanged with rare earth, ammonium or hydrogen ions and may be combined with silica and alumina or with clay and alumina.

GB2119774A
1973-05-23
1974-05-14
Cyclic fluidized catalytic cracking process

Expired

GB1459952A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US00363082A

US3835031A
(en)

1973-05-23
1973-05-23
Catalytic cracking with reduced emission of sulfur oxides

Publications (1)

Publication Number
Publication Date

GB1459952A
true

GB1459952A
(en)

1976-12-31

Family
ID=23428712
Family Applications (2)

Application Number
Title
Priority Date
Filing Date

GB2119774A
Expired

GB1459952A
(en)

1973-05-23
1974-05-14
Cyclic fluidized catalytic cracking process

GB2500175A
Expired

GB1459953A
(en)

1973-05-23
1974-05-14
Cracking catalyst

Family Applications After (1)

Application Number
Title
Priority Date
Filing Date

GB2500175A
Expired

GB1459953A
(en)

1973-05-23
1974-05-14
Cracking catalyst

Country Status (9)

Country
Link

US
(1)

US3835031A
(en)

JP
(1)

JPS5129882B2
(en)

BE
(1)

BE815414A
(en)

CA
(1)

CA1029359A
(en)

DE
(1)

DE2425001C2
(en)

FR
(1)

FR2230711B1
(en)

GB
(2)

GB1459952A
(en)

IT
(1)

IT1013195B
(en)

NL
(1)

NL187581C
(en)

Families Citing this family (59)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3985641A
(en)

*

1974-04-15
1976-10-12
Phillips Petroleum Company
Catalytic cracking of alkanes

US4153535A
(en)

*

1975-12-19
1979-05-08
Standard Oil Company (Indiana)
Catalytic cracking with reduced emission of noxious gases

US4153534A
(en)

*

1975-12-19
1979-05-08
Standard Oil Company (Indiana)
Catalytic cracking with reduced emission of noxious gases

IT1074228B
(en)

*

1975-12-19
1985-04-17
Standard Oil Co

IMPROVEMENT IN CATALYTIC PYROSECTION PROCESSES OF HYDROCARBONS CONTAINING ORGANIC SULFUR COMPOUNDS

CA1093050A
(en)

*

1975-12-19
1981-01-06
Iacovos A. Vasalos
Catalytic cracking with reduced emission of noxious gases

US4071436A
(en)

*

1976-03-11
1978-01-31
Chevron Research Company
Process for removing sulphur from a gas

CA1122912A
(en)

*

1977-04-11
1982-05-04
William A. Blanton, Jr.
Method for removing pollutants from catalyst regenerator flue gas

CA1124224A
(en)

*

1977-04-11
1982-05-25
Chevron Research And Technology Company
Process for removing pollutants from catalyst regenerator flue gas

US4171260A
(en)

*

1978-08-28
1979-10-16
Mobil Oil Corporation
Process for reducing thiophenic sulfur in heavy oil

US4839026A
(en)

*

1978-09-11
1989-06-13
Atlantic Richfield Company
Catalytic cracking with reduced emissions of sulfur oxides

CA1154735A
(en)

*

1978-09-11
1983-10-04
Stanley M. Brown
Catalytic cracking with reduced emissions of sulfur oxides

US4259175A
(en)

*

1978-10-10
1981-03-31
Union Oil Company Of California
Process for reducing sox emissions from catalytic cracking units

US4243557A
(en)

*

1978-12-26
1981-01-06
Exxon Research & Engineering Co.
Sulfur transfer cracking catalyst

US4233276A
(en)

*

1979-03-30
1980-11-11
Standard Oil Company (Indiana)
Process for the desulfurization of waste gases

US4381991A
(en)

*

1979-04-11
1983-05-03
Standard Oil Company (Indiana)
Process for removing sulfur oxides from a gas

US4240899A
(en)

*

1979-11-05
1980-12-23
Exxon Research & Engineering Co.
Sulfur transfer process in catalytic cracking

US4376696A
(en)

*

1979-11-14
1983-03-15
Ashland Oil, Inc.
Addition of MgCl2 to catalyst for cracking carbo-metallic feed oils

US4377494A
(en)

*

1980-01-15
1983-03-22
Phillips Petroleum Company
Cracking catalysts passivated by barium

US4473463A
(en)

