GB1044267A

GB1044267A – Polyureas
– Google Patents

GB1044267A – Polyureas
– Google Patents
Polyureas

Info

Publication number
GB1044267A

GB1044267A
GB5929/64A
GB592964A
GB1044267A
GB 1044267 A
GB1044267 A
GB 1044267A
GB 5929/64 A
GB5929/64 A
GB 5929/64A
GB 592964 A
GB592964 A
GB 592964A
GB 1044267 A
GB1044267 A
GB 1044267A
Authority
GB
United Kingdom
Prior art keywords
diisocyanate
reacted
polypropylene glycol
diamine
organic
Prior art date
1963-02-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB5929/64A
Inventor
Erwin Muller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer AG

Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1963-02-12
Filing date
1964-02-12
Publication date
1966-09-28

1964-02-12
Application filed by Bayer AG
filed
Critical
Bayer AG

1966-09-28
Publication of GB1044267A
publication
Critical
patent/GB1044267A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G18/00—Polymeric products of isocyanates or isothiocyanates

C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen

C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen

C08G18/30—Low-molecular-weight compounds

C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines

C08G18/3225—Polyamines

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G18/00—Polymeric products of isocyanates or isothiocyanates

C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen

C08G18/08—Processes

C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds

C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents

C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers

C08G18/0871—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic

C08G18/0876—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic the dispersing or dispersed phase being a polyol

Abstract

A stable dispersion of a polyurea in an organic liquid polyhydroxy compound is prepared by reacting an organic diisocyanate and a primary diamine, secondary diamine, hydrazine or a difunctional hydrazide wherein the number of NCO groups are substantially equivalent to the number of N atoms having bonded thereto hydrogen atoms which hydrogen atoms are more reactive with respect to the -NCO groups than the -OH groups of the liquid organic polyhydroxy compound which has at least two primary, secondary or tertiary -OH groups, a M.W. of at least 500 and an OH number of less than 225, in which compound the process is carried out. The organic diisocyanate may be aliphatic, cycloaliphatic, aromatic or heterocyclic. The polyhydroxy compound may be a polyester, polyalkylene ether, polythio ether, polyacetal or aliphatic polyol. In examples (1) tolylene diisocyanate and hexamethylene diisocyanate were reacted separately with hydrazine hydrate in polypropylene glycol ether; (2) tolylene diisocyanate was reacted with N-methyldipropylene triamine in polypropylene glycol ether; (3) tolyelene diisocyanate was reacted with tolylene 2,4 diamine in polypropylene glycol; (4) tolylene diisocyanate was reacted with ethylene diamine in polypropylene glycol. In all the examples the mixtures were heated with stirring for an hour and viscous stable emulsions were obtained.

GB5929/64A
1963-02-12
1964-02-12
Polyureas

Expired

GB1044267A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

DEF39001A

DE1260142B
(en)

1963-02-12
1963-02-12

Process for the production of polyaddition products

Publications (1)

Publication Number
Publication Date

GB1044267A
true

GB1044267A
(en)

1966-09-28

Family
ID=7097581
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB5929/64A
Expired

GB1044267A
(en)

1963-02-12
1964-02-12
Polyureas

Country Status (3)

Country
Link

US
(1)

US3325421A
(en)

DE
(1)

DE1260142B
(en)

GB
(1)

GB1044267A
(en)

Cited By (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US4092275A
(en)

*

1975-11-12
1978-05-30
Bayer Aktiengesellschaft
Polyurethane resins prepared from active hydrogen containing material which is a dispersion of polyisocyanate-polyaddition products in hydroxyl containing compounds as dispersing agents

US4093569A
(en)

*

1975-11-12
1978-06-06
Bayer Aktiengesellschaft
Polyurethane resins produced from active hydrogen containing material which is a dispersion of polyisocyanate-polyaddition products in hydroxyl containing compounds as dispersing agents

US4147680A
(en)

*

1975-11-12
1979-04-03
Bayer Aktiengesellschaft
Production of polyurethane resins using as active hydrogen material a stable dispersion of ionic polyisocyanate-polyaddition products in hydroxyl containing compounds as a dispersing agent

