GB1568634A - Creation of Inventions and Patents with Artificial Intelligence

GB1568634A – Vibrating capacitor
– Google Patents

GB1568634A – Vibrating capacitor
– Google Patents
Vibrating capacitor

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Publication number
GB1568634A

GB1568634A
GB12985/77A
GB1298577A
GB1568634A
GB 1568634 A
GB1568634 A
GB 1568634A
GB 12985/77 A
GB12985/77 A
GB 12985/77A
GB 1298577 A
GB1298577 A
GB 1298577A
GB 1568634 A
GB1568634 A
GB 1568634A
Authority
GB
United Kingdom
Prior art keywords
vibratable
piezo
spring element
assembly according
crystal
Prior art date
1976-03-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB12985/77A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Forschungszentrum Juelich GmbH

Original Assignee
Kernforschungsanlage Juelich GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1976-03-30
Filing date
1977-03-28
Publication date
1980-06-04

1977-03-28
Application filed by Kernforschungsanlage Juelich GmbH
filed
Critical
Kernforschungsanlage Juelich GmbH

1980-06-04
Publication of GB1568634A
publication
Critical
patent/GB1568634A/en

Status
Expired
legal-status
Critical
Current

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Classifications

G—PHYSICS

G01—MEASURING; TESTING

G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES

G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means

G01N27/002—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the work function voltage

G—PHYSICS

G01—MEASURING; TESTING

G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES

G01R29/00—Arrangements for measuring or indicating electric quantities not covered by groups G01R19/00 – G01R27/00

G01R29/24—Arrangements for measuring quantities of charge

H—ELECTRICITY

H01—ELECTRIC ELEMENTS

H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE

H01G5/00—Capacitors in which the capacitance is varied by mechanical means, e.g. by turning a shaft; Processes of their manufacture

H01G5/16—Capacitors in which the capacitance is varied by mechanical means, e.g. by turning a shaft; Processes of their manufacture using variation of distance between electrodes

