GB1590425A

GB1590425A – Method for the production of shaped bodies of a fibre composition
– Google Patents

GB1590425A – Method for the production of shaped bodies of a fibre composition
– Google Patents
Method for the production of shaped bodies of a fibre composition

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Publication number
GB1590425A

GB1590425A
GB31979/77A
GB3197977A
GB1590425A
GB 1590425 A
GB1590425 A
GB 1590425A
GB 31979/77 A
GB31979/77 A
GB 31979/77A
GB 3197977 A
GB3197977 A
GB 3197977A
GB 1590425 A
GB1590425 A
GB 1590425A
Authority
GB
United Kingdom
Prior art keywords
fibres
weight
cellulose
fibrous material
zero
Prior art date
1976-08-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB31979/77A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rockwool AB

Original Assignee
Rockwool AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1976-08-12
Filing date
1977-07-29
Publication date
1981-06-03

1976-08-12
Priority claimed from SE7609017A
external-priority
patent/SE400964C/en

1977-02-09
Priority claimed from SE7701418A
external-priority
patent/SE444828B/en

1977-07-29
Application filed by Rockwool AB
filed
Critical
Rockwool AB

1981-06-03
Publication of GB1590425A
publication
Critical
patent/GB1590425A/en

Status
Expired
legal-status
Critical
Current

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Classifications

D—TEXTILES; PAPER

D21—PAPER-MAKING; PRODUCTION OF CELLULOSE

D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR

D21H5/00—Special paper or cardboard not otherwise provided for

D21H5/12—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials

D21H5/18—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of inorganic fibres with or without cellulose fibres

D—TEXTILES; PAPER

D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR

D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR

D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material

D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface

D06N7/006—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the textile substrate as base web

D—TEXTILES; PAPER

D21—PAPER-MAKING; PRODUCTION OF CELLULOSE

D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR

D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material

D21H13/36—Inorganic fibres or flakes

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S162/00—Paper making and fiber liberation

