GB1064126A

GB1064126A – Acylamido sulphonates and sulphates, their manufacture and use
– Google Patents

GB1064126A – Acylamido sulphonates and sulphates, their manufacture and use
– Google Patents
Acylamido sulphonates and sulphates, their manufacture and use

Info

Publication number
GB1064126A

GB1064126A
GB32905/63A
GB3290563A
GB1064126A
GB 1064126 A
GB1064126 A
GB 1064126A
GB 32905/63 A
GB32905/63 A
GB 32905/63A
GB 3290563 A
GB3290563 A
GB 3290563A
GB 1064126 A
GB1064126 A
GB 1064126A
Authority
GB
United Kingdom
Prior art keywords
sulphonate
carbon atoms
sulphate
hydrogen
soap
Prior art date
1962-08-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB32905/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Monsanto Co

Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1962-08-21
Filing date
1963-08-20
Publication date
1967-04-05

1963-08-20
Application filed by Monsanto Co
filed
Critical
Monsanto Co

1967-04-05
Publication of GB1064126A
publication
Critical
patent/GB1064126A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES

C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent

C11D1/02—Anionic compounds

C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof

C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07D—HETEROCYCLIC COMPOUNDS

C07D291/00—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms

C07D291/02—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms not condensed with other rings

C07D291/06—Six-membered rings

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents

C09K23/22—Amides or hydrazides

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents

C09K23/32—Heterocyclic compounds

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations

C09K8/02—Well-drilling compositions

C09K8/03—Specific additives for general use in well-drilling compositions

C09K8/035—Organic additives

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION

C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants

C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives

C—CHEMISTRY; METALLURGY

C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES

C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

C11D10/00—Compositions of detergents, not provided for by one single preceding group

C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap

C—CHEMISTRY; METALLURGY

C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES

C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00

C11D3/16—Organic compounds

C11D3/34—Organic compounds containing sulfur

C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea

C—CHEMISTRY; METALLURGY

C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES

C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

C11D9/00—Compositions of detergents based essentially on soap

C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps

C11D9/22—Organic compounds, e.g. vitamins

C11D9/32—Organic compounds, e.g. vitamins containing sulfur

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION

C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions

C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides

C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts

C—CHEMISTRY; METALLURGY

C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT

C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

C10N2010/00—Metal present as such or in compounds

C10N2010/02—Groups 1 or 11

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC

Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of

Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents

Y10S516/03—Organic sulfoxy compound containing

Y10S516/05—Organic amine, amide, or n-base containing

Abstract

Compounds of the general formula wherein R and R1 are hydrogen or organic radicals containing 1 to 22 carbon atoms, R and R1 having a combined total of 8 to 24 carbon atoms and at most one of R and R1 being hydrogen; R11 is hydrogen or an aliphatic, cycloaliphatic or aromatic hydrocarbon or corresponding substituted hydrocarbon linked via carbon to the carbonyl group; A and B together constitute a single linkage or are separately hydrogen, halogen, or aliphatic radicals containing up to 5 carbon atoms or halogen-substituted aliphatic radicals containing up to 5 carbon atoms; and X is an alkali metal sulphate or sulphonate, alkaline earth metal sulphate or sulphonate, magnesium sulphate or sulphonate, ammonium sulphate or sulphonate, sulphonic acid or sulphuric acid radical are included in detergent or soap compositions as lime soap dispersants. Specified detergents are the alkali metal alkylaryl sulphonates and specified soaps are those intended to be utilized as personal or laundry bar soap or soap flakes or powder for laundering purposes. The sulphonate lime soap dispersant compounds may be formed in situ in a soap by including in the soap composition a 2-dioxy-1,2,5-oxathiazine of the general formula and subsequently hydrolysing said compound at 50 DEG C. or above and neutralizing with an appropriate base in situ.ALSO:The invention comprises compounds of the general Formula (I) wherein R and R1 are hydrogen or organic radicals containing from 1 to 22 carbon atoms, R and R1 having a combined total of 8 to 24 carbon atoms, and at most one of R and R1 being hydrogen; R11 is hydrogen or an aliphatic, cycloaliphatic or aromatic hydrocarbon or corresponding substituted hydrocarbon linked via carbon to the carbonyl grouping; A and B together constitute a single linkage or are separately hydrogen, halogen, or aliphatic radicals containing up to 5 carbon atoms or halogen-substituted aliphatic radicals containing up to 5 carbon atoms; and X is an alkali metal sulphate or sulphonate, alkaline earth metal sulphate or sulphonate, magnesium sulphate or sulphonate, ammonium sulphate or sulphonate, sulphonic acid or sulphuric acid radical. They may be prepared by (1) hydrolysing at 50 DEG C. or above a 2-dioxy-1,2,5-oxathiazine of the general formula to give a compound of Formula I above wherein X is a sulphonic acid radical and, optionally neutralizing the compound so formed to form the corresponding alkali metal, alkaline earth metal, magnesium or ammonium sulphonate salt; or (2) reacting a compound of the general formula or wherein M is an alkali metal, alkaline earth metal, magnesium or ammonium cation, with a carboxylic acid anhydride of the formula (R11CO)2O to produce the corresponding sulphonate or sulphate of Formula I. The 2-dioxy -1,2,5-oxathiazine reactants may be prepared as described in Specification 1,064,125. The vicinal amino sulphuric acid ester reactants may be prepared by sulphating an appropriate vicinal amino alcohol.

