GB1041946A – Production of carbonyl compounds
– Google Patents
GB1041946A – Production of carbonyl compounds
– Google Patents
Production of carbonyl compounds
Info
Publication number
GB1041946A
GB1041946A
GB21212/65A
GB2121265A
GB1041946A
GB 1041946 A
GB1041946 A
GB 1041946A
GB 21212/65 A
GB21212/65 A
GB 21212/65A
GB 2121265 A
GB2121265 A
GB 2121265A
GB 1041946 A
GB1041946 A
GB 1041946A
Authority
GB
United Kingdom
Prior art keywords
hydroperoxide
atom
catalyst
cumene
carbonyl compounds
Prior art date
1964-05-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21212/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon International Inc
Original Assignee
Halcon International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-05-20
Filing date
1965-05-19
Publication date
1966-09-07
1965-05-19
Application filed by Halcon International Inc
filed
Critical
Halcon International Inc
1966-09-07
Publication of GB1041946A
publication
Critical
patent/GB1041946A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
Abstract
A process for producing carbonyl compounds comprises oxidizing an olefinic material with 2-20 C atoms, and at least one H atom attached to an unsaturated C atom, with an organic hydroperoxide, in the presence of a platinum group (i.e. Pd, Pt, Ru, Rh, Os or Ir) catalyst. The olefinic material may be straight chained or cyclic or aromatic, and may contain more than one double bond. It may also bear additional substituents, e.g. Cl. The products are generally ketones, exceptions being CH3CHO from CH2 = CH2, and aldehydes in general from dienes, e.g. butadiene yields crotonaldehyde. As organic hydroperoxides there may be used cumene hydroperoxide, t-butyl hydroperoxide, cyclohexyl hydroperoxide or a -phenethyl hydroperoxide. Preferred types are derived from an aralkyl hydrocarbon having at least one H atom on the C atom adjacent to the ring, e.g. cumene and ethylbenzene. Ketone and hydroxy hydroperoxides may also be used. The catalyst is preferably derived from Pd, and is most suitably a soluble salt thereof, e.g. chloride, nitrate or sulphate, used in an amount between 10-4-10-1 parts by weight per part of hydroperoxide. Reaction temperature is usually – 20 DEG – + 200 DEG C. at atmospheric pressure, but pressures up to 50 At. may be used. The reaction is preferably conducted in an acidic aqueous solution, but non-aqueous solvents may be present.
GB21212/65A
1964-05-20
1965-05-19
Production of carbonyl compounds
Expired
GB1041946A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US36901764A
1964-05-20
1964-05-20
Publications (1)
Publication Number
Publication Date
GB1041946A
true
GB1041946A
(en)
1966-09-07
Family
ID=23453709
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB21212/65A
Expired
GB1041946A
(en)
1964-05-20
1965-05-19
Production of carbonyl compounds
Country Status (6)
Country
Link
BE
(1)
BE664011A
(en)
DE
(1)
DE1518991A1
(en)
ES
(1)
ES313179A1
(en)
FR
(1)
FR1454420A
(en)
GB
(1)
GB1041946A
(en)
NL
(1)
NL6505941A
(en)
Cited By (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
EP0174194A2
(en)
*
1984-09-05
1986-03-12
The British Petroleum Company P.L.C.
Process for the oxidation of alkanes
EP0331590A1
(en)
*
1988-03-03
1989-09-06
Rhone-Poulenc Chimie
Process for the catalytic oxidation of alkanes and aralkyl hydrocarbons into a mixture of alcohols and ketones
Families Citing this family (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3940446A
(en)
*
1971-07-08
1976-02-24
Universal Oil Products Company
Dehydrogenation of alcohols
FR2446271A1
(en)
*
1979-01-11
1980-08-08
Inst Francais Du Petrole
Carbonyl cpds. prodn. – by liq. phase oxidn. of olefin(s) with hydrogen peroxide or organic hydroperoxide using palladium complex catalyst (BE 12.6.80)
CH643226A5
(en)
*
1978-12-18
1984-05-30
Inst Francais Du Petrole
PROCESS FOR THE MANUFACTURE OF CARBONYL COMPOUNDS BY OXIDATION OF OLEFINIC COMPOUNDS.