Y10S162/09—Uses for paper making sludge

Description

PATENT SPECIFICATION ( 11) 1 590 425
tn ( 21) Application No 31979/77 ( 22) Filed 29 Jul1977 ( 19) i, ( 31) Convention Application No’s 7609017 ( 32) Filed 12 Aug 1976 i, 7701418 9 Feb 1977 in v A O ( 33) Sweden (SE) Un ( 44) Complete Specification Published 3 Jun 1981 i – ( 51) INT CL 3 D 21 H 5/18 ( 52) Index at Acceptance D 2 B 11 A 2 Il AY 11 E 36 F 2 36 J 1 36 Q 1 36 QY 41 A B 5 A 1 R 214 F 1 R 460 T 13 P ( 54) A METHOD FOR THE PRODUCTION OF SHAPED BODIES OF A FIBRE COMPOSITION ( 71) We, ROCKWOOL AKTIEBOLAGET, a company limited organised under the laws of the Kingdom of Sweden, having its legal seat in Skovde, Sweden, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which
it is to be performed, to be particularly described in and by the following statement:-
The present invention relates to a method for the production of shaped bodies of a fibre 5 composition which comprise mineral fibres as an essential constituent, and for instance in the form of planar bodies These bodies are intended to replace earlier known bodies containing asbestos fibres as an essential constituent.
Planar bodies which comprise asbestos fibres as an essential constituent have in the past been much used, as, for example, support felt for floors, but the present invention is not 10 limited to this type of shaped body and particularly not to planar bodies In the manufacture of certain types of floor material, a support felt has been used, which was porous and which contained asbestos fibres as an essential constituent.
Asbestos fibres, however, have been proved to have a health risk, in that during the production and subsequent treatment of the asbestos felt, micro-particles of asbestos are 15 dispersed freely in the air and can be breathed in by personnel involved with the production and handling of the shaped body This applies especially during the pulling down of old houses in which such an asbestos felt is used Therefore, there is a need to replace the asbestos fibrous material with some other fibrous material, and artificial mineral fibres were initially considered In this connection, by artificial mineral fibres (hereinafter referred to as “mineral 20 fibres”) is meant such mineral fibres which have been produced by some kind of spinning procedure from a melt of a natural mineral of a mixture of natural minerals As an example may be mentioned stone wool fibres, slag fibres, glass wool fibres and so on These types of mineral fibres do not have the health risks of asbestos fibres.
However, it has not proved successful to replace the asbestos fibres by such mineral fibres, 25 because the latter have very different physical properties to asbestos fibres Thus, whereas asbestos fibres are uneven and, seen under the microscope, have barb-like formations along their length, the mineral fibres are usually smooth Therefore, whereas the asbestos fibres enable a strong friction bond to be formed, the mineral fibres give no such friction bond or, at least they will give only a very weak friction bond 30 It has been attempted to improve the weak friction bond of mineral fibres, as compared with asbestos fibres, by adding binding means, but tests have shown that such a step is not economical The amount of binding means generally required is rather great, and the binding means that may be considered are expensive, so that the cost of a mineral fibre shaped body in which the fibres are bonded will be too high 35 It was then attempted to try mixing in some other type of fibres in combination with the mineral fibres which could reinforce the bond in the product Among such other fibres that have been considered are rag fibres, cotton fibres and cellulose fibres which can be bonded by means that is available at a reasonable price, such as latex Such cellulose fibres are those that are retained on a conventional wire in the filtering of water from cellulose pulp in the 40 manufacture of paper and pulp Tests, however, have not given the desired result, because the shaped bodies including such other fibres lacked the required dimensional stability under the influence of moisture, heat and especially variations of heat.
An object of the present invention is the provision of a shaped body comprising mineral fibres and other materials together, that give the shaped body properties which are compar 45 i Cnn A 1 AZ 2 1,J U,’t J 2 able with those of shaped bodies produced from asbestos fibres for the same purpose, especially planar bodies The most important properties are resistance against moisture, heat and variations in heat, as well as rigidity in the different directions in which the shaped body may be subjected to strains.
In tests leading to the solution of the present invention it was found that, due to the typical 5 tendency of mineral fibres to lie in parallel layers, there is a tendency in the different products on which the tests were carried out to burst by layer separation or slotting which implies a lack of rigidity in a direction perpendicular to the principal plane of the shaped body Furthermore, in other directions the rigidity was sometimes not satisfactory.
For the rigidity in a direction perpendicular to the principal plane of a planar body, the 10 denomination “splitting rigidity” or “z-rigidity” has been introduced The latter expression is derived from the fact that in a planar body the two perpendicular directions in the plane of the body have been called the x-direction and the y-direction, and it was natural to call the direction perpendicular to the principal plane of the shaped body its “zdirection” Good splitting rigidity, of course, is not required when the shaped body is not subjected to any 15 strains in the z-direction, but such cases are very rare Any bending of the planar body will cause such strains, and usually the shaped body will at some stage of its production, transportation or use be subjected to bending Therefore, it is accepted that a splitting rigidity below 5 kg/cm 2 is insufficient, that a splitting rigidity between 5 and 9 kg/cm 2 is in some cases, but not all, sufficient, and that a splitting rigidity of more than 9 kg/cm iscompletely satisfactory for 20 all normally existing purposes.