*

1980-01-15
1984-09-25
Phillips Petroleum Company
Use of cracking catalysts passivated by barium

US4341660A
(en)

*

1980-06-11
1982-07-27
Standard Oil Company (Indiana)
Catalytic cracking catalyst

US4309280A
(en)

*

1980-07-18
1982-01-05
Mobil Oil Corporation
Promotion of cracking catalyst octane yield performance

US4495304A
(en)

*

1980-07-29
1985-01-22
Atlantic Richfield Company
Catalyst for conversion of hydrocarbons

US4957892A
(en)

*

1980-07-29
1990-09-18
Uop
Process for combusting solid sulfur containing material

US4495305A
(en)

*

1980-07-29
1985-01-22
Atlantic Richfield Company
Catalyst for conversion of hydrocarbons

JPS5761085A
(en)

*

1980-07-29
1982-04-13
Atlantic Richfield Co
Conversion of hydrocarbon

US4383916A
(en)

*

1981-08-28
1983-05-17
Standard Oil Company (Indiana)
Sweetening and desulfurizing sulfur-containing hydrocarbon streams

JPS58174770U
(en)

*

1982-05-18
1983-11-22
二葉計器株式会社

taxi meter

GB2138314B
(en)

*

1983-04-21
1987-07-22
Grace W R & Co
Catalytic cracking catalyst and process

US4929338A
(en)

*

1983-04-21
1990-05-29
W. R. Grace & Co. – Conn.
Catalytic cracking catalyst and process

US4836993A
(en)

*

1983-09-27
1989-06-06
Amoco Corporation
Process for removing sulfur oxides from a gas

US4529502A
(en)

*

1984-02-27
1985-07-16
Uop Inc.
Sulfur oxide acceptance from a flue gas

EP0208798A1
(en)

*

1985-07-13
1987-01-21
Uop Inc.
Sulfur oxide acceptance from a flue gas

US4492678A
(en)

*

1984-05-17
1985-01-08
Atlantic Richfield Company
Preparative process for alkaline earth metal, aluminum-containing spinels and their use for reducing sulfur oxide content in gases

US4492677A
(en)

*

1984-05-17
1985-01-08
Atlantic Richfield Company
Preparative process for alkaline earth metal, aluminum-containing spinels and their use for reducing the sulfur oxide content of gases

US4918036A
(en)

*

1984-08-16
1990-04-17
W. R. Grace & Co.-Conn.
Cracking catalyst/sulfur oxide gettering agent compositions

US4925549A
(en)

*

1984-10-31
1990-05-15
Chevron Research Company
Sulfur removal system for protection of reforming catalyst

US5071539A
(en)

*

1985-08-30
1991-12-10
Engelhard Corporation
FCC catalysts of increased effective heat capacity

DE3672264D1
(en)

*

1985-08-30
1990-08-02
Engelhard Corp

FCC CATALYSTS WITH INCREASED HEATING CAPACITY.

US4781816A
(en)

*

1987-10-19
1988-11-01
Phillips Petroleum Company
Cracking process

US5141624A
(en)

*

1989-03-30
1992-08-25
Phillips Petroleum Company
Catalytic cracking process

US5116587A
(en)

*

1990-01-18
1992-05-26
Board Of Trustees Operating Michigan State University
Layered double hydroxide sorbents for the removal of sox from flue gas resulting from coal combustion

US5114691A
(en)

*

1990-01-18
1992-05-19
Board Of Trustees Operating Michigan State University
Process using sorbents for the removal of SOx from flue gas

US5114898A
(en)

*

1990-01-18
1992-05-19
Board Of Trustees Operating Michigan State University
Layered double hydroxide sorbents for the removal of SOx from flue gas and other gas streams

US5514351A
(en)

*

1992-04-15
1996-05-07
Mobil Oil Corporation
Desulfurizing tailgas from sulfur recovery unit

US5292492A
(en)

*

1992-05-04
1994-03-08
Mobil Oil Corporation
Recovering sulfur from ammonia acid gas stream

US5458861A
(en)

*

1992-04-15
1995-10-17
Mobil Oil Corporation
Desulfurizing a gas stream

US5591417A
(en)

*

1992-04-15
1997-01-07
Mobil Oil Corporation
Removing SOx, CO and NOx from flue gases

US5785938A
(en)