Description

PATENT SPECIFICATION
( 11) 1 568634 ( 21) Application No 12985/77 ( 22) Filed 28 March 1977 ( 31) Convention Application No 2613 528 ( 32) Filed 30 March 1976 in ( 33) Fed Rep of Germany (DE) ( 44) Complete Specification published 4 June 1980 ( 51) INT CL 3 HOIG 7/00 ( 52) Index at acceptance HIM 2 J 2 2 L BT GIN 19 B 2 B 19 B 2 X 19 HX G 1 U BS ( 54) VIBRATING CAPACITOR ( 71) We, KERNFORSCHUNGSANLAGE JuLICH GESELLSCHAFT MIT BESCHRANKTER HAFTu NG, of Artilleriestrasse 14, Postfach 1913 5170 Julich, Federal Republic of Germany, a Body Corporate organised according to the laws of the Federal Republic of Germany, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the fol-
lowing statement:-
The invention relates to a vibratable assembly for forming a vibrating capacitor, to apparatus incorporating such an assembly, and to the use of the capacitor.
A particular use of vibrating capacitors is for determining the electronic work function of boundary surfaces of materials The work function of boundary faces of electrical conductors or semiconductors is especially of interest The determination of electronic work function is of considerable importance in assessing surface properties of material.
Methods which can be used for measuring the work function are photo-electric methods, thermionic methods, and methods which measure the contact potential difference The latter method has been preferably employed as a measuring method has been preferably employed as a measuring method which does not affect the surfaces to be tested The measurements are carried out in chambers filled with ultra-pure gases or in an ultra-high vacuum, i e at a pressure below 10-10 mm Hg.
Vibrating capacitors for determining work function have become known and are referred to as “Kelvin probes” By means of “Kelvin probes” the contact potential between boundary faces of two materials having different electronicwork functions is measured (see Review of Scientific Instruments, 1970, Vol 41, page 258) In most cases, the vibrating electrode in these probes is used as a reference electrode It consists of a material whose electronic work function does not change during the measuring time The counterelectrode is formed by the test specimen, the work function of the surface of which is to be determined Owing to the movement of the reference electrode in relation to the test specimen, the capacitance of the capacitor changes When there is a difference between the work function of the reference electrode and that of the test specimen, there flows a displacement current which is proportional to the contact potential difference The vibratory movement of the electrode in “Kelvin probes” can be produced by mechanical or electromechanical means For this purpose, it has been necessary for an electrical excitation system and the measuring signal produced to be electrically isolated from one another in order to keep the sensitivity of the “Kelvin probes” as high as possible Also, because the measurement takes place in measuring chambers filled with ultra-pure gases or situated under a ultra-high vacuum, it has generally been necessary to accommodate the electrical excitation systems outside the measuring chambers Where an electromechanical drive is used this arrangement is very disadvantageous owing to the need for mechanical coupling between the electrical excitation system on the outside of the measuring chamber and the vibrating electrode within the chamber There has also been difficulty in making the adjustment between the vibrating electrode and the counterelectrode for setting the mean spacing.
Therefore, the work function can be accurately determined by Kelvin’s method only with considerable technical expenditure (see Journal of Physics, E: Scientific Instruments, 1970, Vol 3, pages 477 ff).
According to this invention there is provided a vibratable assembly for forming a vibrating capacitor, the assembly having a vibratable electrode carried by a spring element which is coupled to a piezo-electric crystal to be excited thereby when an alternating voltage is applied to the crystal The other electrode of the capacitor can be provided by a test specimen Piezo-electric crystals acting as vibration exciters for “Kelvin probes” are mentioned in an article in Journal of Physics, E: Scientific Instruments, 1970, Vol 3, Ca ( 19) 1,568,634 page 479 However, no suitable connection between the piezo-electric crystal and the vibrating capacitor is described in the article.
For driving the vibrating electrode with a spring element, in accordance with the invention, only a small amount of electrical energy is required, so that the measuring signal generated by the “Kelvin probe” need be subjected only to negligible disturbances by the exciting field The piezo-electric crystal and the spring element form an excitation system for the vibrating electrode requiring only a very small amount of space The excitation system can readily be completely accommodated in the measuring chamber itself, so that only the electrical conductors for the excitation of the piezo-electric crystal and the conductors for the measuring signal have to be passed through the wall of the said measuring chamber The spring element and with it the electrode of the capacitor are set in vibration in a manner known per se by tuning the excitation frequency to the fundamental oscillation or harmonic of the spring element.
Preferably the piezo-electric crystal is, in use, excited by, an alternating voltage on which a direct voltage component is superimposed, and it is thus appropriate that it be electrically connected to means for supplying such superimposed voltages By the superimposition of a constant unidirectional voltage upon the alternating electric field by which the crystal is excited, the piezo-electric crystal is deformed and imparts to the spirng element a bias which determines the mean distance between the vibrating electrode and the counter-electrode The direct voltage component is preferably regulatable i e adjustable whereby a very simple means is afforded of adjusting the reference electrode in relation to the test specimen in the determination of the work function.
In a further development of the invention, the piezo-electric crystal is surrounded by an electrical screen in order to enhance the sensitivity of the vibrating capacitor.
The piezo-electric crystal may be cemented to the spring element A method of securing the crystal to the spring element which has proved successful for use with an ultra-high vacuum is to connect them together by means of a two-component lacquer having a polyurethane base Two component lacquers of this kind have become know for use as vacuum sealing means (see Vakuumtechnik, 1973, part 3, pges 93 ff) These lacquers cure even at room temperature with moderate shrinkage, so that, after the application of a unform lacquer film, an intimate union between the piezo-electric crystal and the spring element can be obtained It is advantageous for the spring element to be leaf spring, since in this way an increase in the amplitude of vibration of the vibratable electrode can be produced with comparable deformation of the piezo-electric crystal.
The material used for the spring element may be metal, or alternatively electrically insulating material In order that maximum excitation frequencies may be attainable, the material(s) employed should have a high modulus of elasticity with low density.
Examples of such materials are W, Ti, Mo and Be, as well as mica.