According to the present invention there is provided a method for the production of a shaped body of a fibrous composition which comprises mineral fibres (as herein defined) together with cellulose fibrous material, the method comprising preparing an aqueous dispersion of from 30 to 90 % of the total fibre weight of mineral fibres and from 10 to 70 % of 25 the total fibre weight of cellulose fibrous material, a portion not less than one-half (by weight) of the cellulose fibrous material comprising zero fibres (as herein defined) dewatering the dispersion and shaping the fibrous composition and drying the shaped fibrous composition to further reduce the water content.
Further according to the present invention there is provided an article of fibrous composi 30 tion when made by the method described in the immediately preceding paragraph.
Still further according to the present invention there is provided a shaped fibrous body comprising from 30 to 90 % of the total fibre weight of mineral fibres (as herein defined) and from 10 to 70 % of the total fibre weight of cellulose fibrous material, a portion not less than one-half (by weight) of the cellulose fibrous material comprising zero fibres (as herein 35 defined) Preferably the maximum content of zero fibres in the cellulose fibrous material is 78 %by weight.
Surprisingly it was found that excitingly advantageous properties are obtained with the shaped product in accordance with the present invention Zero fibres are well known in the art of paper manufacture, being defined as the cellulose fibrous material that is recovered 40 from the filtrant of a paper web formed on the conventional wire of paper forming apparatus, and they are thus of such a small size that they pass through the wire during dewatering of the web Zero fibres also have ends like the end of a needle and they were accordingly originally called “nolfiber” in Sweden where the wire (or vira as it is known there) was first introduced, which translates into “needle fibre” By a misspelling over the years this term was changed to 45 “nollfiber” which translates into “zero fibre” and the latter term has been used ever since.
With the conception of zero fibres one has hitherto regarded the extremely thin and short cellulose fibrous material which passes through the conventional wire of paper forming apparatus and is found in the filtrant water (the so-called back water), as an impurity in the water, where the fibres remain as freely-hovering particles, usually only visible as a muddi 50 ness to the human eye Of course, they may be separated by different kinds of separation steps, for instance centrifuging They were hitherto regarded a dangerous by-product within the cellulose industries, which it has been difficult to get rid of cost effectively Releasing dewatering water containing zero fibres into rivers and other water supplies has caused serious environmental problems 55 The zero fibres used in accordance with the present invention should for reasons which will be evident from the following, be free of such impurities which may act to decrease the rigidity of the shaped product or article produced Amongst such impurities are to be mentioned certain dye stuffs, which are normally used when colouring cellulose on a vira in the production of paper that is coloured all the way through 60 The present invention is based upon the observation that mixing in this cheap product, viz.
zero fibres from the cellulose industry, in accordance with the invention will cause such a good bond between the mineral fibres, that the product thereof will have physical properties, especially moisture and thermal resistance and rigidity, which are comparable with asbestos fibre products It is believed that this depends upon the usual cellulose fibres (such as would 65 3 1,590,425 3 be retained by the conventional wire) being so long that they will preferably arrange themselves in the same layer pattern as the mineral fibres, and that for this reason shaped products comprising usual cellulose fibres do not show especially advantageous properties (especially splitting rigidity) whereas the zero fibres are so short that they will arrange themselves asymmetrically and thereby contribute to an improved bond 5 The best bond, however, is obtained when using zero fibres as well as usual cellulose fibres mixed in with the mineral fibre mass Preferably more than half and less than 78 % of the cellulose fibrous material is in the form of zero fibres.
Hitherto, zero fibres are not known to have been used for industrial purposes, so that their separation from the back water within the cellulose industry has been considered as not cost 10 effective Since the possibility of industrial use of the zero fibres has now, by the present invention, been proposed, most probably the separation of the zero fibres from the back water will take place to an increased extent.
Preferably, also, both the usual fibres and the zero fibres of cellulose material should be of the kind that are used in the production of Kraft paper, and known as Kraft fibres 15 The mineral fibres are advantageously as far as possible free from larger accumulations of molten mineral (so-called pearls), and preferably the mineral fibres are of stone or glass.