1965
1965-05-11
NL
NL6505941A
patent/NL6505941A/xx
unknown
1965-05-17
BE
BE664011D
patent/BE664011A/xx
unknown
1965-05-19
FR
FR17600A
patent/FR1454420A/en
not_active
Expired
1965-05-19
GB
GB21212/65A
patent/GB1041946A/en
not_active
Expired
1965-05-20
ES
ES0313179A
patent/ES313179A1/en
not_active
Expired
1965-05-20
DE
DE19651518991
patent/DE1518991A1/en
active
Pending
Cited By (6)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
EP0174194A2
(en)
*
1984-09-05
1986-03-12
The British Petroleum Company P.L.C.
Process for the oxidation of alkanes
EP0174194A3
(en)
*
1984-09-05
1987-05-20
The British Petroleum Company P.L.C.
Process for the oxidation of hydrocarbons
AU600431B2
(en)
*
1984-09-05
1990-08-16
British Petroleum Company Plc, The
Process for the oxidation of hydrocarbons
EP0331590A1
(en)
*
1988-03-03
1989-09-06
Rhone-Poulenc Chimie
Process for the catalytic oxidation of alkanes and aralkyl hydrocarbons into a mixture of alcohols and ketones
FR2628101A1
(en)
*
1988-03-03
1989-09-08
Rhone Poulenc Chimie
PROCESS FOR THE CATALYTIC OXIDATION OF ALKANES IN MIXTURES OF ALCOHOLS AND KETONES
US4918238A
(en)
*
1988-03-03
1990-04-17
Rhone-Poulenc Chimie
Catalytic oxidation of alkanes into alcohol/ketone mixtures
Also Published As
Publication number
Publication date
FR1454420A
(en)
1966-02-11
BE664011A
(en)
1965-11-17
NL6505941A
(en)
1965-11-22
ES313179A1
(en)
1965-07-16
DE1518991A1
(en)
1969-08-21
Similar Documents
Publication
Publication Date
Title
GB1023446A
(en)
1966-03-23
Production of epoxy-alcohols by the decomposition of hydroperoxides
GB1041946A
(en)
1966-09-07
Production of carbonyl compounds
GB670444A
(en)
1952-04-16
Manufacture of phenol
GB1426260A
(en)
1976-02-25
Process for the production of aldehydes from olefinic compounds
GB1112837A
(en)
1968-05-08
Process for the preparation of cycloalkanols and mixtures of cycloalkanols and cycloalkanones
ES338182A1
(en)
1968-04-01
Oxidation of olefinic compounds with solutions of thallium(iii) salts
GB1149392A
(en)
1969-04-23
Process for the catalytic epoxidation of olefinic compounds
Uemura et al.
1982
Rhodium (II) acetate: an effective homogeneous catalyst for selective allylic oxidation and carbon–carbon bond fission of olefins
GB941951A
(en)
1963-11-20
Improvements in and relating to the production of carbonyl compounds
GB903062A
(en)
1962-08-09
Dimeric p-isopropenylphenol, a process for its production and its use in the preparation of 1:3:3:trimethyl-1-p-hydroxyphenyl-indan-6-ol
Cymerman et al.
1945
24. Studies in the polyene series. Part XXI. Ethynylcarbinols from αβ-unsaturated ketones: their anionotropic rearrangements and other reactions
GB1123320A
(en)
1968-08-14
A process for the production of adamantane
Ishikawa
1964
The synthesis of β-ionylideneacetaldehyde
Ansell et al.
1958
602. Reduced cyclic compounds. Part IV. The intramolecular acylation of some olefinic acids
GB1245593A
(en)
1971-09-08
Formaldehyde production
GB1119728A
(en)
1968-07-10
Process for the manufacture of unsaturated nitriles
GB979295A
(en)
1965-01-01
The preparation of cyclic diketones
GB619014A
(en)
1949-03-02
A process for the production of unsaturated alcohols
GB1122034A
(en)
1968-07-31
Process for the preparation of azines
GB671412A
(en)
1952-05-07
Production of keto compounds
GB1037650A
(en)
1966-08-03
Improvements in and relating to the preparation of methylene-2 propanediol-1,3 and its derivatives
GB988619A
(en)
1965-04-07
Dehydrogenation process
US2347358A
(en)
1944-04-25
Hydroxylation of acetylenic compounds
GB1241103A
(en)
1971-07-28
Process for the alkylation of ketones
US3110744A
(en)
1963-11-12
Hydrocarbon conversion process
None