GB1481509A – Ion selective electrodes and in methods of measuring the concentrations of ions
– Google Patents
GB1481509A – Ion selective electrodes and in methods of measuring the concentrations of ions
– Google Patents
Ion selective electrodes and in methods of measuring the concentrations of ions
Info
Publication number
GB1481509A
GB1481509A
GB34132/73A
GB3413273A
GB1481509A
GB 1481509 A
GB1481509 A
GB 1481509A
GB 34132/73 A
GB34132/73 A
GB 34132/73A
GB 3413273 A
GB3413273 A
GB 3413273A
GB 1481509 A
GB1481509 A
GB 1481509A
Authority
GB
United Kingdom
Prior art keywords
electrode
hydrogen
acid
ion selective
metal
Prior art date
1973-07-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB34132/73A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Research Development Corp UK
Original Assignee
National Research Development Corp UK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1973-07-18
Filing date
1973-07-18
Publication date
1977-08-03
1973-07-18
Application filed by National Research Development Corp UK
filed
Critical
National Research Development Corp UK
1973-07-18
Priority to GB34132/73A
priority
Critical
patent/GB1481509A/en
1974-07-12
Priority to US05/488,244
priority
patent/US4242189A/en
1974-07-17
Priority to DE2434318A
priority
patent/DE2434318C3/en
1977-01-21
Priority to US05/760,954
priority
patent/US4240879A/en
1977-06-30
Priority to US05/811,845
priority
patent/US4152235A/en
1977-08-03
Publication of GB1481509A
publication
Critical
patent/GB1481509A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
150000002500
ions
Chemical class
0.000
title
abstract
6
UFHFLCQGNIYNRP-UHFFFAOYSA-N
Hydrogen
Chemical compound
[H][H]
UFHFLCQGNIYNRP-UHFFFAOYSA-N
0.000
abstract
14
239000001257
hydrogen
Substances
0.000
abstract
14
229910052739
hydrogen
Inorganic materials
0.000
abstract
14
239000002253
acid
Substances
0.000
abstract
5
KDLHZDBZIXYQEI-UHFFFAOYSA-N
Palladium
Chemical compound
[Pd]
KDLHZDBZIXYQEI-UHFFFAOYSA-N
0.000
abstract
4
238000005259
measurement
Methods
0.000
abstract
4
229910052751
metal
Inorganic materials
0.000
abstract
4
239000002184
metal
Substances
0.000
abstract
4
150000003839
salts
Chemical class
0.000
abstract
4
239000003792
electrolyte
Substances
0.000
abstract
3
239000000956
alloy
Substances
0.000
abstract
2
229910045601
alloy
Inorganic materials
0.000
abstract
2
239000011248
coating agent
Substances
0.000
abstract
2
238000000576
coating method
Methods
0.000
abstract
2
238000005868
electrolysis reaction
Methods
0.000
abstract
2
BASFCYQUMIYNBI-UHFFFAOYSA-N
platinum
Chemical compound
[Pt]
BASFCYQUMIYNBI-UHFFFAOYSA-N
0.000
abstract
2
229910052727
yttrium
Inorganic materials
0.000
abstract
2
VWQVUPCCIRVNHF-UHFFFAOYSA-N
yttrium atom
Chemical compound
[Y]
VWQVUPCCIRVNHF-UHFFFAOYSA-N
0.000
abstract
2
OYPRJOBELJOOCE-UHFFFAOYSA-N
Calcium
Chemical compound
[Ca]
OYPRJOBELJOOCE-UHFFFAOYSA-N
0.000
abstract
1
FYYHWMGAXLPEAU-UHFFFAOYSA-N
Magnesium
Chemical compound
[Mg]
FYYHWMGAXLPEAU-UHFFFAOYSA-N
0.000
abstract
1
229910052788
barium
Inorganic materials
0.000
abstract
1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N
barium atom
Chemical compound
[Ba]
DSAJWYNOEDNPEQ-UHFFFAOYSA-N
0.000
abstract
1
229910052791
calcium
Inorganic materials
0.000
abstract
1
239000011575
calcium
Substances
0.000
abstract
1
238000010276
construction
Methods
0.000
abstract
1
230000004069
differentiation
Effects
0.000
abstract
1
239000007772
electrode material
Substances
0.000
abstract
1
239000007789
gas
Substances
0.000
abstract
1
150000004678
hydrides
Chemical class
0.000
abstract
1
238000011065
in-situ storage
Methods
0.000
abstract
1
229910052746
lanthanum
Inorganic materials
0.000
abstract
1
FZLIPJUXYLNCLC-UHFFFAOYSA-N
lanthanum atom
Chemical compound
[La]
FZLIPJUXYLNCLC-UHFFFAOYSA-N
0.000
abstract
1
229910052749
magnesium
Inorganic materials
0.000
abstract
1
239000011777
magnesium
Substances
0.000
abstract
1
239000000463
material
Substances
0.000
abstract
1
229910021645
metal ion
Inorganic materials
0.000
abstract
1
239000000203
mixture
Substances
0.000
abstract
1
229910052763
palladium
Inorganic materials
0.000
abstract
1
229910052697
platinum
Inorganic materials
0.000
abstract
1
239000004810
polytetrafluoroethylene
Substances
0.000
abstract
1
229920001343
polytetrafluoroethylene
Polymers
0.000
abstract
1
229910052712
strontium