The invention also embraces apparatus for mesuring electronic work function including a vibratable assembly according to the invention and a method of measuring electronic work function which includes utilising a vibrating capacitor having a vibratable electrode carried by a spring element which is coupled to a piezo-electric crystal, and applying to the crystal an alternating voltage and a direct voltage in superimposition.
An embodiment of the invention will be described with reference to the accompanying diagrammatic drawings in which:Figure 1 illustrates a vibrating capacitor for measuring electronic work function, and Figure 2 illustrates a circuit arrangement for apparatus for mesuring work function with a vibrating capacitor as shown in Figure 1.
As is shown in the drawings, the vibrating 95 capacitor has a vibratable electrode 1 and a fixed counter-electrode 2 The capacitor is constructed as a “Kelvin probe” and the vibratable electrode 1 of the capacitor is designed as a reference electrode It consists 100 of a material whose work function does not change during the intended measurements, for example gold or Sn O 2 The counterelectrode 2 is formed by the test specimen.
The vibratable electrode is secured to a 105 spring element 3 in the form of a leaf spring, which is coupled to a piezo-electric crystal 4 to be excited by the crystal to carry out transverse vibrations at its other end There may be used instead of a leaf spring other spring 110 elements, more particularly longitudinal vibrators The spring element 3 is made of molybdenum.
The piezo-electric crystal 4 which is connected to the spring element 3 is a piezo 115 electric ceramic foil of a thickness of 0-1 mm, and is coated on both faces with a metal layer connected to the alternating-voltage source which excites the piezo-electric crystal.
For the embodiment shown the piezo 120 electric ceramic foil was formed of lead, zirconate and titanate (i e was a lead-titanium -zirconium ceramic) with 05 % by weight of neodymium as additive This is resistant to heating and to ultra-high vacuum Such a 125 piezo-electric ceramic foil is obtainable under the trade designation PTZ-1 H-42 The piezo-electric ceramic foil was contacted with gold On application of a voltage, the piezoelectric crystal is mechanically deformed and 130 Before the assembly of a vibrating capacitor as described above the piezo-electric crystal provided for the excitation of the vibratable electrode was polarised to over 100 V by an impulse of direct voltage The cemented 70 vibratable reed of the capacitor was ultrasonically treated and dried over three hours at C After installation of the vibratable reed in the measuring chamber, the whole system was additionally heated at 200 C for 75 24 hours in vocuo After this treatment, no impurities were observable in an ultra-high vacuum of 4 x 10-11 mm H g Measurements for the variation of the work function were made with excitation of the spring element in 80 its fundamental oscillation and in the second harmonic In the case of the spring element used in the embodiment described above, this spring element being a molybdenum lea spring having the dimensions given above, a 85 resonance frequency of 145 Hertz was found and a second harmonic of 750 Hertz.
For determining the work function the vibration amplitude of the vibratable electrode was set at 0-2 mm The alternating 90 voltage required for the excitation of the piezo-electric crystal for this vibration was only 03 V at the fundamental oscillation and 1-3 V at the second harmonic, the necessary currents being less than 1 g A Under these 95 operating conditions, the stray fields produced by the excitation field are very small.
For setting the mean distance between the electrode 1 and the counter-electrode 2, the direct voltage which can be set up with the 100 aid of the voltage source 16 could be adjusted between 70 V By variation of this direct voltage the mean distance between the electrode and the counter-electrode could be varied in the range between 05 mm The 105 measuring accuracy of the vibrating capacitor could be ascertained by simulation of a work function change of 1-7 m V with the aid of the voltage source 23 With a time constant of less than 10 sec, a resolution of 01 m V was 110 obtained.
The vibrating capacitor described has high sensitivity and has an electromechanical excitation with a very small space requirement and system which can be disposed within the 115 measuring chamber It offers a reduction in the technical expenditure necessary for determining electronic work function by means of a “Kelvin probe”.
Excitation of the vibrating capacitor by 120 means of a piezo-electric crystal and a spring element makes it readily possible, to employ a electronic circuit arrangement for the selfexcitation of the vibrating reed comprised by the piezo-electric crystal, the spring element 125 and the electrode in the capacitor Also, the voltage source 16 may be replaced by an electronic controller, with the aid of which a predetermined mean distance can be automatically restored between the vibratable 130 transmits its movement to the spring element and hence to the electrode 1 secured to the spring element, so that the distance of the said electrode from the counter electrode, i e the test specimen, changes.
The piezo-electric crystal 4 is surrounded by a metallic screen 5 The sensitivity of the vibrating capacitor is thereby increased The screen 5 also forms the holder for the vi29 bratable reed of the capacitor, the said reed being the vibratable assembly consisting of the piezo-electric crystal 4, the spring element 4 and the electrode 1 The vibratable reedis secured in the screen 5 by means of a clamping Screw 6 between two insulator elements 7 and electrical conductors 8 The electrical conductors 8 are connected to supply conductors 9, 10 which are connected to an alternatingvoltage source 11 The supply conductors 9, 10 are also electrically screened, but this is not shown in the drawings.
The piezo-electric crystal 4 is cemented to the spring element 3 by means of curable twocomponent, polyurethane-based lacquer, which is known per se for use as a vacuum sealing agent For the embodiment shown there was used a thinly-liquid two-component lacquer obtainable under the trade name “Desmodur Desmophen-Lack”, which wets the surface well The vibratable reed has the following dimensions:
Spring element: 26 mm long, 1 5 mm wide and 01 mm thick; contact face of the electrode: 2 x 1-5 mm 2; piezo-electric crystal:
10 mm long, 1-5 mm wide and 01 mm thick.
The screen 5 has a diameter of about 5 mm and is 15 mm long.
For exciting the piezo-electric crystal 4, the supply conductors 9, 10 led out of the measuring chamber 12 are connected-as shown in Figure 3-in a conductor circuit 13 to a secondary winding 14 of a transformer which is fed on its primary side, as alternatingvoltage source 11, by a sine wave generator 15 The conductor circuit 13 further comprises a voltage source 16 for setting a constant direct voltage which is superimposed upon the alternating voltage and with the aid of which the mean distance between the vibratable electrode 1 and the counter-electrode 2 can be adjusted.
The measuring signal is led out of the measuring chamber 12 by way of a conductor 17 and passed on, in a length of conductor 18 connected to the electrode 1, to a synchronous detector 19 which is synchronised by the sine wave generator 15 An automatic null balancing of the measuring signal takes place by way of an integrator 20, so that the change in the work function which is to be measured can be directly registered by means of a recorder 21 There is further situated in the length of conductor 18 a voltage source 22 which serves to simulate a change of work function.
1,5686 i 4 1,568,634 electrode and the test specimen, for example after manipulation of the test specimen.