GB32905/63A
1962-08-21
1963-08-20
Acylamido sulphonates and sulphates, their manufacture and use

Expired

GB1064126A
(en)

Applications Claiming Priority (3)

Application Number
Priority Date
Filing Date
Title

US21843762A

1962-08-21
1962-08-21

US218438A

US3235549A
(en)

1962-08-21
1962-08-21
2-dioxy-1, 2, 5-oxathiazine compounds and processes for their manufacture

US457845A

US3325412A
(en)

1962-08-21
1965-05-21
Vicinal acylamido sulfonates as lime soap dispersants

Publications (1)

Publication Number
Publication Date

GB1064126A
true

GB1064126A
(en)

1967-04-05

Family
ID=27396545
Family Applications (2)

Application Number
Title
Priority Date
Filing Date

GB32905/63A
Expired

GB1064126A
(en)

1962-08-21
1963-08-20
Acylamido sulphonates and sulphates, their manufacture and use

GB32904/63A
Expired

GB1064125A
(en)

1962-08-21
1963-08-20
1,2,5-oxathiazine derivatives

Family Applications After (1)

Application Number
Title
Priority Date
Filing Date

GB32904/63A
Expired

GB1064125A
(en)

1962-08-21
1963-08-20
1,2,5-oxathiazine derivatives

Country Status (2)

Country
Link

US
(2)

US3235549A
(en)

GB
(2)

GB1064126A
(en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE1217393B
(en)

*

1963-05-08
1966-05-26
DEHYDAG Deutsche Hydrierwerke G.m.b.H., Düsseldorf

Process for the preparation of sulfobetaines

DE1218434B
(en)

*

1963-08-01
1966-06-08
Henkel & Cie Gmbh

Process for the preparation of mixtures of surface-active compounds

DE1468026A1
(en)

*

1964-03-12
1969-07-10
Henkel & Cie Gmbh

Process for the production of surface-active olefin sulfonates

CA780896A
(en)

*

1964-01-27
1968-03-19
California Research Corporation
Normal alkenyl sulfonic acids

DE1217367B
(en)

*

1964-04-08
1966-05-26
Farbwerke Hoechst Aktiengesellschaft vormals Meister Lucius & Brüning, Frankfurt/M

Process for the preparation of alkene sulfonates

US3487104A
(en)

*

1966-04-28
1969-12-30
Gulf Research Development Co
Process for preparing alkene sulfonates

US3506707A
(en)

*

1968-02-01
1970-04-14
Lubrizol Corp
Preparation of acrylamidoalkanesulfonic acids

US3544597A
(en)

*

1969-06-12
1970-12-01
Rohm & Haas
Process for manufacturing sulfonated amides

US4034001A
(en)