Inorganic materials
0.000
abstract
1
CIOAGBVUUVVLOB-UHFFFAOYSA-N
strontium atom
Chemical compound
[Sr]
CIOAGBVUUVVLOB-UHFFFAOYSA-N
0.000
abstract
1
PMTRSEDNJGMXLN-UHFFFAOYSA-N
titanium zirconium
Chemical compound
[Ti].[Zr]
PMTRSEDNJGMXLN-UHFFFAOYSA-N
0.000
abstract
1
229910052720
vanadium
Inorganic materials
0.000
abstract
1
LEONUFNNVUYDNQ-UHFFFAOYSA-N
vanadium atom
Chemical compound
[V]
LEONUFNNVUYDNQ-UHFFFAOYSA-N
0.000
abstract
1
238000004804
winding
Methods
0.000
abstract
1
Classifications
G—PHYSICS
G01—MEASURING; TESTING
G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
G01N27/28—Electrolytic cell components
G01N27/30—Electrodes, e.g. test electrodes; Half-cells
G01N27/333—Ion-selective electrodes or membranes
G01N27/3335—Ion-selective electrodes or membranes the membrane containing at least one organic component
G—PHYSICS
G05—CONTROLLING; REGULATING
G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
G05D21/00—Control of chemical or physico-chemical variables, e.g. pH value
G05D21/02—Control of chemical or physico-chemical variables, e.g. pH value characterised by the use of electric means
Abstract
1481509 Ion selective electrode NATIONAL RESEARCH DEVELOPMENT CORP 10 July 1974 [18 July 1973] 34132/73 Heading G1N An ion selective electrode comprises a metal or alloy which forms a hydride and means for supplying hydrogen to or controlling the hydrogen concentration in the metal within a predetermined range. This electrode measures pH and may be partially coated with a mixture of an acid and a salt of that acid for measuring the metal present in the salt. The metal is preferably one of palladium, yttrium, zirconium titanium and vanadium or an alloy between two or more of these elements. The acid is preferably steoric acid and the salt, the steorate of calcium, magnesium, strontium, barium, yttrium or lanthanum. The hydrogen concentration is maintained constant by supplying hydrogen which may be generated electrolytically at the electrode or remotely or may be supplied under pressure. Circuitry. For pH or other ion measurement the potential difference between the ion selective electrode 10 and a reference electrode 14 is measured. Measurement cycles alternate with cycles which test and regenerate the electrode. The hydrogen content may be determined by measurement of potential relative to another electrode 38, Fig. 4 separated from the measurement electrode 10 by electrolyte. It is preferably determined by measuring the resistance of the electrode material which resistance increases with hydrogen content. Threshold circuits respond to a voltage from the resistance measuring circuits and provide signals which (a) indicate adequate hydrogen content, (b) start the hydrogen supply and (c) as in (b) but signal that the hydrogen content is too low for use. The hydrogen is preferably generated in situ between the reference electrode and a platinum electrode 12. The rate of generation is controlled by differentiation of the resistance proportional voltage. This can only be done in the solution being measured when it is flowing, as the reading would otherwise be affected, but may take place in electrolyte contained in the electrode body or remotely. The electrode may be cleaned by pulsing it positive relative to electrode 12. Electrode Constructions. As shown in Fig. 2, a palladium wire 10 wound in threads 16 of an insert body 17 which contains reference electrode 14, electrolyte 19 and leak 18. The electrode requires an external electrode for hydrogen generation. In a similarly shaped electrode Fig. 3 (not shown) the palladium wire is continued inside the electrode and a second electrode therein is used for hydrogen generation. An external reference is required. In the electrode of Fig. 4, hydrogen under pressure is supplied via valve 27 to the centre 34 of electrode 10. The gas may also be supplied to a similar electrode from an electrolysis cell. In a further embodiment the electrode extends from a teated pipette, along a hydrogen supply tube to an electrolysis cell. The metal ion selective electrode are preferably made by coating screw threads a PTFE body with the acid/salt material, winding the electrode wire in the screw threads and back diagonally across the threads and partially coating the wires at the intersections.