US4438252A
(en)

1981-08-08
1984-03-20
Imperial Chemical Industries Limited
Polymer-modified polyols

US4452923A
(en)

*

1981-10-28
1984-06-05
Imperial Chemical Industries Plc
Polymer-modified polyols

Families Citing this family (60)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3531238A
(en)

*

1966-03-23
1970-09-29
Bayer Ag
Process for the continuous dyeing or printing with basic dyestuffs of textile materials consisting of polyacrylonitrile

DE2221750A1
(en)

*

1972-05-04
1973-11-15
Bayer Ag

PROCESS FOR THE PRODUCTION OF POLYURETHANE UREA SOLUTIONS

US3993615A
(en)

*

1973-12-10
1976-11-23
W. R. Grace & Co.
Process and composition for breaking emulsions

CA1043948A
(en)

*

1974-05-17
1978-12-05
Manfred Dahm
Process for the production of polyurethane foams

US4089835A
(en)

*

1975-03-27
1978-05-16
Bayer Aktiengesellschaft
Stable polyurethane dispersions and process for production thereof

DE2627074C2
(en)

*

1976-06-16
1983-12-29
Bayer Ag, 5090 Leverkusen

Process for the preparation of stable ionic dispersions

DE2627073C2
(en)

*

1976-06-16
1983-12-29
Bayer Ag, 5090 Leverkusen

Process for the production of stable dispersions

CA1081385A
(en)

*

1975-11-12
1980-07-08
Bayer Aktiengesellschaft
Process for the preparation of stable dispersions

DE2632513C3
(en)

*

1976-07-20
1979-09-06
Bayer Ag, 5090 Leverkusen

Water-curable mixtures based on polyurethane which can be stored in the absence of water

DE2638759A1
(en)

*

1976-08-27
1978-03-09
Bayer Ag

SOLUTIONS OF POLYISOCYANATE POLYADDITION PRODUCTS

DE2913458A1
(en)

*

1979-04-04
1980-10-16
Bayer Ag

DISPERSIONS OF HIGH-MELTING POLYESTERS IN POLYHYDROXYL COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE IN THE PRODUCTION OF POLYURETHANE PLASTICS

US4296213A
(en)

*

1979-10-17
1981-10-20
Texaco Inc.
Polyurethane foams using a polyurea polymer polyol

US4293470A
(en)

*

1980-07-11
1981-10-06
Texaco Inc.
Stabilizing polyurea polymer polyols by treating with a secondary amine

US4425468A
(en)

1981-12-31
1984-01-10
Ppg Industries, Inc.
Polyurea-polyurethane acrylate polymer dispersions

DE3230757A1
(en)

*

1982-08-18
1984-02-23
Bayer Ag, 5090 Leverkusen

METHOD FOR THE PRODUCTION OF STABILIZED POLYISOCYANATES, STABILIZED POLYISOCYANATES OF RETARDED REACTIVITY AND THEIR USE FOR THE PRODUCTION OF POLYURETHANE

US4497913A
(en)

*

1983-05-31
1985-02-05
Olin Corporation
Process for preparing a stable dispersion of a polymer in a polyol and its use in the production of high resilience polyurethane foam

US4518778A
(en)

*

1983-07-14
1985-05-21
Texaco Inc.
Polymer polyols from alkylene oxide adducts of alkanolamines

US4477602A
(en)

*

1983-07-25
1984-10-16
Mobay Chemical Corporation
Novel system for the production of polyurethanes

US4581470A
(en)

*

1983-09-27
1986-04-08
Union Carbide Corporation
Novel polyols and uses thereof

US4727094A
(en)

*

1983-09-27
1988-02-23
Union Carbide Corporation
Method for producing polyurethanes

US4659772A
(en)

*

1983-09-27
1987-04-21
Union Carbide Corporation
Novel polymer/polyols and uses thereof

US4496678A
(en)

*

1984-05-21
1985-01-29
Mobay Chemical Corporation
Viscosity stabilized dispersions