Claims (12)

WHAT WE CLAIM IS:-

1 A vibratable assembly for forming a vibrating capacitor, the assembly having a vibratable electrode carried by a spring element which is coupled to a piezo-electric crystal to be excited thereby when an alternating voltage is applied to the crystal.

2 A vibratable assembly according to claim 1 having the piezo-electric crystal electrically connected to means for supplying to it an alternating voltage and a direct voltage in superimposition.

3 A vibratable assembly according to claim 2 wherein the direct voltage is adjustable.

4 A vibratable assembly according to any one of the preceding claims wherein the piezoelectric crystal is surrounded by an electrical screen.

A vibratable assembly according to any one of the preceding claims wherein the piezo-electric crystal and the spring element are connected together by means of a polyurethane-based two component lacquer.

6 A vibratable assembly according to any one of the preceding claims, wherein the spring element is in the form of a leaf spring.

7 A vibratable assembly according to any one of the preceding claims, wherein the spring element is of material having a high modulus of elasticity with low density.

8 A vibratable assembly according to claim 7 wherein the material is any of mica, tungsten, titanium, molybdenum or beryllium.

9 A vibratable assembly substantially as herein described with reference to Fig 1 of the drawings.

Apparatus for measuring electronic work function including a vibratable assembly according to any one of the preceding claims.

11 Apparatus for measuring electronic work function substantially as herein described with eference to the drawings.

12 A method of measuring electronic work function which includes utilising a vibrating capacitor having a vibratable electrode carried by a spring element which is coupled to a piezo-electric crystal, and applying to the crystal an alternating voltage and a direct voltage in superimposition.
MEWBURN ELLIS & CO, Chartered Patent Agents, 70-72 Chancery Lane, London WC 2 A l AD.
Agents for the Applicants.
Printed for Her Majesty’s Stationery Office by Burgess & Son (Abingdon), Ltd -1980.
Published at The Patent Office, 25 Southampton Buildings, London, WC 2 A l AY from which copies may be obtained.

