GB1522410A

GB1522410A – Determination of heavy metal ion concentrations
– Google Patents

GB1522410A – Determination of heavy metal ion concentrations
– Google Patents
Determination of heavy metal ion concentrations

Info

Publication number
GB1522410A

GB1522410A
GB38739/76A
GB3873976A
GB1522410A
GB 1522410 A
GB1522410 A
GB 1522410A
GB 38739/76 A
GB38739/76 A
GB 38739/76A
GB 3873976 A
GB3873976 A
GB 3873976A
GB 1522410 A
GB1522410 A
GB 1522410A
Authority
GB
United Kingdom
Prior art keywords
heavy metal
electrode
electrolyte
liquor
counter electrode
Prior art date
1975-09-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB38739/76A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Siemens AG

Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1975-09-25
Filing date
1976-09-17
Publication date
1978-08-23

1976-09-17
Application filed by Siemens AG
filed
Critical
Siemens AG

1978-08-23
Publication of GB1522410A
publication
Critical
patent/GB1522410A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

G—PHYSICS

G01—MEASURING; TESTING

G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES

G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means

G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis

G01N27/416—Systems

G01N27/42—Measuring deposition or liberation of materials from an electrolyte; Coulometry, i.e. measuring coulomb-equivalent of material in an electrolyte

G01N27/423—Coulometry

Abstract

1522410 Determining heavy metal ions electro-chemically SIEMENS AG 17 Sept 1976 [25 Sept 1975] 38739/76 Heading G1N Heavy metals in aqueous liquor are determined by conducting the liquor for a predetermined length of time and at a constant flow-rate past a solid electrode maintained at a negative direct voltage to deposit heavy metal thereon, replacing the liquor by an electrolyte and the negative voltage by a positive direct voltage and determining the charge to remove any deposited heavy metal from the electrode. The negative voltage may be – I to -4V preferably – 1À5 to -2À5V, and the predetermined length of time 1-10 minutes. The positive voltage may be 0À5 to 3V preferably 0À8 to 2V. The electrolyte is preferably sodium chloride or sodium sulphate of concentration 10-1 to 10-3 mol/litre and pH 1 to 7 preferably 3-4, and is preferably stationary during the dissolution. Apparatus for carrying out the determination comprises a measuring cell 24 with working electrode 25, and counter electrode 26 and gas riser pipe 29. The aqueous liquor is supplied via filter 20, and constant head device 21 and valve 22 and the electrolyte from tank 31 via valve 32. A valve is provided in the cell outlet so that the aqueous liquor can flow through the cell during the deposition period but the electrolyte does not flow during the dissolution. A control circuit for the valves and voltages and means for integrating and displaying or recording the dissolution current and generating an alarm if a predetermined heavy metal concentration is exceeded, are provided. The deposition may be conducted with the working electrode stationary or moving i.e. rotating or vibrating. The liquid in the cell may be mechanically circulated. The electrodes preferably have an area of about 20 mm2 and are preferably rods and of platinum; graphite, glass-carbon and carbides being alternative materials. The counter electrode is preferably of larger area than the reference electrode. In alternative embodiments the electrodes may be coiled wires; the counter electrode a coiled wire surrounding a rod working electrode, the counter electrode a cylinder surrounding either a cylinder or a rod working electrode or they may both be cylindrical and set in the walls of a ceramic, glass or synthetic plastics tube. The method and apparatus may be used for the automatic monitoring of heavy metal pollution. The method has a detection limit of about 10-6 equivalent/litre.