US4539378A
(en)

*

1984-09-27
1985-09-03
Texaco Inc.
Vinyl polymer polyols made using epoxy resin-modified polyols

US4539339A
(en)

*

1984-09-27
1985-09-03
Texaco Inc.
Polyurethane foams made from vinyl polymer polyols

DE3500339A1
(en)

*

1985-01-08
1986-07-10
Bayer Ag, 5090 Leverkusen

STABLE DISPERSIONS OF POLYHANE SUBSTANCES AND / OR POLYHYDRAZIDICARBONAMIDES IN HIGHER MOLECULAR, HYDROXYL COMPOUNDS HAVING AT LEAST ONE HYDROXYL GROUP, A METHOD FOR THE PRODUCTION THEREOF AND THEIR PLANT

US4785127A
(en)

*

1985-08-05
1988-11-15
Arco Chemical Company
Vinyl polymer polyols made using partially alkoxylated polyoxyalkyleneamines

US4686240A
(en)

1985-10-25
1987-08-11
Union Carbide Corporation
Process for producing polyurethane foams using foam modifiers

NO176611C
(en)

1988-07-12
1995-05-03
Arco Chem Tech

Polymer polyol useful in the preparation of flexible polyurethane foams and its use

US4847320A
(en)

*

1988-07-28
1989-07-11
Mobay Corporation
Stable dispersions and the manufacture thereof

US4855352A
(en)

*

1988-07-28
1989-08-08
Mobay Corporation
Process for the production of stable dispersions, the dispersions so produced, and the use thereof in the manufacture of polyurethanes

US4906723A
(en)

*

1988-11-28
1990-03-06
Union Carbide Chemicals And Plastics Company Inc.
Aminopolyol stabilizers

US5342855A
(en)

*

1990-01-23
1994-08-30
Miles Inc.
Stable dispersions of polyhydrazodicarbonamides useful in the preparation of polyurethane products having improved load-bearing capacity

DE4024601C2
(en)

*

1990-08-02
1997-04-03
Gunter Prof Dr Bauer

Process for the preparation of polyol-containing dispersions and their use

US5373028A
(en)

*

1991-08-20
1994-12-13
The Dow Chemical Company
Polyurethane foams having reduced visible emissions during curing

HRP920243A2
(en)

1991-08-20
1996-06-30
Dow Chemical Co
Polyurethanes of improved physical properties

DE4216535A1
(en)

*

1991-08-21
1993-02-25
Bayer Ag

FORMKOERPER FOR CONTROLLING SHAEDLINGEN

US5332763A
(en)

*

1992-07-10
1994-07-26
Miles Inc.
Stable dispersions and their use in the preparation of polyurethane foams

US5312847A
(en)

*

1993-03-16
1994-05-17
The Dow Chemical Company
Polyurethane foam containing a particulate organic solid and a process for the preparation thereof

DE4431963A1
(en)

1994-09-08
1996-03-14
Bayer Ag

Process for the preparation of elastic moldings

GB9419562D0
(en)

1994-09-27
1994-11-16
Arco Chem Tech
High resilience polyurethane foam

WO1996021688A1
(en)

*

1995-01-13
1996-07-18
Essex Specialty Products, Inc.
Two-part moisture curable polyurethane adhesive

US5688861A
(en)

1995-11-30
1997-11-18
Arco Chemical Technology, L.P.
Process for the preparation of polyol polymer dispersions

AR005429A1
(en)

*

1996-01-11
1999-06-23
Essex Specialty Prod

POLYURETHANE PRE-POLYMERS, SINGLE-PACK ADHESIVE COMPOSITIONS INCLUDING SUCH PRE-POLYMERS AND PROCEDURE FOR ADHERING SUBSTRATES WITH SUCH COMPOSITIONS

US5922809A
(en)

*

1996-01-11
1999-07-13
The Dow Chemical Company
One-part moisture curable polyurethane adhesive

US5852103A
(en)

*

1996-05-08
1998-12-22
Essex Specialty Products, Inc.
Two-part moisture curable polyurethane adhesive