GB12985/77A
1976-03-30
1977-03-28
Vibrating capacitor

Expired

GB1568634A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

DE2613528A

DE2613528C3
(en)

1976-03-30
1976-03-30

Oscillating capacitor

Publications (1)

Publication Number
Publication Date

GB1568634A
true

GB1568634A
(en)

1980-06-04

Family
ID=5973858
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB12985/77A
Expired

GB1568634A
(en)

1976-03-30
1977-03-28
Vibrating capacitor

Country Status (4)

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Link

US
(1)

US4100442A
(en)

DE
(1)

DE2613528C3
(en)

FR
(1)

FR2346834A1
(en)

GB
(1)

GB1568634A
(en)

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Priority date
Publication date
Assignee
Title

US4367948A
(en)

1979-04-24
1983-01-11
Canon Kabushiki Kaisha
Surface potential electrometer and image forming apparatus using the same

DE3034390C2
(en)

1980-09-12
1985-11-21
Kernforschungsanlage Jülich GmbH, 5170 Jülich

Piezoelectric vibrating element

DE3438546A1
(en)

1984-10-20
1986-04-24
Kernforschungsanlage Jülich GmbH, 5170 Jülich

METHOD FOR DETECTING A SUBSTANCE OR DETECTING AT LEAST ONE COMPONENT OF A SUBSTANCE MIXTURE, AND VIBRATING CAPACITOR FOR CARRYING OUT THE METHOD

DE4018993A1
(en)

1990-06-13
1991-12-19
Max Planck Inst Eisenforschung

METHOD AND DEVICE FOR EXAMINING COATED METAL SURFACES

US6732720B2
(en)

2002-05-30
2004-05-11
Monroe R. Kelemencky
Ultrasonic liquid fuel introduction system

CN100437100C
(en)

2005-07-14
2008-11-26
上海大学
Instrument for measuring surface work function

DE102005037876A1
(en)

2005-08-10
2007-02-22
Siemens Ag

Device for converting mechanical energy into electrical energy and method for operating this device

US8618824B2
(en)

2008-11-24
2013-12-31
The Boeing Company
MEMS based Kelvin probe for material state characterization

CN113030602B
(en)

2021-03-02
2022-10-21
北京纳米能源与系统研究所
Method, device, equipment and medium for measuring electrical property of sample material

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Assignee
Title

US1900038A
(en)

1930-04-15
1933-03-07
Ward E Bower
Oscillation generator

US2368643A
(en)

1941-12-31
1945-02-06
Rca Corp
Variable reactance and control circuit therefor

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1943-12-06
1954-06-29
Univ Leland Stanford Junior
Electrical frequency control apparatus

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(en)

1956-03-30
1961-05-09
Philipps Electronics Corp
Crystal vibrated reed and receiver

US2937562A
(en)

1956-10-01
1960-05-24
Motorola Inc
Electrodynamic spectrograph

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(en)

1960-09-12
1964-01-14
Lockheed Aircraft Corp
Densitometer

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1962-12-03
1967-08-15
Lockheed Aircraft Corp
Vibrating reed frequency responsive device

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(en)

1965-07-15
1970-03-17
Lear Siegler Inc
Frequency selective resonant reed detector

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(en)

1970-09-25
1972-02-29
Avco Corp
Piezoelectric-driven variable capacitor

1976

1976-03-30
DE
DE2613528A
patent/DE2613528C3/en
not_active
Expired

1977

1977-03-21
US
US05/779,837
patent/US4100442A/en
not_active
Expired – Lifetime

1977-03-28
GB
GB12985/77A
patent/GB1568634A/en
not_active
Expired

1977-03-29
FR
FR7709330A
patent/FR2346834A1/en
active
Granted

Also Published As

Publication number
Publication date

FR2346834A1
(en)

1977-10-28

FR2346834B1
(en)

1983-05-06

US4100442A
(en)

1978-07-11

DE2613528C3
(en)

1979-10-31

DE2613528A1
(en)

1977-10-13

DE2613528B2
(en)

1979-03-08

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