GB1486849A – Process for producing a laminate containing oriented nylon film
– Google Patents
GB1486849A – Process for producing a laminate containing oriented nylon film
– Google Patents
Process for producing a laminate containing oriented nylon film
Info
Publication number
GB1486849A
GB1486849A
GB52449/75A
GB5244975A
GB1486849A
GB 1486849 A
GB1486849 A
GB 1486849A
GB 52449/75 A
GB52449/75 A
GB 52449/75A
GB 5244975 A
GB5244975 A
GB 5244975A
GB 1486849 A
GB1486849 A
GB 1486849A
Authority
GB
United Kingdom
Prior art keywords
nylon
laminate
roll
layers
extruder
Prior art date
1974-12-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB52449/75A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co
Original Assignee
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1974-12-23
Filing date
1975-12-22
Publication date
1977-09-28
1975-12-22
Application filed by WR Grace and Co
filed
Critical
WR Grace and Co
1977-09-28
Publication of GB1486849A
publication
Critical
patent/GB1486849A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B27/00—Layered products comprising a layer of synthetic resin
B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B27/00—Layered products comprising a layer of synthetic resin
B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B27/00—Layered products comprising a layer of synthetic resin
B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
B32B37/085—Quenching
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B2250/00—Layers arrangement
B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B2307/00—Properties of the layers or laminate
B32B2307/50—Properties of the layers or laminate having particular mechanical properties
B32B2307/514—Oriented
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B2307/00—Properties of the layers or laminate
B32B2307/50—Properties of the layers or laminate having particular mechanical properties
B32B2307/514—Oriented
B32B2307/518—Oriented bi-axially
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B2307/00—Properties of the layers or laminate
B32B2307/70—Other properties
B32B2307/732—Dimensional properties
B32B2307/734—Dimensional stability
B32B2307/736—Shrinkable
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B2377/00—Polyamides
B—PERFORMING OPERATIONS; TRANSPORTING
B32—LAYERED PRODUCTS
B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B2553/00—Packaging equipment or accessories not otherwise provided for
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S428/00—Stock material or miscellaneous articles
Y10S428/91—Product with molecular orientation
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/00—Stock material or miscellaneous articles
Y10T428/31504—Composite [nonstructural laminate]
Y10T428/31725—Of polyamide
Y10T428/31739—Nylon type
Y10T428/31743—Next to addition polymer from unsaturated monomer[s]
Y10T428/31746—Polymer of monoethylenically unsaturated hydrocarbon
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/00—Stock material or miscellaneous articles
Y10T428/31504—Composite [nonstructural laminate]
Y10T428/31855—Of addition polymer from unsaturated monomers
Y10T428/31909—Next to second addition polymer from unsaturated monomers
Y10T428/31913—Monoolefin polymer
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/00—Stock material or miscellaneous articles
Y10T428/31504—Composite [nonstructural laminate]
Y10T428/31855—Of addition polymer from unsaturated monomers
Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
Abstract
1486849 Laminated films W R GRACE & CO 22 Dec 1975 [23 Dee 1974] 52449/75 Headings B5N and B5B A process for producing a laminate of polymeric films comprises: (a) forming a laminate by co-extruding a film of a nylon having a second order transition temperature of below 150 F. and optionally being in the form of a plurality of contiguous layers of nylon with an adjacent substantially water-impermeable layer or layers of at least one other kind of polymer which is orientatable at a temperature below 150 F. into laminar relationship with one or both of the main surfaces of the nylon film, (b) quenching the extruded laminate to a temperature below the second order transition temperature of the nylon and (c) heating the laminate to a temperature above the second order transition temperature of the nylon and at which the adjacent layer or layers are orientatable, but below 150 F. and stretching the laminate while so heated, to orient the nylon and said other polymer, the process up to the beginning of step (c) being carried out so as to protect the nylon film from substantial contact with water. The nylon may be a polyamide, e.g. nylon-6 or a co-, homo-, block or graft polyamide, the other polymer being preferably polyethylene or an ethylenevinyl acetate copolymer. In the method described with reference to Figs. 1 and 2, nylon from extruder A and olefin polymers from extruders B and C are fed to annular co-extrusion die 1, the inner ply coming from extruder B, the central ply from extruder A and the outer ply from extruder C. A tubular laminate 4 emerging from die 1 is cooled by cooling ring 5 and collapsed between pinch rollers 6 in cooling bath 7 to form flattened tubing 9 which is fed across guide rolls 8 and wound on roll 10, no water having contacted the nylon film thus far in the process. The roll of flattened tubing 10 is then unwound and fed through pinch rolls 12 into heated bath 13, thence over guide roll 14 and through pinch rolls 15 where it is expanded into bubble 16 by the trapped bubble technique, the resultant stretched laminate passing over roll 18 to wind-up roll 19. In an alternative procedure, the laminate made by co-extrusion through a slot die with the nylon layer sandwiched between two adjacent layers, stretch orientation being effected uniaxially by racking. Example I describes the manufacture of a sixply laminate comprising layers of polyethylene, an ionomeric ethylene copolymer, nylon, nylon, an ionomeric ethylene copolymer and polyethylene.