Mineral fibres formed from slag may be used although due to their lower rigidity and resistance they will not give the same result as using stone or glass.
The proportional relation between mineral fibres and cellulose fibrous material has been 20 carefully investigated, and it has been shown that this proportional relation may, under certain circumstances, be rather critical and that the correct proportions must be the result of a compromise As a matter of fact, it has been found that a substantial quantity of cellulose fibrous material is required in order to obtain a satisfactory wet rigidity, which is necessary due to the method of production of the shaped bodies, which will be further described below, 25 and this especially applies to the initial part of the production process Without such a wet rigidity the product cannot, for instance, be driven through a paper machine Further, a substantial quantity of cellulose fibrous material is required in order that the finished product shall have a satisfactory rigidity, especially against splitting, as previously described This especially applies to shaped bodies in the form of sheets, discs and similar rather thin shaped 30 bodies, and for said products it is necessary to prevent delamination and splitting These circumstances therefore are in favour of a high content of cellulose fibrous material At too high a content of cellulose fibrous material, however, a dimensional instability problem arises This is the reason why one has had to find the proportions of mineral wool and of cellulose fibrous material by a compromise method The result of extensive investigations for 35 finding this compromise has been that the proportion of mineral fibres should not be more than 90 % by weight and preferably not more than 70 % by weight of the total weight of fibres, and should not be less than 30 % (preferably not less than 50 %o) by weight of the total weight of fibres.
In the method of the present invention, certain additives may be added to the fibrous 40 composition for different purposes A wetting means is one such additive, preferably in the form of a cationic wetting agent Other additives may comprise glue, filler material and/or thickening means The wetting means may be of great use in promoting an even distribution of material in the dispersion, because the mineral fibres could otherwise form pellets Glue may be used in those cases when the binding action of the cellulose fibrous material is not 45 sufficiently strong As a filler, one may use, for example, finely ground diatomaceous stone, clay, bentonite or other finely divided, inorganic constituents which should be chemically inactive relative to both the mineral fibres and the cellulose fibrous material The thickening means may be of any kind known per se and many be of advantage, because it may otherwise be difficult to treat the mass in moist state 50 When preparing the product one proceeds substantially in the following way:
First, the fibre dispersion in water is produced, and this is dewatered Either simultaneously with the dewatering or in sequence thereafter, the products are shaped from this dispersion, and thereafter they are dried In preparing the dispersion one may include such additives as desired, as mentioned above In the usual case the dewatering takes place on a 55 wire, for instance a plane wire; however, one may principally use any method known for the dewatering The shaping, also, preferably takes place on the same wire, particularly when the product is to be a planar body, but if the shaped body is to be of a more complicated type, the shaping suitably takes place by moulding after the dewatering has, at least in part, been carried out in perforated moulds It has been found that the presence of mineral fibres in the 60 dispersion facilitates dewatering, and the shaped body does not have any tendency to shrink.
The characteristic property of the invention will be clarified below in connection with the accompanying diagram In this, the weight of zero fibres as a percentage of the total weight of fibres is plotted along the horizontal scale, the percentage weight of the cellulose fibrous material which cannot be said to be zero fibres (referred to herein as “cellulose fibres”) is 65 4 1,590,425 4 plotted along the left sloping scale, and the percentage weight of mineral fibres is plotted along the right sloping scale All of the indicated percentages are thus weight percentages of the total fibre weight.
In the diagram, a number of different compositions have been marked from a h as shown in the following table: 5 Content of Content of Content of Composition mineral fibres zero fibres cellulose fibres a 90 10 0 b 30 70 0 10 c 30 35 35 d 80 10 10 e 70 30 0 f 50 50 0 15 g 50 25 25 h 60 20 20 20 As seen from the diagram, the eight compositions indicated above describe two irregular four-edged figures, the one of them being inscribed in the other one The invention will give advantages with all of the compositions within the four-edged figure limited by the points a, b, c and d, but the best results are obtained with compositions, situated inside of the smaller 25 four-edged figure, e, f, g and h.
The invention will now be further explained by way of some examples In all of these examples zero fibre material was used, which had emanated in the production of cellulose for manufacture of paper without any additions, especially without dyeing stuffs, and Examples 3 and 4 illustrate use of the zero fibre material in accordance with the invention 30 Example 1