DE60124264T2
(en)

2000-08-07
2007-05-31
Dow Global Technologies, Inc., Midland

MOISTURE-HARDENABLE ONE-COMPONENT POLYURETHANE ADHESIVE

US6582771B1
(en)

2002-05-03
2003-06-24
Bayer Corporation
Method for producing a polyurethane/geofabric composite

WO2004094506A2
(en)

*

2003-04-23
2004-11-04
Stepan Company
Liquid hardness agent for open cell foams

US20050158131A1
(en)

*

2004-01-20
2005-07-21
Markusch Peter H.
Geotextile/polyurethane composites based on blocked isocyanate compositions

BRPI0516275A
(en)

*

2004-10-25
2008-09-02
Dow Global Technologies Inc

polyol polymer having a continuous phase of polyol and dispersed polymer particles, method for preparing a polyol polymer, dispersion of polymer particles in a continuous phase and polyurethane polymer

US20080269367A1
(en)

*

2005-10-18
2008-10-30
Neill Paul L
Prepolymer containing a Liquid Hardness Agent For Open Cell Foams

EP2172501A1
(en)

2008-09-24
2010-04-07
Recticel
Process for the preparation of flexible, resilient polyurethane foam and the resulting foam

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(en)

2009-12-08
2012-05-28
Recticel

Procedure for the preparation of flexible polyurethane foam and foam thus obtained

WO2012126934A1
(en)

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Bayer Materialscience Ag
Moulded parts consisting of reinforced polyurethane urea elastomers and use thereof

US10066047B2
(en)

*

2012-02-02
2018-09-04
Covestro Llc
Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams

US9683334B2
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Covestro Llc
Free-flowing coated rubber particles, methods for their production and use

US10119223B2
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Covestro Llc
Carpet and synthetic turf backings prepared from a polyether carbonate polyol

CN106117501A
(en)

*

2016-07-30
2016-11-16
淄博德信联邦化学工业有限公司
Fire-retardant polyurea polylol and preparation method thereof

EP3794065A1
(en)

2018-05-17
2021-03-24
Recticel
Improved method of recycling polyurethane materials

US20220325031A1
(en)

2019-08-08
2022-10-13
Recticel
Improved method of recycling polyurethane materials

Family Cites Families (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US2929803A
(en)

*

1955-01-31
1960-03-22
Du Pont
Elastic copolyureas from secondary diamines and process for making the same

US2929804A
(en)

*

1955-01-31
1960-03-22
Du Pont
Elastic filaments of linear segmented polymers

1963

1963-02-12
DE
DEF39001A
patent/DE1260142B/en
active
Pending

1964

1964-02-06
US
US343145A
patent/US3325421A/en
not_active
Expired – Lifetime

1964-02-12
GB
GB5929/64A
patent/GB1044267A/en
not_active
Expired

Cited By (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US4092275A
(en)

*

1975-11-12
1978-05-30
Bayer Aktiengesellschaft
Polyurethane resins prepared from active hydrogen containing material which is a dispersion of polyisocyanate-polyaddition products in hydroxyl containing compounds as dispersing agents

US4093569A
(en)

*

1975-11-12
1978-06-06
Bayer Aktiengesellschaft
Polyurethane resins produced from active hydrogen containing material which is a dispersion of polyisocyanate-polyaddition products in hydroxyl containing compounds as dispersing agents

US4147680A
(en)

*

1975-11-12
1979-04-03
Bayer Aktiengesellschaft
Production of polyurethane resins using as active hydrogen material a stable dispersion of ionic polyisocyanate-polyaddition products in hydroxyl containing compounds as a dispersing agent

US4438252A
(en)

1981-08-08
1984-03-20
Imperial Chemical Industries Limited
Polymer-modified polyols

US4452923A
(en)

*

1981-10-28
1984-06-05
Imperial Chemical Industries Plc
Polymer-modified polyols

Also Published As

Publication number
Publication date

US3325421A
(en)

1967-06-13

DE1260142B
(en)

1968-02-01

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