*

1992-11-16
1998-07-28
Board Of Trustees Operating Michigan State University
Process using recyclable sorbents for the removal of sox from flue gases and other gas streams

US5358701A
(en)

*

1992-11-16
1994-10-25
Board Of Trustees Operating Michigan State University
Process of using layered double hydroxides as low temperature recyclable sorbents for the removal of SOx from flue gas and other gas streams

US5545604A
(en)

*

1993-07-30
1996-08-13
Intercat, Inc.
Processes for reacting bastnaesite with alkaline-earth metals

US5422332A
(en)

*

1993-07-30
1995-06-06
Intercat, Inc.
Processes for reacting bastnaesite with metal oxides

US5426083A
(en)

*

1994-06-01
1995-06-20
Amoco Corporation
Absorbent and process for removing sulfur oxides from a gaseous mixture

US5843862A
(en)

*

1994-06-01
1998-12-01
Amoco Corporation
Process for manufacturing an absorbent composition

JP2925963B2
(en)

*

1994-12-05
1999-07-28
石油公団

Method and apparatus for oxidative coupling of methane

US6074984A
(en)

1996-11-18
2000-06-13
Bulldog Technologies U.S.A., Inc.
SOx Additive systems based upon use of multiple particle species

US6048821A
(en)

*

1996-11-18
2000-04-11
Bulldog Technologies U.S.A., Inc.
SOx additive systems based upon use of multiple particle species

US5990030A
(en)

*

1997-06-13
1999-11-23
Tricat Industries, Inc.
Sox reducing additive for FCC systems

US10005072B2
(en)

2012-07-23
2018-06-26
W. R. Grace & Co.-Conn
High matrix surface area catalytic cracking catalyst stabilized with magnesium and silica

US9993810B2
(en)

2012-07-23
2018-06-12
W. R. Grace & Co.-Conn
Silica sol bound catalytic cracking catalyst stabilized with magnesium

Family Cites Families (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

FR1358164A
(en)

*

1962-06-02
1964-04-10
Fichtel & Sachs Ag

Hydraulic vibration damper for washing machines

JPS466445Y1
(en)

*

1966-09-17
1971-03-06

US3459679A
(en)

*

1967-03-07
1969-08-05
Mobil Oil Corp
Catalyst prepared by steaming alkali metal aluminosilicate in a matrix with polyvalent metal salt

CA964255A
(en)

*

1970-12-23
1975-03-11
Geoffrey E. Dolbear
Cracking catalyst containing nickel and magnesium exchanged zeolites

1973

1973-05-23
US
US00363082A
patent/US3835031A/en
not_active
Expired – Lifetime

1974

1974-05-10
CA
CA199,505A
patent/CA1029359A/en
not_active
Expired

1974-05-14
GB
GB2119774A
patent/GB1459952A/en
not_active
Expired

1974-05-14
GB
GB2500175A
patent/GB1459953A/en
not_active
Expired

1974-05-16
NL
NLAANVRAGE7406561,A
patent/NL187581C/en
not_active
IP Right Cessation

1974-05-20
IT
IT51132/74A
patent/IT1013195B/en
active

1974-05-22
BE
BE144641A
patent/BE815414A/en
not_active
IP Right Cessation

1974-05-22
FR
FR7417990A
patent/FR2230711B1/fr
not_active
Expired

1974-05-22
JP
JP49057764A
patent/JPS5129882B2/ja
not_active
Expired

1974-05-22
DE
DE2425001A
patent/DE2425001C2/en
not_active
Expired

Also Published As

Publication number
Publication date

JPS5021004A
(en)

1975-03-06

IT1013195B
(en)

1977-03-30

FR2230711B1
(en)

1977-10-14

US3835031A
(en)

1974-09-10

NL187581C
(en)

1991-11-18

GB1459953A
(en)

1976-12-31

CA1029359A
(en)

1978-04-11

JPS5129882B2
(en)

1976-08-28

DE2425001A1
(en)

1974-12-12

NL7406561A
(en)

1974-11-26

FR2230711A1
(en)

1974-12-20

BE815414A
(en)

1974-11-22

DE2425001C2
(en)

1986-12-04

NL187581B
(en)

1991-06-17

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Legal Events

Date
Code
Title
Description

1977-05-11
PS
Patent sealed [section 19, patents act 1949]

1993-01-13
PCNP
Patent ceased through non-payment of renewal fee

Effective date:
19920514

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