A fibre suspension was prepared from 50 % of mineral fibres and 50 % of Kraft cellulose fibres without any addition of zero fibres Due to the experiences which have been accounted for above, it could be expected that the product derived therefrom should not in all respects 35 be satisfactory A sheet of the said fibre composition was shaped on a continuous wire, on which dewatering simultaneously took place Thereafter the sheet was dried as far as possible The rigidity in all directions was found to be unsatisfactory To increase the rigidity % of the initial weight of material of a binding means in the form of a latex solution in water was added, and the product was carefully dried up to about 95 % dry weight of material A 40 surface weight of 300 g/m 2 was obtained, and the product showed a good evenness of surface, a good tensile rigidity and a good tearing rigidity The splitting rigidity against strains in a direction perpendicular to the plane of the product, on the contrary, was completely unsatisfactory at only 3 2 kg/cm 2 The product produced therefore was classified as less good, which was also to be expected per se 45 Example 2
A fibrous composition was prepared in the same way as according to Example 1 above, however with the difference that all of the quantity of cellulose fibrous material comprised zero fibres It was expected that a bad rigidity would be obtained, especially bad wet rigidity 50 because there was no long Kraft cellulose fibre present It also proved difficult to dewater the fibre composition on a conventional continuous wire without breaking up the composition, because the product could not withstand the strains that are unavoidable during such treatment in its wet state.
Example 3 55
In accordance with the present invention a fibrous suspension was prepared corresponding to the point h in the diagram, comprising 60 % of mineral fibres, 20 % of zero fibres and 20 % of Kraft cellulose fibres The product was treated on a wire and by subsequent drying as described in Example 1 above, but without any addition of binding means A plane shaped 60 body was obtained having a surface weight of 300 g/m 2 and with excellent rigidity properties both against pulling and tearing The rigidity under a strain in a direction erpendicular to the plane of the shaped body, however, now had increased to 11 kg/cm which completely corresponded to high demands on such a rigidity under normal treatment, and the product therefore was classified as completely satisfactory 65 1,590,425 Example 4
This Example referred to the production of a three-dimensional body according to the present invention, thus no longer to a plane shaped body, and the body therefore had to be moulded As such a body a diffusor was chosen such as is used in an outlet for ventilating 5 means The reason for this choice was that such diffusors have previously been produced from a material comprising asbestos fibres as the principal constituent In the present case, the diffusor comprised a conical body of circular cross-section and with a major diameter which was essentially greater than the height A fibre suspension was prepared from 65 parts by weight of mineral fibres, 35 parts by weight of zero fibres, 10 parts by weight of usual Kraft 10 cellulose fibres and, finally, 15 parts by weight of diatomaceous earth The suspension was diluted to a dry weight content of 2 %, whereafter 5 % of a 20 % emulsion of polyvinylacetate was added The dispersion obtained was poured into a mould made from a filtering metalcloth and was subjected then to successive dewaterings as further amounts of the dispersion were added, until the mould was filled with dewatered material Then the body was removed 15 from the mould with a rigidity that was sufficient for subsequent handling, which included drying at a temperature of 90 WC until practically no more water could be removed After the body had cooled, it was further tested, and it was found that it had a very high rigidity in all directions, a very high resistance to erosion as well as to attacks by moisture, and a very good mechanical workability The surfaces which had not been in contact with the mould were 20 thereafter worked, and a functionable diffusor had been produced.
When the above mentioned tests were repeated with zero fibres of a different type, however, it was found that the result in some cases could be rather different from the optimum result obtained when using pure zero fibres The reason for this was also investigated and thereby the following resulted: 25 Rather often, a manufacturer of paper requires that the paper shall, for instance, be dyed throughout and not only coloured on its surface Thereby it has been found convenient to mix in dye stuff into the pulp mass in its wet state before the dewatering has taken place The amount of dye which has been taken up by the zero fibres is usually so small that it will not provide any observable inconvenience Much more important is the fact that, when collecting 30 the zero fibres, dye will also be collected from the dewatering liquid, and this dye therefore will be contained in the mass of zero fibres, where it appears as an impurity Such impurities appear to be a reason for a reduction in the properties of a product produced according to the method of the invention.
In this connection it should also be mentioned that, dependent upon how finely divided the 35 cellulose fibrous material is which is used in the production of the cellulose product, and upon the mesh size of the filter formed by the wire, there may also exist a variation of the mean dimension of the zero fibres However, they will preferably have a freeness of at least 700 SR.
Finally, in the production of certain types of paper, cardboard and the like, other additives may be used, which are not dye stuffs but which may nevertheless be concentrated into the 40 mass of zero fibres to a non-desired level in the same way as may the dye stuffs.
In short terms: The zero fibres should be as uniform in size and as pure as possible for use in the method of the present invention.