GB52449/75A
1974-12-23
1975-12-22
Process for producing a laminate containing oriented nylon film
Expired
GB1486849A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US53577274A
1974-12-23
1974-12-23
Publications (1)
Publication Number
Publication Date
GB1486849A
true
GB1486849A
(en)
1977-09-28
Family
ID=24135704
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB52449/75A
Expired
GB1486849A
(en)
1974-12-23
1975-12-22
Process for producing a laminate containing oriented nylon film
Country Status (10)
Country
Link
US
(1)
US4095012A
(en)
JP
(1)
JPS5192882A
(en)
AR
(1)
AR207667A1
(en)
AU
(1)
AU8778275A
(en)
BR
(1)
BR7508345A
(en)
CA
(1)
CA1061067A
(en)
DE
(1)
DE2557272A1
(en)
FR
(1)
FR2295840A1
(en)
GB
(1)
GB1486849A
(en)
IT
(1)
IT1051860B
(en)
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1982-03-15
1983-10-19
Grace W R & Co
Quenched nylon multilayer casings
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1982-10-29
1984-05-09
Kureha Kagaku Kogyo Kabushiki Kaisha
Heat-shrinkable composite laminate film and process for preparing the same
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*
1986-05-23
1990-01-09
Kureha Kagaku Kogyo Kabushiki Kaisha
Heat-shrinkable laminate film and process to produce the same
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1992-09-23
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Method and apparatus for making improved laminating film and improved film
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Mitsubishi Petrochemical Co., Ltd.
Process for preparing laminated resin product
US3997383A
(en)
*
1975-03-10
1976-12-14
W. R. Grace & Co.
Cross-linked amide/olefin polymeric laminates
US4056419A
(en)
*
1975-12-01
1977-11-01
Moldex, Inc.
Method and belt of oriented nylon with rubber sheet adhered thereto
1975
1975-01-01
AR
AR261739A
patent/AR207667A1/en
active
1975-07-18
CA
CA231,766A
patent/CA1061067A/en
not_active
Expired
1975-12-17
BR
BR7508345*A
patent/BR7508345A/en
unknown
1975-12-19
DE
DE19752557272
patent/DE2557272A1/en
not_active
Withdrawn
1975-12-22
JP
JP50152044A
patent/JPS5192882A/ja
active
Pending
1975-12-22
FR
FR7539357A
patent/FR2295840A1/en
active
Granted
1975-12-22
AU
AU87782/75A
patent/AU8778275A/en
not_active
Expired
1975-12-22
GB
GB52449/75A
patent/GB1486849A/en
not_active
Expired
1975-12-22
IT
IT30643/75A
patent/IT1051860B/en
active
1976
1976-08-02
US
US05/710,511
patent/US4095012A/en
not_active
Expired – Lifetime
Cited By (7)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2117702A
(en)
*
1982-03-15
1983-10-19
Grace W R & Co
Quenched nylon multilayer casings
EP0107854A2
(en)
*
1982-10-29
1984-05-09
Kureha Kagaku Kogyo Kabushiki Kaisha
Heat-shrinkable composite laminate film and process for preparing the same
EP0107854A3
(en)
*
1982-10-29
1985-05-08
Kureha Kagaku Kogyo Kabushiki Kaisha
Heat-shrinkable composite laminate film and process for preparing the same
US4892765A
(en)
*
1986-05-23
1990-01-09
Kureha Kagaku Kogyo Kabushiki Kaisha
Heat-shrinkable laminate film and process to produce the same
US5698279A
(en)
*
1992-09-23
1997-12-16
Viskase Corporation
Heat shrinkable nylon food casing having a functionalized ethylenic polymer core layer
EP2117839A1
(en)
2007-01-29
2009-11-18
Cryovac, Inc.
Shrink film containing semi-crystalline polyamide, articles made therefrom, and process for making and using same
EP2117839B1
(en)
2007-01-29
2015-10-14
Cryovac, Inc.
Shrink film containing semi-crystalline polyamide, articles made therefrom, and process for making and using same
Also Published As
Publication number
Publication date
JPS5192882A
(en)
1976-08-14
US4095012A
(en)
1978-06-13
AR207667A1
(en)
1976-10-22
DE2557272A1
(en)
1976-07-01
FR2295840B1
(en)
1980-12-12
AU8778275A
(en)
1977-06-30
BR7508345A
(en)
1976-08-24
CA1061067A
(en)
1979-08-28
IT1051860B
(en)
1981-05-20
FR2295840A1
(en)
1976-07-23
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Legal Events
Date
Code
Title
Description
1978-02-08
PS
Patent sealed [section 19, patents act 1949]
1981-08-05
PCNP
Patent ceased through non-payment of renewal fee