GB38739/76A
1975-09-25
1976-09-17
Determination of heavy metal ion concentrations

Expired

GB1522410A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

DE19752542863

DE2542863A1
(en)

1975-09-25
1975-09-25

METHOD AND DEVICE FOR THE ELECTROCHEMICAL DETERMINATION OF THE CONCENTRATION OF HEAVY METALS IN WATER

Publications (1)

Publication Number
Publication Date

GB1522410A
true

GB1522410A
(en)

1978-08-23

Family
ID=5957443
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB38739/76A
Expired

GB1522410A
(en)

1975-09-25
1976-09-17
Determination of heavy metal ion concentrations

Country Status (7)

Country
Link

AT
(1)

AT350511B
(en)

CH
(1)

CH599550A5
(en)

DE
(1)

DE2542863A1
(en)

FR
(1)

FR2325927A1
(en)

GB
(1)

GB1522410A
(en)

IT
(1)

IT1068936B
(en)

SE
(1)

SE7610040L
(en)

Cited By (3)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2117120A
(en)

*

1982-03-01
1983-10-05
Secr Defence
Anodic stripping voltameter

CN102565172A
(en)

*

2010-11-22
2012-07-11
株式会社堀场制作所
Heavy metal ion measurement method and heavy metal ion measurement device

CN109298062A
(en)

*

2018-11-02
2019-02-01
山东建筑大学
A kind of material sound state of paddling impregnates the detection device and method of water test

Families Citing this family (6)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE2928123C2
(en)

*

1979-07-12
1983-03-03
Dornier System Gmbh, 7990 Friedrichshafen

Device for displaying the metal-specific loading of ion exchangers

GB8411448D0
(en)

*

1984-05-04
1984-06-13
Albery Wyndham John
Gas sensor

NO873013L
(en)

*

1987-04-13
1988-10-14
Electrolyt Zinc Australasia

PROCEDURE AND APPARATUS FOR DETERMINING ELECTROCHEMICALLY ACTIVE COMPONENTS.

DE4231273A1
(en)

*

1992-09-18
1994-03-24
Henkel Kgaa

Bath control of copper-containing metal treatment baths

DE4424355C2
(en)

*

1994-07-11
1996-07-18
Fraunhofer Ges Forschung

Electrochemical analysis method

DE102006005949B3
(en)

*

2006-02-09
2007-10-25
Chmiel, Horst, Prof. Dr.-Ing.
Measuring electrode e.g. mercury drop electrode, for voltammetry measurement of liquids, has permeable membrane for retaining impurities of liquid on retentate side of membrane, and conductive film placed on permeate side of membrane

1975

1975-09-25
DE
DE19752542863
patent/DE2542863A1/en
active
Pending

1976

1976-07-06
CH
CH861076A
patent/CH599550A5/xx
not_active
IP Right Cessation

1976-08-03
AT
AT573276A
patent/AT350511B/en
not_active
IP Right Cessation

1976-09-10
SE
SE7610040A
patent/SE7610040L/en
unknown

1976-09-17
GB
GB38739/76A
patent/GB1522410A/en
not_active
Expired

1976-09-21
IT
IT27438/76A
patent/IT1068936B/en
active

1976-09-23
FR
FR7628676A
patent/FR2325927A1/en
active
Granted

Cited By (3)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2117120A
(en)

*

1982-03-01
1983-10-05
Secr Defence
Anodic stripping voltameter

CN102565172A
(en)

*

2010-11-22
2012-07-11
株式会社堀场制作所
Heavy metal ion measurement method and heavy metal ion measurement device

CN109298062A
(en)

*

2018-11-02
2019-02-01
山东建筑大学
A kind of material sound state of paddling impregnates the detection device and method of water test

Also Published As

Publication number
Publication date

CH599550A5
(en)

1978-05-31

SE7610040L
(en)

1977-03-26

FR2325927B1
(en)

1978-12-15

FR2325927A1
(en)

1977-04-22

DE2542863A1
(en)

1977-03-31

AT350511B
(en)

1979-06-11

ATA573276A
(en)

1978-11-15

IT1068936B
(en)

1985-03-21

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Legal Events

Date
Code
Title
Description

1978-12-20
PS
Patent sealed

1989-05-10
PCNP
Patent ceased through non-payment of renewal fee

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