Claims (12)

WHAT WE CLAIM IS:-

1 A method for the production of a shaped body of a fibrous composition which 45 comprises mineral fibres (as herein defined) together with cellulose fibrous material, the method comprising preparing an aqueous dispersion of from 30 to 90 % of the total fibre weight of mineral fibres and from 10 to 70 % of the total fibre weight of cellulose fibrous material, a portion not less than one-half (by weight) of the cellulose fibrous material comprising zero fibres as herein defined, dewatering the dispersion and shaping the fibrous 50 composition, and drying the shaped fibrous composition to further reduce the water content.

2 A method according to claim 1 in which a wetting agent is added to the aqueous dispersion.

3 A method according to claim 2 in which the agent is a cationic wetting agent.

4 A method according to any one of claims 1 to 3 in which glue and/or filler material 55 and/or thickening means is added to the aqueous dispersion.

A method according to any one of the preceding claims in which the fibre composition contains between 50 % and 70 % (by weight) of mineral fibres.

6 A method according to any one of the preceding claims in which the maximum content of zero fibres in the cellulose fibrous material is 78 %by weight 60

7 A method according to any one of the preceding claims in which the zero fibres have a freeness of at least 700 SR.

8 A method for the production of a shaped body of a fibrous composition substantially as herein described with reference to Example 3 or Example 4.

9 An article of fibrous composition comprising a combination of mineral fibres and 65 6 1,590,425 6 cellulose fibrous material which is made by the method claimed in any one of the preceding claims.
A shaped fibrous body comprising from 30 to 90 % of the total fibre weight of mineral fibres (as herein defined) and from

10 to 70 % of the total fibre weight of cellulose fibrous material, a portion not less than one-half (by weight) of the cellulose fibrous material 5 comprising zero fibres (as herein defined).

11 A shaped fibrous body as claimed in claim 10 in which the maximum content of zero fibres in the cellulose fibrous material is 78 %by weight.

12 A shaped fibrous body as claimed in claim 10 or claim 11 in which the fibre composition contains between 50 % and 70 % (by weight) of mineral fibres 10 URQUHART-DYKES & LORD lth Floor, St Martin’s House, Tottenham Court Road, London Wl P OJN 15 and 3rd Floor, Essex House, 27 Temple Street, Birmingham B 2 5 DD 20 Chartered Patent Agents Printed for Her Majesty’s Stationery Office, by Croydon Printing Company Limited, Croydon, Surrey, 1981.
Published by The Patent Office, 25 Southampton Buildings, London, WC 2 A l AY, from which copies may be obtained.

GB31979/77A
1976-08-12
1977-07-29
Method for the production of shaped bodies of a fibre composition

Expired

GB1590425A
(en)

Applications Claiming Priority (2)

Application Number
Priority Date
Filing Date
Title

SE7609017A

SE400964C
(en)

1976-08-12
1976-08-12

PROCEDURAL KIT FOR PREPARING FORMS OF A FIBER COMPOSITION

SE7701418A

SE444828B
(en)

1977-02-09
1977-02-09

PROCEDURAL KIT FOR PREPARING FORMS OF A FIBER COMPOSITION

Publications (1)

Publication Number
Publication Date

GB1590425A
true

GB1590425A
(en)

1981-06-03

Family
ID=26656733
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB31979/77A
Expired

GB1590425A
(en)

1976-08-12
1977-07-29
Method for the production of shaped bodies of a fibre composition

Country Status (9)

Country
Link

US
(1)

US4159224A
(en)

CA
(1)

CA1094265A
(en)

DE
(1)

DE2735371A1
(en)

DK
(1)

DK358377A
(en)

FI
(1)

FI62158C
(en)

FR
(1)

FR2361317A1
(en)

GB
(1)

GB1590425A
(en)

NL
(1)

NL176663C
(en)

NO
(1)

NO152260C
(en)

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GB2117753A
(en)

*

1982-04-06
1983-10-19
Printsulate Limited
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EP0001539B1
(en)

*

1977-09-28
1981-12-23
Rockwool Aktiebolaget
A method for the production of a fibrous mat or sheet

SE440801B
(en)

*

1979-05-04
1985-08-19
Rockwool Ab

DIMENSION STABLE BERARM MATERIAL BASED ON CELLULOSA FIBER AND MINERAL FIBER AND USE OF THE BEAR MATERIAL FOR COATING WITH A PLASTIC MATERIAL

US4244781A
(en)

*

1979-06-11
1981-01-13
Nicolet, Inc.
Non-asbestos millboard composition

FI78814C
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*

1987-03-30
1989-10-10
Cultor Oy

NOLLFIBER INNEHAOLLANDE FODERRAOAEMNE OCH FODER SAMT FOERFARANDE FOER DERAS FRAMSTAELLNING.