*

1972-01-07
1977-07-05
The Lubrizol Corporation
Bis-amidoalkanesulfonic acids and salts thereof

US3998796A
(en)

*

1972-09-22
1976-12-21
The Lubrizol Corporation
Nitrogen and sulfur-containing amphoteric compounds and polymers thereof

US3960918A
(en)

*

1973-06-26
1976-06-01
The Lubrizol Corporation
Preparation of esters of amidoalkanesulfonic acids

US3978094A
(en)

*

1973-07-31
1976-08-31
Ciba-Geigy Ag
Process for the manufacture of 1,4-diamin O-5-nitroanthraquinone

US3978095A
(en)

*

1973-07-31
1976-08-31
Ciba-Geigy Ag
Process for the manufacture of 1,4-diamino-5-nitroanthraquinone

NL171267C
(en)

*

1975-12-19

Ciba Geigy

PROCESS FOR PREPARING FLUORINATED SULPHONIC ACIDS AND THEIR SALTS, AND PROCEDURE FOR PREPARING COMPOSITIONS CONTAINING THESE COMPOUNDS.

US4000188A
(en)

*

1975-12-19
1976-12-28
Ciba-Geigy Corporation
Alkylthioamido sulfonic acids and derivatives thereof

LU84800A1
(en)

*

1983-05-11
1985-03-21
Oreal

COSMETIC COMPOSITION FOR THE TREATMENT OF HAIR AND SKIN, CONTAINING OXATHIAZINONES

US10295163B1
(en)

2017-03-20
2019-05-21
Brandon Cohen
Lighting assembly with junction box support

Family Cites Families (15)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US2367010A
(en)

*

1945-01-09

Amides and sulphonated derivatives

US1932180A
(en)

*

1929-04-12
1933-10-24
Ig Farbenindustrie Ag
Sulphuric acid derivatives of amides

DE550572C
(en)

*

1930-05-17
1932-05-12
Ig Farbenindustrie Ag

Process for the production of ethionic acid or carbyl sulfate and their homologues

NL50165C
(en)

*

1937-11-20

US2216617A
(en)

*

1938-08-31
1940-10-01
Katz Jacob
Surface active anionic compounds of amino alcohols

GB717903A
(en)

*

1950-05-08
1954-11-03
Wolfgang Benjamin Reinisch
Improvements in the manufacture of synthetic detergents

US2727036A
(en)

*

1951-08-25
1955-12-13
Exxon Research Engineering Co
Hydrocarbon oil additive

US2821536A
(en)

*

1953-02-16
1958-01-28
Ruhrchemie Ag
Production of wetting, emulsifying and washing agent

NL95122C
(en)

*

1954-11-22

US2810746A
(en)

*

1955-04-08
1957-10-22
Tennessee Corp
Sulfonation of propylene trimer and tetramer

US3067143A
(en)

*

1958-02-24
1962-12-04
Dow Chemical Co
Composition and method for washing textiles

US3038932A
(en)

*

1958-07-02
1962-06-12
American Cyanamid Co
Preparation of ortho-aminobenzenesulfonic acids

US3076766A
(en)

*

1959-08-12
1963-02-05
Colgate Palmolive Co
Detergent bar

US3143552A
(en)

*

1961-10-27
1964-08-04
Pure Oil Co
Reaction products of nitriles and sulfur trioxide

US3187026A
(en)

*

1961-12-07
1965-06-01
Pure Oil Co
Preparation of acylamido-substituted esters of sulfuric acid

1962

1962-08-21
US
US218438A
patent/US3235549A/en
not_active
Expired – Lifetime

1963

1963-08-20
GB
GB32905/63A
patent/GB1064126A/en
not_active
Expired

1963-08-20
GB
GB32904/63A
patent/GB1064125A/en
not_active
Expired

1965

1965-05-21
US
US457845A
patent/US3325412A/en
not_active
Expired – Lifetime

Also Published As

Publication number
Publication date

GB1064125A
(en)

1967-04-05

US3325412A
(en)

1967-06-13

US3235549A
(en)

1966-02-15

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