GB34132/73A
1973-07-18
1973-07-18
Ion selective electrodes and in methods of measuring the concentrations of ions
Expired
GB1481509A
(en)
Priority Applications (5)
Application Number
Priority Date
Filing Date
Title
GB34132/73A
GB1481509A
(en)
1973-07-18
1973-07-18
Ion selective electrodes and in methods of measuring the concentrations of ions
US05/488,244
US4242189A
(en)
1973-07-18
1974-07-12
Apparatus for measuring the concentrations of ions
DE2434318A
DE2434318C3
(en)
1973-07-18
1974-07-17
Device for measuring the ion concentration in liquids
US05/760,954
US4240879A
(en)
1973-07-18
1977-01-21
Methods of measuring the concentrations of ions
US05/811,845
US4152235A
(en)
1973-07-18
1977-06-30
Ion selective electrode
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
GB34132/73A
GB1481509A
(en)
1973-07-18
1973-07-18
Ion selective electrodes and in methods of measuring the concentrations of ions
Publications (1)
Publication Number
Publication Date
GB1481509A
true
GB1481509A
(en)
1977-08-03
Family
ID=10361782
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB34132/73A
Expired
GB1481509A
(en)
1973-07-18
1973-07-18
Ion selective electrodes and in methods of measuring the concentrations of ions
Country Status (3)
Country
Link
US
(2)
US4242189A
(en)
DE
(1)
DE2434318C3
(en)
GB
(1)
GB1481509A
(en)
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2470014A
(en)
*
2009-05-05
2010-11-10
Medermica Ltd
pH measurement device
Families Citing this family (20)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
CA1096940A
(en)
*
1977-12-05
1981-03-03
The Babcock & Wilcox Company
High temperature reference electrode
EP0080753A1
(en)
*
1981-11-10
1983-06-08
FISONS plc
Measuring device and method
US4500402A
(en)
*
1982-04-29
1985-02-19
Olin Corporation
Reference electrode
US4566950A
(en)
*
1982-04-29
1986-01-28
Olin Corporation
Method of monitoring an electrolytic cell
US4502214A
(en)
*
1982-04-29
1985-03-05
Olin Corporation
Method of making reference electrode
DE3217987A1
(en)
*
1982-05-13
1983-11-17
Gerhard Dipl.-Chem. Dr.-Ing. 5628 Heiligenhaus Kunz
Method and apparatus for quantitatively analysing ion concentrations in aqueous solutions, such as all types of water
DE3217989A1
(en)
*
1982-05-13
1983-11-17
Gerhard Dipl.-Chem. Dr.-Ing. 5628 Heiligenhaus Kunz
Method and apparatus for quantitative analysis of the bicarbonate hardness of aqueous solutions, such as all types of water
NL8300057A
(en)
*
1983-01-07
1984-08-01
Cordis Europ
ELECTROCHEMICAL SEMI CELL.
US4788491A
(en)
*
1984-12-24
1988-11-29
Electron Transfer Technologies, Inc.
Method of the measurement of interstitial atoms in alloys including the hydrogen content of solid hydrides, and of sorbed species on surface
IT1215930B
(en)
*
1988-02-22
1990-02-22
Eniricerche Spa
SOLID STATE SENSOR FOR DETERMINING THE CONCENTRATION OF GAS WITH A SOLID REFERENCE ELECTRODE.
