GB1065439A

GB1065439A – Cobalt and chromium 2:1 dye metal complexes
– Google Patents

GB1065439A – Cobalt and chromium 2:1 dye metal complexes
– Google Patents
Cobalt and chromium 2:1 dye metal complexes

Info

Publication number
GB1065439A

GB1065439A
GB3773065A
GB3773065A
GB1065439A
GB 1065439 A
GB1065439 A
GB 1065439A
GB 3773065 A
GB3773065 A
GB 3773065A
GB 3773065 A
GB3773065 A
GB 3773065A
GB 1065439 A
GB1065439 A
GB 1065439A
Authority
GB
United Kingdom
Prior art keywords
formula
group
radicals
dyestuff
dyes
Prior art date
1964-09-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB3773065A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer AG

Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-09-11
Filing date
1965-09-03
Publication date
1967-04-12

1965-09-03
Application filed by Bayer AG
filed
Critical
Bayer AG

1967-04-12
Publication of GB1065439A
publication
Critical
patent/GB1065439A/en

Status
Expired
legal-status
Critical
Current

Links

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Classifications

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES

C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves

C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring

C09B62/465—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an acryloyl group, a quaternised or non-quaternised aminoalkyl carbonyl group or a (—N)n—CO—A—O—X or (—N)n—CO—A—Hal group, wherein A is an alkylene or alkylidene group, X is hydrogen or an acyl radical of an organic or inorganic acid, Hal is a halogen atom, and n is 0 or 1

C09B62/47—Azo dyes

C09B62/477—Metal complex azo dyes

Abstract

The invention provides 2:1 metal complex dyes free from sulphonic and carboxylic acid groups which dyes have the formula in which A denotes substituted or unsubstituted identical or different phenyl or naphthyl radicals, B denotes the radicals of identical or different coupling components, X is the radical -O- and/or -COO-, Y denotes identical or different radicals -O-, -NH-, -N- aryl, -N- aroyl or -N- aryl-sulphonyl of which the aryl radicals may be substituted, the radicals X and Y in A and B are in ortho positions to the azo group, m is 1-4, Me is chromium or cobalt and K is a cation, R1 is hydrogen or an alkyl or aryl group, R2 is a saturated or unsaturated haloalkyl group, a vinyl group or a a -halovinyl, di- or trihalovinyl, a – or b -alkyl-vinyl radical or a substituted or unsubstituted a -hydroxy-methylene or -b -hydroxyethylene radical which is esterified with an aliphatic or aromatic sulphonic acid and in which the fibre reactive group may be attached by a direct link or a bridging group to radicals A or B of the complex. The dyes are obtained by metallizing with a cobalt or chromium yielding agent a dyestuff or mixture of dyestuffs having the Formula II in which A, B, Y, R1 and R2 are as above and Q is -OH, -COOH or -O-alkyl group and m1 is 1 or 2, alternatively a dyestuff of Formula II may be metallized in mixture with a second dyestuff of Formula IIa Metallization is preferably effected in a neutral or alkaline medium. The dyes may also be prepared by reacting a 1:1 dye metal complex (the dye is of Formula II or IIa) with another metallizable azo dye of Formula II or if the 1:1 complex already contains a group with a metallizable dyestuff of Formula IIa. A further method comprises reacting a complex of formula in which the symbols are as above with a methylol compound of formula HO-CH2-NR1-CO-R2 in the presence of an acidic condensing agent the starting materials being free from sulphuric and carboxylic acid groups.

GB3773065A
1964-09-11
1965-09-03
Cobalt and chromium 2:1 dye metal complexes

Expired

GB1065439A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

DEF43959A

DE1259483B
(en)

1964-09-11
1964-09-11

Process for the production of metal-containing azo dyes

Publications (1)

Publication Number
Publication Date

GB1065439A
true

GB1065439A
(en)

1967-04-12

Family
ID=7099806
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB3773065A
Expired

GB1065439A
(en)

1964-09-11
1965-09-03
Cobalt and chromium 2:1 dye metal complexes

Country Status (5)

Country
Link

BE
(1)

BE669432A
(en)

CH
(1)

CH484255A
(en)

DE
(1)

DE1259483B
(en)

GB
(1)

GB1065439A
(en)

NL
(1)

NL6511832A
(en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

BE579968A
(en)

*

1958-06-23
1959-10-16
Ici Ltd

New azo compounds

1964

1964-09-11
DE
DEF43959A
patent/DE1259483B/en
active
Pending

1965

1965-08-16
CH
CH1144865A
patent/CH484255A/en
not_active
IP Right Cessation

1965-09-03
GB
GB3773065A
patent/GB1065439A/en
not_active
Expired

1965-09-10
BE
BE669432D
patent/BE669432A/xx
unknown

1965-09-10
NL
NL6511832A
patent/NL6511832A/xx
unknown

Also Published As

Publication number
Publication date

BE669432A
(en)

1965-12-31

DE1259483B
(en)

1968-01-25

CH484255A
(en)

1970-01-15

NL6511832A
(en)

1966-03-14

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