DK167198B1
(en)

*

1988-10-25
1993-09-13
Hartmann As Brdr

PROCEDURE FOR THE PREPARATION OF FORMED ARTICLES OF A FLUIDIZED CELLULOSE FIBER MATERIAL

EP0399252A3
(en)

*

1989-05-22
1992-04-15
R.J. Reynolds Tobacco Company
Smoking article with improved insulating material

US5215625A
(en)

*

1992-03-02
1993-06-01
Burton R Edward
Method for producing articles from waste fiber, waste/surplus paint, and waste/surplus ink

WO2020025908A1
(en)

*

2018-08-03
2020-02-06
Saint-Gobain Isover
Wet method for producing a panel or a pole, products produced by said method and use of products produced by said method

FR3084679B1
(en)

*

2018-08-03
2020-11-06
Saint Gobain Isover

METHOD OF MANUFACTURING A PANEL OR A MAST BY WET METHOD, PRODUCTS MANUFACTURED BY THIS PROCESS, AND USE OF THE PRODUCTS MANUFACTURED BY THIS PROCESS

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1958-03-25
1961-02-08
British Insulated Callenders
Improvements in paper for use in the manufacture of electric cables and capacitors and other purposes

US3300372A
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*

1963-08-23
1967-01-24
Kaiser Gypsum Company Inc
Fire-resistant building board and process

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(en)

*

1964-01-16
1968-04-23
United States Gypsum Co
Water-felted mineral wool building and insulation product including nonfibrous cellulose binder

FR1420990A
(en)

*

1964-01-16
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United States Gypsum Co

Products intended for construction and their manufacturing processes

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(en)

*

1968-12-28
1973-03-29

CAPACITOR PAPER

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(en)

*

1974-07-18
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Kagan Henri
Rough card board or fibre board includes waste fibres – recuperated from paper converting process

1977

1977-06-07
US
US05/804,296
patent/US4159224A/en
not_active
Expired – Lifetime

1977-06-27
NL
NLAANVRAGE7707087,A
patent/NL176663C/en
not_active
IP Right Cessation

1977-07-11
FI
FI772166A
patent/FI62158C/en
not_active
IP Right Cessation

1977-07-29
GB
GB31979/77A
patent/GB1590425A/en
not_active
Expired

1977-08-05
DE
DE19772735371
patent/DE2735371A1/en
not_active
Ceased

1977-08-09
FR
FR7724476A
patent/FR2361317A1/en
active
Granted

1977-08-11
DK
DK358377A
patent/DK358377A/en
not_active
Application Discontinuation

1977-08-11
NO
NO772818A
patent/NO152260C/en
unknown

1977-08-11
CA
CA284,514A
patent/CA1094265A/en
not_active
Expired

Cited By (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2117753A
(en)

*

1982-04-06
1983-10-19
Printsulate Limited
Compositions

Also Published As

Publication number
Publication date

US4159224A
(en)

1979-06-26

FI772166A
(en)

1978-02-13

FI62158C
(en)

1982-11-10

NL7707087A
(en)

1978-02-14

CA1094265A
(en)

1981-01-27

NO152260B
(en)

1985-05-20

FR2361317A1
(en)

1978-03-10

DK358377A
(en)

1978-02-13

DE2735371A1
(en)

1978-02-16

FI62158B
(en)

1982-07-30

NO772818L
(en)

1978-02-14

NL176663B
(en)

1984-12-17

FR2361317B1
(en)

1982-12-17

NO152260C
(en)

1985-08-28

NL176663C
(en)

1985-05-17

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Legal Events

Date
Code
Title
Description

1981-08-19
PS
Patent sealed [section 19, patents act 1949]

1985-03-20
PCNP
Patent ceased through non-payment of renewal fee

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