GB9102371D0
(en)
*
1991-02-04
1991-03-20
Du Pont Canada
Monitoring and control of process streams at elevated temperatures
US7237429B2
(en)
*
2002-08-30
2007-07-03
Nano-Proprietary, Inc.
Continuous-range hydrogen sensors
US7287412B2
(en)
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2003-06-03
2007-10-30
Nano-Proprietary, Inc.
Method and apparatus for sensing hydrogen gas
US6849911B2
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2002-08-30
2005-02-01
Nano-Proprietary, Inc.
Formation of metal nanowires for use as variable-range hydrogen sensors
US20070240491A1
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2003-06-03
2007-10-18
Nano-Proprietary, Inc.
Hydrogen Sensor
KR20080036627A
(en)
*
2005-08-03
2008-04-28
나노-프로프리어터리, 인크.
Continuous range hydrogen sensor
US8512641B2
(en)
*
2006-04-11
2013-08-20
Applied Nanotech Holdings, Inc.
Modulation of step function phenomena by varying nanoparticle size
RU2007127132A
(en)
*
2007-07-16
2007-12-10
ЗАО Научно-исследовательский центр “Икар” (RU)
METHOD FOR DETERMINING THE ACTIVITY OF A STRUCTURED LIQUID
US20110022158A1
(en)
*
2009-07-22
2011-01-27
Boston Scientific Scimed, Inc.
Bioerodible Medical Implants
FR2966602B1
(en)
2010-10-25
2013-02-08
Commissariat Energie Atomique
APPARATUS FOR MEASURING PH IN TEMPERATURE
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Assignee
Title
DE433520C
(en)
*
1925-11-28
1926-09-09
Alfred Thiel Dr
Production of well-defined high concentrations of active hydrogen
US2882212A
(en)
*
1956-02-08
1959-04-14
Honeywell Regulator Co
Hydrogen concentration measuring apparatus
DE1027431B
(en)
*
1956-09-22
1958-04-03
Hartmann & Braun Ag
Process and device for keeping the O partial pressure constant and measuring the O consumption
US2886497A
(en)
*
1957-04-12
1959-05-12
United States Steel Corp
Method for determining the permeability of steel to hydrogen
US3258414A
(en)
*
1961-01-30
1966-06-28
Polytechnic Inst Brooklyn
Multilayer membrane electrodes
DE1256919B
(en)
*
1961-02-22
1967-12-21
Voith Gmbh J M
Method and device for determining the oxygen consumption during oxidation processes, in particular for determining the biological oxygen demand
US3357903A
(en)
*
1961-05-12
1967-12-12
Jr Samuel C Lawrence
Monitoring system and method for electroplating steel or other hydrogenpermeable metas
US3336215A
(en)
*
1963-12-30
1967-08-15
Continental Oil Co
Apparatus for the production of a gas by electrolysis including pressure responsive means for monitoring and controlling said electrolysis
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1966-03-21
1969-05-21
Emilio Volpe
Apparatus for Electrochemical Analyses
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Continental Oil Co
Corrosion-analytical monitoring apparatus
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1969-12-08
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Atomic Energy Commission
Determination of hydrogen in a high temperature fluid and apparatus therefor
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Cambridge Instr Co Inc
Chemical detector
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Gen Electric
Oxygen sensor and electrode device therefor
1973
1973-07-18
GB
GB34132/73A
patent/GB1481509A/en
not_active
Expired
1974
1974-07-12
US
US05/488,244
patent/US4242189A/en
not_active
Expired – Lifetime
1974-07-17
DE
DE2434318A
patent/DE2434318C3/en
not_active
Expired
1977
1977-01-21
US
US05/760,954
patent/US4240879A/en
not_active
Expired – Lifetime
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2470014A
(en)
*
2009-05-05
2010-11-10
Medermica Ltd
pH measurement device
Also Published As
Publication number
Publication date
US4242189A
(en)
1980-12-30
US4240879A
(en)
1980-12-23
DE2434318C3
(en)
1981-10-29
DE2434318B2
(en)
1981-02-19
DE2434318A1
(en)
1975-02-06
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Legal Events
Date
Code
Title
Description
1977-12-14
PS
Patent sealed [section 19, patents act 1949]
1988-03-09
PCNP
Patent ceased through non-payment of renewal fee
